Physical Chemistry I, (10802) | Homework Three |

FOCUS 7 Quantum theory 7F

Hand your homework paper to 物化一 T.A. 沈伯叡 (CH231)
Due: May 15 (FRI.), by 17:00 pm

1. The molecules 16O12C32S with atomic masses in amu are as follows: 16O:15.9949; 12C:12;
32
S:31.9721. Calculate the moment of inertia I if the bond lengths of 16O12C32S molecules
are = = . and = =

2. The 1H35Cl molecule with a bond length of 91.68 pm, rotates on a surface in two dimensions.
What is the smallest energy that can be absorbed by this molecule in a rotational excitation?
m(1H) = 1.0078 amu, and m(35Cl) = 34.9688 amu.

3. The rotational energy of 7Li2 in the J = 5 state is 4.0126 ×10-22 J. Calculate the bond length of
the molecule. m(7Li) = 7.016 amu