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Zirconia Restorations:: Evolution and Innovation
Zirconia Restorations:: Evolution and Innovation
Zirconia Restorations:: Evolution and Innovation
R E S TO R AT I O N S :
EVOLUTION
A N D I N N O VAT I O N
By Dennis J. Fasbinder, D.D.S.
Z I R C O N I A R E S T O R AT I O N S : E V O L U T I O N A N D I N N O VAT I O N
CONTENTS
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A L L C O N T E N T S © 2 0 2 0 S P E A R E D U C AT I O N
Introduction
Zirconia Mircostructure
Monolithic Restorations
Strength
Esthetics
Conclusion
References
About Spear
INTRODUCTION
Interest in ceramic materials has While there is a wide range of
continued to increase over the past material options available for crowns,
few decades as higher strength a survey of more than 1,700 dentists
ceramics have afforded expanded in the National Dental Practice-Based
clinical applications. Optimal goals Research Network indicated that
for ceramic materials would be monolithic zirconia is the most
to deliver superior esthetics, common choice of material for a
with predictable, cost effective posterior crown. (Makhija et al 2016)
fabrication, and long-term durability. Several factors were suggested as
influencing the shift toward monolithic
Glass ceramic materials have zirconia crowns, including increased
consistently provided enamel-like patient demand for esthetic
appearance; however, they are also restorations, the cost effectiveness
brittle materials. Clinical research of zirconia, and that zirconia has
has consistently reported that the significantly greater strength than
primary failure mechanism of glass glass ceramic materials and offers the
ceramics is chipping and fracture. additional advantage of allowing for
(Pjetursson, 2007) more conservative tooth preparations.
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ZIRCONIA MICROSTRUCTURE
The tetragonal phase accounts for the It generally requires a porcelain veneer
high strength properties of 3 mol% to create the desired esthetic outcomes.
zirconia. As a result of externally applied Examples of these include: Lava
stresses, such as a crack initiation, the Zirconia (3M), BruxZir (Glidewell), Cercon
energy at the leading edge of the crack (Dentsply Sirona), and IPS e.max ZirCAD
causes the tetragonal crystals to locally MT (Ivoclar Vivadent). (Zhang 2018)
phase shift to monoclinic crystals.
The challenge for manufacturers of 3
The monoclinic crystals are volumetrically mol% zirconia was to improve the
larger than the tetragonal crystals and esthetic appearance of the material
this expansion results in a localized while maintaining the desired high
compressive force applied to the leading strength properties. This fostered the
edge of the crack. The compressive introduction of “anterior zirconia” or
forces essentially prevent the crack “translucent zirconia.” Development
from propagating. This t > m of translucent zirconia has included
transformation, or transformation techniques such as increasing the
toughening, is a major contributor to amount of yttria, reducing the c
the high strength of zirconia and its oncentration of alumina, eliminating
ability to resist fracture under loading. porosity by sintering at higher
temperatures, reducing the crystalline
While the term “full contour zirconia” grain size, and increasing the amount
is often used to describe a monolithic, of cubic phase in the material.
high strength, tooth-colored material, (Zhang 2018)
there is considerable variation in
zirconia. The original zirconia materials
introduced prior to ~2014 were 3 mol%
that were 90%-100% tetragonal
polycrystals and had very high strength
The challenge for manufacturers
properties. However, it tends to be
relatively opaque, with a high value, of 3 mol% zirconia was to improve
and less esthetic than glass ceramics
the esthetic appearance of the
for matching natural tooth structure.
material while maintaining the
desired high strength properties.
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Two early initiatives to improve
translucency of these materials were
to significantly reduce the amount
of alumina dopant added and
reducing porosity by sintering
at higher temperatures. These
improvements paved the way for
monolithic full-contour zirconia
restorations. Material examples of
this were Lava Plus (3M), Vita YZ
HT (Vita), BruxZir Full Strength
(Glidewell), Katana HT/ML (Kuraray
Noritake), and InCoris TZI (Dentsply
Sirona). (Zhang 2018)
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As the composition of zirconia At this point, one may be thinking
materials has evolved, it can be helpful that this may be more information on
to consider some sort of general zirconia structure than really needed.
classification system to provide a basis This categorization obviously reveals
to understand differences in materials. the changing physical properties of
One simple categorization of zirconia different types of zirconia is directly
materials is based on the mol% of related due to the different proportions
yttria. (Burgess 2018) 3 mol% zirconia of the polycrystalline phase. There can
are the early zirconia materials that be considerable variation in material
are 85-90% tetragonal phase with properties within each category as
flexural strengths in excess of 1100 yttria is actually measured in tenths
MPa. They are also relatively opaque of a mole percent.
with a high value that limits the
esthetic applications. However, the trend in improving the
translucency of the zirconia is evident
4 mol% zirconia has about 25% cubic moving from 3 mol% to 5 mol%. A
phase with improved translucency similar trend is also noted in the
and flexural strengths in the 750-900 decreasing physical strength properties
MPa range. 5 mol% zirconia has about from 3 mol% to 5 mol% zirconia.
50% cubic phase with significantly
increased translucency. The flexural
strength is further decreased to the
650-800 MPa range.
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STRENGTH
In essence, strength is a conditional While the small sample size from each
property, meaning it depends on an dental laboratory was not statistically
adequate thickness or volume to have significant, the results lend credence
the reported strength. Use of the to the importance of material and
material without regard to its processing relative to expected
recommended dimensional thickness strengths of zirconia materials.
does not ensure the expected level of
material strength and may compromise
the clinical outcome.
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ESTHETICS
Translucency of ceramic materials has These results are consistent with the
been well documented in laboratory general perception that zirconia is
studies. One study measured the a more opaque material than glass
translucency of zirconia core materials ceramics at the same thickness. But
compared to lithium disilicate ceramic ceramic materials are recommended
in equal thicknesses. The translucency to be 1.5 mm thick occlusally while
of zirconia copings was significantly zirconia materials are recommended to
less than that of the lithium disilicate be 1.0 mm thick occlusally. The authors
glass-ceramic control as one would noted that at clinically recommended
expect of 3 mol% zirconia. thicknesses, the translucency parameters
(Balidissar 2010) of the translucent zirconia materials
were not only similar to those of the
A more recent study compared the lithium disilicate ceramic material but
translucency of lithium disilicate also comparable to the translucency
ceramic (IPS e.max CAD HT) to four parameters reported for 1.0 mm of
different high translucency zirconia in dentin or enamel.
0.5 mm, 1.0 mm, 1.5 mm, and 2.0 mm
thick specimens. (Church 2017) Lithium
disilicate had significantly higher
translucency than translucent zirconia
materials at similar thickness. The
translucencies of the zirconia materials
were fairly similar at each thickness,
however translucency significantly
decreased for each zirconia material
at each increase in thickness.
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Z I R C O N I A S U R FA C E W E A R
A second point of view holds that A second aspect of the surface finishing
even if the surface of the zirconia is is concerning an occlusal adjustment of
polished, it will also wear, resulting in a zirconia crown post-cementation. Any
the same surface profile as if the glaze adjustment to the occlusal surface of
were applied and degraded during the zirconia must be repolished to
function. However, zirconia is relatively return the smooth surface to the
resistant to wear due to its high restoration. Failure to do so may result
fracture toughness. in abrasive wear of the opposing
dentition. (Sabrah 2013, Chong 2015)
Surface wear of materials generally
involve some degree of degradation Most of the evidence for the wear
of the material as it is slowly worn caused by zirconia is a result of
down through microfractures of the laboratory studies with simulated
material surface. Zirconia has a high occlusal function systems. One recent
fracture toughness, preventing these systematic review of clinical studies
microfractures of the surface, and related to the antagonist enamel wear
thereby maintaining its rough and of monolithic zirconia posterior crowns
potentially abrasive surface once the included five clinical studies after review
glaze has been worn away. of 198 potential publications. (Gou 2019)
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CONCLUSION
The evolution of full contour zirconia
illustrates the continued effort to
improve the material for expanding
clinical applications. The high strength
properties of the initial 3 mol% zirconia
are very desirable to clinicians since it
prevents the most common failure of
glass ceramics: chipping and fracture.
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REFERENCES
Pjetursson BE, Sailer I, Zwahlen M, Hämmerle Zhang Y and Lawn BR. Novel Zirconia Materials
CHF. A systematic review of the survival and in Dentistry. Journal of Dental Research 2018
complication rates of all-ceramic and Vol. 97(2) 140–147.
metal-ceramic reconstructions after an
observation period of at least 3 years. Part I:
Single Crowns. Clin Oral Implants Res 2007 Pittayachawan P, McDonald A, Young A,
Jun;18 Suppl 3:73-85. doi: 10.1111/j.1600- Knowles JC. Flexural strength, fatigue life, and
0501.2007.01467. stress-induced phase transformation study of
Y-TZP dental ceramic. J Biomed Mater Res B
Appl Biomater 2009 88:366–77.
Makhija SK, Lawson NC, Gilbert GH, Litaker
MS, McClelland JA, Louis DR. Dentist material
selection for single-unit crowns: Findings from Zhang F, Inokoshi M, Batuk M, Hadermann
the National Dental Practice-Based Research J, Naert I, VanMeerbeek B, Vleugels J. 2016.
Network. J Dent 2016;55:40-7. Strength, toughness and aging stability of
highly-translucent Y-TZP ceramics for dental
restorations. Dent Mater. 32:e327–e337.
Sailer I, Makarov NA, Thoma DS, Zwahlen
M, Pjetursson BE. All-ceramic or metal-
ceramic tooth-supported fixed dental McLaren EA, Lawson N, Choi J, Kang J,
prostheses (FDPs)? A systematic review of Trujillo C. New high-translucent cubic-
the survival and complication rates. Part I: phase–containing zirconia: clinical and
Single crowns (SCs). Dent Mater. laboratory considerations and the effect of
2015 Jun;31(6):603-23. doi: 10.1016/ air abrasion on strength Compend Contin
j.dental.2015.02.011. Educ Dent. 2017 Jun;38(6):e13-e16.
Lawson NC, Burgess JO. Dental ceramics: a Burgess JO. Zirconia: the material, its evolution,
current review. Compend Contin Educ Dent and composition. Compendium Oct 2018, Vol
2014 35(3):161-166. 39, Spec issue 4, pgs 4-8.
Helvey GA. What is in your zirconia? Kontonasaki E, Rigos AE, Ilia C, Istantsos T.
Compendium Apr 2017, 38(4): 213-217. Monolithic zirconia: An update to current
knowledge. optical properties, wear, and
clinical performance. Dent J. 2019 Sep
2;7(3):90. doi: 10.3390/dj7030090.
Z I R C O N I A R E S T O R AT I O N S : E V O L U T I O N A N D I N N O VAT I O N
Sulaiman TA, Abdulmajeed AA, Donovan Park JH, Park S, Lee K, et al. Antagonist
TE, et al. Optical properties and light wear of three CAD/ CAM anatomic
irradiance of monolithic zirconia at variable contour zirconia ceramics. J Prosthet Dent
thicknesses. Dent Mater. 2015;31(10):1180-1187. 2014;111:20-29.
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ABOUT THE
AUTHOR
Dr. Fasbinder is currently the Director
of the Computerised Dentistry
Program and a clinical professor
in the Department of Cardiology,
Restorative Sciences and Endodontics,
University of Michigan, School of
Dentistry. He is board certified in
general dentistry and maintains a
part-time private practice in Ann
Arbor, Michigan.
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