SHRIDEVI INSTITUTE OF ENGINEERING & TECHNOLOGY

(An ISO 9001:2015 Certified Institution)

Sira Road, Tumkur – 572 106. Karnataka
DEPARTMENT OF CHEMISTRY

1. There are two common oxides of sulphur. One of which contains 50% of O2 by weight.
The other almost 60%. The weight of sulphur which combine with 1 g of O2 (fixed) are
in the ratio of
a) 1:1
b) 2:1
c) 2:3
d) 3:2
2. A gaseous hydrocarbon gives upon combustion,072g of water and 3.08 g of
CO2. The empirical formula for the hydrocarbon is,
a) C2H4
b) C3H4
c) C6H5
d) C7H8
3. The number of neutrons in dipositive zinc ion with mass number 70 is
a) 34
b) 36
c) 38
d) 40
4. Which one of the following sets of ions represents a collection of isoelectronic species?
a) Li+, Na+ , Mg2+ , Ca2+
b) K+, Cl- , Ca2+ , Sc3+
c) Ba2+, Sr2+ , K+ , Ca2+
d) N3-, O2- , F- , S2-
5. Electronic configuration of M3- is (Ar)3d104S2, it belongs to
a) s- block
b) p- block
c) d- block
d) f- block
6. To which block does 106th element belong?
a) s- block
b) p- block
c) d- block
d) f- block
7. In which solvent NaCl has maximum solubility?
a) H2O
b) C2H5 OH
c) CH3COCH3
d) C2H5 OC2H5
8. Which of the following does not contain any coordinate bond
a) H3O+
b) BF-4
c) HF-2
d) NH+4
9. 6 g of O2 gas at STP is expanded so that volume is doubled. Thus work done is
a) 22.4 L atm
b) -5.6 L atm
c) 5.6 L atm
d) 11.2 L atm
10. An example of reversible reaction is
a) Pb(NO3)2 (aq) + 2Nal (aq) Pbl2(S) + 2NaNO3 (aq)
b) AgNO3 (aq) + HCl (aq) AgCl(S) + HNO3 (aq)
c) 2NaS(S) + H2O (l) 2 NaOH(aq) + H2(g)
d) KNO3 (aq) + NaCl (aq) KCl(aq) + NaNO3 (aq)
11. The oxidation number of C in CO2 is
a) -2
b) +2
c) - 4
d) + 4
12. On reaction with Mg, very dilute nitric acid produces
a) Ammonia
b) Nitrous oxide
c) Nitric oxide
d) Hydrogen
13. Which of the following statement is correct regarding alkali metals?
a) cation is less stable than the atom
b) cation is smaller than the atom
c) Size of cation and atom is the same
d) cation is greater in size than the atom
14. In India at the occasion of marriages, the fireworks used give green flame. Which one of the
following radical is present?
a) Na
b) K
c) Ba
d) Ca
15. The hardest substance amongst following is
a) Be2 C
b) Graphite
c) Titanium
d) B4 C
16. Boric acid heated to red hot gives
a) HBO2
b) H2BO2
c) B2O3
d) Borax
17. IUPAC name of CH3COCH (CH3)2 is
a) 4-methyl isopropyl ketone
b) 3-methyl-2-butanon
c) Isopropyl methyl ketone
d) 2-methyl-3-butanon
18. Methyl bromide, on being heated with Zinc in closed tube produces
A) Methane
B) Ethane
C) Ethylene
D) Methanol
19. SO2 as pollutant in the air
A) Causing cough and breathing difficulties
B) is corrosive to most metals
C) Affect certain sensitive plants
D) All of the above are correct statements
20. Ultraviolet radiation from sun causes a reaction that produces:
A) Fluorides
B) Carbon monoxide
C) Sulphur dioxide
D) Ozone
21. In general, among solids the highest melting point is established by
A) Covalent solids
B) Ionic solids
C) pseudo solids
D) Molecular solids
22. Which of the following is noncrystaline solid
A) CsCl
B) NaCl
C) CaF2
D) Glass
23. Find the molality of H2SO4 solution whose specific gravity is 1.98 g ml-1 and 95 % by
volume H2SO4
A) 7.412
B) 8.412
C) 9.412
D) 10.412
24. Which one of the following material conducts electricity?
A) Dimond
B) Crystalline sodium chloride
C) Barium sulphate
D) Fused potassium chloride
25. The highest electrical conductivity of the following aqueous solution is of
A) 0.1 M acetic acid
B) 0.1 M Chloroacetic acid
C) 0.1 M Fluoroacetic acid
D) 0.1 M difluoroacetic acid
26. The rate constant of a reaction is found to be 3x10-3 mol L-1 min-1. The order of the reaction is
A) Zero
B) 1
C) 2
D) 1.5
27. For a reaction 3A products, it is found that the rate of reaction doubles. If
Concentration of A is increased four times, order of reaction will be
A) 1
B) 1/2
C) 2
D) 3
28. The rate of physisorption increases with
A) Decrease in temperature
B) increase in temperature
C) Decrease in pressure
D) Decrease in Surface area
29. The extent of adsorption of a gas on a solid depends on:
A) Nature of gas
B) Pressure of gas
C) Temperature of gas
D) All are correct
30. Which ore contains both iron and copper?
A) Cuprite
B) Chalcocite
C) Chalcopyrite
D) Malachite
31. The most abundant element on earth crust is
A) Hydrogen
B) Oxygen
C) Silicon
D) Carbon
32. Which of the following statement is in correct?
A) NO is behavior than O2
B) The formal of heavy water in D2O
C) Nitrogen diffuses faster than oxygen through an orifice
D) NH3 can be used as a refrigerant
33. Among the trihalides of Nitrogen, which is the least basic?
A) NF 3
B) NCl3
C) NBr3
D) NI3
34. Zinc –copper couple that can be used as a reducing agent is obtained by
A) Mixing of zinc dust and copper gauge
B) Zinc coated with copper
C) copper coated with Zinc
D) Zinc and copper wires welded together
35. Variable valency is generally shown by
A) S-block element
B) S-block element
C) Transition elements
D) All elements in periodic table
36. The pair of compounds having metals in their highest oxidation state is
A) MnO2, FeCl3
B) MnO4-,CrO2 Cl2
C) [Fe(CN)6]3-,
D) None of the Above
37. Which of the following complexes show six coordination numbers?
A) [Zn(CN)4]2-
B) [Cr(H2O)6]3+
C) [Cu(CN)4]2-
D) [Ni(NH3)4]2+
38. The negative ligand is
A) Aqua
B) Suphato
C) Carboxyl
D) Nitro sodium
39. Dehydrohalogination in monohaloalkalines produces
A) A single bond
B) A double bond
C) A triple bond
D) Fragmentation
40. The catalyst used in the preparation of an alkyl chloride by the action of dry HCl on an
alcohol is
A) Anhydrous AlCl3
B) FeCl3
C) Anhydrous ZnCl2
D) Cu
41. Which of the following compounds is oxidized to prepare methyl ethyl ketone?
A) 2-propanol
B) 1-butanol
C) 2-butanol
D) Tert-butyl alcohol
42. Methyl alcohol on oxidation with acidified K2Cr2O7 gives
A) CH3COCH3
B) CH3CHO
C) HCOOH
D) CH3COOH
43. Lucas test is used for
A) Alcohols
B) Amines
C) Diethyl ether
D) Glacial acetic acid
44. The Reagent with which both acetaldehyde and acetone react easily is
A) Fehling’s reagent
B) Grignard reagent
C) Schiff’s reagent
D) Tollens’s reagent
45. When acetaldehyde is heated with Fehling’s solution it gives a precipitate of
A) Cu
B) CuO
C) CU2O
D) Cu + CU2O+ CuO
46. Hydrogenation of benzyle chloride in the presence of pd on BaSO4
A) Benzyl Alcohol
B) Benzaldehyde
C) Benzoic acid
D) Phenol
47. In hypobromite reaction of amide, carbonyl carbon atom is lost as
A) CO
B) CO2
C) CO3-2
D) None of above
48. Which of the following compounds on reduction gives an amine?
A) Alkyl cyanide
B) Aldoxime
C) Alkyl iso cyanide
D) All above
49. N-Ethyl phthalimide on hydrolysis gives
A) Methyl alcohol
B) Ethyl amine
C) Dimethyl amine
D) Diethyl amine
50. Vitamin C is:
A) Ascorbic acid
B) Lactic acid
C) Citric acid
D) Paracetamol
51. Which one of the following metal Ions is essential inside the cell for the metabolism of
glucose/ synthesis of proteins?
A) Na+
B) K+
C) Mg2+
D) Ca2+
52. Which of the following bases is not present in DNA?
A) Cytosin
B) Guanine
C) Uracil
D) Adenine
53. Cis-1, 4-polyisoprene’ is
A) Thermoplastic
B) Thermosetting plastic
C) Elastic (Rubber)
D) Resin
54. Which of the following is a natural polymer?
A) Polyester
B) Glyptal
C) Starch
D) Nylon-6
55. Which of the following polymer is an example of fiber?
A) Silk
B) Dacron
C) Nylon-6,6
D) All of these
56. Polyethylene is
A) Random copolymer
B) Homopolymer
C) Alternate copolymer
D) Cross linked copolymer
57. Which of the following is not tranquilizer?
A) Luminol
B) Seconal
C) Reserpine
D) Piperazine
58. A substance which can act both as an analgesic and antipyretic is
A) Quinine
B) Apirine
C) Penicillin
D) Insulin
59. Chemically heroin is
A) Marphine diacetate
B) Marphine monoacetate
C) Marphine dibenzoate
D) Marphine monobenzoate
60. Which of the following is hypnotic drug?
A) Luminol
B) Salol
C) Piperazine
D) Novalgin