Gases Ideales

Para hallar volumen

molar (cc/mol) 3741.3
P (Bar) 10
T (K°) 450
R ((bar* cc)(mol*K°)) 83.140

Ecuación Virial 2 términos

B (cc/mol) -140 5.4424791047677
V0 3741.3
Vi+1 3601.3 3595.85752089523
Z 0.961063826300794

Ecuación Virial 3 términos

B (cc/mol) -388 47.5304942054809
C ( cc/mol)^2 -26000
V0 3741.3
Vi+1 3346.35054392858 3298.8200497231
Z 0.879712060380472

FLUIDOS NO POLARES
Temp. Red (Tr) K° Presion Red. (Pr) Bar B°
0.838301043 0.193236714975845 -0.476593215380027

Factor de Comprensibilidad
Z 0.885795022242233
 DATOS

Pc 51.75
Tc 536.8

% ERROR
0.220133208525112 0.008917800866129 0.00036129142 1.463722083E-05 5.930069165E-07

3595.63738768671 3595.62846988584 3595.62810859 3595.628093957 3595.628093364

% ERROR
6.50236167708044 0.904433802187214 0.12608915557 0.017583985044 0.002452314714

 BP
3292.31768804602 3291.41325424383 3291.28716509 3291.269581103 3291.267128789 
 c
  B º  wB1
 BP  Pr  RTc 
z  1   c 
 RTc  Tr 0,422
S B º  0,083  1, 6
B1 Factor Pitzer (w)
Tr
-0.221784955233672 0.085

Volumen Real Pitzer

Vol. (cc) 3314.0249167
 RT  B C
vi 1  1   2 
P  vi vi 
2.4024757295E-08 9.73159330897033E-10 3.95630195271224E-11

3595.62809334017 3595.6280933392 3595.62809333916

0.0003420092066 4.76979553241108E-05 6.65214656692115E-06 9.27734618017E-07

 BPc 3291.2667867793 1 3291.26673908134 3291.26673242919 3291.26673150146

   B º  wB
 RTc 
0,422 0,172
B º  0,083  1, 6 B1  0,139  4, 2
Tr Tr
1.29385625769E-07

3291.26673137207
 Constantes Vanderwalls Para Calculo Z
A* 3.6057666796875
B* 0.9245
a 159513570.220992
b 1537.2586
Pc (bar) 2.5
Tc (K°) 369.8
R((bar* cc)(mol*K°)) 83.14
P (bar) 16
T(K°) 320
Coeficiente 1 1
Coeficiente 2 -1.9245
Coeficiente 3 3.6057666796875
Coeficiente 4 -3.33353129537109
Z 1.21497
MASA MOLECULAR 44.1
Videal(cc/mol) 1662.8
Vg(cc/mol) 2020.252116
V*(cc/mol) 26604.8
ENTALPIA RESIDUAL
TERM1 5719.233856
TERM2 -78957.2593230697
h-h*(cc*bar/mol) -73238.0254670697
h-h*(J/mol) -7323.80254670697
ENTROPIA RESIDUAL
TERM1 -118.971208571106
TERM2 -214.324056687336
s-s*(bar*cc/mol*K) -333.295265258443
s-s*(J/mol*K) -33.3295265258443
s-s*(J/g*K)(RESIDUAL) -0.755771576549757
 Constantes Redlich-Kwong Para Calculo Z
A* 0.747267040362995
B* 0.17261866567658
a 8188216.32429398
b 57.140560413913
Pc (bar) 46
Tc (K°) 364.9
R((bar* cc)(mol*K°)) 83.14
P (bar) 100
T(K°) 398.15
Coeficiente 1 1
Coeficiente 2 -1
Coeficiente 3 0.544851170946452
Coeficiente 4 -0.128992239411548
MASA MOLECULAR 42.081
V ideal(cc/mol) 331.02191
Z 0.43
Vg (cc/mol) 142.3394213
V*(cc/mol) 33102.191
term1 -72545.264272429 ENTALPIA RESIDUAL
term2 -41047.8096796561
term3 22200.739833803
h-h*(bar*cc/mol) -91392.3341182821
h-h*(J/mol) -9139.23341182822
h-h*(J/g)(RESIDUAL) -217.181944626511
term1 -42.6696455881598 ENTROPIA RESIDUAL
term2 -60.7352875988355
term3 -453.041520907337
s-s*(bar*cc/mol*K) -556.446454094332
s-s*(J/mol*K) -55.6446454094332
s-s*(J/g*K)(RESIDUAL) -1.32232231670904
Pr 2.17391304347826 METODO LEE-KESSLER
Tr 1.09112085502878
W 0.144
((h^R)R*Tc)^0 -3.0325 ENTALPIA RESIDUAL
((h^R)R*Tc)^1 -1.4186
h^R/RTc -3.2367784
h^R(J/g)(RESIDUAL) -233.351608632453
DESVIACION(h*-h) 233.351608632453
(s^R/R)^0 -2.10205 ENTROPIA RESIDUAL
(s^R/R)^1 -1.3847
s^R/R -6.90661698598809
S^R(J/mol*K) -57.421613621505
S^R(J/g*K) -1.36454964524382
DESVIACION(S*-S)(J/g*K) 1.36454964524382
 Constantes Soave Redlich-Kwong para calculo Z
A* 0.146768239077079
B* 0.019971380354267
a 20543628.4330966
b 74.7189253194203
Pc (bar) 51.75
Tc (K°) 536.8
R((bar* cc)(mol*K°)) 83.14
P (bar) 10
T(K°) 450
Fw 1.390936416
w 0.622
Coeficiente 1 1
Coeficiente 2 -1
Coeficiente 3 0.126398002689557
Coeficiente 4 -0.002931164326534

ENTALPIA RESIDUAL

ENTROPIA RESIDUAL

ENTALPIA RESIDUAL

ENTROPIA RESIDUAL
 Constantes Peng Robinson para calculo Z NAKAMURA
A* 0.153180160777729 ξ
B* 0.017933672571122 b
a 21441125.9965243 a
b 67.0952491903382 c (L/mol)
Pc (bar) 51.75 ϒ (adimensional)
Tc (K°) 536.8 δ (K^-1)
R((bar* cc)(mol*K°)) 83.14 β atm*K*(lt/mol)^2
P (bar) 10 α atm*(lt/mol)^2
T(K°) 450 Vo (L)
Fw 1.22949799072 P (atm)
w 0.622 T (K)
Coeficiente 1 1 R (atm*L)/(K*mol)
Coeficiente 2 -0.982066327428878 Función ξ
Coeficiente 3 0.11634796579982 Vi+1
Coeficiente 4 -0.00241969846888 %Error
Z
NAKAMURA
0.005874610388 0.00644952 0.00651082 0.00651741 0.00651812 0.0065182 0.00651821 0.00651821
0.025708527654
5.351286829781
0.01
1.5589
5.93E-05
1161.7
3.1307
1.094052454371
39.21046
523.15
0.082
1.023847234956 1.02621892 1.0264722 1.02649945 1.02650238 1.0265027 1.02650273 1.02650274
0.996528886248 0.98714658 0.98614789 0.98604048 0.98602892 0.98602768 0.98602754 0.98602753
-0.09752356812 -0.00938231 -0.00099869 -0.0001074 -1.1564E-05 -1.2451E-06 -1.3407E-07 -1.4437E-08
0.901262930257