179.

A lady sues a man for support of her child she has blood group B, her child is of blood group O
and that of man is B. Could the man be the father?
(a) Yes, but chances are 1/4% (b) Yes, but chances are 1/8%
(c) Yes, but chances are 1/16% (d) Yes, but chances are 1/2%

Chemistry:
Answer Key:
1. c 2. a 3. b 4. b 5. b 6. a 7. b 8. d 9. c 10. a
11. a 12. a 13. a 14. b 15. d 16. c 17. c 18. d 19. c 20. b
21. c 22. b 23. b 24. c 25. c 26. d 27. c 28. a 29. b 30. c
31. d 32. c 33. c 34. a 35. c 36. d 37. d 38. d 39. d 40. a
41. d 42. a 43. a 44. a 45. a

Physics:
Answer Key:
46. c 47. c 48. d 49. b 50. b 51. b 52. d 53. d 54. a 55. b
56. a 57. d 58. d 59. d 60. d 61. d 62. b 63. c 64. c 65. a
66. c 67. a 68. c 69. d 70. b 71. d 72. b 73. d 74. a 75. a
76. b 77. d 78. b 79. c 80. d 81. a 82. a 83. d 84. a 85. b
86. a 87. a 88. a 89. c 90. b

Biology:
Answer Key:
91. d 92. b 93. a 94. d 95. c 96. c 97. c 98. a 99. b 100. d
101. b 102. c 103. d 104. b 105. c 106. c 107. d 108. d 109. a 110. c
111. a 112. c 113. d 114. a 115. a 116. b 117. d 118. d 119. a 120. c
121. c 122. d 123. b 124. a 125. d 126. b 127. b 128. b 129. b 130. d
131. d 132. b 133. b 134. d 135. c 136. d 137. d 138. c 139. b 140. d
141. d 142. c 143. a 144. b 145. d 146. a 147. c 148. b 149. b 150. c
151. c 152. b 153. a 154. b 155. d 156. b 157. a 158. c 159. c 160. b
161. d 162. b 163. a 164. b 165. b 166. b 167. a 168. a 169. b 170. b
171. c 172. b 173. a 174. b 175. a 176. a 177. b 178. b 179. b 180. a

www.vedantu.com 21
 Chemistry
Solutions:
1. After removal of 2nd electron from 2P , fluorine will get half-filled configuration but for oxygen
half-filled configuration has to be disturbed.
P1 P2
2. =
T1 T2

100 100.4
=
T1 T1 + 1

100T1 +100 = 100.4T1

T1 (100.4 −100) = 100

0.4T1 = 100

1000
T1 = = 250 K
4
3. SO2 is a bent molecule has net dipole moment

4. → 2 AgCl + Ca ( NO3 )2
CaCl2 + 2 AgNO3 ⎯⎯

4.31
moles of AgCl =
143.5
4.31 1
 mole of CaCl2 =  = 0.015
143.5 2

5. E1 = −2.18 10−18 J atom−1

2.18 10−18
E4 = − = −0.136 10−18 J atom−1
16

Energy released = ( 2.18 − 0.136)10

−18
J atom−1

= 2.04 10−18 J atom−1

Now E = hv

E
v=
h

2.04 10−18
= = 3.08 1015 S −1
6.625 10−34
6. Other oxides are not inert on heating

Cu is Cu ( I ) in Cu ( CN )2 and has 3d10 configuration, All others have Cu ( II ) and 3d 9 configuration.

−
7.

8. H2 SO4 + SO3 → H2 S2O7 (Oleum)

9. Na2 S2O3 + Cl2 + H2O ⎯⎯

→ Na2 SO4 + 2HCl + S

10. B (OH )3 + H2O → B (OH )4 + H +

−

H2 + I2 2HI
11.
(g) (g) (g)

t=0 1 1 0

teq 1 − 0.8 1 − 0.8 2  0.8

V V V
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 2
 1.6 
 
KC =   = 64
V
0.2 0.2

V V
12.  = CRT

We know that 1 = C1 RT1 and  2 = C2 RT2 (T1 = T2 )

n
C= (no. of moles per litre)
V
V = 1lit

1 2
 =
C1 C2

2 1.52  36
C2 = C1 = = 0.061M
1 4.98 180

V2
13. W = −2.303 nRT log
V1

20
W = −2.303  2  8.314  298log = −2.303 2  8.314  298 0.3
10
W = −3435J
14. −Go = nFE o
= 2  96500 1.1
= 212.3KJ

Go = −212.3KJ mol −1

Go = H o − T S o
H o − Go
S o =
T
−216.7 − ( −212.3)
=
298
= −0.01476 KJ K −1mol −1

−14.76 JK −1 mol −1

15. Na2 SO4 .nH2O

molar mass = (142 + 18n )

12.6
mass of water =  (142 + 18n )
26.8
12.6
18n =  (142 + 18n )
26.8
n=7

16. Radioactive change is 92 U 238 ⎯⎯

→82 Pb206

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 Decrease in mass = ( 238 − 206) = 32

Let the number of  − particles emitted be x

4x = 32
x =8
2.303 100
17. K = log
20 100 − 20
2.303 100
= log
20 80
2.303
= ( log5 − log 4)
20
2.303 2.303
= ( 0.6989 − 0.602) = ( 0.097)
20 20
1 0.693  20
t = = 62.13min
2 2.303  0.097
MV 0.1 40
18. Number of moles of HCl = = = 0.004
1000 1000
MV 0.45 10
Number of moles of NaOH = = = 0.0045
1000 1000
Remaining moles of NaOH after neutralization = 0.0005
0.0005
Molarity of OH − = 1000 = 0.01M
50

 POH = 2 PH = 12
19. 10 −  − Hydrogen atoms are present
20. 1  2  3 is stability order of Carbon ions

21. H2O2 → O2 + 2H + + 2e−

1 mole H2O2 = 2 moles c

= 2  96500C = 193000C = 1.93 105 C

22. Compound has one chiral centre and one double bond. Hence, Stereo isomers are four.
23. Carbylamine test is given by 1o amines only
Whereas 2o amines reacts as follows

24. CHO CHO

(CHOH) 4 Ac2O
(CHOAc) 4

CH2OH CH2OAc
glucose penta acetate
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25. Br Br Br D D

COCH3 C(OCH3)2CH3 C(OCH3)2CH3 COCH3

[A] [B] [C] [D] [E]

26. Cl OH
O2 N NO 2 O2 N NO 2

+H2O warm

NO 2 NO 2

27. CH3OCH3 ,CH3OCH2CH3 ,C2 H5OC2 H5

28. Oxidation number of Cr in the given compound is +6 for Fe is 0 in Fe (CO)5 and Fe is in +2 in

ferrocyanide complex, Mn in the given compound is +3.

29. Due to two lone pairs of oxygen atom and 2 hydrogen atoms.
30. D2O has lower dielectric constant (78.06) than H2O (78.39) thus solubility of salts is less in D2O

than in H2O .

31. Lithium forms monoxide only.

32. +1 + x = 0; x = −1

33. B3N3H6

34. Graphite has a layered structure in which each carbon atom is bonded to three other carbon atoms
through sigma bonds by means of sp 2 hybrid orbitals.

35. Parent chain should be numbered from the end nearer to OH group.
36. Longest chain is one containing the multiple bond.
37. The reaction represents Wurtz reaction which follows free radical path. 2 moles of Bromoethane
give butane. 2 moles of 2-Bromopropane give 2, 3 – dimethyl butane. 1 mole Bromoethane & 1
mole 2 – Bromopropane give 2 – methylbutane.
38. Molecular formula is C4 H8 . The degree of unsaturation = 1.

Hydrocarbons with molecular formula C4 H8 represent alkenes and cycloalkanes.

a
b c d e f

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 Number of possible isomers with molecular formula C4 H8 = 6 .

39. O2 → O + O; O2 + (O) O3

40. Number of corner atoms = (1/ 8)  8 = 1atom of A

Number of face cantered atoms = (1/ 6)  6 = 3 atoms of B

Thus, the formula of the compound = AB3

41. MW of NaCl = 58.5, 1g contains = (1/58.5) 6.0231023 NaCl molecules = 11022

But 4 NaCl molecules form one unit cell. Number of unit cells in 1g = 1/ 4 1022 = 2.5 1021
Tf 0.73
42. Tf = K f .m  K f = = = 5.087Kmolal −1
m 0.1435
100.Kb .W2 1000  0.5118
43. Molecular mass of solute = = = 180
W1.T 150  0.34

44. Zn prevents rusting of Iron in galvanisation.

45. One coulomb of electricity will deposit the mass called electrochemical equivalent.

Physics
Solutions:

46. k =
(
U x2 + a2 ) = Joule − m2 = Joule − metre
x m
 dx   dy 
47. V =   iˆ +   ˆj
 dt   dt 

V = 2ct iˆ + 2btjˆ

48. The apparent weight of a person in a moving lift is given is by W = m ( g − a ) = 0

49. M1V1 + M 2V2 = D (LCM )

 M1V1 = −M2V2 (LCM )

−GM1M 2 1 1
 + M1V12 = M 2V12 = D ( LCE)
d 2 2

P12 P2 GM1M 2
+ 1 =
2M1 2M 2 d

2G ( M1M 2 )
2
P1 = P2 =
d ( M1 + M 2 )

VRV = V1 − V2

= V1 + V2

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 1  2G ( M1M 2 )
2
 1
= + 
 M1 M 2  d ( M1 + M 2 )
50. P = hpg

P = (l cos ) pg

h
 h = r cos   r =
cos 
51. As the thickness is less, elongation is more.
Fl
l =
Ay

52. W = T  4 r 2
1
Here r1 = 2 3 r
2 1
W 1  r1 
=   = 23
W  r 

1
W 1 = ( 4) 3 W

4  
53. 6 yRVt =  R2 Pg 1 − 
3  P

2 ( P − ) 2
 Vt = gR
9 4

 Vt  R2

54. W =  AT 4
4
 T1 
W =W  
1
T 
 
4
1 W
= W .  =
3 81

W T1 − T2
55. =
Q T1

800 300
=
Q 600
Q = 1600 J

56. mgh = 4200J / cos ( mst )

gh 9.8  84
t = =
5  4200 1 4200
= 0.196C

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57. n1 = n + 0 ( 4)

n10 = n + 9 ( 4)

n10 = 2n1

−v v
58. m = ( or )
u u
v = −3u ( or ) v = 3u

1 1 1
+ =
v u f

 u = 32cm ( or ) 16cm

1
59. = for refracted ray through the prism A = 2c
sin c

1 A
 = = 1 + cos2
 A 2
sin  
2
w1 w2
60. + =0
f1 f 2

−w2 f1
f2 =
w1

f2 = −2 f

61. R11 + R21 = R1 + R2

R1 (1+  t ) + R2 (1 − t ) = R1 + R2

R1  t = R2 t

R1 
=
R2 

62. P1 = 100W , V1 = 200V

P2 = 200W , V2 = 100V

V 2 200  200
R1 = 1 = = 400
P1 100

V 2 100 100
R1 = 2 = = 50
P2 200

P1 = i12 R1

P2 = i22 R2
2
 i  P  R 1
  1  =  1  2 =
 R2   P2  R1 16

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 (3 + R ) 10
63. R = 3+
13 + R

13R + R2 = 39 + 3R + 30 + 10R

R = 69
64.  = i1 ( R1 + r ) = 0

 − i2 ( R2 + r ) = 0

V  V 
 i1  1 + r  = i2  2 + r 
 i1   i2 

 0.9   1 
 0.3  + r  = 0.25  +r
 0.3   0.25 
r = 2

mV 2mE
65. r = =
Bq Bq

m
r
q

rP mP q
= 
r m qP

1 2 1
=  =
4 1 1
1
66. w = = constant
LC
L2C2 = 49

49 C 1
L2 = = L =
C2 4c 4

E0
67. i =
Rv + ( X L − X C )
2

E 100
i= 0 = = 2A
R 50
V = iR = 100V
68. b8 = + KEMax
12400
KEmax = = −2
4000
= 3.1− 2 = 1.1ev
 1 1
69. = . Further,   , r  n2 ;     3 
r n n 
16 1
70. Number of half-lives, n = = 4, m = m0 n .
4 2

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 m = 0.625g .

71. Keff = K + 2K = 3K

m
T = 2
3K

RT =  I 2 Rdt +  I 2 Rdt
T 2 T
72. Let us find the rms value of rectified current, I rms
2
0 T 2

Since only half wave is rectified,

  I 2 Rdt = 0
T

T 2

RT = 
T 2
 I rms
2
I 2 Rdt
0

RT = 
T 2
or I rms
2
I 02 sin2 t Rdt
0

I 02 R T I
or I rms
2
RT =  or I rms = 0
2 2 2
E0 200
Similarly, Erms = = V = 100V
2 2
mg
73. For A T = = 2 ma
2
For B mg − 2T = ma

Solving a = 0

 
 

74. The angular acceleration of the body  =  
g sin
  K2  
 R 1 + 2  
  R 

Radius of gyration of solid sphere is less compare to remaining objects given, therefore angular

acceleration is maximum for solid sphere.

9 D
75. Y9 = Position of 9th bright fringe =
d

 1  D 3 D
Y2 = Position of 2nd dark fringe =  2 −  =
 2 d 2 d

Y9 − Y2 = 7.5mm

 = 5000 A0
76. Ph = e

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 h h
=
PPh Pe

EPh 2Ee
=
C V
EPh 2C
=
Ee V

1  1 1 
77. = Z 2R 2 − 2 
  n1 n2 
1 1 1
For K line = Z 2R 2 − 2 
 1 2 

1 1 1
For K  line = Z 2R 2 − 2 
 1 3 

 27
=
 32

27 27
 =  =  0.32 = 0.27 A0
32 32

P T 5 36
78. n = = = 5  2 = 10Hz
2l m 2 1.5 1
1.5
m= = 1kgm−1
1.5
m → linear density

1 q
79. The change on sphere A and B are V =
4 0 r

 qA = ( 4 0 R )V

 R
qB =  4 0 V
 5
When they are connected by conducting wire, the entire charge will
6R
flow to outer sphere, so that their potentials become equal. Thus q = qA + qB = ( 4 0 ) V
5

( 4 0 ) 
6RV 

Final potential of A now V =
1 q
1
=  5  = 6V = 600 = 120V
4 0 r 4 0 R 5 5

GMm
80. mR 2 =
R2
GM = R3 2
r 3 2
g=
R2

( 4nR)  2
3

g1 =
n2 R 2

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 g1 = 64nR 2

 76.3 
81. r = 9.5  − 1  1.7
 64.8 
82. High initial permeability

83. f = 24 106 Hz R = 0.6m

mV
B= V =  R = 2 fR
qR

84. i = 5 A

qm2 q2 1 2
= + Li  qmax = 6c
2c 2c 2

V 
l Ml 2  l 
85. mV = I  =  
2 3 2
 
 
M 3
 =
m 4

86. 4 = K ( a − l0 ) …. (1)

5 = K (b − l0 ) …. (2)

9 = K (l − l0 ) …. (3)

Solving l = 5b − 4a

d dq dq
87. id =  0 = 0 = =i
dt dt 0 dt

88. Q = m 11
 6 ( ) ( )
C − m 11  c2 (Note m has been doubled)
6 B − 2me 
 e

Using given masses, Q = 0.961MeV .

Q = Ed + Ee + Ev

The daughter nucleus is too heavy compared to e + and v. so it carries negligible energy ( Ed  0) .

If the kinetic energy ( Ev ) carried by the neutrino is minimum (i.e., zero), the position carries

maximum energy, and this is practically all energy Q; hence maximum ( Ee  q).

89. When S is closed t1 = RC

3RC t1 2
When S is opened t2 =  =
2 t2 3

90. For objective u = 200 cm f0 = +50 cm

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1 1 1 200
− =  V0 = cm
V0 u f 3

For eye lens Ve = −25 cm fe = +5 cm

1 1 1 25
− =  Ve = − cm
−25 ue 5 6
200 25 425
L = V0 + Ve = + = = 70.80 cm
3 6 6

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