AA SH 9a s geet fader -Cor Refter sare fear at te Bertor ofte er ads Rem we ae fice wiew aie, wen 2 faftraiiee seaat fefie a eer ear cet 2KCIO, —*2KcI +30, Boyt Rites cr genie After oe ae age e meses care Fee en, wee oF faeces Bey ‘afer TA | UAH, + 1, = 2H pe er mm Wetec cheer 3 dt ORIG, c = (-) Fefaeata eratat x (+) Seis water = molLs~* Ba] moldm-#s~* UR SAS: WNT 0 CTT BOA Se Pelee ears fafa eh ees aCe | ‘faftema aaa Boe eters Rerrett aes (i) Riterces erpfts: ff Patera os fafeq Gi) ftemcen cantar: fefseurr era an faeces THREE MTgTIES | (iii) Cran: fea ree fafsears aa Be ATT | 10°C SraTa zacw ea 2-3 oF TF (iv) bts ort Pfam ee 1 Oe peer ec oaseenneel (vi) sores: Referra aa gfe aa aca creme after k=Ac MA ates, K= ffir stein coer = Rita arte A= arate antares teas =f: Tore fattoara sramaie ames aerk wear aT eT CoM Cone feleceR ae wer fafemcer THAT Brora Gt fart Site ofS ars sea feu wea CoySsr Wels ata | wee 2 faftena Afar ae) fafemen @ agern Se afters afe ars eer wiors Ter Ars SY AREA Serre are Rene Set Fire: om ‘faftara aa o after “fea wane aoe wert: cw Afteus afew “fe cP ere afea we eT GAIA Cr fRfeem aieas fe ey era shen Get cat 1 aie Fata fs cx eters Hecoce Stasifoe wr ate Frafere aT peter eM AE dt t,-t, At. dt Gi) =k, did - 2 -F -11R [Qh 0, Po Qe BAER P # Q RitrrH ares rE (bd) Bracefiara ator: © Gi) ne (-3[ 4| Cu aan, Co= orefire wratat: C,= Benno WHAT, (= E, Ju-1 @K=Ae™™" Gi) wa )-[- ri | TI, oproen PfSrat eo: () tema ae, k=S Be OP ace ‘Sara- Saget ATE$— taf FF (Slope) ffm @ Inka 2 crete Bet = = (i) logk re 2 concn ort = — (g) fatemerwes Fema oe Ey 2.303R Whi ty © ty TART a, @ ay celts emiata ST ree AAS Sat BE ET, ‘fafeere ar (h) are ecw ffterte won fief (k wr ae): (i) te wy es wT Ke: Sin“, We, day, yo (i) faster ae eT K 7 AFF: Lmol-'s!, Lmol~min~, Lmolhr=? (ii) 0 WH Ga wT K a See: moll s+, moll*min“*, moll hr lated Oustons vb) Ol. Ror fee eftemarr ‘aT STAT Fae St that Bh? [Ans: d][RU708-09) (@ Ca(Hco,), CO, © cae, rab R 02. Sif iiniba vice Feferat ora? [Ans; a][RU?07-08] 0 () HCL (©) NaHCO, (@ NH,CL @ se os sores Ret sari aks stents Fe or Rem HOD Ice Beer e-[ Asia] [CU°08-09] (a) CH,CL+HCL (b) CH,Cl, +HCI (©) CHCl, +HCI WTA, +H) C+HCI 70° Cement See NaOH acts Bee fer Cl, we ears Beg ar [Ans: d][CU’07-08} (a) NaCl+HCIO (b) NaCl + NaClO (c) NaCl +NaClo, (a) NaCl + Naclo, (e) NaCl+Naclo, 05. A+2B > D feftour coon feferma aq WAteat Ga", rate = k[A][B] | wh Sea faiterces wore fied eat, ‘reget Fas Bea ge EA [DU_KA’14-15] (@)2 times (b) 4 times. (©) 6 times (8 times . Sol”: (0); ty = K(A][B]; 12 = k 2[A]2(B] = 4 [A [B] = 4r, Zn+HNO, (1) > aa Bere wet fAns: a][JU'10-11] GY ZeANO,), +H,0+NO, () Zn(NO,), +1,0+NO (¢) Zn(NO,), +H,0+N,0 () crabe an car fara ae? [Ans: e][RU*08-09} iP (a) Cy807+ 2KI = Cul, +K,S0, (©) CuSO, + 2K1=Cu0 +K.30, +], 2CuSO, + 4K1=Cugl +2K $0, +] + (0) ere ay Ca igre STATS HT TT we Soa- Sayer “feaei enreee AR SH 9 08, GB abe _{Ans: d][RU°08-09] (@) N, +3H, = 2NH, (0)2S0; +0, = 280, (©) Zn+H,SO, = ZnSO, +H, fart 03 Bonk : NaCl 48 B30 aties cnet eat Ree ces sieg? [309-10] (@)CeCO, —(b) CaCl, © - ‘eh cont Sol": CaCl, +NaCO, — NaCl+CaCo, aC.) + CaCO, —> feferar wa aT Bey NaCl at wre. Gias Gmc ae ae ban eroe 1799 mice Beat tara cafe Sc | @ evte Riera a {Ans: b][RU’08-09] (a) SITE ere AR font she eer (©) fefters a sift eet “(d) wrt Bert LL, roa carat ares sae [Ans: ¢][RU’08-09] (a) No}3H: 2NHs (b) PCls = PCIs+Cly NaCl+AgNO;7=NaNOs+AgCl (d) C2s + Cs: 197 K fefaears ae sere et logk Ie 1/T caefione om eo (Ans: a][RU°10-11] ~E,/2.303R (b) -E,/R @E,/2303R (d) E,/R soar afta ere ee ice Fete sree [Ans; b][RU*08-09] (a) sateen ay ‘eafrchibeone or (c) Rarer Sor (d) Satbibrers ag 14, 2A+2B->2C+2D feats crests fer on abe aftiarnit iter sa [Ans: ¢][DU"04-05] ow oA G3) @ MP1, a di 4 dt dt dt 15. ceri arc eae eset [Ans: d][RU°09-10] (a) Zn+H,SO, = ZnSO, +H, (b) K,SO, + BaCl, = BaCl, +2KCL (¢) Na,CO, +2H,0 = 2NaOH +H,CO, _(@) Ca0-+H,80, = CaSO, +H,0 @ faftems ara fea ere [Ans: a} [JU?10-11) RTT (b) Greene (c) tapfew me — (d) CHABR AT 17. Refarurr siftex Bom oer ok cornea? [5010-11] (a) ort (b) tere ET (c) gee baby Fife otc tet Solana sere, Soa, RAAT ae epereacerm eee FATA | SW some CTSA COT STETE AIC AT | NaCl arcs athe eer esa AI [Ans: b][CU"13-14] (@) NaOH + HCl Gf Na‘ (H,0)+ C1 (H,0) (©) NaOCl + Hz (@) H'+OH" — (@)HCIO+Na fie fafaeamra aa (rate of reaction) —feH ia {Ans: a][ImU"15-16] reer Te (0) afapa ga eet (>free Ours ae 20. KI wa mate corm PARE MeATETA HO, BAT CT FRET 10 CRETE 10-Smol arate ae ar eae Bee Rents 9 Reuia sty facet fete IKU'15-16] Sal241+ HS, +H:08 + K,S0, ++ 2H20+ Ip Fafieatba og ferent = 222 = Mimalel = 107moleL-? see“*(Ans.) 2. 2A+B eo C+D RReuTD eTeeTeTA Hw eon cow foe cam aS Hpi eTMeeR A? [RU'15-16) (©) et or caf errata @) Fro Bereta PoP ozs Cera (Fao eR SETETSE onan WAR ST Sol?:(0); FoR AAG, OF, Riders @ Been aaecenc ao aca fre wa OHTA FREER, IE HH IATA ae Beaty Be He ey, SS ah or ATS A fet Ritu aa ecenase cen? ee) (a)s“4mol?—(b) mol 74574 (6) Lmol™s~! (als Sol’ (¢) $4 = vfa[B] = k= Sao MIS = Lmol™s! cad ea ex faftens 34q 10 min We, 2 Ba IS ES? [CU'14-15, DU? 13-14) ‘esse 107 min“ (g) 69.3 x 10°? min“ ) 6.93 x 10°? min (d) 0.0693 « 107? min=* Sot: (93 ty = BB = 0.0693 min~ = 6.93 x 10°? min! ; Bot es teem 6.710% s 1 tombe wirgee v0? IDU'1L-12] (9472 min (b) 16.0 min (275 min (4) 18.1 min Sol”: ,. = m2 =1034,55sec = 17.24 min 25, Ra oath fftoms freer con areas canter | cern Faken oltre faftem ace aca? [Ans: e][DU09-10] @A+B>P,v=k [AP (bt)C+D +P, v=k[C] [DP Se¥O +02 + Nz 053+N2, v= K{O] [02] [No] (@)(CHs)s CC1-+ OH > (CHs); C-OH + CH, v= k [(CH;); CCI] Gor steer ae Fees WET Ss eT, 98.4375% Falteal Tm ew ae ARE ATCT? [RU'I5-16) (@)30s (b) 255 (035s (4) 60s Sol": (a); t= tin ae Ingapctargg 880 (Sx6)sec= 30sec LED KAY — ZRettra er i worms RRS Sots se cr Aiea abe con-afeat comb? [X]/molL* 1.0 1.0 3.0 [Ans: ¢][DU?08-09] [Y],/molL* 1.0 2.0 ‘10 ‘wafacen (Initial rate)/mol LS“ 0.01 0.02 0.01 (@®) v=KXITY] @v=(X][YP ey V=kly] @ veka) Graf A+ 2B + P faftenba aise ea-attene Rote aca? s [DU_KA‘16-17] (a) -a[AY dt = k{AT[B) (b) -d[pyae = kay ze (©) 4[Pyde = k[P}* PMPyae = Kajeya}s Sol" (dH = Kal (BI, a 6 B-en am feftemawor Bae Ree 29, Gam Riera To SPST Ce BITAT? [DU_KA‘16-17] (@) First order Zero order (©) Second order = (@) Fractional order Sol": (b); "(50 ara Peftears Waatar ar area waetaRRS | Ch ‘Sioa onset aa ate eee ee? om “oy HE @ua (@ HNO, ones 31,“ 2N,05(8) = 4NO2(g) + 02(g) FfEFMPTE AFF NO, oe AT 3.0 x 10-3 mol/L We ots 6 orere, uaa fafivara apa Fe mol /L/S? (KU6A7] (0.7510 —(B) 2.50 10-* (©)1.25%10-* ~~ @) 3.00 x 10-+ Sols (0r=2 Bt = a =125x10+ 32, Ny-+3H, # 2NHs CREA K, 8K, S| [Ans: b][CUN6-17] (@) Ky = Ke(RT)*S YPKy = Ke(RT)-? (0) Kp = KCRT)? @K,= KRIS (6) Ky = K(RT)? CT CRS ARTA TI TTA age Sos- Cate fiat“efi era HR 3 A ohn eer gee MATOS: stroe Ae aera PR wHrdce Catalyst AEH BEA sree ora wi oe fart Fefaeaces see Cafe cae atiafie Roars af afi arg wer w eftrare cree Fite 9 6 Sea BRAM ae Oe eI Ae | CHAT, ATETAT ANT MnO, aa Ba KCIOs ee ofa oafea Ris pews wet) 2KC1O; “#245 2K C1430, ecotacet otert saree eer: fefzeua afeee yk eer | GR- MnO) Mn0Op, Cu, Fe, Al2Os, bb, No, Pt, V20s, Ni, HCI, Al2(Si03). wares aes: Referers ah sor ice SrareeT, HsPO,, fife, CO, wees, TEL, era, Be, confer, arena @ H:0, 2, + 0, (ii) Na,SO3+0, "5 Na,SO, (iii) CHCI#0, 2 COC +HCL (iv) HO, 250. SOEs: Gn arafis fefiems berg ane eo feet areree ef eM AT TORS fom: CH Te sds Bafefed Set STATE OSHS NRTA ae amale Tee ROT CATS eT feet | CA, As:03 TORE FITS: CONE MTOM Boren Tact ereratad ewera eNUT BH AE VIET SETAE ATS IT | GE: Mo. oy Fe tere ae | RE aeRe: com fefeme we fimcer core Br wom Rte med oT GM ends fee TE | SITS Ora wes cate Fast wb ar | & ere Rfterites orem fafa enfee ereree aor | ae Fs TTR CCM STAT PAfemMTT He THT MSR MMT AICS ALS AG SHA AT 280r(g)+O2(g¥ 4+ 2803(g) SHAG EHH: 2S02(g)}+Or(g) M4 280; > TREE CORA: aoe eo Sew Cito anthers caw Berg, Bor oMige ease ARETE aa contre wba tera ome | onFCS oat SACHS LEM Sea AR ST SHS BASH LH AEHTE | 342g Osa + NO + aC Heese sore RU GyHlpaO4s + Hy ———+ 2G 0, 1 CgH,20, > 2€, HOH + 2CO, er (sre) 81 H,N— CO—NH; + H,0 ——>2NHs + CO, fo rae afore HACER IE 8 BTR ANTE HT SOE i fo. fase aaa aera Not3Hp 2NE Fours wa9#), Mo HO. onoetes 2503 Peat V,05 HNO; 3NH;+50, == 4NO+6H20 Ptr Sine, >C=C H >C-CH< Ni [Fre CO+2H, —9 CHOW ZOHO} eh lid COHLO —> CoHent HO CO-Fe-Ni es Tera eT Te see Serer eaeSRG roe FE ag OL. 02. 03. 04. 05. 06, 07. 08. 10. CA, Pt +e + Fae rch ne RO | CH .y 5 CH, -C-(CH,)-CH, | CH, Toone art CH;-CH;-OH+0: CHy-COOHHH,O | Wren aaa saa — : ‘Bacay Related Questions: Grad ew ARTE Rete aE MnO, fe fortes ster sea? [Ans: a] [KU711-12] THETERTS (dT aos (cere aye (d) saRBe HATE area eafites cote (Ans: d][KU’09-10) (a) cat Se Staite oa AAR (b) ae core are Freep cobs east ome (c) er comnter monte fie stots ware cen dR 2K C10, ZOPEs 2x«C1430, (JU"10-11] (a) Ni ef (6) Ticl, (©) Fe (a) MnO, Sola Rome ater MnO, at actus eteiae Roce ste ea | “wf weeny amet cera? [Ans: e][RU°07-08] (@) HCL () H,S0, (©) CHO, (@ HNO, SP ae Reqs cami ene [Ans: d] (RU’07-08} (a) Foe (b) Brewer (Ree @ Rent ROT I ae erat [Ans: nes -06,JnU"07-08) (ayer freeones eS alate Sc) SETTER Frc corns aie aa? - e][{CU"05-06} (a) sarge quate Ren wafire eer (b) SaRDs Petra aOITER afrass we AT (0) santos sree area an fsa aftaes watts or (a) Rte areas weet Ferm re Ree erat ae App Saar ese Fearne irr ae BP oT ar t Pes eee eres ge [Ans: d] (CU°03-04) (a) snore aes SAT (b) ererecen arias afte (c) Bertman eens stferes at (gfitemn ter foram ). ASRS ANTES WARE a [Ans: b][RU’09-10} pore a (Ove wee ore eH nour SrerereD frre FREE Fon — Ferre cr [30°09-10] (a) Sree wERDe (b) a ade — (c) STETURTS (d) aero sot: sara = KCI, —MBOL_+0, KCL, eee =Na,50, +0, PARE, Naso, eRe =Mn'*, IRB = Na,SO, rts RE aE? [3U°09-10] (a) onfears seed (b) onfea ware (c) criemm ae (d) onftan ada Sol": (6); ao falters wre ae fefteue celts eae wre MIRE eee aT | qum-Na,AsO, @® Na,SO, «4 0, +e aRCt Na,SO, wit aes | CAPT OES HSA AST TT 88 “Sua Sane aAefit ST AR 3a 12, H,SO, alee aia esraces few erate [Ans; ¢][RU’09-10] (@) B,O, (b) Cr,0, (c) As,0, @ ALO, 2 aR Ra [Ans: e][RU°08-09] (@) oF ear Saree (b) a erate Sdarre RO BI OT et (d) ee ASIC SS {Ans: b] [DU’13-14] (a) suey OF fice GT _DRienaater fs, E=ater (co) Refers arate ae eat (d) ray Fiero Bertcna % faa gfe cat . 2CH,CHO +0, = 2CH,COOH fefrntts cere crib: [JU"10-11] (@) Mno, (b) FeCl, (© (CH,COO),Mn (@) Pt-Rh So: soafeatres wfsrery wat ores Fete eee Pt—Rh a Cu | TSH Cory Beat falters Aye 6 sto fica Hfeca ae RU, wie APA ATTA CT apes splays reece apie ara ee eteta | aa— @) ey FPOTeY: weer ere © Beare ek wT eee | QHI(g) —— H,(g) + ha(g) Gi) sorry aoe: falarre © errs fog AT ee 1 CaCO\(s}—= Ca0(s) +008) TS SAG SRT NE Ashe NH,OH(aq) —=NH,"(aq)+OH (aq) @) ares BE (vi) stfera (ii) Ben fre care greet (vii) Frames every iii) Fafters arytor (viii) Fra wee (iv) corres SReraret (ix) weeds cr (vy) 8exter (x) ie eae nett MIMICERRTCES ABs care Boat (lear AATTE are ST AH a aE OTT ca Free AA SPATE, BIT Sai a HE eh AS rN sees en na en are ee vom ace fee TA - mone AS cya feftems arora Bee feldq faeces ersres OUR eT erga fear orerata yfaea Aree Serena ahs Be oT | reason Reems wera ees Bena AT Gi) tered Fearn Te rere BPacs Taye Oreos ARENT FCT | wroaen vileat: logk,= at +constant WICre ere: ico eaeerS aera: Coe sor fafteas Cen fire fetes @ Teor cr Het AN, CIT CRE DICH TROT CAA EL, CATT Dr TTT Pte creer Fee wars er falters corer oie Serer OTT aoa eer ea ae, wes bist ater PAfem AIT Fire Ses aT Beet a ey eats oer fafseat xem Bie Tar aia at agers OS care Patera Cen face mate acdsee TIM, eA ORES BIA eFETE TE | ‘Pai rere arena: renee eee Cace Fe T CA ence MITT FETE eA AT Ree etwas TAROT HUTA ST AIT TET AT TIS TT OBE aes ee aT Oy ATE ST we ae Same ETee es ; m0 veaa afore NH, Seana Not3Hz => 2NHs+92k) [450-550°C eremram ; eres: Fe; see —Mo/AlOs: BI 200 3 1nf mefbre H,SO, Beer “ Qo nC S+O2. == $0 2802+0 == 2805+192.5 KI [errata 450°-500°C : teres: V>06-a1 Pes os a V2Os a1 Pt; ort: 2 atm) © | aes siRcER FE arf telBce HNO, Sema N2+Oz=—= 2NO+180 KJ [si1aH: 3000°C] 8 1 ferret Bem: CO —= CH OH+95.05 [errmer: 300-400°C : rete: ZnO+CrOs ; BI 200-300 atm] 3 Related Questions: Ol. wart Faftram worn gee em Beene ofits [Ans: b][JU’14-15, JU? 10-11, CU? 03-04) @) saa UE UA (o) FRSIRTS int (d) SafraSS anee 02. =f orefSTSH,S0, BOA SO, wa Tad aa SO, BemnmT esa [Ans: a][JU"14-15) sorret (&) Nigt Feet (@) Al0; 03, SRNBS RIS Bet ee See ee [Ans: e][JU"14-15] (@) Urfice (0) aafies Corre a artes ar 04. 2502(g) + O2(g) = 250.(g), (AH = -197 kj] Rfsrnta com Beer cece. (Ans: a][RU?14-15] Qtr arent () Sr SITET () Ba arg (@) B46 BY TARA STA TEI 05. Srerarar 3a sate fice Crate fafsram creates Seana fers srerfaw ee? [Ans: b][DU_KA’14-15] N,(g) +3H,(g) = 2NH3(g); AH = —92kj/mol (a) Increase ‘Gy beeae (©) Remain same (4) None of these 06. Ritu dereces He oT [Ans: b][DU_KA?13-14] (a) aro GM fee oT (6 toe ee, E, =a (©) ferme arart ofe eat (d) rar Rees Seetora % fara fe wat 07. From ern arnIcrE arya A? [Ans: a][JU"10-11] (a) Sern are Cesnacaa Srorart feorca orca cere (b) HNO, Seonmcra aréemre-ortees Rye ere refers NO, aq (c) ™pf eerftce H,SO, Seomaet (py Sores ter 08. 25° C errant aef rans Crem ST NH,Ci(s) = NH," (aq) +Cl-(aq) (AH =+3.5 keal mol") 1 com aRieda arenes Brfice warehte sara puri] (@) decreasing the temperature to 15°C fnereasing the temperature 0. 35°C (c) dissolving NaC! crystals in the equilibrium mixture (@dissolving NH.NOs crystals in the equilibrium mixture Sol: (b); oxcey Pare wren we Creare ATT ATTA Sr Fee TCT 09. N,(g)-+3H,(g) <= 2NH,(g) emt erent | FeieM CE Freon Com Sh site am wuilibrium constant decreases with temperature 2 o aan increases the rate of the reaction {Ans: ¢][DU*09-10] (c) Equilibrium constant increases with pressure (a) Yield of NH, increases with pressure. Care SES ASAT HM TUT ae,fie SAE FIRST 9, Rene fftra Protea ree ata eres ea? 280,(8) = 250. (e) +0, (g); AH=+ 198K] [Ans: d][JnU07-08) (a) x AM SO, Her her (b) fee sft SO zat eee (c) SPATE St TI (a), (b) wae (c) 1, cerrafene NH, Cermer estes Ree teas en cer? | JU°10-11,RU°09-10,JU°09-10,RU'10-11] eet (b) V,0, (©) Pd (@P sol” (a); NH, Sx ereree er Fe Bf aE eer Re eI Mo at Al,O, 12, cee rafooe NH, Benny aaeven cath ee cera ede [sU?10-11] (a) FR ORAS ST (b) aFionas ar (.) sro 6 ah ere LS cP oe ere Sol: (4); arreartrrat Seon feted weet aay fetteme eT gE Ae eT ET Te al Hes @ ST ELT seer APH Beans SRT AT | 13, SRE TCE RUBS com Boye flea sey acer TTS TS aA fAns: d][RU?10-11] (a) feiteuces offers gfe (b) Beene aa (0) Sores BARS ¢) Srstatg fae 14, faerertmant N,(g)+3H,(g) € 2NH,(g) +92.22k) fatten srarrrere ore yf wae St ub ray (2) Gr fare wore ee (b) aE aH fies worms ea [Ans: a][RU?08-09] (©) aw Fea tere (d) ero an 1S, 2N,(g) +0, (2) <> 2N,O(g); AH =+160k) mol Rea cor Sete N,O(e) ~+3H> == 2NH; (atm)? = (kPa)? | mol? 1? [errr array, An= 12; NLC] — NERC (atmy" a (kPay | moFL te (@-ayb=a) (0) Hythe 221 Rema we ky = ke= 4a* 9 _ fap (ii) N20, ==> 2NO; feftena eT: k= av’ k 1-a?? 2 2 (i) PCL PLC REE he = A 5 y= pond Rel uestions: O01. Nog) +3Hz¢q 2 2NHo% PAfRMTETE K, wae K, 0 ALT HOTS BRR (a) K, =K(RT)? fb) Kp = KART)? = (C} Kp = K-(RT"! (ed) Ky = Ke(RT)® 02. WHat (II) watts wit Fea Rites sepia ort 9 eifteaita armas Prone cert em am? [Ans: b]J[KU'14-15) 2Hg0(s) = 2Ha(!) +0,(g) (DU_Kar13-14) [Hg]'(0,] —lgI[0,] K=[Hg][0,] @ K=[0, @) HOF () K {He0} (© K=[Hg][0,]_ @ K=(0,] Sol"; (d); AUS SHUM COTS TT ALOT « = e ETS = Se" “o- Sorel aeaTaSe TTT FA ST 03. 18.5% N,O, 25°C sriaian eae tatm viet Rents et K, oa 6? {DU?12-13] (@) 0.142atm = —(b) 0.185atm (©) 0.220atm (d) 0,125atm Sot’: (@); N2Ox(g) — NOB) |p _ 2p (es) mie Pao, oe l-a 2 185 1 =0.312236 atm (oar a 0.68776 PaUTTETT HD cater eT Lea, p - Ln.185 14175 aim Oi Gon Tea 14.185 = 0.68776 atm = 0.142 atm =l+a, 04, Foss Rie AEE Kaa ate wee corte [DU710-11] w(aq) +2x(aq) = 2y(aq) + 32(aq) (a) mol dm —(b) mol? de® =e) mol dm? (dy mo? dn . fyi xtP mol‘dm'* (0); Ks» gap = mold SPOS Re ate 05. N,+3H, -> 2NH, ee@ sorts feftom, are Ke K, aa ot Picea cored? (@ K, =K.(RTY @) K, K(RTY4 ()K, =K, (RT? @) K, = K(RTY =mol’dm® Sol”: (@); An =2-(1+3)=-2«.K, =K(RT)* [DU’10-11,DU"06-07,RU08-09] 06, fern cer sags afascr eee abpirete aoe K aes ea? [Ans : a] ‘emperature (b) Pressure [DU08-09,70°09-10,DU"04-05] (c) Concentration of reactants (d) Concentration of products 07, A+3B=C+2D Rftruiby K, aa area [DU"07-08,DU"0-01] @ tA) BY Ic) pr ASCO WE TAB? (©) [A] 3B] /[C} [2D] (@) None of the above Sol’: (b); A+ 3B =C+2D Rfteme K,. ORE ler 08. Feast com faftemtba Ky = Ke? [DU’06-07,DU"03-04,RU’08-09] (@) PCls<5 PClx(g)+Clo(g). (b) No(g)}+3Ha(g) < 2NHs3(g) HI(g) < Ha(g)+h(e) (d) CO(g)H:lg) CH0H(g) Sol": (¢); 2H = Hy + ai) kp =K,(RT)* An =n, -n, =2-2=0..k, =k (RTP =k, 09, 25°C Baer 1 atm N,O, 18.5% Pattee er Se freee wo K, rae atm? — [JUL 1-12] (a) 0.132 (b) 0.142 (©) 0.152 (@) 0.162 hat, Ae(0.185 10.1417 tm| a=/22 0.185, P=tam i-a?’ 1-(0.185) 100 10. 25°C Seer N,O, 6 NO, se mTTeRs fies wows site oH TECH 0.694x O.31atm NO, Facarers faftrare K, oa SIA FS? [JU'11-12] (a) 0.1393 atm (b) 1.1393 atm ——_(¢) 2.1393 (d) 3.1393 atm Pond 03. 0.13927 atm Frsoe Sol’: (b); K, = Sol":(a); N,O, = 2NO,; K, = cm aes aerate ae we S99- Safire FTSRB sree FT a 9g 11, 280,(¢)+02(s)>50,(g), ftemtre sarees 0.27 mol/dm® $O,, 0.40 mol/dm’ 0, ex 0.33 mol/din? SO, text cree feftrnta aay rae ee? BU) (@) 3.7 mol/dm’ (b) 4.7 mol/dm?—(c) 3.7 mol/dm® (a) 6.7 mol/dm? (80,7 (33)"__3.7345 mot/dm’ Sol"; (a); 280, +0, +280, > Ke “Bo. OF = (a7F (40) 12. 30°C Beer 1.5 atm veAPC, 15.6% Rene ae Be fecarersa we K, are? (JULI) (@) 7.48107 atm (b) 4.98x102atm (c) 3.74x107atm (d) 5.55*107atm 15.6 Sol’: (c); a= —— =0,156 ; P= =f (©); a 1 0.156 ; P=1,5 atm ; Kp #1.5=3.74«107atm PCL, ox feces feftema Ky = xp = orgs 7 l=a 1-0.156° 13. An=0 &, K, aaa er 5.51x10° moll, orem K, ae ae [JU"10-11) f@o (9) 5.5110 moll." (c) 5.51107 mol mL" (d) $.51x107 mol L* Sol: (b); An=0 em, K, =K, ai ¢ 14. 500°C wrratant N,+3H, —= 2NH, eq After K, 4 a 1.44x10°% atm 1 ey APT RR Srrtetes Sioa See OH MARS mol/L fecasat wee Fates Ka we eT — [3U’10-11] (a) S.81x107L’mol* (b) 2.81<10° Lol" (c) 5.81107 moll" (d) carat ar Sol":(a); K, =K,(RT)* >K, =K, (RT) [. An=2-4=-2] =9 K, = (0821x773) +1.44x10% ; Ke=5.81x107L'mol * 15. 50°C Seem N,O, Raracm Ky 64 3 3.25 atm 1 ay Reet NO, oe ShAte ott 0.48 atm = N,O, ea wtite 54 oe [Ans: b][JU°09-10] (a) 0.0807 (b) 0.0708 (e) 0.0801 (d) 0.0703 16. cary firma K, 08 ee mol*L? [Ans: ¢][RU’10-11] (@) N,0, = 2NO,(b) 2NH, =N, +311, (€) 2NO+0, =2NO,(@) Ny +3H,=2NH, 17, cory fetes K, or amt Bee Koa a Bers] aH? [Ans; d][RU? 10-11] (@) N, + 3H, =2NH,(b) Hs +1, =2H(6) PCL, +Cl, =PCI, (4) 280, =280, +0, Sol”: (d); An =3-2 [0 K, =k(RT)™ 18. 25°Ceremat © 1 SEFER De PCI (B)=* PCL (g)+Cl,(g) Rte K, = 1.76 ager HER Ke ara 0? Ans: al[RU’10-11] (a) 0.072mol/L (b) 0.00297 mol/L (c) 0,0786mol/L. (d) 0.0354 mol/L : ek 1.76 Sol’: (a); K, =K,(RT), An=2-1=1..K,=—2=—__ 1.76 (@5 K,=K.d - RT 0.0821=(2734 25) 19. aERTe Hit cia aa abe aa? Ans: d][RU?10-11) = 2 [Ans d][RU?10-11] (b) arate Pens fence eet or (0) fea ¢ Serer afar eer armrest (G) Bera Tea area tea aE Caer Pe STAT IT ate ‘oa- SagetHD AT 20. a 22. 23. 24. 25, 26. 27. 28. 29. 30. ARR a 35°Cetrtaix Puree Feet NO, © NO, oF Sie ve gate 72kPaw 28kPa WA Gk STAT feat aT rae gor [Ans: b][RU07-08] (a) 0.1089 (b) 10.89 (©) 0.389 @2.57 1.0 mol H,(g)® 1.0 moll, (g) t @ee Stra ea ‘TH ANTE 0.8 mol H,(g) Sa eee, @ TTT Sem HI(g) -94 crt Heo es AP [Ans; b][RU07-08] (a) 0.2 (b) 0.4 (c) 0.6 (08 280,(8) + 0,(g) > 280,,(g) fatten K,-a8 aee fr (a) mol dm* —_() moldm’? (7Gn' mot"! @) mold? AOB+C Riemer aH 10 am, fis Rliems mae aA ae? (a) 100 (b)10 (OL sit a Sol: (d)3 KL =—=— (ds K, rae [Ans: c][RU°07-08] (Ans: d][CU°08-09] (6.1 (©)0.01 ARLES oe OTH eteatey [Ans: b][KU? 12-13] (a) Falters afte mec ata one (Cb) Ffseuta amie ace stat ort (0) beta afteeer armesacen afer (d) seated Boies aeaces ee ee corm fAREERTA teat 25°C cece 35°C Bite wa @ afteua we water SH fened ae) wee RRM afer after am fae carat? 13U709-10] (@) 38.85 KJ mol" (b) 85.83 KJ mol” (c) 83.85 KJ mol (d) 83.58 KJ mol! K. Sol": (c); log oe E P 4 —| —-— laytog3=——F» _(_! | lag 93; 1 1 2300R(T, TJ ®°" 2303x831( 298 308) Ts 783.85 KI mol ee fafirara K, = 4.0 x 1074, R = 0.09 L. atm/(kmole) 44¢ dn = 2 WH 1000 Ke Ky Goa PE? (a) 324, (b) 324 24 (354 [RU'S-16] Sol”: (©); Kp = K_(RT)8" = 4x10" (0.091000)? = 3.24 car Rea An 3a a 0.5 | we eae orate Fetentite K, om K, oa am warmer 32.5 6 2.5 Be xf R =0.0821 LatmK"'mol*? [DU*07-08] (a)273K (b) 388.26 K (©) 934.26 K (@) 2058.26 K Sol": (d); Kp =K (RT) = 32.5 = 2.5(0.0821 xx) > 13 = /(10.082xx) ¢.x = 2058,26K car Afra ards 04 ae or Bent a Pane aa aes ae eT {Ans: b]{DU_KA°15-16] (a) Catalyst only _ {by Temperature only (©) Pressure only (d) Temperature, pressure and catalyst 45°C wiry N20, PCR Ky 43 FIN 3.0 atm! ATA NO, 4 SERS BIH O41 atm WA NO, AT eft Or SS atm? {9U'15-16} (a) 0.65 (b) 0.56 i (©) 0.065 (@) Gabe a Sol": (d); NoO, = ZNO, a CRG Ky = me + ayo, = 22 = 0.05603 atm A+3B 20420 K_ QUA Be [Ans: by(JU'6-17] po 2 31a)(8) {toy latte: foun @ 28 @ ©) far init)? 2160) (ap) sat . CEC-13 ea CS aT I i (@) CHIE, () CFC, Gf crcl @cra, Sol":(c); CFC X y z 1 t ee. StH) CAAT 383 Sega Sarre FTA ;SD cores DEL Co re Rear seme CHT) a tee MRC 2 TE am) p= — logit’) BE cans 29°C wom fer om te 10" em ae com Been He NE NOTTS Bet pH Okekerk, = aR a 10" @ oe is Strength of Base Ky DH S2.8c¢ shortcut taftre eat wa) 9? mga shorteut mics Wir SucMt Tara Bata ‘Technic 1: ante Go (H'] = [OH] era) we ar HELEN CEM OK CCRTET Cran pefires oa crautt ate pH © pO ee) OL. 0.0001 M HNOs st pH e? Ans: 4 sta wetter ca bref wee TCE ‘Technic 2: Power te pH pOH fit | Fite fieye Power direct Bet | com, 01. 10° HNO; at pH ¥e? [Ans: 3 #4 power -3=3) ‘Technic 3: pHs pOH *ae cece era eft: 3am eoaie eet = 10°"? [Power Gi gv (-) a Rea a (4) HA ge] eat = 10°F y OL. THE pH aa 3 2 ere 5.9 alee wer Has wars fea fier Ta? Solution: water freer = 10°" P= 10° = 107 ‘Technic 4: "eat (%) cice pH/pOH AA: O1. 2.5% NaOH aera pH 0? - | soation: (ore 2220 = 25*10 Tay Power (-) #H@e :. HAART 1000 84 P57 | =0.625M Lo g/§ = & NEY] ., pH= 14 pOH=14--1g0(0.625)}= 13.796 (Ans) | “ en war fra ee oT Magic™) Technic 5: Fra Se at K, Tk, BA AFL NAO TGS RY wr? OL. NH, egg or (NH) #5 Kye 5.8x10" een, NE or ky wea|F 2-57. BTA, TS 299 qT? Shortcuts Sy#8t at eres ae cma, kyeky= 10 Ye Lovwl oa , 4 Oth 22° ee enim tals al 58x10 open Technic 6:71 6 orca sate PR Shortcut: Pre svat = 10°"; 1 wre safe = 1077 21 {SOND * Related Questions: ans = Gf SER welt eae are wate Ree els o cof Reema fe eaMTE fre eats BR? [pK AE OL, GRR BACT PH A S CCS 7 0 fe CT He oH ATT BS oe BPA oT? (@2et TWR00 4 () 200-04 (@) 300¢8 gol (oy, oar feb 2 = 10°? = 84 «100-08 ar ta 02, WEP! TIN SC? SOTA (ob) 47 (0) 49 @o94 CaP IHS HUTT HT TNA a8 ata tt (BAU*i4-15, JU’ 14-15] [Ans; a}[SAU’ 14-15]FETE FA 9 ta) @ = pl ae ofards eon Gham acaba 2a? [Ans: 2](J0°14-15] ° Be (b) 0.5 (©) 0.6 @ 04 DTA srefoce ena aati ona wee pH Waa ae ae (Ans: b][JU"14-15] O~ 70 Ser i0.0 (55 a) 66 (GB) Wes ores ofa PH — (Ans: c][JU"14-15} (a) 635-668 —(b) 6.6-6.9 AEG8-15 (74-78 pH AIGIS aro [Ans: a][JU"14-15] Pras (by areas (o) Bread (d) onfarr o7. Reaenfis OH- stem TMT Fe? [Ans: b][NU"14-15) (a) 10*mol* —YoyT0-"moL-* (c) 10°molL* (qd) 10-5 molt FRR Sse pH sics aq [Ans; a][JU"14-15] 37.0 (b) > 6.0 (Q>50 (d) > 7.0 09, “0,001 M HCl 23 poH aa ara ee? [RU'14-15] (a3 F3 (b)2 (9 (a6 Sol": (None); pOH = 14+ log(H*) = 11 3 10. sou VL SAT Bae ‘SR (H,01) BATH pOH Se? [Ans: a][DU_KA’14-15] (©) 10 (d) 14 aE coi ails az SCREEN A sea tiegee os [Ans: a][DU_KA’14-15] {aYCHACOOH —(b) CI,CHCOOH —(c) CICH,COOH (a) CyHgCOOH 12. 0.1 M CH3COOH sate pH 87 K.=1.8x10° (a) 2.672 (&) 2.772 (©) 2872 (a) 2.972 Sol": (c); [H*J=aC = JKC =V18x107 x01 =1.3416x10° PH tog") =-|1 3416x107 |=2872 13. 0.0L mol/L rater RR: ‘SRA (Hy) BACT pOH Be? was 2 1 [Ans:b] [RU'16-17] (©) 10 @14 14. caftiouent H,SOJ—an pH =e? [3u710-11) (a) -2 sib} 2 ()l @-7 Sol’ io ans); @PPereta H,SO,, -at wat @ 0.01m=2x0.01mHt 2. PH=—log( 20.01) =1,699 | 15. 0.002 M amafeehre ofrs gare pH e- [DU"10-11,5U714-15, JU? 11-12} (a) 2.70 (b) 4.20 40 (@) 3.00 Sol”: (c); p" =—log( 2.002) =2.40 16, Roe aA aCe pH 7.0 Borat Pte (a) 0.01MCHyCOOH (b) 0.01M NaCl (c) 0.01MNH,CL Ady 0.01MNa,CO, Sol": 0.01M Na,CO, POH=~log(2x.01) =1.698 ». p!' =14-1.698=12.3 [DU"08-09,07-08,04-05] 17, CH,COCH, (aq) +1, (aq) = CH,COCH, I(aq) + HI(aq) feftrmiba a corafta wamrara Bora Féa aay @l, (&) CH;COCH, (©) HI_(@) CH,COCH,1 [Ans: b][RU°12-13] 18. 01M CHSCOOH weet pH #2? Ke-18%10% (DU'13-14] (a) 2.672 (b) 2.772 (92.872 (d) 2.972 )3[H* Jac = JKC = 1.810 x0.1 =1.3416x10" PH x loge") =-[1. 3416x107 |-2.872 x99 aga Sahn ARwR sete Nife - FAIA 9a one 19. 20. 21. 22, wee pH=7.4 Rem, SRR Str Grate est [JnU711-12,JnU707-08,U" 11-12) )4.0x10* molL” (b) 4.0%10"7molL.” (e) 1.0x107molL (a) 14x10" moll." [Ans: a] erie aieer FMEA AR 10% | et pH HN FS? [Ans: b][JnU’10-11] @1 2 @is (@3 . CPG PHS AT 8.45 eer Batt VR cee SATA TTT FE EA? [Ans: b][JnU"08-09) (@) 5.00x104M (6) 3.55x10°M (©) 182x10°M — (d) 9.25x10'M on Sagi arses erat eT (sU711-12) (a) HC\(pE=1) (8) CH,COOH(pH = 0.1) (c) H,S0,(pH=4) (4) HN,O[pH=1.5) Sol": (b); pH=“loglH* ]arete pH ear ara ge wr eet RIO SHAE TERT SER CAA A 23. enews nftiee carer oman cree fem Rep ota ert pH Fe Ra? [SU"11-12] (@)pH>7 fo pH Rete Pre axe refine fire toe ce HT Ka ae a AS | > COT SOLOS Rots a eh RY og Ka eae aT | 2. HNC, 1 pK, = log K, 41 30. Ra tafte amen we ae aon acts ifs pH cab? [x0'10-11) (a) 10 3 (os @oo sol’: (b); pH ‘A SE ST HT SSE Cat eT | Com eee ST CY or: Sap BeSAE ETRE WA ON 31, “it pK, 4a 5 Fe? [RU?12-13,JU"10-11,RU’10-11] @)6 0)7 ©8 (14 Sol”: (d); pK, = pH+pOH=7+7=14 32, cefronett HCl 4% pH Fer [JU"10-11,RU'09-10] (a)-1 (b)7 (@1 (d)-7 Sol’: (¢); COPE = .] CT! pH=-log. l= 33. Samia eo eoreate Ser pH «a x eer [3U709-10} @<3 (b) 4-5 ()>10 (a) 7-8 Sol”: (d); W4 pH3 wa oar at 9.5 68 fA RA TROT AT AN | WIT pH 7-8 34, 1.5%NaOH axes pHs? [RU’12-13] (a) 13.57 (b) 3.0 (c) 0.425 (a) 0.425 Sol": (a); M = .375 = [OH] PX = 14 ~ pOH = 14 — (log 0.575) = 13.57 35. ait Batt [H,O"]=4.83x 10" mol /dm’ ea geie pHs? [RU?12-13] (a) 483 (b) 8.50 (o) 7.32 (a) 2.50 Sol’: (c); pH=~log [H"] = —logl 483 x 10°] = 7.32 36. wT 0.02M Ba(OH), 240% pH aH fAns: ¢][RU"10-11] (a 12 (b) 13 (c) 12.6 @B5 37. HC] Sacta ra 1.0 cena aor eR aT pH aa aes ea? [Ans: a][RU?10-11] @r (by sta ot @7 38. at aettn gece Bre cat sac p HRT an fe ofirey aT- [Ans: b][RU’09-10] (a) 7S pre (c) afrear (d) sera IGS ET 39. 4.9% sTARRas JPreaaeta pH Fer oe ‘ue [Ans: ¢]{RU"09-10] @)1 (b)2 @o0 Mays 40, cer fret 25ml. IMHClaat at 25ml. IN NaOHat! ashe wx, Rife gett pH ee war (a0 (b) 14 ()3 (d)7 [Ans: a]{RU’09-10] 41. @ pHe commas figs eae eae saat ¢ ordre wa fem ace, oF pH@ fer? ~— [RU’09-10] (a) figa rerre (b) ere cad (c) BeBe (d) aR rer Ans: d] 42, Prearra pH 9g faeys corte [Ans: ¢][RU709-10] (a) 78 0) 69 (©) 74 (a) 6.0 43. Ginga pH4 wr Qaet OW Sata wr eas [Ans: b][RU*08-09, RU? 07-08] (@)10"'molt (6) 10" moll (©) 10“ moll (d) 10° mol L* 44, Roe once OH” Snmaa Waar FE? [Ans: b][RU*08-09,CU’05-06,CU04-05] (@)10%molL? (b) 107 molL* ~— (©) 10° moll — (a) 10° mol L* 45. eefbagse pH4.25 em [H! ]#s creo? [ARE ARLE (@) 5.6107 (b) 52x10 (©) 5.010% (a) 5.6x10% 46. comgaeta OH” sree want 4x107 or/iia at eo wee pHet aa et (Ans: a][RU°07-08] (a) 96 (b) 0.96 () 2.510" (a) —10g,,(4%107°) 47.1.0 Maat CHN ea “recat we ort Rremftre er creer, Ka = 4.0107" [Ans: a][KU709-10] (a) 20%10%% (b) 2.010% — () 4.010 (d) 4.0210° Oh ies sera mem EOE ane Soa Sepere itisSPE rT FATE 90 oy 48. pHa creat ercee 1Ans: al[KU°07-03) (a) Puissance @hydrogen-cirw (b) Pressure d’hydrogen-ca7 (©Puisan dhydrogen-cace (d) Passion @’hydrogen- t= 49. 0.023 gm Na“ 100cm' ifr fiton ae eet at pH [CU"12-13} (a) ) 10 O12 @9 (c) 10.5 Sot?:(©); .023gm Na =10" mol Na ; 10° mol =10-mol NaOH; [NaOH]=10molL""; pH=12 50. 10°M NaOH agers test ay aac ofits eat pH wou [Ans: b][CU"12-13] (a) 5-6 (b) 6-7 (7-8 (d) 8-9 (@) 9-10 Sl. pH= 2eneee PRE pH = Sanat ye et wr sSa7 {Ans: ¢] |CU"08-09,11-11,12-13,13-14) (a3 (b) 10 (©) 1000 (d) 100(¢) 10° 52. aie pHs etet atesitg? [Ans: b][CU°08-09] (a) 6-7 (b) 7-8 (©) 8-9 (d) 5-6 (c) 0 53. wRagtcert ena wa Cot ee pH oa aH? [Ans: b][CU’07-08] @)ae (b) =r © (dye (eee 54, SRC ae 0.01 crys aaa pH Fe? [KU"13-14] (i (b) 10 (2 (@14 Sol": (c); pH = — log [H"] =-log [0.01] =2 55. 0.020M Ba(OH): act pH «4 51 +e ea? {Ans: a][CU?12-13] (a) 12.6 (b) 11.6 (©) 10.6 (a) None 56. GaP, HX © NaOH «a faftema sated fF qT HX(aq) + NaQH(aq) + NaX(aq) + H0() INaX eat wT FRAUE ASTAT pH Ba- [DU_KA’15-16] (0) 7.0 (85 (@3.0 + (oy; feat eres Macrae wa « pH > 7 57, SE NaOH aa wrStE Bete pH Fe? [CU'15.16 (a) 10 (b) 1 (c) 12 (ao (e) 13 Sol’: (¢); 0.4 g/LitreNaQH IC S* mol/Litre = 0.01 mol/LitreNaOH ‘wedie, BAC OH” eH VATA O.01M: «BEC POH = — log(0.01) = 2 wax pH = (14 — 2) = 12 58. 10-°MKOH- oa BAICe Ge OF ATEAT (dilute) FATA pH FSA? [cu'15.16 (a)5-6 (b) 6-7 (} 9-10 (8-9 (e)7-8 Sol’: (c); 10°6M KOH Bae Sera et een eae Be OH 6 CG HARTA A= (10-9 + 10-7 2 TRUE pOH = — log(10~” + 10") = 6.995 « pH = 14 6.995 = 7.005 i FEat7 ata ea weg 59, FRaLrR Harts GAN Bates pH SS? [Ans: b]JUIS-16) (a) 6.75 (b) 7.0 (o) 7.25 (@) 7.50 60, GOH BRC pH A 14 eH era zee (H*] Sere UST eae 1% NAOH TAH pH aaa RET wT Sol*: H* ACH era = [H*] = 10°F = 10-14 = 0.03991M (Ans.) [KUS-16] 1% NaOH = {}moleL-*NaOH = 025M OH” Wet pH = 14—pon = 14— {-log(o.25)) soaefba pH = 1339794 (Ans. ) 61. 0.01N NaOH Batt NaOH 100% Stafiw ex; Se Baca pH we? IRUIS-14 @12 2 (0) HATE Bae pH ats HE @artea Sol": (a); NaOH 44 YT AUT 1 REET O.O1N NaOH = 0.01N NaOH 100% ‘OMS Rew, Batt OH" BT ETAT = 001M 1 “BACT pOH = ~ log(0.01) = 2 -. wate pH = 14-2 = 42 62, sabe pHa cree cory eas Aa Tee ea e? @) Fa (b) Tea Oaratam (dares See es CR TER ATA FT AE Sse Gan. Sap [Ans: b][KU10-11]63. 65. WAR 7 a aifta pH gts Heqe A ae [Ans: c][DU_KA'16-17] (@) Potassium nitrate(b) TSP (c) Dolomite (@) Silica Sol": (c); "FS CUM ACH pH ACH! ASAT dolomite Fw WS ef aniboe cst sae, aIfba pH atey 0.01 M HOLS pOH ete pH wa [DU_KA'16-17] (131 () 14,0 (122 @ 113 Sol?: (¢); PH = —log[H*] = ~log(0.01) = 2,pOH = 14—pH = 14-2 = 12 arid aren ara fftrma aa eae ke = 4.2%10°35-1 | fafeutta wag eo? [Ans: e]{CU'16-17] (@)3.75 min (6) 3.25 min (©) 1.75 min (4) 2.25 min (©) 2.75 min Sol: (©); Tye = 2 = 275 min Stoon corm fafteara frases Benn cafit 3? [Ans:b] [RU'16-17] (a) H2(g) + I(g) + 2HIfg) (b) PCI;(g) © PCI,(g) + Clz(g) (©)Nz(8) +3H2(2) © 2Ni(@) (@Nz(g) + 02(g) + 2NO(g) Se WCET Salen Te SSE eae oe ae tt are eae sePAR Hef aT enweRE we eM aa efePTS AE Gar HCl, H)SO,4 SIRES FES WHE TET THNS AT RIRCTSIRG, rat wees tee ART wea at © UT Dery Sar EFT CaO, NaOH Sewanee Tea ] SRAM Ter (i) SE we ery Bee {Se cht wat why act HY AI Fo | (ii) ere Ray RT Ae CAT UAT SAT wat ON” a eet Ahaeeen (i) eceta yeas oA CT ye ee aero et Se act eMeH aT cae ETE @ Hea SE OE NTR SPN EHS TA AT Gi) CuSO, © AICI; aa ott gat eee ete NaCO; aa wate eet wath) a orn ee we STRAP TSA AT | Saobe mst wwe et ces MEAT G) Se er or ae othr ar ares a war sates conde He eRCT MCT Gi) Fr Sr ar asi CN at rT TT MIE ROS cet stest ACT “et NH} HHC] == NHA“+CI HCL aeita wer aca Cl tela eee HCL ors | wrt NH, tides ster etd NH," os aS ey | SE eB wre Epa Se TTI Es TR PE ae oe catia CMON TOT Ge Ee ae aH OIE OF wraLeR SETA wet Sag eran rae EET aT rR AA se ty eT Bawa aT AGUNG were Ce cece ee cade SepTAETE FH Cx areT IB aE Oe Se WET FE IT Sig rae eget ere Eee er pt eee we ee Gig aT ‘Serer: () HCL+ HO aor + A Gi) gl + NH SNe SROOE Tea CETTE STATS oaTE ITE Pee Pow Rae STATA EA ATE ST HAS AH | OP: NHG, H. ES cain Ginna cin nea cen ieee UE 6 Sted aH Wea Wer aPre: qa ars Twa PHC rere Boral ater eT tans TAR APRS | OMA- FeCh, ZnCh Fa ae a TERE NER | THEA H*, BF 6 «TES IRTAR Cu*, Ca”, AICI, eV we : ow corp Bevelie erate ww tare see GT FA CURT HO, CH3-NHp, NHs, OH", CO, 388 Son Sara fareSRG core FARA 9a Ra, Se oat Rotie we ree RIS aH Geyer eg zea ar whore cll Tew aT OH Ci ET ATOR LR caf oar ea wit RI Sey are BF CRT) eR IMS SE ORTEe Rota went | ok ROE Rone ate en tes aft at tere ws Ba Gee ea aT Sa: Rent seme, eta cee, Bar, commen Benth | aeten, TEA ea eT ‘Roa oifhce Frac of oT at pH Gas 7, Robie ate weir at witearoee et [af ataeora pH sare Core wie wi AAT 8.3-10.0 aT aie a 8.3-10.5 for ae i ie 7.28.8 CPR GS SH rer 6.8-8.4 CTR oul aT 6.0-7.6 Soar eT a 60-8.0 Feet Cae RT =F 42-63 Fale eae cs | EG 31-44 Tarcfeee he eit | “Aer 38-54 Deine cease afte 6 wire Pear Sra home | geet Race pH aeons Rete Oa afie Cig ie | cae: HCl « NaOH sat Gxcubasansd 3.19.7 6-11 357 ‘pH ws Ste Sica afeaea (i) Sea Fre we GA (Ka) a EB we fer Gi HCI, HBr, HI, HNO;, H,SO, #efe we aa gat oT weepfacet orifie eH | wos Sg SE eT | oor K, aa aT gee a | Gi) wrafee CH,COOH agit ara 5% Freanfes war ky=1.8x10% 1 Gi wan afte ARE Sfier mn ye ePromes oat eas at mea Te lr 2 uficer Saw we caf eT 47 4604548 41 HCIO,> H,S0; > HNO;> H,S03> HNO; >HCIO Civ) ee Fices eda or TREE BET CUT ANTS eT SH CRT ATE IG HE CUD RMR DF RAO wx YE epi oi aren Cigar cote #747 HT HCIO2HBr0,-H10, Related Questions: Ol, Wifes waa 3 (Ans: d][RU714-15] (a) HCOOH (b) CHCOOH ()CHsCH,COOH (ay CICH,COOH 02. Na,CO, «a winaet apr ager? [Ans: b][CU’08-09] (a) srr ( (6) eaters (a) et (¢) erie ae 03. ag coma K, aaa acto? (gU°11-12] (a) CH,CH,COOH (PYCICH,COOH = (c) Cl,CCOOH (d) Cl,CHCOOH 9 i Sol”: (b); Cl” Ae rT ser cH aPiee ae a Cl” Tae aA —C-O-H ae -O-H FER Sead Wag BERS A eT TS 04, Sara camenrenrierra xf fear [Ans: aJ[RU*08-09] (@) erent (b) Ht (o) #4 (a) cet CaP a RITA TH cod on- Seger ATEA ETE SRR 05. eat ena era? [Ans: b][RU’08-09} @BH; =. (b) NH; (c) PHs (d) SbH; 06. Bs afte e SEF er com Rote apES MTP [Ans: b][RU°08-09] (@) arr (b) Freee seta (0) fesrerpefiny (d) tery 07. my Corr CaS nt aay [Ans: d][RU’08-09] (a) sr (b) "tr (6) Fravore (@ ¥en 08. Mg0, V,0,. SIO,@ Nao SAN oRBoe ag 6 wire Ben tof fear? [Ans: b][RU?07-08] @ MQ Ov V,0, (©) SiO, (d) Na,O. 9, HANS, SC aR, x weetea ot {Ans: c][RU'07-08] (@) HF>H,S> HNO, > HIO, (b) HF> HNO, > H,S>HIO, (e) HNO, > HIO, > HF> HS (@) HNO, > HF>H,S> HIO, 10, rr we female y be [Ans: a][RU07-08] (a) (0) CH,COOH ~—@) Hind, (d) HPO, lds ‘eat — Buy peed ‘Fafa nF ei [Ans: d][CU?10-11] @ ere tt, Ours rT frat (c) wav ore 12. facqre eau COR core et: [Ans: e][CU"09-10] @ese a ANG? © a “ge @ AMS ‘Ib, 13, Geta saree fend ee ° [Ans: d][CU*08-09} (a) NaOH“. (b) KOH (©) LioH (a) CsOH () RLOH 14. cart Gini afte Bry [Ans: ¢][(CU’07-08] (a) CH;~CH, (b) CH, =CH, _(¢) CH=CH (d) CH,CH = CH, (¢) NaCl +NaClO, 15. treet cere wf nitatirs pH afean wa. [Ans: c][RU’08-09] (a) 7.0-9.0 (b) 6.5-8.5 or 83-100 (@)5.8-7.0 16. Peas core afirett acicorser mifererat? [Ans: e][CU'1S-16] (@)H,SO; (6) H;Se0 ClO, @HIO, (©) H,PO, 17. SRP “ier aie wr eer ([DU_KA’15-16] (a) HCIO, > HNO > HzS03 > H,50, — (b) HNO, > H,$03 > H,S0, > HCIO, (©)84g503 > H:50, > HCIO, > HNO, {OHCIO, > HS0, > HNO, > H,S05 Sor": (@); HCIO, > H,50, > HNO, > 1,80, 18. Og Pre 6 yy ates DRUM ere Sige Robie emt (Ans: a]PRUP14-15} oft @aameatia (aerate @ eRe 19. “Ceneetr aa af ofaeert pH afer se? [JU"09-10] (@)3.1-40 (b) 42-63 3-100 (a) 1.2-2.8 Sol’: (c); crreeaiy 83-10 frat arte =3.1-4.4 fete ae =4.2-6.3 POA 6.0-8.0 20. cary cite ser aerate aac AE [Ans: d][RU?07-08] (@) H,C-F (b) H,C-Cl (c) H,C-Br (d) H,C-1 21. Frees corm afiinaa Ky ata AF ACER TAN? [DU_KA‘16-17] (@) HySO, (b) HBrO, (c) HNOs @ HClO, Sol": (d); HCLO, aceca “feta FS 2 Semiattemes oo mg tg eed Aes PEface aPices Slaw atte arm cera? & 10, > H,S0, > HNO; >H2S0, —(b) HNO > H2S0; > HCIO, > H,SO, [Ans: a] [KU'L6-17] (¢) HS0, > HNO, > H2S03>HCIO, (4) H2S0; > HNO; > HCIO, > H,S0, = Ses nee en ate toa Sanne aaOPA creme FATT SH oy a a a ‘ORE Ae TE EAE AAT AIM afer acon get GT Fate TS PHL oe WR SHARES Ice we TERT a | Stas SE THE Sto METS Hy ere @ aftceR AEN Sig Te MAMET IB MAT ATH ACA | Gea: CH3COOH ¢ CH;COONa et Rees | rhe arate eertoret By Fe @ 2 eceR ace Cle PIE CNT ee WB ret ae GT CE: NH,OH ¢ NHC] agai! “SBR TR Bet: CHsCOOH + CHxCOONa a? were are: PH = pK, + log (Stl (cesta recreated ater) [Acid] SEEAEEET: NILLOH +NHUCI st era eREe: pOH = pK! log SD SRE, pH=pK.-pKy-log = ase] ea wer fem ae PO, HCO; 6 caida ares fem wel om | Te em Carrs Begs tia ae A, DH 7.4 a erent ce | wi wer rw tore Rte cathe TU BAT | WEA TT pH WF 0.5 oH A afaATeE Ra wre Bhat Heeb Ig RC tee | Urs ASR ERC ST pH= 7 ace 7.8 as Te afaaASS Ew CH Related Questions: Ol, Fras Rereena es car were aet? [DU_KA’13-i4] (a) 0.2 M 10 mL CH,COOH +0.2M 10mL NaOH se / & (b) 0.2 M 10mLCH;COOH + 0.1 M 10 mLNaOH. oF fe (©) 0.1 M 10mL CHjCOOH + 0.2 M 10 mL NaOH cee (0.1 M10mL HCl + 0.2 M10 mL NaOH 2 Sol”: rer Hecst waeye AAA OY I Mae ae MAT MTSTS REA “ (a) Gar get 8 ater at eR rat afte er ae alee aT | (b) 6S" CH,COOH =a (CH,COONa) 3 axe aor afte L&, (c) 9 NaOH « wat (CH,COONa) ace ar aise ae (d) a eer ee aT Be CART ACT AP FT | 02. 20 mi 02M Banfte fie (K, =1.8x10") ee 20 mL 0.19/M NaOH Fata Fielets atom aeegs SAPP ACT DH [DU’11-12,RU°07-08} (a)47 (b) 5.0 (47 Sol"; (a); CH,COOH + NaOH = CH, COONa+H,0 a (eee » 2 PHaph + log Fea foal 8x10 *) log De 4474474 10g 2020-1 is 20x02—20x01 03. Fraps cert area ere? ~ [Ans: b][DU°06-07,CU"03-04,JnU°04-05,12-13] (7.0 474 (a) CH;COOH & NaOH CH3COOH & CHyCOONa (c) NaOH & NaxCOs (@) HCl & NaCl 04, 20°C SrtA O.016M SIPIPS afe 4% Sine en ont aia emer enews? | RU'LI-12] (a) 2.56x10% — (b) 2.56x10" (c) 3.1x10° @) 4.0107 [Ans: a} 05, Se ara afro a re et cart eae aE, pH Rear Ans: bj [09-10] (a) are oats Dy ofaets ac at (¢) sire wee veda er @) apis tata Nee ee EE aaR ae ee TT TA we aAit TE IRA 06, ape anaes AI Se aT IES CT caTeIe CH Flere pH fis aa wT alee CHS aA — [RU"08-09) QfrraE = (b) SETA rar ret @) arte [Ans: a] 07, Sofie aPreE K, <4 1.810% &F 0.3M SmPe atces erawate pH *e7[Ans:c][RU08-09 (a) 1.63 (b) 2.06 (c) 2.63 (d) 2.03 08. 0.1 Gr RATATAIe ATE 6 0.1 cote crfem Petcarcad FAB wae pHFe? (pK, = 5] [Ans:e][RU'07-08 (@) 10x10 —(b) 2 (Ss @1 09, WR SRR AT [Ans: a][RU707-08] GN Tee — er ae (0) eRedets - crete ofr (c) Re afte - aed (d) cornfte aar 10, 10 mL O.IM®etefie ae (pK, =4.76) at 4ml.0.1M NaQHEe cot exer Seg BAC pHa We ea? [Ans: b][RU’07-08] (a) 8.74 (b) 4.58 (04.67 (a) 7.46 11. 0.2 mol eit det wee seater fre eae oe 0.02 mol coeur wat fA Geet pH3.8 at aPreBe pKa aa ae carat? [Ans: b][RU’07-08] (a) 5.8 (b) 4.8 (3.8 (2.8 12, 10cm’ stress O.2niol dm am€8Ee fire 400cm> sHrema O.lmol dm? KOHamt wae AReqatta [H*] we mar [Ans: a][RU°07-08] (a) 10° mol dm™(b) 10° moldm~ — (¢} 6x10? moldm™(d) 12x10 mol dm? Sol": (a); Complete neutralization => pH = 7 -.(H™] = 107 mol dm [0.1x0.2«2=0.4x0.1x1] 13. 0.1M CH,COOH(K, =1,0*10)¢ 0.1. M CH,COONa ff? tiiaaats pHs? — (RU*07-08] @s5 b)6 @)7 @s [Ans: a] 14. Bact pH waa Bre arena fear Foaere [Ans: b][RU°07-08] (@) pH thraéa wa (b) pH aftasa cre enc) pH xere aE (d) CoABE AT 15, oat sof6s apes gacta wD acta wr fot seer SERS pH wisews ee? (Ans: e][(CU*12-13] (a) 0 (b) -log2 (c) log2 (d)1 (e) core ae Sol": pH= pK, + tog td 3 pH, —pH, =log. etl =log2 16, 25°C Sprran Soits aPred kPa = 4.76, OnSaTs SPREE cate S.0pH 4a SR eet era eee =n aE? (a) The ratio of Na & Acetic (b) The ratio of Na & Acetic asid is 1:1.738 (c) The ratio of Na & Acetic (@) None (Ans: a][CU*12-13] 17, Rca crinft apeta wae FH? (Ans: c][CU°15-16] (a) CH,COOH + CH;COONa (b) NH,OH +.NH,CI (ef HCI + NaCl (a) NajCO; + NaHCO; (©) CH, - CH, — COOH + CH,CH, — COONa 18, wea aera crate pH an 7.4 Be aera Rees siAhie aPioes wD fea? [RU'15-16] <(@) 1:10 2:5 (@) 1:25 @ 20:1 Sol’: Giank) ; ee Pres K, reat at erat Bea Pte es AL 19, oP Aretg race ANNAN X™ S HX SIR! HX 4K, = 10-6 Remy ATS HAA pOH FS? [RU'IS-16] (@)3 (08 (6 (d)14 Sol*: (b); FTAA X“ATLHX WH pH = pKa -: PH = —logKa = —log(107°) = 6 -. pOoH = 14-6 =8 a Sea Safire fata ge Here em TEOPA errr ‘SA IH Pa 20. CH,COOH- ea wits gat CH,COONa cit saeraact- [RU*12-13] (a) He *eot age (b) p Hager (c) pH#e @) SARE = t Sol: (a); pH=pka- loge we CH,COONa mt #41 pH a1gct 21. eneteh ¢ fafiem wrest weg sé [Ans: b]{JU16-17] (a) dH =AU + PA (b) AH = Aq (©) Bene (¢) @rRe aa 22, 6a ACTER Wal Ka aa ae BCA MTT [Ans: No Answer][JU'16-17] QR Owes CE whem mmnpnfeeta) hye TITIES Sine ees a ‘stots Tae eee SIS HO AT wihee sera iad ara Seer ws of ct ea arent Gil) *iFFicw FoR at erat orttert | (iv) catace sree | (v) rece ont 9 nfs cee ate eat eae SIT aT arernits sitet ww Vltatate cor 25°C 298K eirmate afie ¢ wreves fefaeT 1 mol ons TH ES or TT ‘atten Gea ee wlcw etter armen ae 1 He Ste elite ar Sig a cAe oP SCORE AT ANY 6 $7.31 kJ 25°C vista Big afte 6 IEEE etaT OIC TA tg ate Oe aa {— HCI NaOH FSO, NaOH HNO; | NaOH HCI KOH wis aioe yar (i) smteahion = wore I: corm artnre: frame cx afer ote eC ob Fea Rebs TE @ ask afta wrt Ie, Gra foe Farts aE | Hoag her oiers 0x8) —> Cu06); alt= Eins 1 ©2046) —veuly+ 04g; aHEST KamadS (i) RE FE svs0 at WH RA G.H Hess wre aerate atheonere oat emp wnfrera Fs ara CS AT ARR MICE TT CHR ew a HE Wp ot cee pashan tal cere MTT A” * COT TES AST HET TA SoS, Sgn Bane Gaoie TE FAN SF 2 ol. 02. 03. 05. 07, scram: dt ~re enthalpein sé to wamin, Tr Bote wees afer ate Rote ot 6 ameerE oer AS CM HE CH CTP He IC ar ae | aT HL WaT eer eT A AH=AU+PAV AH= H.-H, AU=U,-U, (i) SH = H,-H,, Hp= Ceara caid =f; H.= fteeres cad fe (ii) AG = AH -TAS, AG = qe «fez oad, AS = eB hta afd (iii) AH = AU+PAU = AU+AnRT (iv) Gort sae aE eT Beery St QT, Q=msad m = 38a 5 = F8F SRS SI; AG = wera aftaes (v) sar ff eas Feira wrt Refees omar aT, AH=Hg-Hp 251 Bae 100. snes aSat 300 kj wT eMC TACT TCM ee? [SAU*L4-15] (a) 120K} mol™* (6) 300k] mal? {¢) 600k] mol“? (d) 750k) mol-* Sol: (d); FE Sie = VO — 750 Kjole“ NaOH (aq) + HCI(aq) = NaCl(aq) + H20(1) at aH? ear (Ans: b)[SU"14-15] (a) -S7.24K} (b) -57,28K] (©) -58.03K} (d) =55.2K] CHyCOzH (aq) + NaOH (aq) » CH,COONa(aq) + Hz0()) «4% AH? At [Ans: ¢][JU"14-13} (@)-50.4K) (b)~55.6] (©)-55.2K} (@) -68.6K) + A90.3K] HEA Slt BOM WE CHy + 20r4—) > COrrg) + ZH2Oqy FUfsrMECE eS ATT O, AEA? ——|KUP14-15] (a) 64 (b) 16. (c)32 (d) 12 Sol": (c); CH, + 20, > CO, + 2H20;4H =-890Kj 2%, 890K] a3 ST 02 AI 64g #890.3K] 49 FT 0, FM 64g -. 490.3K) oa GT 0p aes SALE? a, 35.259 = 32g 090 ores fom ace Riftrur afena “fe eae AH Fe? [Ans:b)[KU"14-15] at Bc 47OK & z 5 t + Natare of rection (a) 112 KJ mol™!, -35 KJ mol™? (b) 112 K} mol~!, 35 Kj mol-! (c) 211 KJ mol“, 35 Kj mol-* (d) —112 Kj mol, -35 K] mol-* fate corm afters qarera setae wir adifire 2 [Ans: b][RU"14-15} (a)HCI-KOH — (b)HE=NnOU (6) CHCOOH — NaOH (6) HF — NH,OH or Afra bP ar ae? IDU_KA’14-15] (a) 2C(s) + 02(g) + 2CO(e) (b) 2H2S(g) + S0.(g) > 3S(s) + 2H,0(g) (c) 4Fe(s) + 30; (g) + 2Fe,05(s) (d) CO(g) + 2H2(g) — CHOH() Sol": (c); werps fafieaa Oa 51 AOE! frome fafitrme erie fafaom arent, AH, we? wy (C), WeCEIET (H,) wae Beer (C,H) erat we BM, AH? WHET —394, —286, R -1561kI mol” | 2C(s) +3H,(g) > C,H,(e) (a) AHS =—394-286+1561kI mol" (6) AHg =—1561 —(2x—394)— (3x-286)kI mol () AH, =—1561+294+ 286k mol” (d) AHS, = (2-394) +(3x-286)~(-1561)kJ mol" Sot"s(d); Feftem wrt = Riess werent - Beoneces FETE [DU_KA’13-14] Cn ees err Tem RTA ae. Sogn. Sager aTSa ermice 09. ream cory Feftemts corms mera AH, erat aca (@) H,SO,,(@q) + Ca(OH); (aq) ~> CaSO (aq) + 241,0(1) (b) H,SO, (aq) + 2NH, (aq) — (NH, ), SO, (aq) (©) HCI(aq)+ J4 Ca(OH), (aq)—> ¥ CaCl, (aq)+H,0(1) (d) 2HCI(aq) + Ca(OH), (aq) -> CaCl, (aq) +2H,0(1) Sol": SIF Ie ETP oPis o Hee my era false 1 mofe MT Bey LE LAI 10. 25°C wrewranm-e Latm sre Bi, eT © Rrwcra eR wr HEN - 1410.92 KT, -284.24 Ke 1560.24 KJ. Bafeera Rena Oye era fas ser (DU"11-12] (@) 144.925 (6) 244.92K) =) 34.92 (d) -134.92 KJ Sol": CH, +30, +200, +2H,0...-.n-(i) 3 Coy +202 9 2C0; + 3H,0~+ + Gil) H;4+20, $F HOn uli); +()— GRE MR, CH, +H, +H, AH = (C,H, o@ Fer oI) + (H, CERAM) -(C,H, aR eI) =+1410.92 -284.24 - (-1560,24) =-134.92 KI ll, MLeeit arma citi oa onbee gage eae oreo AE ore Res cat eT ABA oT TER araraft AH, (kJ) Fo? [DU’08-09,DU’02-03] ML(s) + Water —> ML(aq) ML) + xH,0 > MLxH,0(8) mL.xH,0(s)+Water—>ML(aq) AH, = LOKI (a) +60 (&) - 60 (©) -40 ~(d) +40 Sol’: (b); AH, = AH ~ AH, =-50-10 =-60 kJ > 12, 10 Sm on 4° Gr, caee 14° GF, Beta Cate Tate Se WIAA wit are? [DU°08-09] (a) 10 Calories (6) 14 Calories (¢) 100 Calories. (d) 140 Calories ¢ Sol": (c); Q= MSAO =10x1x10 =100Calories. P ae [m=10 g; S=1 Cal/ g®; AO=(14-4PC=10°C] ~N3, HCl-aa aca NaOH (8s Fa) ¢ NH,OH (1 WH) oe eT BAIT $7.32 8 -51.46 kJ mol NH,OH 8 face wt 5? [DU°04-05] (@) 5.86 kT mol (b) 10.26 kI mol (c) 15.86 kJ mol (d) 58.6 kJ mol Sol": (a); NaOH «a sri Recufere vice | NH,OH -ce aa sac crac Feemiire sare em aa wR Heat CRE OT AES RH | FAME TI = = $1.46 — (37.32) = 5.86kImol! 14. Cu+HNO, (1o% 1g) > ax Boome ear [Ans: a][JU°10-11] (a) Cu(NO,), +H,0+NO (b) Cu(NO,), +H,04NO, (¢) CHO+H,O+N, (@) arREar 15, GR sates abe (JU? 11-12] (a) Q, =AE+PAY (b) SE=Q, + PAV (c) PAV =AE+Q, (d) coat a Sol": (a); Q, =AB+PAV; Q,= STS ee AE = way ster afiees PAV SUTey ofiqvrafae ore Sepi aro 16. 17. 18. 20. 2h. 22. 23, 24, PT OFT ne CT's commie aR ee [JU’ 11-12] (@) AH=AE+AnRT (b) AB = AH+ AnRT (c) AnRT =AE+ AH (d) conta Sol®: (d); AH = AE =AnRT ; AH =urrafts ofaadet AB = Sere fea AE 5 ANRT = Sites otetate Ger carr aaa Aa? [JU'11-12] (a) Q, x Stata ater = ons oat x tthe ater (b) Q, = aa aaa x aie eset x wrt ates (©) Q, = “if fast + (ater srretet 2c ereratae antes) @) Q, = Cafta afr nf sien) + crate adap Sol": (b); SIRT Sift, Q = mSAO 94s St = on we x SIPS Set x BTS aT ape 6 ATO ATE GA AST? [su?11-12] (a) ies Feta eI = 1/ meds facmTER wit (b) aICeE ROTA wrt = AH ate FecmTERT wT (co) area mena wit = eimicda Fem wt (d) TOE RE eI = stares CMTE eT = 1 Sol": (@); tated Aes Rome AT aea Tesh eA | a HE afer Bua eB | seared CraTS ae! aEAOCAT SPATS BH A HR ee, eter MS CHEE AB | ). HNO, § NaOH a eens eres? (JU"10-11] (a) -57.35 KI (b)-67.34KJ — (¢) -53.34KT —(d) -59.44 KI Sol": (a); HNO, + NaOH =~$7.35 KJ, HCl+ NaOH =-57,35 KJ ae® wore fatten — [Ans: ¢}[JU°10-11RU*12-13] (a) AH>O (b) AG>0 (2) aG<0 G) art Ea soir col fafaear wrt Beth ar we fefiemen weTeae wee BeomreT wepatte eer oT — [Ans: b] @* (b) ot (7 (d) saeert ae (JU"10-11,RU"07-08) aPRCRRIR MTNA St AEP [5010-11] (a) +249.2 KJ/mol (b) +218.0KJ/mol (c) +106.0 KJ/mol (@) +112.0 KJ/ mol Sol’: (a); *aafert wis, H=+218.0 KI/mol, O=+249.2KI/ mol SUT RTS AT Sh ea aT FH? [yU710-11] (a) are (b) sare ei (c) cqaraiira afteea (d) tet ae eTET Sol": (a); corer eer awa BETES Orr | are BRS ore eer TEE | kg Set °C EP tee MOA EP Praca wer aA — 890.3 KImol! Bet 1780 KJ era Sexg sacs f ifr eer teat ey (a) 701.83 g (6) 107.83 g (32g @u7g (3010-11) Sol": (6); fears wrafes |x 16 | 890 KJ wre Benq eat 16 at Faces ceca . 2.1780 KJ er *T6RT ae weenie a2 gn Ree ee | ea ere eae CRC SAATT SH A? [JU'10-11] (a) Pizareis Rte (b) cater a (c) Ted) eta toa eh Sol"; (b); A, Cy D aae firera atten ererara Fre we RTT ACAI | 26. Se ETE CET NT ae Goa Mer AE co OF CATA wre Cte Ceo are ere oT MeO wT OTR & ohens fe were [Ans: b][JU*10-11] (a) bre (by aeRO (o) TT HA (A) FaeeeTR BE se AN OE eee OES ASAT AS AT are kegs Seg EATSire sree as asc 27. OP apf ators a Bos gree © eratbce Fy Rerem Be xcar 28. 29, (a) S51 aaQ Ato an Baap stan (©) STP aay tay oa wore Arex, WoT 3 Ra [3U709-10] (b) 341 eras stem oa B were her (d) 228 were Fee aa B eres ste Sol": (a); Ra Fee ape or a SIM eae 1 wee nce aren eon wie co aL AIP ATC ROAR Rea wreoreenht ser a a eS | Cu TR Cart Pree ctw Fes ace sh emia ett wee aaa WAT eT, WT COTA etfieut? (a) wre (by sa (©) 7c (d) Feorts [yU709-10} Sol”: (c)3 HBT = P feet Feare = T fess areerhts Prtew errors aCe coc TAT AT | coral ret Beene faftem2 @ Cls)+0,(¢)= Co, (2) (©) 30,(g) = 20,(g) [Ans: a][RU?12-13,08-09,SAU714-15] (b) Ni(g}+0,(g) = 2NO(g) @ C(s)+Sls)= cs, (1) 30. awh eter fattema cao corn CRS Hie {Ans: e][RU"11-12] (a) AH #8 (b) AH ST (c) AH «ange (qd) AH Warge 31. Gr arms Riri ora afrads craita Bx free wer ate {Ans: d][RU*10-11] (a) fafa 6 Benacaa ors weg (b) iter o Setters eight (0) Fetes sat © cre arent afte (¢) Ferma were Fag wre RAR 32. C (diamond) + 0, (g) =CO,(g) ear wren 4 fafeaTee KI/mol ei Bey Ta? [RU?10-11] (a) 393.5 (b) 395.5 (©) 3985 (4) 399.5 {Ans: b] 33. can weer tried wet cote [Ans: a][RU?09-10] (a) oF (b) 1 (c) ea (@) een 34. H,SO, aa gay wit ey [Ans: d][RU°09-10] (a) 64.52 ferepr (b) 72.52 Ree (¢) 78.03 RET (A) 84.52 eT 35. Wem mero eo? [RU*09-10) (a) 783k) (b) 797i (©) 799k; (a) 787kj Sol": #8 Bem: 394.5k Jmol” 36. C (armed) + 02(g) = CO, (g) eftraita emamiir afeaes, AH — ery [RU’08-09] (a) -393.4 kJ mol™ (b) +390.4 kJ mol"(c) +393.4 kJ mol (d) 390.4 kJ mot 37, Nye srt. 46,19K) tN, + 3H, = 2NH, fates Aiea ert ee: [RU*08-09,RU°07-08] (a)-46.19 KJ (b) 46.19 KI (6) - 92.38 KI (d) 92.38 KJ [Ans: ¢] 38. erat Ce Feet Terr VIER wr (Ans: ¢][RU"08-09] (a-1 b) +1 @o (d)+2 39, free arnt wieght Risen (@) C+0, +0, (&) N, +0, NO (©) S+0, >S0,() 2H, +0, + 2H,0 40, ater oxy wrmares HET areinfh qeneCT —385.40 kT mol’ ~ 1594.6 kJ mol” or are cree cate ERTS ater Sritecrs arti rasa ea [Ans: a}[RU°07-08] (a) -1890 joule (6) +768.91 joule (c) 768.91 joule (4) +1980 joule Al, Reema we SI —902.83KI mol, CO, (g) 8 H,O(1) aa mer erm wa —406.13K Jmol"! = 285.85 KJ mol” @ CH,(g) ea Fenda wrt wor (a) ~686.17K Jmol (b) -116.49K Jmol” (c} -226.76KImol"(d) None ae CSC TAns: b][RU’07-08] {Ans: dj{CU12-13]ie SATE ‘WAR Sa SS 8 42, “Towarm in" 205 corm “cw Baa atocep [Ans: d][KU?12-13] (a) «ahr (b) Sete (c) STIR (d) erat 43, Gn aor [Ans: b][KU’12-13] (2) AG > 0, Pitan -zargs (b) AH <0, feu rere (©) AH <0, Peftea afez (d) Gabe ar 44, fi Deities ereefis wy (Hp) Remcer cera ate (Hr) ey er ee RST a (AH) (a) -ve (b) + ve @o (d)araPEar (Ans: AJ[KU"11-12] 45. ROR ARPA Ss atitatts mitece— [Ans: d][KU°10-11] (a) Great (b) Ram saa (c) eA wal et e SMT SAT TE (das b Cente ar 46. Ste ofie ¢ Sig eras cone wR TR [Ans: ¢][KU?10-11] (ayo (b) -S.73KF (6)-S7.34KJ — (d) +57.34KT 47. ‘ro Cora apiratere ecm a Saree AY [Ans: ¢][RU’09-10] @) saa hore ()enpTE mm Go) smeNinatE gE (0) Renae a 48. caraid wrerart faferm [Ans: ¢][CU’08-09) (a) C+0, +00, (b) 2H, + O, + 2H, (c) C+28-+€8, (d) N, +3H, > 2NH, (¢) 280, +0, +280, 49. 25°C err Gy fie 6 Gig ee om [Ans; ¢][RU°09-10] (a) +57.34K Jmol (b) —75.43K Jmol * (c) -57.34KJmol™ (d) +45,37KJmol™ 50, Fema car eters etter Fafa wren am ase RA? (Ans; d][CU'11-12] (a) 8a aE 6 ae yeahs Er (0) am afie © yee (as ofe e Syme (©) arte a $1. CO(g) + 2H2(g) = CH,OH(g) fefiraa K, aa ae eT [DU_KA‘15-16] @) Kp = K-(RT) (b) Ky = K(RT)? = OK, = Ke @) Ky = K (RT)? Sol": (b); An = 1-1-2=-2; Kp =K-(RT)!" = K.(RT)-? 52. NaCl aa ANS H,0 Fe warm fee WB? TAns: b]{DU_KA"15-16] (@) NaOH (aq) + HCl(aq) () Nat (aq) + Cl (aq) (©) NaOH(aq)*Cl, (g) (d) OH” (aq) + CI" (aq) 53. Pegs fafa een ecw ender erate ret ret faifer ea [DU_KA’ 15-16] (@ C() +202(g) > CO(g) aH? = -111.0 Kj mol* (i) CO(g) + $02(g) + CO2(g) AH = ~283.0 KJ mol* (@) -173.0 KJ mol™}(b) —394.0 KJ mol“ (c)373.0 KJmol~! (4) 394.0 K) mol“ Sol": (b); €(s) +3 02(g) + CO(g) AH? = ~111.0KJmol~* CO(g) 4+ 02(g) + CO,(g) AH = ~283.0K}mol"* ‘I FT, C(s) + O2(g) + CO2(g) | AH? = ~394.0K] mol~* . 54. 25°C wietaTaTy 001M NaOH Hata pH 8? [Ans: a]{CU'16-17] @i2 5s ron @2 10 (a); pH = 14 — pOH = 14+ loglOH™] = 12 Ka koa taetet stan iol. 02. 03. 05. 07. 08. Carre srg Ree [Ans: dj{SnU°09-10,RU'09-10] @ om (yaa (© attr FRG COR Baer pret Resa cca rr See cece RapgtS arco cet Ee? {Ans: b][JnU708-09] (a) n-CIcSa @ n-Ca em (©) ares Pier (@) Rare 9 ares CaarSrATRS coat pet ame [yu'11-12] (a) Barret ) Rares abrelef ay (a) crea a Sol":(c); Rare, OUT ony, wReGAS fe ee wae wae | aT eT fea Ie Ret) ee aT 78% THRICE TIER | . Mae gat. acs gree carat? {JU?11-12] (a) H, (b) CO, A (d) He Sol: (chs Ty wr Fafeq sic Fert | aoe tT -78% N, AA ACF N, SaGaT THT OIG e ARS wire aa maPRoR Bae ESAS 120.5°C, sy Tee aProes Ee Fe? [Ans: b][JU"LI-12] (a) 08sec poy Bec (© 78°C (d) 68.4°C no er Acar S we — 0d (yU'11-12] (0) raf Retr ra pore chaste cans yt (¢) wits feria war TF (a) GaRRR ar Sol’: (b); © Ef Relies + TCE art + cater e anise felts = Bais + ai; cert + oT corpfice a ARB aT CoA? [JU'1i-12] art a (b) Free (C) Gebers Pat (d) oe re Sort:(a)s ALE AUTEN N,(78%) wers ace ecokew ae FTI (O, CO, H,) | amar fleet NT TH SI ACS STEM PAO et? [sU"09-10] (107 -10*em () 10°7=10%m (6) 107—10%mm (4) 107 -10% nm Sor":(a); 7m7e Reet ae BT 10” ern cs OE CE wre 10? — 10 em. ee es aT PAGO carat cataract aero 1? [Ans:d][RU'16-17] (a) arate Qe abe (Confer cracHs Orvis ats . 500g are 30g Abia Bact as Hoi CURT OCT FOP [Ans: e][RU°09-10] (a) 0.99780.003 (©) 0.990% 0.010 (© 0.9938 0.007 (@ 0.898 0.102 = er et eae [Ans: d][RU°08-09) (@) Rae s AE TTT (©) Greater s afta Bet (cere aT ahi Ca ag SAT ET oe Soa Sarnia oTee ANA SF A ee O—EO Oe Se 12. fiero IF Cort? [Ans: ¢][CU*07-08] @rtt 6 RAR ~ (b) ae or “a8 AREA (d) ah « afethe OBE (otf 6 Beta 13, “ears Tg ST A ee FY [Ans: b][RU’09-10] @aet (¢) ost (d) START 9 febtscaea fier 14. fea aera Sas Fy [Ans: b][RU08-09] (@ ate Loy Sera saa SF (¢) wette (d) set 15, WING cate CnTeT Cay? [Ans: d][RU708-09] (@)NaHCO, (b) Na,CO,.5H,O (©) NaHCO,.3H,0 Att) Na,CO,.10H,0 16, ARCRIOSE CeCe CT FI oreS aT ATR? © [Ans: e][CU'10-11] (a) BaF (b) =a _foeetiar (a) RecA ore vibT (e) HR 17, feces oa reee comtb? [Ans: e][JnU'09-10] (2) CryHssCOONa (b) CisHy,COONa }C12H»sOSO3Na (d) @rBR ar 18° "Sun Screen agent "#4 Taw BE. [Ans: ¢][RU’09-10] (2) 2,4-9% Greate oPiPs fe = (b) sitar wef areranierr are Feat citeree (@ otras antes 19, state Prom Serere Rone trem am? [Ans: b][RU’09-10] (a) etre of fetes (cy of (d) Barwer 20, fecrna aerce fie gu [Ans: d][RU’09-10] (a) Row entities afte (b) SIPs aires 25% erate yet (c) shite oBres 50% wate ET Ad) sire fren 6-10% BA aR 21. Ger tard shepa oree E eH? TAns: a}{JnU'15-16] Agee () Hel (@)Aqua—regia (4) HPO, 22." contt shir Breaceits? [Ans: a][JU?15-16] Crise aca (o) feats cot (o) ofa Bet (d) Be va BO ste we % oT ate? (Ans: c] [(JU'15-16] (a) 78.2 (b) 80.2 oh 87.2 (0) 90.2 4, aneiee ge Rotation fen wae a [Ans.: a][RU'15-16] JORG are (Weer (aaaD A @ cratreats 28, eae 4 Pape Pere eT PS TUTTI? [Ans: b][KU'L6-17] (01-20 (e) 2-500 (@)500-1000 (4) 1000-1200 26. ameter eT wes er | [Ans: a][CU'16-17] @) carta ) art are (oxtest at (¢) RoR 21. -SemBR Becta BIAS TCH IATA (light scattering) SC FAI [Ans:b][RU'16-17] ()aeRa ees (d) b Ge BRR ) TTS RRS forwr BorT