Solution Slot - 3 (Chemistry) Page # 143

EXERCISE -V MATRIX
1. A  P; B  Q,R; C  S
CH3
2 X  CH3 — CH — CH — CH3 Secondary alcohol
OH
CH3
Y  CH3 — CH — CH2 — CH2 — OH
CH3 — CH2 — CH2 — CH2 — CH2 — OH
CH3
CH 3 — C — CH 2 — OH Primary alcohol
CH 3
CH3

Z CH3 — C — CH2 — CH3 Tertiary alcohol


OH
A–ii; B–i, iv, v; C – iii

+ O H
3 A
O
H—O O
O + H
B
H—O O
OEt

O + 2 EtoH H
C
OEt
OH
OCH3
H
D CH3OH
OCH3
OCH3
SEt
2 Et–SH
E O
H
SEt
A–P,S; B–P,S; C–P,S; D–R,S; E–R
O OH

4 A Ni/H2

OH O

B P.C.C.

OH

C H3PO4

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 Page # 144 Solution Slot - 3 (Chemistry)

OH Cl

D CON.HCl

A–P; B–Q; C–R; D–S

CrO3 /CH2Cl 2/Cold KMnO4
Ph — CH — CH 3 Ph — C — CH3
5 A Cu / 300ºC
OH O
CrO3 /CH2Cl2
B Ph — CH2 — CH2 — OH Cu / 300ºC
Ph — CH2 — CHO
Cold KMnO4
Ph — CH2 — CH2 — OH Ph — C H2 — C — HO
C
O
hot dil.KMnO4
Ph — CH — CH3 Ph — C — OH
D
OH O
A–Q,R,S; B–R,S; C–Q; D–P

OH Br

HBr
6 A

OH Br

B HBr

K2Cr2O7

CH2 — OH COOH

CrO3, H2SO4
C

HBr CH2 — Br
CrO 3 /CH2Cl2

CHO

OH

FeCl3
D Violet colour

A–R; B–R,S; C–P, R, T; D–Q

394 - Rajeev Gandhi Nagar Kota, Ph. No. 0744-2209671, 93141-87482, 93527-21564
IVRS No. 0744-2439051, 0744-2439052, 0744-2439053, www.motioniitjee.com, email-info@motioniitjee.com
Solution Slot - 3 (Chemistry) Page # 145
7 A
Pyridine
EtOH + CH3 — C — Cl CH3 — C — OEt + HCl
O
Esterification Reaction

Acetylation Reaction
M.F. of alcohol increase by C2H2O
B
H CH3 — C — OEt + CH3 — C — OH
Et — OH + CH3 — C — O — C — CH3
O O O
H CH3 — C — OEt
Et — OH + CH 3 — C — OH
C
O O

D H CH3 — CH2 — O — CH2 — CH3

Et — OH + Et — OH
M.F of alcohol increase by 2.8

A–P,R,Q; B–P,R,Q; C–P,R,Q; D–S

H3O
R — C — OH
O
OH / H2O
R—C N R—C—O
8 A
O
LiAlH4
R — CH2 — NH2

RO COOH
H3O
O
RO C — OEt RO CH2 — OH

B
RO COO

H3O
Ph — C — OH
O
LiAlH4
Ph — C — NH2 Ph — CH2 — NH2
C
O
OH / H2O
Ph — COO

H3O
R — C — OH
O
LiAlH4
R—C—O—C—R R — CH2 — OH
D
O O
OH / H2O
R—C—O
A–P,R,S; B–P, Q,S; C–P,R,S; D–P,Q,S

394 - Rajeev Gandhi Nagar Kota, Ph. No. 0744-2209671, 93141-87482, 93527-21564
IVRS No. 0744-2439051, 0744-2439052, 0744-2439053, www.motioniitjee.com, email-info@motioniitjee.com