DATE: 19-12-2018

COURSE JEE-MAIN MOCK TEST-12 TEST CODE

NUCLEUS XII 1 1 3 0 1

Q.No. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15
Ans 3 4 3 2 1 2 3 4 2 3 2 2 1 1 3
Q.No. 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30
Ans 2 1 1 2 2 3 4 3 2 3 4 1 2 3 2
Q.No. 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
Ans 3 1 3 3 4 1 3 3 2 4 3 3 2 2 2
Q.No. 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60
Ans 4 1 4 1 2 2 1 3 1 1 2 1 1 2 4
IOC OC PC IOC OC PC IOC OC PC IOC OC PC IOC OC PC
Q.No. 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75
Ans 4 2 3 4 1 2 1 4 3 2 3 4 2 3 2
IOC OC PC IOC OC PC IOC OC PC IOC OC PC IOC OC PC
Q.No. 76 77 78 79 80 81 82 83 84 85 86 87 88 89 90
Ans 1 2 4 1 3 1 4 2 2 4 4 3 4 2 2

HINTS & SOLUTIONS

M AT H E M AT I C S If x = 1
100 (4)99 · (6) = a1 + 2a2 + ........... +
Q.1 Let x + 1 = t
300
1
300 · a300 =  r ·ar ........ (2)
 (t  1) · lnt dt r 0
0
4100 = a0 + a1 + ......... + a300 = k ....... (3)
1 By equation (2) & (3)
 t2  1
t 
=   t  · lnt
2      1 dt 300
  0 0
2  150 · k =  r ·ar
r 0
1
t2  3
= 0 –   t = a tan  1 
 4 0 4 Q.4 = = =
a sec   a 3 3
Q.2 Each diagonal element of matrix A has three B (a sec , a tan )(2a , 3a )
choices.
A 30°
Q.3 (1 + x + x2 + x3)100 (– a, o)
= a0 + a1x + a2 x2 + .......... + a300· x300 .......(1)
By differentiating both side C (– a sec , a tan ) 
100 · (1 + x + x2 + x3 )99 · (1 + 2x + 3x2)
= a1 + 2a2 x + ............ + 300 · a300. x299
XII MT-12 [JEE Main] Page # 1
 Q.11 y = ax3 + bx2 + cx + 5
 3a 
2
Now, AB = ( 2a  a ) 2  0 = – 8a + 4b – 2c + 5 .............. (1)
y' = 3ax2 + 2bx + c
= 12a 2 = 2 3a 0 = 12a – 4b + c .............. (2)
[ parallel to x-axis]
Q.5 sec2 ((n (m + 2)) = 1 – (m + 1)2 and 3 = 3a (0) + 2b (0) + c .............. (3)
only possible value of m = – 1 [ intersect y-axis]
 sec2 ( n ) = 1 by equation (1), (2) and (3)
n=0 1 3
 A ( – 1, – 2) a=  and b = 
2 4
So, straight line passing through
A (– 1, – 2) and with slpoe m = 2 is 1 3
So, a – 2b =   2  = 1
y + 2 = 2(x + 1) 2 4
y = 2x

Q.6 g' (0) = 1, g'' (0) = 0, g''' (0) = – 2018

Q.12 g (x) =   sin x  2x  4) dx
= – cos x + x2 – 4x + 5 ( g (1) = 3)
= (x – 2)2 + ( 1 – cos x)
z1

10 b
3
b 2 1   x 2 
  bx 
 x    dx
 z  2
r=1   Q.13 Area =
Q.7  z 
  0   b 

b2
 
= 2

6C 6 b2  1
Q.8 1 odd 5 even 1 × 26
3 odd 3 even 6 C3 × 26
5 odd 1 even 6C × 26
5
————————
= (6C1 + 6C3 + 6C5) · 26= 32 × 26 = 211
(0, 0) 1 
 ,0
Q.9 Prime number = 2, 3, 5, 7 b 
Total outcomes
b2
= 2 · · · · · · · · · = 49 = 218 Let f (b) =  f (b)max at b = ± 1
6 (b 2  1) 2
favourable out comes
= 2 · 2 · 2 · 2 · 2 · Q.14 Equation of tangent
25 1 dy
Requried probability = 18 = 13 = 25 y – y1 = (x – 0)
2 2 dx
dy
y = y1 + x ........(1)
4 b 2 9 a dx
Q.10 Lim f ( x ) = e 2b = e3
x0  y1  0   dx 
Now,     = – 1
 4b2 – 6b – 9a = 0  b  R  0 1   dy 
1
D0a
4

XII MT-12 [JEE Main] Page # 2

 4
x2 + 1 +  4 and 4 cos2   [0, 4]
p (o, y)
x 12
90°
4
So, x2 + 1 =
x2 1
 x = ± 1 and cos  = 1
So, x cos  = ± 1
Q (1, 0)

Q.19 xî  yˆj · 6ˆj  4î  xî  yˆj = 3

x2 + y2 – 4x + 6y – 3 = 0
dx
y1 = .......... (2) centre (2, – 3), r = 4  9  3 = 4
dy
By equation (1) and (2)


So, | r  2î  3 ĵ |max = 2 2  13 . 
2
dy  dy 
 y  x  = 1
(  2)  (12)12
4
12
dx  dx  Q.20
3
  1 [  – 6 =  ]
( )
12 

Q.15 xî  yˆj · (xî  yˆj  8î  10ˆj)  41 = 0 = [3 – 8 – 6 ( – 2) ]4

= [[2 – 6 + 12] – 8]4 = 84
x2 + y2 + 8x – 10y + 41 = 0 So, ab may be 212, 46, 84 etc.
centre (– 4, 5), r = 16  25  41 = 0 So, (a + b)min = 4 + 6 = 10
2
So, minimum value of  4î  5 ĵ  2î  3 ĵ Q.21 At  = 1, radical axis of circles are parallel.

 
2
2
=  2î  2 ĵ 1
= 44 =8 Q.22 AA– 1 = [ A 2  9 A  A 3 ]
10
10I = A2 + 9A – A3
After solving above  = 2
Lim

tan x  sin tan 1 (tan x ) 
Q.16
x
 tan x  cos 2 (tan x )
2  7!   8!  2
Q.23   3!· 3!   3!· 3! = (7!)
cot h  cos h  4!· 3!   4!· 4!· 2!  16
= Lim =1
h 0 cot h  cos 2 (cot h )
Q.24 f ' (x) = 6x2 – 6 · 2 2 × sin2  + 6 sin2 
D0
2
Q.17 5 + 2sin x – sin2x = 1 + 5sec y
 36 · 8 · sin4  – 4 · 6 · 6 sin2   0
2  sin2  (2sin2  – 1)  0
 (sin x – 1)2 = (5 – 5sec y )
1
 sin x = 1 and sec y = 1  sin2  
2

So, (x + y)min = .
2 Q.25 One of its period is 3.
25 3

Q.18 4 cos2  =
x 4  2x 2  1
 2
4 So that  f (x ) dx = 10  f (x ) dx = 50.
x 1
2
x 1 15 0

4
4 cos2  = (x2 + 1) +
( x  1)
2
XII MT-12 [JEE Main] Page # 3
 2x  5x Q.34 Pressure difference between lungs of student
Q.26 Equation of tangents are y= and y= and atmosphere
5 2
= (760 – 750) mm of Hg = 1cm of
Here, m1m2 = – 1.
Hg = 13.6 cm of water
Hence h = 13.6 cm.
Q.27 Let x1 > x2 > x3 > x4 ................... > x20
x10  x11 Q.35 No friction is required for pure rolling of ring.
Median =
2
x1 – 3, x2 – 3, x3 – 3,.............., x10 – 3, x11  
Q.36 v I, L  m 2 ( v O , L )
+ 5, x12 + 5, ......., x20 + 5
 0 – (–vL) = n2 (vO – (–vL))
x10  3  x11  5 x10  x11
Median = = +1 vL
2 2 vO

Q.28 | z + 1 – 2i | = 3 O
Centre C1 (– 1, 2), r1 = 3
| z – 2 – 6i | = 2 screen (fixed)
Centre C2 (2, 6), r2 = 2
 C1C2 = r1 + r2 = 5 1 n2 
 vO =  2  v L towards screen
 n 
Q.29
Q.37 Applying Snell's law at O and P
x 1 × sin 90° = n(y) sin 
Q.30 tan  = = 1
x R
 = 45°.  n(y) = cosec  =
Ry
 y

R
R-y
x 
P
y 
 x
tan  x O

P H YS I C S
Q.38 Let v be the velocity of the particle at point B.
tan 60 YB
Q.31 = Y  YB = 3YA Applying conservation of mechanical energyat
tan 30 A point A and B, we have
GMm GMm 1
Q.32 From kinematics and symmetry in vertical    mv B 2
ascent and descent motion of the ball, 2R R 2

2h 2h / 2 t GM
required time =  = t  vB 
g g 2 R

Intensity of magnetisation (I)

Q.33 ( ) 
Magnetizing field (H )
or, I =  H

XII MT-12 [JEE Main] Page # 4

 A V R
u=0
R
B i
M C
v V

R C i

2V 2R
D
V – VC – iR – V = 0
GM
Thereafter v  = constant  |VC| = iR =
V
R 3
 
( inside shell, Fg  mE g  0 )
K.E max
2R Q.43 eV0 = K.Emax  V0 =
 tBD = e
v
Q.44   = 0e–t  5 = 10e–(100 × 2)
Q.39 I1 = I and I2 = 4I
ln 2 0  2  1
 Inet = I1 + I2 + 2 I1I 2 cos    = and Q.F. = =  .
200 2  T  2
 IA = I + 4I = 5I ( A = /2)
& IB = I + 4I – 2 4I . I  I ( B = )
2GM 2gR 2
Q.45 v e  Escape velocity (from height h )  
 IA – IB = 4I Rh Rh
 vsatellite > ve  it escapes earth's gravity
T(say) 2T T/2 along a hyperbolic path.
Q.40
aA A aB B aC C Q.46 For concave mirror
  T fu
T . a  0  – TaaA – 2TaB – aC = 0 v= = – 1100 cm
2 u f
 2aA + 4aB + aC = 0  I1 is 100 cm left of A

S1 S2 S3 100m
+ I1 45°
E=0 +
E=0 A
+ 100m
Q.41 +
+ I2

 I2 will be formed as shown

4 0 bd
Ceq = C between S2 & S3  Q.47 The circuit can be redrown as shown in the
db
figure
Q.42 In a steady state no current will pass through R
P
the capacitor. In the outer loop
R Req
V
2V – 2iR – iR – V = 0  i = Q
3R R
For the upper loop,

XII MT-12 [JEE Main] Page # 5

 (2R  R eq )R y
v0
 Req = R  (2R  R )
eq B 
 R2 eq + (2R) Req – 2R2 =0 t=t

 Req = ( 3 – 1)R 0
t=0
x

Hence velocity of particle at time t would be

Q.48 Wnet = (Q)cycle = 10 + 15 – 10 = 15 J 
v  v 0 cos î  v 0 sin ĵ
Qin = 10 + 15 = 25 J 
or v  v 0 cos(B0t )î  v 0 sin(B0 t ) ĵ
15
   100 = 60%
25 Q.52 U = 8x2 – 4x4
dU
Q.49 ar = a sin 37° = 3m/s2 .  16 x  16 x 3  0
dx
v 2 25  x = 1, 0  positions of equilibrium
Also, r   m
ar 3  x = 0 is stable equilibrium position
Y  d2U 
  0 
ar v  dx 2 
a  
37°
 dU
X  F  16 x 3  16 x  – 16 x
dx
(for small x).
Q.50 Capacitance per unit length is given by
 2 0 16
C     8 rad/sec
V ln (D 2 / D1 ) 2
where  = charge per unit length
Q.53 The minimum length of transmitting antenna is
 
E core    1c
2 0 rcore  0 D1 lmin =   75m
4 4f
2V
= D ln (D / D ) Q.54 I = Imax (1 – e–t/)
1 2 1
dI
dE core D2 L
 for Emin  dD  0  D1 = dt
1 e
Q.55 We know that c hange in pressure =
 
Q.51 Magnetic field is in –Z-direction. v  B  BS
P  &willbe maximum at t= 0 when
 path of particle will be a circle in XY plane. x
qB0  100 x 
Angular speed  =  B 0 cos    1
m
 17 
In time t, the particle will rotate an angle
Use option in above equation to justify it.
 = t = B0t as shown in figure.
Q.56 From the given input and output waveforms,
the truth table can be constructed as given
A B C
0 0 0
XII MT-12 [JEE Main] Page # 6
 1 1 1 Q.62 Rate of SN1 solvolysis  stability of C
0 1 0
 
1 0 0 CH2 CH2
the logic circuit is hence anAND gate.

C
Q.57 Mean absolute error is greater then the least > > >
count hence we consider mean absolute error
as error in place of least count in the reported
data.

Q.58 Speed of sound is c = 10u. If frequency of
source is f Q.63 
CaCO3(s)  CaO(s) + CO2(g)
u 11.2
Incident sound
= n CO2
c 22.4
Wall (observer) moles 0.5 0.5
u CaO(s) + H 2O(l)  
  Ca(OH)2(aq)
Reflected sound 0.5
c - 0.5
Wall (source)
Ca(OH) 2 (aq) + 2HCl(aq)  
 c  u  18f CaCl2(aq) + 2H2O(l)
f in  f   0.5
 c  u / 2  19
Required moles of HCl = 1
v rel cu 19u Required mass of HCl = 1 × 36.5 = 36.5 g
 in   
f in 18f / 19 2f
Q.64 Theory based

Q.65 Atleast one -H should be present for aldol

v (c  u ) (11) (19) u
 ref  rel   condensation.
f ref f in 18f
O
Me
(1)  –H present
Q.59 Use I = I0 / 2 When unpolarised light pass
through a polariser and use I = I0 cos2 when
polarised light passes through a polariser. O

OH
(2)
V 62 
Q.60 R= = = 400 
I 10 103

O

C H E M I S T RY
Q.61 Na2O2(yellow solid) + Moist air  Na2CO3 Unstable enolate ion
+ NaOH

XII MT-12 [JEE Main] Page # 7

   a 
O Q.69  P  2 (V )  RT
O  V 

a
(3) OH

PV +  RT
V
Less stable enolate ion
a
Z = 1–
VRT
O Me a
Slope = = 0.22
(4) C – C – Me  RT
Me 5.5
 0.22
No -H present 0.08T
5 .5
T=
1 1 1  0.08  0.22
Q.66  RZ 2  2  2 
 1 n  = 312.5 K Ans.
1  1 
 R 1  2  Q.70 Zone refining is based on the principle that
  n  impurities aremoresoluble in moltenmetal than
R in solid metal.
n=
R  1

Q.67 Energy order of molecular orbital of N2 is Q.71 Br

2  
/ CCl 4

OH
(1s )  (1*s )  ( 2s )  (*2s ) <
Br
:

Br OH
2p x  2 p y   2pz  *2p x  *2p y  *2pz O


NO2 NO2
Q.68 3a 3
Q.72 (rx   ry  )    654 = 283.15
, 4 4
Ans.
NO2
Deactivating group Q.73 Group II radicals
present (Pb2+ , Cu2+, Bi3+, Ag2+, Cd2+)

H2S + HCl
NH2 NH2 – AlCl3
PbS, CuS, Bi2S3, HgS, CdS
AlCl3 Black Yellow
Hot & dil. HNO3

After Lewis base–Lewis acid

2+ 3+ 2+
reaction, it becomes deactivating Insoluble Pb , Bi ,Cu (blue colour)
2+
group. Hg excess NH4OH
2+
[Cu(NH3)4]
(deep blue)

XII MT-12 [JEE Main] Page # 8

 H P
PT 
Br N Br x 3
4 3 2
Q.74
O
2
OCH
3 
Br 1 P0
k = t ln P  x
0

H
1  2P 
k  ln 
H3CO N Br t  3(P  PT ) 
4 3
2
O Br
Q.79 1st I.E. order : Na < Mg > Al < Si
3s1 3s2 3p1 3p2
More stable C forms at carbon 4. (fully
filled)
Q.75 Tb = Kb.m
100 – 99.63 = (0.52) (m)
OH
0.37
m=
0.52
n sucrose 0.37 Q.80
m= × 1000 = O2N NO2
w H 2O ( g ) 0.52 COOH
121.67 1000 Strongest acid due to S.I.R. effect
w H 2O = × × 0.52
342 0.37
Q.81 Theory based
w H 2O = 500 g
Q.82 [Co(NH3)5(SO4)]Cl and [Co(NH3)4(SO4)]Cl
Q.76 (1) [Fe(CO)5] : (CO) Has no isomerism because molecular formula
Due to synergic bonding is different.

O O
||
H + Me  C  H  
dil.NaOH
Q.77 H

O O Q.83 > > >
*
CH2–CH2–C–H + CH3–CH–CH2–C–H
OH OH OMe Me Cl
(1) (2)
(+M) (+H) (–I)
Total product will be (3)

Q.78 A  2B + C
P0
P0 – x 2x x
>
– 2P0 P0
O2N NO2 O2N NO2
P = 3P0
(–I) NO2 CN
P0 = P/3 (–M)
PT = P0 – x + 3x

XII MT-12 [JEE Main] Page # 9

 (3) Cr(NO3)3 
Q.84 PCl5(g) PCl3(g) + Cl2(g) 3+ excess NaOH
1 - - Cr NaCrO3
1–d d d excess NH 4OH 2+
[Cr(NH3)6] (Pink)
2
 d  (4) Hg(NO3)2 
 .P 
1 d  2+ excess NaOH
Hg Hg(OH)2
KP =  1  d 1
 .P  excess NH 4OH
1 d  HgO.HgNH2

d 2 .P
KP = Br
1 d2 Br

2 *
Q.89
 d << 1 CCl 4
*
* Br
 1 – d2 = 1 H H
Me Me
KP
d2 = (3 chiral centre)
P
1 R
d Q.90 Cm = C v1m 
P 1 x
During process P  T3
Q.85 Aluminium itselfis averystrongreducingagent. P'T–3 = K
1–x
P T =K x

H
Me
H
Me Me PT x / 1 x = K
H
Br Br Br
x
Q.86  –3
Et Me Me 1 x
H H H
Both side anti Only one anti No anti -H x = – 3 + 3x
-H present -H present
3
x=
2
Q.87 H2(g) + 2H+(aq) n=2 2H+(aq) + H2(g)
5R R
1 xM 10–8 1 Cm = 
2 1 3

0.180 =
0.06
log
H   2 2
2 [10 8 ]2 5R R
=  2R 
[H+] = 10–5 2 2
pH = 5
pOH = 9

Q.88 (1) Pb(NO3)2 

2+ excess NaOH
Pb Na2PbO2(soluble)
excess NH4OH
Pb(OH) 2
(2) Zn(NO3)2 
2+ excess NaOH
Zn Na2ZnO2(clear)
excess NH4OH 2+
[Zn(NH3)4] (clear)
XII MT-12 [JEE Main] Page # 10