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Effect of Calcium Addition at High Temperature On Fly Ash's Activation Character
Effect of Calcium Addition at High Temperature On Fly Ash's Activation Character
⌏ᗻ⡍ᕕߚᵤЏ㽕⍝ঞ K a ⊩⦃๗ঞ∈⊹⦃⌚ޔ๗DŽ
⊩⦃๗ঞ݊䅵ㅫԧখ✻ࠡᳳⷨお[1,4]ˈᑊ䖯㸠ᠿᦣ⬉ᄤ
ᰒ ᖂ 䬰 ˄ SEM ˅ ߚ ᵤ DŽ ᦎ ㉝ ✸ ♄ ∈ ⊹ ⦃ ⌚ ޔ๗ 䆒 䅵
(FA/CFA3-2)䞛⫼ 0.40 ∈♄↨ǃ㉝✸♄ᦎ䞣↨՟Ў 45%DŽ
៤ൟ䆩ӊሎᇌЎ 40mm×40mm×40mm ゟᮍԧˈ䆩ӊ៤ൟ
1d ৢᢚˈ㕂Ѣ‵㛊༫Ёᆚᇕ˄䱨㒱∈ߚ˅ݏᡸˈࠄ㾘ᅮ
Fig.1 Activation distribution of materials in CaO-SiO2-Al2O3 system
29
CFA-4 Ka
A. Si/27Al NMR ߚᵤ
80 LCFA1 Al/Si 80
2 3 㒣催⏽䩭ৢ㉝✸♄ⱘ 29Si/27Al NMR 䈅DŽ
⌏ ᗻ A l2O 3/S iO 2
CFA-4 Al/Si
⬅ 2 ৃ㾕ˈLCFA1 ⱘ⸙⇻ಯ䴶ԧᄬ Q1ǃQ2ǃQ3 ঞ Q4
K aؐ /%
⾡㘮ড়ᗕˈ݊Ё Q3 Ϣ Q4 ⱘዄؐ䕗ᆑϨᯢᰒˈ䇈ᯢॳ⢊
60 60
㉝✸♄ⱘ⸙⇻ಯ䴶ԧ㘮ড়ᑺ䕗催DŽCFA-4-1200ćⱘᴀ䲚
ЁЎ Q1 ⱘ⡍ᕕዄˈϨዄᔶবじѺᔎˈ⸙⇻ಯ䴶ԧ㘮ড়
ᑺᯢᰒ䰡ԢDŽ⬅ 3 ৃ㾕ˈॳ⢊㉝✸♄ⱘ䪱⇻䴶ԧ㒧ᵘ
40 40
ҹ 6 䜡ԡ˄࣪ᄺԡ⿏ į 㑺Ў-20 ppm˅ 4 䜡ԡ˄࣪ᄺԡ⿏
į 㑺Ў 30~40 ppm˅ᮍᓣᄬDŽ㗠 CFA-4-1200ć࣪ᄺԡ
⿏ į-20 ppm 䰘䖥ⱘዄؐᴀ⍜༅ˈ㗠࣪ᄺԡ⿏ į30~40
20 20
ppm ໘ⱘዄؐᯢᰒࡴᔎ [5] DŽ䖯ϔℹॄ䆕ⳌᇍѢॳ⢊㉝✸
♄ˈ㒣䖛催⏽䩭ᬍᗻৢⱘ㉝✸♄݊ᔎዄ㒓ԡ⿏ᳱℷؐᮍ 1d 3d 7d 14d
⿏ࡼˈਜ⦄ߎ⬅催എⱘ䲚ЁԢഎⱘߚᬷ䍟ˈѺ䇈ᯢ ডᑨᯊ䯈
݊㔥㒰㒧ᵘ㘮ড়ᑺ䰡ԢDŽ
Fig.4 Ka value and Al2O3/SiO2 ratio of fly ash
䗮䖛ᇍᬍᗻ CFA-4-1200ćⱘᤃ㤵㉝⺼໘⧚ˈ݊↨㸼䴶
Q3 4
LCFA1 Q2 Q ⿃ࠊЎ 375m2/Kg ᎺেDŽ 4 Ў㉝✸♄ⱘ啘ᳳ⌏ᗻ
Q1 Al2O3/SiO2 ↨ؐঞ ؐDŽ⬅ 4 ৃ㾕ˈ㒣 CFA-4-1200ć
啘ᳳⱘ ؐഛ催Ѣॳ⢊ LCFA1 ⱘˈᑊϨⳌᇍѢ LCFA1ˈ݊
ᮽᳳⱘ ؐᦤ催ᐙᑺˈ1d ⱘᦤ催њ 97.94%ˈ3d ⱘᦤ催
њ 82.63%ˈ䇈ᯢ䗮䖛催⏽䩭ᬍᗻৢˈCFA-4-1200ćⱘ
ᮽᳳ⌏ᗻᏆᕫࠄ᳝ᬜ▔থDŽ䗮䖛݊啘ᳳⱘ⌏ᗻ
Al2O3/SiO2 ↨ ؐ ↨ 䕗 ߚ ᵤ ৃ ⶹ ˈ CFA-4-1200ć ⱘ
Q1 Al2O3/SiO2 ↨ؐ䕗Ў〇ᅮˈᴀᕬᕞѢ 66.3%ᎺেˈⳌᇍ
CFA-4-1200ć
Ѣ LCFA1 ⱘ Al2O3/SiO2 ᑇഛ↨ؐ˄㑺 31.6%˅催ߎϔס
ˈ䇈ᯢ催⏽䩭ⱘ䖛ϡҙᇍ㉝✸♄ⱘ Si-O 䬂᳝⸈
ണˈᇍ Al-O 䬂ⱘ⸈ണѺࡴᯢᰒDŽ
CFA-4-0d CFA-4-7d
29
Fig.2 Si NMR spectra of modification fly ash
CFA-4--1d CFA-4-14d
CFA-4-1200ć
LCFA1
5897
ᯢᰒϡৠDŽॳ⢊㉝✸♄ⱘডᑨ䖛ᯢᰒ㓧᜶ˈᄬ㾷㘮㛑 ᦎᬍᗻ㉝✸♄ⱘ CFA3-2 ডᑨᑺ啘ᳳ˄ᇸ݊
䞣ⱘ㌃⿃䖛ˈ䖒ࠄϔᅮᑺৢᠡӮ⬅㉝✸♄乫㉦㸼䴶 28d Пࠡ˅ഛᯢᰒ催Ѣৠ啘ᳳⱘ FA3-2ˈᑊ 14d~28d ᯊ
݊ݙ䚼䖯ϔℹডᑨˈ䖒ࠄᅠܼ㾷㘮ⱘⳂⱘ[6]DŽ㗠 CFA-4 Ң ⬅ 11.89%䎗छࠄ 16.62%ˈ䇈ᯢᬍᗻ㉝✸♄ⱘ࣪ᄺ⌏ᗻᬜ
ডᑨᓔྟˈ⺅ᗻҟ䋼ህⳈϢ݊㸼䴶ঞݙ䚼ᅠܼ㾺ˈᑊ ᑨℸ䰊↉ⱘডᑨᑺࡴ᳔ᖿˈ 60d Пৢ݊ডᑨᑺ
Ϩডᑨ䗳⥛䕗ᖿˈ߱ᳳህᔶ៤䕗ᯢᰒⱘࠏ㱔⦄䈵ˈ ⱘ䭓䍟ᯢᰒޣ㓧ˈЏ㽕ᰃЎ∈࣪ѻ⠽ঞ⌚ԧᆚᅲᑺ
14d ᯊᅲ⦄ᅠܼ㾷㘮ˈᔶ៤ᵒᬷⱘẦ⢊⠽㇛ᢹԧDŽ ᦤ催䰏䱨њ։㱔ҟ䋼Ϣ㉝✸♄⌏ᗻ㒘ߚⱘ㾺ˈᓊ㓧њড
ᑨ䗳⥛[10]DŽ
C. ᄺᔎᑺߚᵤ
6 Ўᦎ㉝✸♄∈⊹⌚ޔ䆩ӊᡫय़ᔎᑺDŽ⬅ 6 ৃ㾕ˈ E. XRD ߚᵤ
ᦎࡴᬍᗻ㉝✸♄ⱘ CFA3-2 ⱘ啘ᳳᡫय़ᔎᑺձ✊ԢѢ㒃 7 Ўᦎᬍᗻᦎ㉝✸♄∈⊹⌚ޔ䆩ӊⱘ啘ᳳ XRD ߚ
∈⊹ԧ㋏ⱘ 0-2ˈԚⳌᇍѢ FA3-2ˈᦎࡴᬍᗻ㉝✸♄ⱘ ᵤDŽ⬅ 7 ৃ㾕ˈ2ș˙9.65º 䰘䖥Ў AFt ⡍ᕕዄˈᑊ䱣ⴔ啘
CFA3-2 ᮽᳳ˄28d Пࠡ˅᳝ᯢᰒӬˈϨ䭓䗳⥛䕗 ᳳⱘᓊ䭓ˈ݊ዄؐᯢᰒᔎDŽ2ș˙18.08º Ϣ 34.14º ໘Ў
ᖿˈ䇈ᯢᬍᗻ㉝✸♄ CFA-4 㛑᳝ᬜᬍ∈⊹ⱘ⌚ޔᮽᳳᗻ Ca(OH)2 ⱘЏ㽕⡍ᕕዄˈ݊ዄ催ৃϔᅮᑺϞড⌚ޔ
㛑[7,8]DŽⳌᇍѢ ⊩Ё⌟䆩ⱘ㒧ᵰℸ䭓⥛⬹ᰒϡ䎇ˈЏ㽕 ⱘ ∈ ࣪ ᑺ DŽ ᦎ ㉝ ᬍ ᗻ ✸ ♄ ԧ ㋏ Ё ˈ CFA3-2 ⱘ
ॳѢ∈⊹⌚ޔԧ㋏ⱘ∈࣪⦃๗Ϣ ⊩⦃๗Ⳍ↨ϡ㛑⒵䎇 Ca(OH)2 ⱘ⡍ᕕዄዄ催䱣啘ᳳⱘᓊ䭓ϔⳈਜ⦄䗦ޣ䍟ˈ
ᬍᗻ㉝✸♄ CFA-4 ⱘ▔থ㽕∖ˈℸ݊࣪ᄺ⌏ᗻᬜᑨ᮴⊩
䇈ᯢᬍᗻ㉝✸♄ CFA-4 ∈࣪ডᑨ߱ᳳे໘Ѣᖿ䗳ডᑨ䰊
ᄺᔎᑺᮍ䴶ᕫࠄᰒ⼎DŽ
↉ˈϡᮁ⍜㗫∈⊹ⱘ∈࣪ѻ⠽ Ca(OH)2ˈ࣪ᄺ⌏ᗻᯢᰒᦤ
催ˈ䖭Ϣ݊ᡫय़ᔎᑺⱘᮽᳳ㸼⦄Ⳍϔ㟈DŽ
Ʒ
Ʒ Ƹ
Ƶ
ᡫ य़ ᔎ ᑺ 03D
CFA3-2-90d
CFA3-2-60d
CFA3-2-28d
)$ CFA3-2-14d
&)$
CFA3-2-7d
G G G G G
啘ᳳ CFA3-2-3d
Fig.6 Compressive strength of cement paste with fly ash
D. 䴲㪌থ∈䞣Ϣডᑨᑺ
㸼 2 Ўᦎ㉝✸♄∈⊹⌚ޔ啘ᳳ䴲㪌থ∈䞣ঞ㉝✸♄ ƵˉAFt; ƷˉCa(OH)2; Ƹˉ¢-C2SH/C2S/C3S
ডᑨᑺDŽ⬅㸼 2 ৃ㾕ˈᦎࡴᬍᗻ㉝✸♄ৢⱘ∈⊹⌚ޔ Fig.7 XRD of cement pastes with CFA-4 at different ages
CFA3-2 ⱘ啘ᳳ˄ᇸ݊∈࣪ᮽᳳ˅䴲㪌থ∈䞣ഛ催Ѣ
㒃∈⊹ ⌚ޔ0-2 ঞ݊ᦎॳ⢊㉝✸♄ⱘ FA3-2ˈ䇈ᯢᴀ䆩偠 IV. 㒧䆎
ᴵӊϟᬍᗻ㉝✸♄ᯢᰒᦤ催њড়ԧ㋏ⱘᮽᳳ∈࣪䗳⥛ˈ 1˅㒣催⏽䩭ᬍᗻⱘ CFA-4 ⳌᇍѢ LCFA1 ᮽᳳⱘ
Џ㽕ॳѢ㱑✊ᬍᗻ㉝✸♄ⱘ乫㉦ᔶ䉠থ⫳ᬍবˈԚᬍ K a ؐᐙᑺᦤ催ˈ䇈ᯢ CFA-4 ⱘᮽᳳ⌏ᗻᏆᕫࠄ᳝ᬜ▔
ᗻ㉝✸♄ⱘ࣪ᄺ⌏ᗻᬜᑨㄝ䍙䖛њॳ⢊㉝✸♄ⱘ乫㉦ᔶ䉠
থ DŽ CFA-4 ⱘ ⌏ ᗻ Al2O3/SiO2 ↨ ؐ Ⳍ ᇍ Ѣ LCFA1 ⱘ
∈ޣᬜᑨঞ࣪ᄺ⌏ᗻᬜᑨ[9]DŽ Al2O3/SiO2 ᑇഛ↨ؐ催ߎϔסˈ䇈ᯢ催⏽䩭ⱘ䖛ϡ
Table 2 Degree of reaction of fly ash and non-evaporable
water content of cement pastes with fly ash /% ҙᇍ㉝✸♄ⱘ Si-O 䬂᳝⸈ണˈᇍ Al-O 䬂ⱘ⸈ണѺ
㓪ো 0-2 FA3-2 CFA3-2 ࡴᯢᰒDŽ
3d(䴲㪌থ∈䞣/ডᑨᑺ) 10.79 11.86/5.32 12.18/8.66
7d(䴲㪌থ∈䞣/ডᑨᑺ) 12.99 12.15/7.77 13.56/10.57 2˅ᬍᗻৢⱘ CFA-4 K a ⊩⦃๗ϟϡᄬࠊ㑺㋴
14d(䴲㪌থ∈䞣/ডᑨᑺ) 13.59 13.19/9.89 15.05/11.89 ˄े⒊㱔⌏࣪⚍ⱘߎ⦄˅ˈ݊㸼㾖⌏࣪㛑ᯢᰒ䰡ԢˈSi-O-
28d(䴲㪌থ∈䞣/ডᑨᑺ) 14.64 14.01/12.84 16.78/16.62
Al 㔥㒰㘮ড়ԧⱘ㘮ড়ᑺ䰡Ԣˈডᑨҟ䋼ৃҹᖿ䗳Ϣ㾷㘮ৢ
60d(䴲㪌থ∈䞣/ডᑨᑺ) 15.67 14.58/14.08 17.58/19.48
90d(䴲㪌থ∈䞣/ডᑨᑺ) 17.19 15.02/18.68 19.25/20.67
ⱘ SiǃAl 䖯㸠ডᑨˈ㗠ᛄᗻⱘ㥿ᴹঞ/ᮄ⫳ⷓ⠽⊌
ϡখϢডᑨϨ⅟ԭৢᔶ៤Ầ⢊⠽DŽ
5898
3˅ᦎᬍᗻ㉝✸♄ԧ㋏ЁˈCFA3-2 ⱘ Ca(OH)2 ⱘ⡍ᕕዄ [3] S Antiohos I, S. Tsimas. “Investigating the role of reactive silica in the
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⊹ⱘ∈࣪ѻ⠽ Ca(OH)2ˈ࣪ᄺ⌏ᗻᯢᰒᦤ催DŽ activity of pozzolanic materials,” Journal of Building Materials, vol 3,
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ᛳ䇶ᆊ䞡⚍⸔ⷨおথሩ䅵ߦ (973) ˄乍Ⳃ㓪ো˖
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