DRAFT INTERNATIONAL STANDARD ISO/DIS 4628-8 Isortc a5/Sc 9 Secretariat: BSI Voting begins on Voting terminates on 2002-10-03 2003-03-03 Paints and varnishes — Evaluation of degradation of coatings — Designation of quantity and size of defects, and of intensity of uniform changes in appearance — Part 8: Evaluation of corrosion around a scribe Peintures et vernis — Evaluation de la dégradation des revétements — Désignation de la quantité et de la dimension des détauts, et de lintensité des changements uniformes d'aspect — Partie 8: Evaluation de la corrosion autour dune rayure ICs 87.040 1SO/CEN PARALLEL ENQUIRY ‘The CEN Secretary-General has advised the ISO Secretary-General that this ISO/DIS covers a subject of interest to European standardization. In accordance with the SO-lead mode of collaboration as defined in the Vienna Agreement, consultation on this ISO/DIS has the same effect for CEN members as would a CEN enquiry on a draft European Standard, Should this draft bbe accepted. a final draft, established on the basis of comments received, will be submitted to a Parallel two-month FDIS vote in ISO and formal vate in CEN To expedite distribution, this document is circulated as received from the committee secretariat. ISO Central Secretariat work of editing and text composition will be undertaken at Publication stage. Pour accélérer la distribution, le présent document est distribué tel quill est parvenu du secrétariat du comité. Le travail de rédaction et de composition de texte sera effectué au Secrétariat central de I!SO au stade de publication, In accordance with the provisions of Council Resolution 15/1993 this document is circulated in the English language only. | Conformément aux dispositions de la Résolution du Consell 15/199, ce document est | distribué en version anglaise seulement. } Tiils DOCUMENT Is A DRAFT CIRCULATED FOR COMMENT AND APPROVAL. TIS THEREFORE SUBJECT TO CHAN AAS AN INTERNATIONAL STANDARD UNTIL PUBLISHED AS SUCH ANDMAY NOT BE REFERRED 10 IN ADDITION TO THEIR EVALUATION AS BEING ACCEPTARLE FOR INDUS INTERNATIONAL STANDARDS MAY ON QEGASION HAVE TO BE CONSE REFERENCE MAY BE MADE IN NATIONAL REGULATIONS, FRED IN THE Li HE L, COMMERCIAL AND US TOF THEIR POTENTIAL 70 BECO A PURPOSES, ORAF ;ARDS TO WHICH © International Organization for Standardization, 2002ISO/DIS 4628-8 Copyright notice under the applicable laws of the user's country, neither this ISO draft nor any extract from it may be reproduced, stored in a retrieval system or transmitted in any form or by any means, electronic, photocopying, recording or ‘otherwise, without prior written permission being secured. Requests for permission to reproduce should be addressed to either ISO at the address below or ISO's member body in the country of the requester. 1SO copyright office Case postale 56 « CH-1211 Geneva 20 Tel. +4122 7490111 Fax +41 22 749 09 47 E-mail copyright@iso.ch Web www.is0.ch | This ISO document is a Draft International Standard and is copyright-protected by ISO. Except as permitted Reproduction may be subject to royalty payments or a licensing agreement. Violators may be prosecuted. ii 1150 2002 — llrightsreservedISO/DIS 4628-8 Foreword {SO (the International Organization for Standardization) is a worldwide federation of national standards bodies (ISO. member bodies). The work of preparing Intemational Standards is normally carried out through ISO technical committees. Each member body interested in a subject for which a technical committee has been established has the right to be represented on that committee. International organizations, governmental and non-governmental, in liaison with 1SO, also take part in the work. ISO collaborates closely with the Intemational Electrotechnical Commission (IEC) on all matters of electrotechnical standardization, International Standards are drafted in accordance with the rules given in the ISO/IEC Directives, Part 3. The main task of technical committees is to prepare International Standards. Draft Intemational Standards adopted by the technical committees are circulated to the member bodies for voting. Publication as an International ‘Standard requires approval by at least 75 % of the member bodies casting a vote. Attention is drawn to the possibility that some of the elements of this part of ISO 4628 may be the subject of patent rights. ISO shall not be held responsible for identifying any or all such patent rights. ISO 4628-8 was prepared by Technical Committee ISO/TC 35, Paints and vamishes, Subcommittee SC 9, General test methods for paints and varnishes. ISO 4628 consists of the following parts, under the general title Paints and varnishes — Evaluation of degradation of coatings Designation of intensity, quantity and size of common types of defects: Part 1: General introduction and designation system Part 2: Assessment of degree of blistering Part 3: Assessment of degree of rusting Part 4: Assessment of degree of eracking Part 5: Assessment of degree of flaking Part 6: Assessment of degree of chalking by tape method Part 7: Assessment of degree of chalking by velvet method Part &: Assessment of degree of delamination and corrosion around a scribe Part 10: Assessment of degree of filiform corrosion Part 1 of ISO 4628 defines a system for designating the quantity and size of defects and the intensity of uniform ‘changes in appearance of coatings and outlines the general principies of the system. This system is intended to be used, in particular, for defects caused by ageing and weathering, and for uniform changes such as colour changes, for example yellowing. The other parts of ISO 4628 provide pictorial standards or other means for evaluating particular types of defect. As far as possible, already existing evaluation schemes have been used as the basis. 1 1SO 2002 — Allsights reserved itISO/DIS 4628-8 Introduction Alter exposure of a coated and scribed test panel in a corrosive environment, the following phenomena can occur around the scribe: — delamination, — corrosion, or a combination of both It is recommended that delamination and corrosion around the scribe be evaluated separately to obtain more detailed information about the coating system In addition to the procedure described in this standard, assessments of delamination and corrosion around the scribe can be carried out using optical image processing, © 1S 2002 — A rights reservedDRAFT INTERNATIONAL STANDARD ISO/DIS 4628-8 oe Paints and varnishes — Evaluation of degradation of coatings — Designation of quantity and size of defects, and of intensity of uniform changes in appearance — Part 8: Evaluation of corrosion around a scribe 1 Scope This part of ISO 4628 describes a method for assessing delamination and corrosion around a scribe in a coated panel or other coated test specimen, caused by a corrosive environment, NOTE An example of a corrosive environment is salt spray (fog) as used in the test method described in ISO 7253, Paints and varnishes — Detormination of resistance to neutral salt spray (09). 2 Normative references The following standards contain provisions which, through reference in this text, constitute provisions of this part of 'SO 4628. At the time of publication, the editions indicated were valid. All standards are subject to revision, and Parties to agreements based on this part of ISO 4628 are encouraged to investigate the possibility of applying the Most recent editions of the standards indicated below. Members of IEC and ISO maintain registers of currently valid International Standards, ISO 9270:1984, Paints and varnishes and their raw materials — Temperatures and humidities for conditioning and testing. ISO 4628-1:—1, Paints and varnishes — Evaluation of degradation of coatings — Designation of quantity and size defects, and of intensity of uniform changes in appearance — Part 1: General principle and designation system, 1SO 4628-2:—2, Paints and varnishes Evaluation of degradation of coatings Designation of quantity and size of defects, and of intensity of uniform changes in appearance Part 2: Assessment of degree of blistering. 1SO 4628-3:—3, Paints and varnishes — Evaluation of degradation of coatings — Designation of quantity and size of defects, and of intensity of uniform changes in appearance — Part 3: Assessment of degree of rusting. ISO 4628-4:—4, Paints and varnishes — Evaluation of degradation of coatings — Designation of quantity and size of defects, and of intensity of uniform changes in appearance — Part 4: Assessment of degree of cracking. 1 Tobe published. (Revision of ISO 4626-1:1982) To be published, (Revision of ISO 4626-2:1982) > Tobe published, (Revision o ISO 4628-3:1982) To be published. (Revision of ISO 4628-4:1982) (© 180 7002 — Allnghts reserves 1ISO/DIS 4628-8 1SO 4628-5:—5, Paints and varnishes — Evaluation of degradation of coatings — Designation of quantity and size of defects, and of intensity of uniform changes in appearance — Part 5: Assessment of degree of flaking. ISO 4628-10:—8, Paints and varnishes — Evaluation of degradation of coatings — Designation of quantity and size of detects, and of intensity of uniform changes in appearance — Part 10: Assessment of fiform corrosion. 3. Terms and definitions For the purposes of this part of ISO 4628, the following terms and definitions apply 34 delamination loss of adhesion of a coating 3.2 corrosion area of visible corrosion products 4° Principle The delamination around a scribe is assessed either in the wet condition immediately after removal of the test panel from a previous conditioning environment, or after conditioning for a specified period. The corrosion around. the scribe is assessed either in the wet condition immediately after removal of the test panel from a previous conditioning environment, or after removal of the coating. Both the area of delamination and corrosion, is determined either by measurement and calculation, or by using pictorial standards. If required, other defects such as blistering, rusting, cracking, flaking or filiform corrosion are also assessed, using the relevant International Standards. 5 Procedure 5.1 General Where appropriate and unless otherwise specified or agreed, the procedure described in 5.2 and 5.3 shall be used in preference to the assessment using pictorial standards (5.4). 5.2 Measurement and calculation of the area of delamination 5.2.1. Inwet condition Rinse the test panel with fresh tap water immediately after exposure, blow off residues of water from the surface using compressed air if necessary, and inspect for visible changes. Carefully remove the loose coating using knite blade held at an angie, in the manner of an eraser. NOTE If desired, a high pressure system or adhesive may be used instead of a knife blade. It necessary, rinse the test panel again with fresh tap water. Determine the average overall width, in millimetres, of the zone of delamination. To this end, measure the width of the zone of delamination at six points at intervals of about 20 mm and determine the arithmetic mean, Deduct the width of the original scribe from the average overall 5 Tobe published. (Revision of ISO 4628-5: 1982) ® Tobe published. 2 180 2002 — allights reservesISO/DIS 4628-8 width of the zone of delamination. Ignore delamination beyond the beginning and end of the original scribe. Calculate the delamination, D, in milimetres, using Equation 1: wW,-W, a “, _ is the overall width, in millimetres, of the zone of delamination (arithmetic mean); w, is the width, in millimetres, of the original scribe. Where the delamination is uneven, increase the number of measuring points, i.e. bring the measurement points closer together, or state the delamination Da, calculated by Equation 2. Ignore delamination beyond the beginning and end of the original scribe. Determine the size of the area, for example, by counting the corresponding squares of transparent millimetre grid paper laid over the area. (2) where: A, _ is the overall area, in square millimetres, of the zone of delamination; ‘A, is the area, in square millimetres, of the original soribe; 1 is the overall length, in milimetres, of the original scribe. 5.22 After conditioning In some cases, it is of interest to determine to what extent achesion can regenerate itself after drying. To this end, rinse and condition the test panel after exposure. Assess the delamination in the same way as described in 5.2.1, after conditioning for 1 h and again after conditioning for 24h at a temperature of (23 + 2) °C and a relative humidity of (50 * 5) %, as specified in ISO 3270. 5.3 Measurement and calculation of the area of corrosion 5.3.1 In wet condition Rinse the test panel with fresh tap water immediately after exposure, blow off residues of water from the surface using compressed air if necessary, and inspect for visible changes. Carefully remove the loose coating using a knife blade held at an angle, in the manner of an eraser. NOTE If desired, a suitable paint remover or other means, ¢.g. high pressure system or adhesive, may be used instead of a knife blade, lf necessary, rinse the test panel again with fresh tap water. Determine the average overall width, in millimetres, of the zone of corrosion. To this end, measure the width of the zone of corrosion at six points at intervals of about 20 mm and determine the arithmetic mean. Deduct the width of the original scribe from the average overall width of the zone of corrosion. Ignore corrosion beyond the beginning and end of the original scribe. Calculate the corrosion, C, in milimettes, using Equation 3: (3) © 180 2002 — Al nights reserved 3ISO/DIS 4628-8 Ww» is the overall width, in millimetres, of the zone of corrosion (arithmetic mean); i, is the width, in millimetres, of the original scribe. Where the corrosion is uneven, increase the number of measuring points, ic. bring the measurement points closer together, or state the corrosion Ca, calculated by Equation 4. Ignore corrosion beyond the beginning and end of the original scribe. Determine the size of the area, for example, by counting the corresponding squares of transparent millimetre grid paper laid over the area (4) where: A, _ isthe overall area, in square millimetres, of the zone of corrosion; A, _ isthe area, in square millimetres, of the onginal scribe; 1 isthe overall tength, in millimetres, of the original scribe, 5.3.2. Evaluation of corrosion on stripped test panels 2) Remove the coating carefully from the test panel with a suitable paint remover that will not exacerbate the corrosion. Rinse the test panel rapidly with clean tap water, blow dry with compressed air and immediately coat completely with clear coating material, an aerosol lacquer is suitable. Rate the zone of corrosion according to the pictorial standards, or if possible, measure the area, in square millimetres, using optical image processing, Note any etched areas, which appear bright. 5.4 Assessment using pictorial standards If specified or agreed, assess the area of delamination and corrosion using the pictorial standards given in figure 1 ‘These pictorial standards are based on the rating system defined in ISO 4628-1 The numerical rating shall be given as indicated in the following example: Delamination and corrosion around a scribe; grade 3. 5.5 Assessment of other defects It required, assess blistering in accordance with 1SO 4628-2, rusting in accordance with ISO 4628-3, cracking in accordance with ISO 4628-4, flaking in accordance with ISO 4628-5 or filform corrosion in accordance with ISO 4628-10, 6 Test report The test report shall contain at least the following information: a) a reference to this part of !S0 4628 (ISO 4628-8) b) all detaiis necessary to identify the coating examined; ©) a description of the corrosive environment; d) whether the coating was removed or not; €) the result(s) of the test, as indicated in clause 5: 4 (150 2002 — Allrights reservedISO/DIS 4628-8 1) any particular observation; 9) any deviation from the procedure specified; fh) the date of the examination ©1SO 2002 — All rights reserved 5ISOIDIS 4628-8 re ee 1—Very slight OR ACI te ITO CAD 2—Slight 3 — Moderate 4— Considerable —Severe Figure 1 - Pictorial standards for assessment of corrosion around a scribe (approximate scale 1:1) 2002 — All ights reservedEXPLANATORY REPORT RAPPORT EXPLICATIF TSO/CD 4628-8 isortc 035 isc 09 secrotanat BST This form should be sent to the ISO Central Ce formulaire doit ee envoye au Secrétariat central de FSO en Secretariat. together with the English and French _méme temps que les versions anglaise et francaise du projet de comité, versions of the committee draft, by the secrotanat of parle secrétarat du comité technique ou du Sous-comité concemné the technical committee or subcommittee concemed, The accompanying document is submitted for Le document cijoint est soumis, pour diffusion comme DIS, au vote circulation to member body vote as a DIS, following _comité membre, suite au consensus des membres (P) du comité Consensus obtained from the P-members of the obtenu comioe 2002-04 Bl itumonu 10107 02 Vorressiuton ne WL angie. document N 1545 by posal bat inated on Fe sarunvote pa conespondence démaréle 2000-06-19 Number Counties P-members in favour: Membres (P) approuvant le projet: 16 UK, Australia, Belgium, China, Czech Rep., Grmany, Israel, Italy, Korea, Netherlands, Poland, Portugal, South Africa, Spain, Sweden, USA P-members voting against 0 Membres (P) désapprowvant: P-mombers abstaining: Membres (P) s'abstenant P-mambers who did not vote: 6 ae caer eer vee Denmark, France, Japan, Norway, Romania, Russian Federation Romarks/Remarques The CD ballot was completed 2000-11-30. Comments were discussed and actions agreed at the Pittsburgh meeting of ISO/TC 35/SC 9/WG 26, June 2001. | hereby contirm that this draft meets the requirements of part 2 of the ISO/IEC Directives Je confirme que ce projet satisait aux prescriptions de la partie 2 des Directives |SOICEI Date Name and signature of the secretary Nom et signature du secrétaire 2002-06-28 Berend Sesbed — Bernard Shelley FORM § & (/S0) FORMULAIRE 8 4 (180)