Professional Documents
Culture Documents
Chap 27 PDF
Chap 27 PDF
Chapter 27
Boilers for Industry and Small Power
Many industrial processes generate byproducts and superheater (if included) in the flue gas stream
which can serve as boiler fuels, significantly contrib- provides the rest of the necessary heat transfer surface.
uting to the plant operating efficiency and effectively As shown in Fig. 3, as pressure increases, the
reducing product cost. Examples of these are gas prod- amount of heat absorption required to evaporate wa-
ucts from the steel industry (blast furnace and coke ter declines rapidly, and the absorption required for
oven gas), products from the petroleum industry (car- superheating and water preheating increases. In
bon monoxide (CO), refinery gas, petroleum coke), some modern very high pressure industrial units, a
products from agriculture (sugar mill bagasse, peanut smaller boiler module separate from the steam drum
hulls, coffee grounds), waste from the pulp and pa- provides the same function as the traditional boiler
per industry (wood, bark, process chemicals, sludge) bank (see Fig. 4), but at a lower cost.
and municipal solid waste. Steam generation and fuel A separate economizer and/or air heater can be used
handling for some of these fuels and applications have downstream of the boiler bank to further reduce the
become quite specialized. This chapter and the follow- flue gas exit temperature to a more economic value.
ing chapters are devoted to these units:
Steam requirements
Chapter 28 – Chemical and Heat Recovery in the
To assure prompt fulfillment of all steam demands,
Paper Industry
i.e., the delivery of heat to all points of use at the re-
Chapter 29 – Waste-to-Energy Installations
quired rates, it is necessary to select steam producing
Chapter 30 – Wood and Biomass Installations
equipment of sufficient capacity, range of output and
Chapter 31 – Marine Applications
responsiveness. The demand may be steady, as in most
One of the distinguishable features of most indus- space heating systems, or it may fluctuate widely and
trial boilers is a large saturated water boiler bank be- rapidly, as in a heavy forging plant. Many steam
tween the steam drum and lower drum. (See Figs. 1 heated processes, as in the initial heating of a liquid
and 2.) The boiler bank serves the purpose of preheat- batch, require high peak flows of short duration. Rap-
ing the inlet feedwater to the saturation temperature and idly changing rates of steam flow characterize require-
then evaporating the water (generating steam) while ments to produce the electrical power to drive a steel
cooling the flue gas to a cost effective exit temperature. rolling mill. Combined cycle systems often require
In lower pressure boilers, insufficient heating sur- rapid steam load responses during cycle transients.
face is available in the furnace enclosure to absorb all The steam flow requirements should, therefore, be
of the energy needed to accomplish this function. There- accurately established for a number of conditions to
fore, a boiler bank located downstream of the furnace ensure that the boiler system selected will meet all of
Fig. 1 Two drum Stirling® power boiler system for pulverized coal with environmental control equipment.
ing equipment for process heating service usually a. for a gas turbine-based system
ranges from 125 to 250 psig (0.86 to 1.7 MPa) and su- 1. If steam demand typically exceeds power de-
perheat is usually not required. For this service, boiler mand, auxiliary burners are supplied with
manufacturers have generally standardized on a pres- the HRSG.
sure of 250 psig (1.7 MPa) for small water-tube boilers. 2. If electrical load demand typically exceeds
It is customary American stationary boiler practice the steam demand requirements, the re-
to hold the main steam line pressure practically con- mainder of the power may be purchased
stant for all loads, on the premise that this condition outside.
satisfies all pressure and quantity requirements of the b. for a steam-based power system
steam-using equipment. Automatic combustion con- 1. If steam demand typically exceeds power de-
trol apparatuses are accordingly designed to function mand, the turbine exhaust steam flow can
on this basis. be supplemented with boiler auxiliary firing,
Cogeneration Many manufacturing operations, and then the additional steam can be passed
such as in paper and textile mills, in the production through a pressure reducing and attemperating
of chemicals and in processing rubber, require me- system.
chanical or electrical power as well as steam for pro- 2. If power demand is typically higher, either
cess heating. For such cogeneration applications, stud- an extraction condensing turbine system
ies are made of the relative merits and costs of: 1) a can be used or the incremental power can
plant where the power is purchased and steam is gen- be purchased outside.
erated to supply the heating requirements only, and If the process requirements for steam and power
2) a plant where steam and power are generated in are reasonably parallel and steady, cogeneration, in-
the same system. A sound appraisal of the relative cluding capital, operating and maintenance costs, can
merits of the two alternatives requires knowledge of be beneficial. Where discontinuous service, low capac-
the steam and power requirements, ability to corre- ity factor or significantly different steam and power
late these requirements, economic studies and good requirements exist, electrical supply from the local
judgement. The following general summary may be power grid and on-site steam generation is frequently
of assistance. more cost effective.
1. The basic economic advantage in generating steam Power generation Except for small isolated instal-
and power in the same system arises from the use lations, the high speed turbine is the prime mover of
of a much larger portion of the heat supplied in choice for steam power generation because of its effi-
the fuel. When generating electricity alone, as ciency, compactness and low cost. Continued improve-
much as 60% of the heat supplied in the fuel is ment in reliability, reduction in cost, and availability
lost to the condensing system, even in a modern of packaged systems have made on-site power genera-
central station. (See Chapter 2.) tion more popular. Where natural gas is available and
2. Despite this fundamental thermodynamic advan- cost effective, simple gas turbines, especially package
tage, it is frequently more economical to purchase units, have tended to dominate on-site power produc-
power when it is available at reasonable rates from tion needs. Where a waste fuel (or low cost coal) is
a dependable source, except where: available, a boiler and steam turbine system can prove
a. waste fuels and waste heat, such as bagasse, to be the most economic system to supply on-site power.
blast furnace gas, sawdust or hogged wood, and The selection of steam pressure and temperature for
hot gases are available at low cost from the plant such systems depends upon an economic evaluation
process, and along the guidelines presented in Chapter 37. Steam
b. the steam heating and power demands are rea- temperature control using one or more of the meth-
sonably parallel and relatively large, i.e., 50,000 ods outlined in Chapter 19 is usually provided when
lb/h (6.3 kg/s) of steam or more. electrical output exceeds 25 MW. Steam temperature
3. Two approaches are used for cogeneration. Where control is also very important where variations in the
natural gas is available on site, a gas turbine can flow of the fuel and the fuel quality would otherwise
be used to generate power, with the waste heat in lead to wide swings in power output.
the turbine exhaust gas used to produce steam in
a heat recovery steam generator (HRSG). HRSGs are
discussed in more detail later in this chapter. Where Combined cycles
a waste fuel such as petroleum coke, bark, biomass, The concept of using waste energy for increased
tires or other fossil fuel such as coal is the economic steam generation in industry has been around for
fuel of choice, a steam turbine topping cycle is used. many years. The progressive increase in fuel costs, the
Here, high pressure high temperature steam is pro- need to capture heat from various industrial processes,
duced in the boiler system and is first passed through and the increasingly stringent environmental regu-
a steam turbine to generate power. The exhaust steam lations have created the need for using waste heat to
is then conditioned (brought to appropriate tempera- its fullest potential.
ture and pressure) and sent to the process. In the power industry, the waste heat from one
4. Variations in process heat and power demands power system such as a gas turbine can serve as the
usually do not coincide. To compensate for the dif- heat source for a steam turbine cycle. Such combined
ferences, a variety of options can be used depend- cycles can push overall electrical power cycle efficiency
ing upon the economic evaluation: to nearly 50%. Overall energy use can substantially
exceed even this level when electrical generation is the gas turbine is usually in the range of 950 to 1050F
combined with process steam use. (510 to 566C) while the optimal SCR catalyst tempera-
Industries such as steel making, oil refining, pulp ture is 650 to 750F (343 to 399C).
and paper, and food processing have used many A variety of more complex configurations are pos-
unique steam generating systems to get the most out sible. A key improvement in the steam cycle efficiency
of their waste heat. These systems allow reduced con- can be obtained by adding multiple separate pressure
sumption of traditional fuels, recovery of waste heat circuits to the HRSG to supply low pressure steam for
for safety and economy, and elimination of process deaeration and feedwater heating. This replaces the
byproducts. steam extraction regenerative feedwater heating used
In its broadest terms, a combined cycle plant con- in conventional steam power cycles.
sists of the integration of two or more thermodynamic
power cycles to more fully and efficiently convert in- Commercial combined cycle systems
put energy into work or power. With the advancements Actual configurations are typically more complex
in reliability and availability of gas turbines, the term because of application requirements and the degree
combined cycle plant today usually refers to a system of integration. The gas turbine-generators and steam
composed of a gas turbine, heat recovery steam gen- turbine-generators are commercially available in a
erator and a steam turbine. Thermodynamically, this number of specific sizes and arrangements. HRSGs
implies the joining of a high temperature Brayton gas are built from standardized components to suit a wide
turbine cycle with a moderate and low temperature variety of steam uses and turbine exhaust conditions.
Rankine cycle – the waste heat from the Brayton cycle Frequently, multiple gas turbines with HRSGs may
exhaust serves as the heat input to the Rankine cycle. feed a single steam turbine system. A gas bypass stack
The challenge in such systems is the degree of inte- and silencer are typically installed downstream of the
gration needed to maximize efficiency at an economic gas turbine so that it can be operated independently
cost. Chapter 2 discusses the thermodynamic processes of the steam cycle. With the high levels of oxygen re-
and benefits of this application. maining in the gas turbine exhaust, supplemental fir-
The following brief discussion focuses on the com- ing systems can be installed upstream of the HRSG.
bination of a gas turbine with a heat recovery steam This permits greater operating flexibility, improved
generator and steam turbine. steam temperature control, and higher overall power
capacity. The HRSG can be designed with one to four
Simple combined cycle system separate operating pressure circuits to optimize heat
As shown schematically in Figs. 5a and 5b, the recovery and cycle efficiency. In selected cases, further
simple combined cycle system can consist of a single cycle efficiency gains are possible with the addition of
gas turbine-generator, HRSG, single steam turbine- steam reheat.
generator, condenser, and auxiliary systems. In ad- A range of cycle efficiencies is possible depending upon
dition, if the environmental regulations require, a the complexity of the system and components. Sample
selective catalytic reduction (SCR) system to control overall electrical power generation cycle efficiencies for
emissions of nitrogen oxides (NOx) can be directly in- a system using a gas turbine with a 2200F (1204C) tur-
tegrated within the steam generator. (See Chapter 34.) bine inlet temperature are provided in Table 2. These
This is particularly attractive because the SCR cata- are based upon the fuel higher heating value.
lyst can be positioned in an optimal temperature win- The environmental emissions from combined cycle
dow within the HRSG. The gas temperature leaving systems are generally low. If natural gas is fired, sul-
Water treatment
Industry today is intensely competitive, and a
company’s survival may often depend on uninter-
rupted production. When industrial plants generate
their own power or when steam is required for the
manufacturing process, the availability of the boiler
becomes a very important consideration. Fig. 6 Rapid installation of modular components minimizes schedules.
FGD systems. (See Chapter 35.) Fluidized-bed boil- are some other designs that serve special fuels, capaci-
ers, discussed in Chapter 17, offer an alternative to ties, pressures and temperatures, making them a good
FGD systems. These boilers are capable of achieving alternative under special conditions.
very high SO2 removal rates via limestone addition di- Pre-engineering While the SPB is custom designed
rectly into the combustion process (bed). to meet specific steam and fuel conditions, the design
The combination of FGD systems with efficient par- is done within a framework of pre-engineered compo-
ticulate control has shown the potential for effective nents to minimize engineering costs and delivery time.
control of many HAPs. It is anticipated that the EPA’s The furnace width and depth are pre-engineered
future HAP regulations may require retrofits of these in 1 ft (0.3 m) increments so that all of the closures at
combined controls on most large (new and existing) the corners are established. Drum centerlines, in 2 ft
coal-fired industrial boilers. (0.6 m) increments between 16 and 32 ft (4.9 and 9.8
m), have been pre-engineered to locate all of the ac-
cess doors, sootblower openings, buckstays and plat-
B&W boilers for solid and multi- forms. Combinations of steam and lower drum sizes
fuel applications are designed so that all of the bend angles for drum
Brief descriptions of the boiler types that follow are entry are established.
intended to introduce the types of steam generating These pre-engineered increments allow flexibility
units that meet the wide range of fuel and perfor- in the design to satisfy the job-specific requirements
mance requirements of the industrial sector. of furnace exit gas temperature, burner clearances,
residence time, grate size, gas velocity, convection
Stirling® power boilers surface spacing, etc.
Description The Stirling Power Boiler (SPB) is a top SPB design range
supported, two drum, single gas pass unit. (See Figs. Steam capacity
1 and 2.) In some cases, it is cost effective to replace pulverized coal, oil, gas up to 1,200,000 lb/h
the two drum design with a single drum and a smaller (151.2 kg/s)
shop-assembled boiler module. (See Fig. 4.) stoker coal 150,000 to 400,000 lb/h
The furnace is completely water cooled using mem- (18.9 to 50.4 kg/s)
brane wall construction [normally 3 in. (76.2 mm) tubes stoker wood, bagasse, 180,000 to 600,000 lb/h
on 4 in. (101.6 mm) centers] and is satisfactory for ei- and biomass (22.7 to 75.6 kg/s)
ther pressurized or balanced draft operation. Shop as- Steam pressure to 2200 psig (15.2 MPa)
sembly of wall panels is maximized to facilitate field erec- design
tion. Wall panels always come with the headers attached, Steam temperature to 1000F (538C)
regardless of the number of shipping pieces.
Cyclone steam-water separators, discussed in Chap- Towerpak® boiler
ter 5, along with primary and secondary steam scrub- Description The Towerpak is a version of the SPB
bers, are included in the steam drum to provide the designed for lower capacities that are often required
high quality dry steam needed for present day super- by smaller industrial plants. (See Fig. 9.) It incorpo-
heater and turbine designs. rates many of the features of the SPB including mem-
Furnaces include a nose arch which serves to di- brane walls, cyclone steam-water separators, and stok-
rect gas flow over the superheater section and to shield ers for wood or biomass combustion.
the superheater. Towerpak boilers are one drum or two drum bottom
SPBs are capable of firing solid, liquid or gaseous supported units. For the smaller sizes, they can be
fuels. There are several furnace configurations to shipped in a single unit or in modules for ease of field
complement the type of fuel fired, as shown in Fig. 8. assembly (see Fig. 10). Larger units follow the SPB
A hopper-bottom furnace is used for pulverized coal format of maximum subassembly of wall panels,
firing; a flat floor for gas or oil firing; and an open again for ease of field assembly. This unit is a preferred
bottom to receive a stoker for stoker coal, wood, ba- design at low steam capacity for hard to burn solid
gasse, biomass, refuse-derived fuel (RDF) and as-re- fuels such as wood, biomass and stoker coal.
ceived municipal solid waste (MSW). Pre-engineering Like the SPB, these units are custom
Furnaces for fuels having a significant amount of designed to meet specific conditions for each application,
fines and/or high moisture such as wood, biomass, but within the framework of pre-engineered components.
bagasse and RDF are arranged with an overfire air
system consisting of multiple rows of nozzles. These Towerpak design range
nozzles inject air at various locations above the grate Steam capacity 40,000 to 300,000 lb/h
to provide the turbulence necessary for combustion. (5.0 to 37.8 kg/s)
The SPB is equipped with an economizer and/or air Steam pressure to 1800 psig (12.4 MPa)
heater to provide economical heat recovery. For many design
fuels, air heating is important for combustion. Pulver- Steam temperature to 1000F (538C)
ized coal requires hot air to dry the fuel, and hot air is
required to promote combustion of moist fuels such as Circulating fluidized-bed boiler
wood, bagasse and biomass. Description Fluidized-bed boilers feature a unique
Because of the design features, the SPB is the pre- concept of burning fuel in a bed of particles to control
ferred industrial boiler for many applications. There the combustion process and, when required, control
SO2 and NOx emissions. Two options are offered – the and sulfated limestone particles (limestone is used as
circulating fluidized-bed boiler (CFB) and the bub- a sorbent for SO2 removal). When firing low-ash and
bling fluidized-bed boiler (BFB). (See Figs. 11 and 12.) low-sulfur fuel, additional inert bed material (typically
Both options can be used in new as well as in retrofit sand) may be introduced into the furnace. Compared
applications. Fluidized-bed technologies are discussed to the fuel quantity present in the unit, the circulat-
in depth in Chapter 17. ing bed material is many times greater. Total solids in
The CFB is a top supported boiler. (See Fig. 11.) One the flue gas passing upwards through the furnace are
or two drums are used depending on the need for a a function of how much heat must be absorbed by the
generating bank to absorb heat. Fuel is admitted to the waterwalls.
lower part of the furnace by screws, air-assisted grav- Varying the bed density maintains the desired con-
ity chutes or pneumatic feed, depending on fuels fired stant temperature necessary for maximum SO2 re-
and plant design. moval [about 1550F (843C)]. The B&W Internal Re-
The bed medium is typically composed of fuel ash circulation CFB (IR-CFB) design features a two-stage
Steam Drum ever the bubbling fluidized bed is often a more eco-
nomical choice for these fuels. The CFB, because it
operates at a reduced combustion temperature, inher-
Boiler ently generates about one half the NOx as the other solid
Bank fuel-fired industrial boilers previously described.
The CFB is an alternative to the pulverized coal or
stoker coal-fired SPB which frequently must be
equipped with a wet or dry scrubber (for SO2 removal)
and ammonia injection, catalytic or non-catalytic re-
duction (NOx removal) equipment. The choice of tech-
nologies requires in depth evaluation of a number of
factors including required amount of emissions re-
moval, fuel cost, reagent cost and capital cost.
Pre-engineering The CFB is custom designed to meet
each specific application, but like the SPB, it is designed
within a framework of pre-engineered components to
minimize engineering costs and delivery time.
Burners
In-Furnace
U-Beams U-Beams
Superheater
Steam Drum
PrecisionJet Feedwater
Air System Lower Downcomer to Drum
Drum
Internal
Evaporative
Fuel PrecisionJet Circuit
Chute Air System Multi-Cyclone
Wingwall
Dust
Fuel Bunker Collector
Economizer
Ash
Recycle
System
Air
Heater
Gravimetric
Feeder
Fuel
Chute
Refractory Flue
Line Gas
Fluid Bed
Cooler
Steam Drum
Attemperator
Generating
Bank
Screen
CFB design range
Steam capacity up to 1,500,000 lb/h
(189 kg/s) or greater
Steam pressure to 2850 psig (19.7 MPa)
design
Steam temperature to 1040F (560C)
Economizer
Fig. 19 PFT integral furnace boiler. Fig. 20 Enhanced oil recovery boiler on location.
mounted in one piece for shipment. Larger sizes are High Intermediate Low Stack
Pressure Pressure Pressure
shop-assembled in several sections for final field as- Drum Drum Drum
sembly. Unit capacities are limited by shipping con-
straints and not because of design limitations.
EOR design range (oil and gas) Duct
Burner
Steam capacity up to 250,000 lb/h (31.5 kg/s)
Steam pressure to 2500 psig (17.2 MPa) design Non-Metallic
Expansion
Joint
Once-through HRSG designs are also available. In 2. Steam pressure and temperature – The steam
a once-through design, feedwater is converted directly pressure and temperature are selected to provide
to superheated steam without the need for a drum. an economical design. In general, higher steam
As a result, there is no distinction between economizer, pressures increase system efficiency but can limit
evaporator or superheater surface. The water-to-steam total heat recovery from the flue gas in single pres-
transition point is variable within the unit and is depen- sure HRSGs due to the higher saturation tempera-
dant upon the heat input and mass flow of the water. ture. To overcome this problem, multiple pressure
Most heat recovery steam generators are too large HRSGs are offered. One to four separate pressure
to permit shop assembly of an entire unit. Therefore, sections may be used. The superheater, reheater,
most HRSG components are shop fabricated to the boiler and economizer sections at each pressure are
maximum extent possible and delivered to the site as arranged to reduce overall cost and increase heat
modules. Typically, each module is structurally inde- recovery.
pendent and includes lifting lugs and temporary steel 3. Pinch point and approach temperatures – The
so that field transport and setting is readily accom- pinch point temperature and approach tempera-
plished. Some of the smaller HRSG units can be en- tures have a significant impact on overall unit
tirely shop-assembled and skid mounted. size. They are illustrated in Fig. 23 for a single
Typical parameter ranges for HRSG units are sum- pressure HRSG. Small pinch point and super-
marized in Table 4. heater approach temperatures result in larger heat
Special HRSG designs are also available for en- transfer surfaces and higher capital costs, while
hanced oil recovery applications. The gas turbine ex- the economizer approach temperature is typically
haust gas is used in the HRSG to generate wet steam set to avoid economizer steaming at the design
(approximately 80% quality) at pressures up to 2500 psig point. Experience has generally indicated that the
(17.2 MPa). The steam is injected into wells to enhance following ranges provide economical and techni-
heavy oil recovery. A unique feature is that relatively cally satisfactory designs, although lower values
dirty (up to 10,000 ppm dissolved solids) feedwater is used may be appropriate in specific applications:
in a once-through steam generator design.
Technical considerations The HRSG is basically a
Pinch point = ∆Tp = 20 to 50F (11 to 28C)
counterflow heat exchanger composed of a series of Superheater approach =∆TSH = 40 to 60F (22 to 33C)
superheater, reheater, boiler (or evaporator), and Economizer approach = ∆TE = 10 to 30F (6 to 17C)
economizer sections positioned from gas inlet to gas 4. Stack outlet temperature – As with feedwater tem-
outlet to maximize heat recovery and supply the rated perature, the minimum flue gas exit or stack tem-
steam flow at proper temperature and pressure. To perature needs to be controlled to avoid corrosion
provide the most economical and reliable design, it is due to acid condensation. Typical values are iden-
necessary to evaluate the following: tified in Chapter 20.
1. Allowable back-pressure – Back-pressure is signifi- 5. Load response and cycling requirements – Many
cantly influenced by the HRSG cross-sectional HRSGs today are cycled. That is, they are brought
flow area. Higher back-pressures reduce HRSG up and down in load on a daily basis, thus requir-
cost but also reduce gas turbine efficiency. Back- ing frequent warm-ups and cool-downs. As a re-
pressures are typically 10 to 15 in. wg (2.5 to 3.7
kPa) in most units.
Table 4
HRSG Parameters
Turbine application:
Gas turbine sizes 1 MW to 220 MW
Gas flow 25,000 to 5,000,000 lb/h (0.32 to
630 kg/s)
Gas turbine outlet
temperature ≤ 1200F (≤ 649C)
Supplemental firing
temperature ≤ 1650F (≤ 899C)
Steam flow: 15,000 to 600,000 lb/h (1.9 to 76 kg/s)
Operating pressures:
High ≥400 psig (2.76 MPa)
Intermediate 50 to 400 psig (0.34 to 2.76 MPa)
Low 15 to 50 psig (0.10 to 0.34 MPa)
Steam temperature up to 1005F (541C)
Supplemental fuels #2 oil, natural gas
Fig. 23 Temperature profile in single pressure HRSG.
sult, special consideration must be given to the There are also many smaller refineries that have
thermal and mechanical stresses associated with cracking units in the general range of 12,000 barrels
this type of operation. Pressure parts and their at- (1908 m3) per day or less which produce from 75,000
tachments must be designed in a manner which to 175,000 lb/h (9.5 to 22.1 kg/s) of CO gas. CO boil-
allows them to expand freely. Steaming in the ers for this capacity are often small enough to be shop
economizer is inevitable at off-design points. As a assembled. A shop-assembled boiler modified for CO
result, economizers must incorporate up-flow tube firing is shown in Fig. 24. CO gas is admitted through
circuitry, recirculation lines, steam-water separa- ports in the side walls and front wall to promote mix-
tion equipment in the drum, or gas bypasses. ing and rapid combustion. The burners, for firing
Stack dampers may also be necessary to keep the supplementary fuel, are located in a refractory front
HRSG warm if it is to be brought off line for short wall and fire into a horizontal furnace.
periods of time. The maximum steam requirements of the cracking
6. Emissions – Emission requirements can have a unit may occur at normal, full load operation or dur-
physical impact on the design of an HRSG. De- ing startup of the cracking unit, depending on the
pending on permit requirements and the type of plant steam cycle. The supply of CO is normally not
fuels fired in the duct burner, an SCR or CO cata- sufficient to generate the maximum amount of steam
lyst may be required. In some instances, it may required; supplementary fuel is then needed.
be necessary to have both. The location of either Supplementary fuel is also required to raise the tem-
is driven by temperature (see Chapter 34). There- perature of the CO gases to the ignition point and to
fore, tube banks must be arranged to accommo- assure complete burning of the combustibles in the CO
date the SCR and/or CO catalyst blocks which are gas stream. The following design criteria have been
sized to meet the removal efficiency required at the established:
design conditions specified. It may also be neces-
1. The basic firing rate should produce a tempera-
sary to install a distributor grid upstream of the
ture of 1800F (982C) in the furnace for a suitable
catalyst section to distribute the flue gas evenly
residence to provide safe and stable combustion of
across the catalyst.
the fuels.
2. Air is supplied by the forced draft fan to provide
CO boiler 2% oxygen leaving the unit when burning CO
gases and supplementary fuel.
In the hydrocarbon processing industry, the opera-
3. Supplementary firing equipment is provided
tion of a fluid catalytic cracking (FCC) unit, depend-
which is capable of raising the temperature of the
ing on the FCC arrangement, produces gases rich in
CO gases to 1450F (788C), the temperature
carbon monoxide (CO). To reclaim the thermal energy
needed for ignition of the combustibles.
in these gases, the FCC unit can be designed to in-
clude a CO boiler to generate steam. Because of possible variations in the combustible
For refineries generating large quantities of CO, and oxygen content of the CO gases, the sensible heat
field-erected boilers such as the PFI boiler are used. of the CO gases and the amount of supplementary fir-
ing, it is impractical to set up a fuel-air relationship. Many existing CO boilers have been upgraded to
Consequently, it is necessary to directly determine the handle the new conditions. Changes have included
amount of excess oxygen leaving the unit. This may elimination of combustion zone refractory, use of mem-
be determined intermittently by a portable oxygen braned water walls, and resizing of heat transfer sur-
analyzer, or continuously by an oxygen analyzer or face. (See Fig. 25.) New heat recovery boilers on FCC
combination oxygen-combustible recorder. units are designed for these new process conditions.
Water seal tanks are installed upstream of the CO
boiler to act as shutoff valves in the large gas lines so
that the CO gases from the catalyst regenerator may General waste heat boiler
be passed through the boiler or sent directly to the The progressive increase in the cost of fuel has fos-
stack. This permits independent operation of the CO tered technical progress in the utilization of waste
boiler without interfering with the operation of the re- energy, including specialized designs and applications
generator. Water seal tanks are preferred to mechani- of boilers. There are many industries or processes that
cal shutoff dampers because of the high gas tempera- generate large quantities of high temperature gases
ture, the size of the CO ducts, and the need for leak from which the sensible heat may be extracted for
proof construction. steam generation. Such gases are produced in cata-
The operation of the CO boiler is coordinated with lytic regenerators; blast furnaces; copper reverbera-
that of the catalytic cracker. Normally, the boiler will tory furnaces; annealing, forge and billet heating fur-
be required to supply steam for the operation of the naces; and fired kilns of many types.
catalytic cracking unit and will be started using The heat contained in these exhaust gases can of-
supplementary fuel. The CO boiler should always be ten generate all the steam required for an industrial
started using only the supplementary fuel burners process via properly designed boiler equipment.
and bypassing the gases from the regenerator to the Where the waste gases carry some of the noncombus-
atmosphere. CO gases should not be introduced into tible process material in suspension, suitable hoppers
the boiler until it is brought up to temperature because will collect a portion of the material, and the cooled
these gases usually are at or below 1000F (538C) and, gases leaving the boiler may be passed through dust
consequently, tend to cool the furnace. They ignite collectors to recover the remaining particulate. Many
quite readily and burn with a non-luminous flame. types of boilers are necessary to meet the wide range
As the CO is introduced to the boiler, it is necessary to of requirements in this field. Boiler design depends on
reduce the supplementary fuel and the combustion air. the chemical nature of the gases and their tempera-
This readjustment in the air requirement is deter- ture, pressure, quantity and dust loading.
mined from the oxygen recorder reading.
Because there are only slight variations in the op- Heat transfer from waste gases
eration of the catalytic cracking unit, the CO boiler is
normally base loaded. It handles all the gases from The rate of heat transfer from the gas to the boiler
the regenerator regardless of the carbon dioxide (CO2) water depends on the temperature and thermophysical
to CO ratio. A change in this ratio merely affects the properties of the gases, velocity and direction of flow
quantity of supplementary fuel necessary to maintain over the absorbing surfaces, and the surface cleanli-
the required furnace temperature of 1800F (982C). ness, as discussed in Chapter 4. Temperatures of many
This temperature provides a reasonable operating process gases are relatively low as shown in Table 5.
margin for possible variation in the operation of the To obtain the proper velocity of the gases over the
regenerator or the boiler. Stable operation can be surfaces, a sufficient pressure difference or draft must
maintained at a furnace temperature as low as 1500F be provided, either by a stack or a fan. The draft must
(816C), but the margin above the ignition tempera- overcome the pressure losses caused by the flow of
ture of the CO gas is considerably reduced. gases through the unit, with adequate allowance for
The economics of the CO boiler depend on the normal heating surface fouling.
amount of available heat in the regenerator exhaust The radiation heat transfer component is low and
compared with an equivalent amount of heat from an the tendency is to design many waste heat boilers for
alternate fuel. The heat from the CO gases is calcu- higher gas velocities than prevail on fuel-fired units.
lated by taking the sensible heat above an assumed However, high velocities with dust-laden gases can
boiler stack temperature plus all of the heat from the cause tube erosion, particularly where there are
combustibles. The additional steam generated in the changes in gas flow direction. Therefore, process-spe-
CO boiler by the supplementary fuel is comparable cific velocity limits must be met.
with the steam generated in a conventional power Diagrams A and B, Fig. 26, show the approximate
boiler. Normally, the supplementary fuel requirement convection heating surface required for usual condi-
will account for one fourth to one third of the output tions in waste heat boilers.
when the temperature of the entering CO gas is main- A water-cooled furnace is a feature of some waste
tained at 1000F (538C). heat boiler applications where it is necessary to cool
Changes in FCC catalysts and in process conditions the furnace gases to the temperature required to pre-
have permitted reductions in the CO content of the vent slagging in the following tightly spaced convec-
gases leaving the unit. These changes also result in tion surfaces. The approximate amount of surface re-
the gas temperature to the CO boiler increasing from quired for such furnace applications is given in Dia-
the 1000F (538C) level to as high as 1450F (788C). gram C of Fig. 26.