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Heat Transfer in LTV FF Evaporator
Heat Transfer in LTV FF Evaporator
-Nomenclature-
"film side" refers to the inside of H = heat of vaporization of kt = thermal conductivity of
the tube with the fall- film side (Btu/lb m ) = the tube (Btu/ft-sec-
ing film H(Tl) deg F)
Hs = heat of vaporization of L = length of tube (ft)
"steam side" = refers to the outside of steam side (Btu/lb m ) M = mass flow rate of the
the tube where steam = H,(T,) liquid on film side
is condensing (lb,„/sec) = Mix)
h = local heat transfer coef-
the mean slope of the ficient on film side = .!/„ = mass flow rate of vapor
curve relating vapor h(x) (Btu/ft 2 -sec-deg on film side (lb„,/sec)
temperature to vapor F) = M.(x)
pressure = lis = local heat transfer coef- M D = measured distillate rate
Ts - T l ficient on steam side (lbm/sec)
= h,(x) (Btu/ft 2 -sec- M Da = apparent distillate rate
P(TS) P{TL,)'
deg F) = M,CHJH
deg F-ft 2 M K = actual steam conden-
hc = actual combined heat
lbr transfer coefficient = sate rate
hc(x) (Btu/ft 2 -sec-deg Pr = Prandtl number of liq-
D = diameter of the inside of F) uid on film side =
the tube (ft) Pr (Tl)
h' = dimensionless heat
<7 = acceleration of gravity transfer coefficient = P = pressure of vapor on film
= 32.2 ft/sec 2 h(x)\p side (lbt/ft 2 ) = P(x)
k = thermal conductivity of A P = pressure difference =
gc = conversion factor = liquid on film side P(0) - P(x)
32.2 ft-lb m /lbf-sec 2 (Btu/ft-sec-deg F) (Continued on next page)
=Nomenclature-
U„ = apparent overall heat He viscosity of vapor on
= pressure gradient inside
dx transfer coefficient = film side (lbm/ft-sec)
3600
tube (lbt/ft 3 ) =~(x) M,CH, or
dx ATrirDL " ' viscosity of steam con-
r = inside radius of tube (ft) Hp. densate = fiK(Tt)
= 900 ARe£ density of liquid on film
rs = outside radius of tube LATL P
f = average radius = (r + Btu side (lb m /ft 3 ) = p(TL)
''J/2 (hr-ft2-degF, Pr density of vapor on film
Re = Reynold's number of variable instance down side (lb m /ft, 3 ) =
film side liquid = the tube (ft) with x PV(Tl)
L
Krf \gM/\ P J
ARe d{ARe)
film side (deg F) = I =
f.
(gjg"-/3)
T(x) R =
T, = temperature of con- 2p1'V/j
densing steam (con- _4 4k /p^V/> 7 d(ARe)
stant) Hp.\p ~ H \ M6 / o
AT = temperature difference (PVM2)1/3 = \(TL)
= T. - T(x) viscosity of liquid on Subscripts
Mv = Mo - M = — ARe (2)
From a heat balance through the tube wall as shown in Fig. Fig. 1 Heat flow through the tube cross section
1, considering a differential amount of heat flux (dq):
dq = hcAT(2xr)dx = dMvH = dM,cH, (3) assuming film thickness is negligible compared to the tube radius.
The dimensionless shear coefficient (/?) from Dukler [10] can
where hc is the actual combined heat transfer coefficient between then be expressed in terms of the pressure gradient:
the steam side temperature (J1,) and the film side temperature
(T), defined arbitrarily over the area 27rr dx. Differentiating Ti <Jc —
(11)
equation (2) with respect to x and combining with equation (3), p ' V A q"1'' dx
using the definition for the dimensionless heat transfer coefficient
where
4A T 1 d{ ARe)
(4) 1 0c
Hut dx ?= 2 p( V3„V3
'/y, g
Using equations (2) and (3) and the definition of Reynolds num-
ber for the steam condensate flow: It is desirable to obtain equations in terms of j3, since /3 must be
considered in using Dukler's calculations for the local heat trans-
„ H r a . fer coefficient.
Re«c = 77 — — A R e (5)
Hs r, nsc Using equation (11) in equation (4), the dx can be eliminated.
Then equation (9) can be substituted for AT in equation (4)
As shown in Fig. 1, the heat flow from the steam side to the which upon integration becomes:
film side will encounter three thermal resistances: the condens-
ing film outside, the tube wall, and the falling film inside. Sum-
ming these resistances, using the dimensionless heat transfer
coefficient, and cancelling common factors:
{ (7. - b)PL -Pi} - (T. - b)P +
H
•' AReL
AReL g
2
1 1
' h' tp + k—
rip
(6) /' ARe
h + rji- t
p, d(ARe') (12)
It can be shown that the above may be simplified
A; to obtain:
-h"*' - J - - sL v
If an expression for (3 in terms of ARe is known, then h' and
h,' can be evaluated for various values of ARe from the calcu-
lation of Dukler [10].
r ar,, 1 2a f A R e i 13
tZ(ARe') (13)
If the pressure drop in the tube is negligible, then the tempera-
ture difference is constant down the tube. Letting AT = ATu In order to simplifj' notation the following quantities are
equation (4) can be integrated to give: defined:
-r /.
ARe/.
h
L = (7) - ci(ARe')
KA TL
If the pressure drop is significant, then AT cannot be assumed AT2 = A ? V e(JL - J) (15)
constant and must be expressed in terms of the vapor pressure
Now substituting equation (15) into equation (4) for AT and
(P). This can be clone easily using steam tables and assuming
setting limits of integration over the length of the tube:
a linear relation between vapor pressure and temperature. This
assumption is very good for the magnitude of temperature differ- CL 1 f A R e i d( ARe)
a
ence of primary interest, namely, from 0 to about 20 deg F. I dx — L — — I , (16)
Jo K Jo h/VAT. - e (Jl ~ J)
AT = (T, - b) - aP, (9)
Equation (16) is the basic equation to be solved. However,
T. T,. it cannot lie integrated until an expression for the two-phase
where a = evaluated from steam tables, and b
P{T,) - P{Tl)
Using a force balance, it can be shown that, if acceleration and tion is by empirical means. Lockhart and Martinelli [12] intro-
gravitational effects on the vapor flow are negligible, then the duced two groupings to correlate data. Dukler [10] used these
interfacial shear can be expressed in terms of the two-phase groupings and his own data at atmospheric conditions to obtain
annular pressure gradient: the following:
r (d-P\ dP
(10) — = -10.9 dP\o-ls Aj^Y-2 (17)
Ti = - ¥ dx dx/v \dx,
dP\
Now let us assume that /3 and .7 are related as follows:
P = eJ» (24)
in the tube and ( — ) is the pressure gradient if liquid were
\dx/1
where e and n may depend on Re0, D, and TL, but not ARe.
flowing alone in the tube. Using the Fanning and Blasius equa- It can be shown that this equation is exactly /3 = ej"ll+" when
tions [13]: ARe .
h j is constant and is approaching zero. In our equipment
Re 0
dP
= - A Re 0 - 3 9 R e „ " (18) hc' does not vary radically because of the interaction of h' and
dx
h,', and is small in most cases in our range of interest.
where Reo
Therefore equation (24) is a good approximation. Substituting
1.712 ^ . ' - y - "
equation (24) into equation (23):
f
A =
8) .3 pi.nptM
- T " . (25)
Equation (18) is inadequate for temperature levels less than eJ"V(ATL• - eJL) + eJ
212 deg F at which the pressure gradient increases considerably. Jo
There is no known correlation for vacuum conditions. There- This integral may be solved by applying integration by parts
fore only the form of equation (18) was assumed to be applicable. continuously to form an infinite series starting with u = [(AT L2
From equation (2) - eJL) + and dv = J~"dJ. The result is:
Jl1-' l/2q
//ARe KL = 1 +
Re„ = (19) eATL(l - n) (2 - »)
fJ-v
(1/2X3/2)
Then the form of the pressure gradient equation is assumed to + (2 - n)(3 - n)
a2 + (26)
be:
dP <f> where
— = — Re2ARe" (20)
dx r3
J 'Jl
0 /?V(AJV
dJ
- *Jl) + tJ
(23) L can be found for various values of ARe L using equations (28)
and (29).
„ 0- 5 2. 33 -
Re ARe Re (ARe) 10 " 4 P 1/h' 0/h'
"V
1 • io-3 J • io"3
H 4 s c c
1000 0 0 0. 210 CO 5. 033 0 0 0
975 25 31. 22 0. 1808 0 . 0257 0. 211 0. 40 6. 946 0. 179 0. 160 -
950 50 30. 82 0. 910 0. 128 0. 214 0. 320 7. 366 0. 942 0. 340
900 100 30. 00 4. 57 0. 625 0. 226 0. 258 7. 708 4. 82 0. 719 0. 155 0. 345
800 200 28. 28 22. 95 2. 96 0. 266 0. 230 7. 431 22. 00 1. 48 1. 43 0.326
700 300 26. 46 59. 00 7. 12 0. 315 0. 219 7. 035 50.08 o 20 4. 93 0. 315
600 400 24. 49 115. 5 12. 90 0. 375 0. 211 6. 679 8 6 . 15 2. 89 11. 69 0.314
500 500 22. 36 194. 3 19. 61 0. 432 0. 210 6. 358 125. 96 3. 54 22. 32 0.318
400 600 20. 00 297. 0 27. 09 0. 530 0. 210 5. 945 161. 09 4. 16 36. 71 0. 325
300 700 17. 32 425. 0 33. 57 0. 635 0. 210 5. 644 189. 47 4. 74 54. 56 0. 343
200 800 14. 14 581. 1 3 7 . 60 0. 750 0. 210 5. 411 203.45 5. 30 74. 21 0. 3 7 2
100 900 10. 00 764. 5 3 4 . 80 0. 905 0. 210 5. 190 180.61 5. 83 93. 40 0. 460
25 975 5. 00 921. 2 21.0 1. 100 0. 210 5. 001 105. 0 2 6. 21 104.10 0. 600
0 1000 0 0 w 0. 210 4. 124 0 6. 80 105. 30
The variation of J /I(i is a measure of validity of the approxi- The development of both these theories is unique in two ways.
mation of equation (24). If the equation were exact, this 1 The actual pressure drop data of the evaporator were used
quantity would be invariant with a variation of ARe, since n to develop expressions for the pressure gradient at all temperature
is assumed to be constant. Table 1 shows that this variation is levels investigated. Dukler, et al. [9] did not have an expression
great only as ARe/Reo approaches 1 which is consistant with for the pressure gradient at vacuum conditions so one was
our initial constraint. From this table, it appears that the ap- assumed.
proximation is good for values of AI?e/Re 0 approaching 0.8. 2 The development was sufficiently simple so that a computer
Since, under most practical conditions, this ratio is not nearly was not necessary to calculate numerical values as was done by
0.8, the approximation would seem to be justified. Dukler [9]. However, a computer is desirable if a number of
It was found while calculating the tabulated values that the values is to be calculated.
value of n varied little from the value of y/l + y. Therefore
n can be assumed to be y/l + y and equation (29) becomes: Experimental Analysis
The experimental equipment is shown schematically in Fig. 2.
1
Jl = (30) Water from the citj' line is heated to the boiling point and intro-
l + y duced into the water inlet chamber. Here it is distributed in a
film on the inside wall of the tube by a vortex feed mechanism.
This equation simplifies calculation significantly because now
Saturated steam is introduced into the steam chamber outside
only I L needs to be calculated by graphical integration.
the tube at a temperature {Te) which is ATL greater than the
If there are bubbles present in the falling film then Theoiy I
temperature level { T L ) of the evaporator. Heat flows from the
will not accurately describe the system. However, if the number
steam on the outside to the falling film on the inside. Vaporiza-
of bubbles is not great enough to alter the essential liquid texture
tion takes place on the inside, condensation on the outside. The
of the film, as postulated by Sinek and Young [5], we can assume
vapor flows out the bottom of the tube, turns 90 deg and flows
that Dukler's calculations for the heat transfer coefficient are
to a condenser where the condensate yield is obtained. The
applicable. Then Theoiy I can be modified to account for these
unvaporized portion falls straight to the bottom of the vapor
bubbles. Using equation (1), assuming the function F is linear
chamber where it is pumped out of system. The steam con-
as was done previously:
densate flows in a film down the outside of the tube and is pumped
from the bottom of the steam chamber.
+
A?" = T, T' = T,
"(P 7) (31)
PRESSURE
1/2 d/2)(3/2)
L = 1 + a' + a" +
kAT, (2 - n ) (2 - re)(3 - n)
(32)
TO V A C U U M
PUMP
where
COOLING WATER
4c —, .m 4a . eJ,,
AT,' = AT, - a; AT' = ATL r- a; a' = ==£.
SL 8 AT - DEMISTER
CONDENSATE
CONDENSER
A T l represents the measured temperature difference while ATL' VAPOR
COOLING WATER CHAMBER
represents the effective temperature difference at x — L. AT'
represents a mean effective temperature difference. Arbitrarily, Md
YIELD
it was decided to let 8 be the value of 8 at ARe/2. The variation
of 8 was not found to be veiy critical in our range of interest.
Dukler's calculations for the film thickness were used to deter- T-TEMPERATURE PROBE X - VALVE
The tubes were 3 /i in. O.D. (0.61 in. inside dia), Admiralty brass.
Not all possible combinations of the above values were investi-
gated. Special runs were made to measure pressure drop to de-
termine the relations for the pressure gradient used hi the theo-
retical analysis. Also special runs were made for L = 13.1 ft at
atmospheric conditions to measure entramment.
/ \
\
/ O1 \
•"TL=I80 F \
\
\
\
\
\ \
D = .61 IN
\
D =.61 IN Tl=I80°F
M0= . 0 7 4 L B m / S E C ATl= 20°F
AT l = 2 0 F °
M 0 = .074 LBm/SEC
EXP DATA
EXPERIMENTAL DATA
X-TL=2I2°F
A-Tl= I80°F THEORY I
THEORY E
• -Tl= I60°F
THEORY 1
THEORY n
J I
I I _L_ 0 4 8 12
2 4 6 8 10 12 14 LENGTH ( L ) , FT.
900
5 700
EXPERIMENTAL DATA X
THEORY I
D = . 6 I IN
THEORY H
Tl=I60°F
D= 1.84 IN
L = 2 4 FT
200 0.0. = 2"
Tl»"I80oF
ATLc|0°F
THEORY
nflTA - W R I G H T S V I L L E
U B BEACH
Broker [2] observed that the distillate rate actually decreased 5 The apparent overall heat transfer coefficients (U a ) should
with increasing length at lengths greater than a critical value for be used in comparing the performance of various evaporators
a 'A in. dia tube at atmospheric conditions. We did not observe rather than the actual heat transfer coefficient (hc). This is
this for our 3 / , in. tube even at vacuum conditions. Moreover, because the value of lie may be very high, but the actual heat
the theory predicts that the distillate will asymptotically ap- flux through the tube may be low due to the decrease of AT.
proach a maximum and the phenomena observed by Broker 6 The two-phase annular pressure gradient is a significant
should not occur. However, there may be effects of a diameter factor. To predict the heat transfer over a wide range of tem-
change not taken into account in the theory. perature levels, data must be obtained for the pressure gradient
Theoretical calculations show that the heat transfer coefficient over this range. The parameter (3 which is directly related to
on the inside of the tube is generally greater than that of the the pressure gradient is more significant than the value of the
steam side. Typically h is twice ha. This indicates that im- Reynolds number (Re).
provement in heat transfer can be made most readily by increas- 7 The same diameter and length should probably not be
ing the steam side coefficient. This can be done by increasing used for all effects (values of T L ) in a multieffect plant.
the vapor shear on the outside of the tube or treating the tube 8 For higher rates of heat transfer in the practical range of
to promote dropwise condensation. operation, the inlet flow rate should be made as high as possible
The same diameter and length should probably not be used at. most temperature levels. However, this situation graduallj'
for all effects (value of TL) in a multieffect plant. Theory indi- reverses as the temperature level is decreased to a low value.
cates that the apparent overall heat transfer coefficient (U a )
will approach a maximum as length and diameter both approach
zero; the experimental data substantiate this for length. Con-
Acknowledgment
sidering heat transfer onlj', the optimum evaporator would have This paper is the result of research work done at the Depart-
lubes with diameters and lengths approaching zero, which is ment of Engineering, University of California, Los Angeles.
absurd. Therefore economic factors must be considered to ob- Funds for Saline Water Conversion Research are granted as a
tain unique optimal values for length and diameter at each value special item in the University of California budget by the Cali-
of TL. fornia State Legislature.
The practical range of Re 0 for our evaporator was 1000 <
Re0 < 13,000. Both experiment and theory indicate that higher References
heat transfer for T L = 212 deg F and all lengths can be obtained 1 " O p e r a t i o n of P i f o t Plant L T V E v a p o r a t o r at Wrightsville
with Re 0 as large as is practical. This practical limit is the point B e a c h , N o r t h C a r o l i n a , " W . L. Badger and Associates, Inc., Office of
where the vapor flow cross section becomes significantly de- Saline W a t e r , D e p a r t m e n t of Interior, Research and D e v e l o p m e n t
Progress R e p o r t N o . 26, D e c . 1959.
creased. As Tl is decreased, the situat'on gradually reverses
2 Broker, B., and M c C u t c h a n , J. W . , Heat Transfer in a Single
until the lowest practical flow rate (Re ~ 1000) is best. This Tube Falling Film Evaporator With Dropwise Condensation, The
lower limit is determined by our ability to distribute the film L . M . K . Boelter Anniversary V o l u m e , M c G r a w - H i l l , N e w Y o r k ,
evenly to prevent local dry spots. Dry spots occur when the 1964, pp. 8 - 3 4 .
3 D y k s t r a , D . I., " S e a W a t e r Desalination b y the Palling Film
film is completely evaporated at some particular area on the
P r o c e s s , " Chemical Engineering Progress, V o l . 61, July 1965, p p .
tube. 80-88.
4 N o r m a n , W . S., and M c l n t y r e , V . , " H e a t Transfer to a Liquid
F i l m 011 a Vertical S u r f a c e , " Transactions of the Institution of Chemical
Conclusions Engineers, L o n d o n , Vol. 38, N o . 6, 3 0 1 - 3 0 7 , D e c . 1960, discussion pp.
317-323.
1 The comparison of theory with experimental data was 5 Sinek, J. R . , and Y o u n g , E . H . , " H e a t Transfer in Falling Film
quite favorable. The average absolute difference was 11.5 per- L o n g T u b e Vertical E v a p o r a t o r s , " Chemical Engineering Progress,
cent for Theory I and 8.1 percent for Theory II. Vol. 58, D e c . 1962, pp. 7 4 - 8 0 .
6 Unterberg, W . , " S t u d i e s of L i q u i d Film F l o w and E v a p o r a t i o n
2 Dukler's development for the heat transfer to a liquid film
W i t h R e f e r e n c e to Saline W a t e r Distillation," D e p a r t m e n t of E n g i -
is quite accurate. neering, University of California, L o s Angeles, R e p o r t N o . 61-26,
3 Theoretically, the distillate rate (M D a ) should asymptoti- O c t . 1961.
cally approach a maximum with increasing length. 7 Unterberg, W . , " E v a p o r a t i o n F r o m Falling and W i p e d F i l m s
of Pure and Saline W a t e r , " P h D in Engineering, University of Cali-
4 The heat transfer coefficient on the falling film side (h) is,
fornia, L o s Angeles, Jan. 1964, pp. 1 5 - 2 2 and 191.
in general, substantially greater than the coefficient on the steam 8 W e b b , R . , " A C o m p a r i s o n of Falling and W i p e d Film E v a p o r a -
side (hs). tion in a Saline W a t e r Still," M S in Engineering, University of Cali-