g ==) ABU DHABI INDIAN SCHOOL ~ABUDHABI ELECTRO CHEMISTRY ~ ELECTROCHEMICAL CELLS WORK SHEET 1 2) a)What is a galvanic cell ? b)How does a galvanic cell differ from electrolytic cell ? ©)Draw the galvanic cell in which the cell reaction is 2Cr + 3Cue* - ~ 3Cu + 2Cr3* 2) Consider the electrochemical cell given in the diagram and answer the following questions _ Cia ved 4 eiteeyy agicay) a) Whats the net cell reaction ? b)Mark the anode cathode ,positive and negative terminals,©) Mark the direction of flow of electrons. what is contained in salt bridge ? e) what happens if salt bridge is removed ? 3)Write the aode and cathode reactions in the following cells ? a)2Br-# 2H? -enee- Bra + Ha b) Mg + Cu —~ -Mge + Cu Fe? + Age Fe +Ag= = ABU DHABI INDIAN SCHOOL ~ABUDHABI ELECTRO CHEMISTRY — WORK SHEET 3 NERNST EQUATION 1) Write the Nernst equations for the the given cells a) AI/AB*+// Cu®*/Cu b) Cr /Cr®* // Cu? /Cu in which the cell reaction is 2)Calculate the cell potent a)2Gr(s) + 3Cu2+(aq)(.01M) >3Cu (s) + 2Cr*(aq)(.001M) b) Pt(s) /Br2/Br(0.010M) // H*(0.030M) /H2{g) /Pt ¢] Fe(s)/Fe?* (001m)//#H* /(1M) H2(G)/(tbar) /Pt(s) 3)Calculate EMF of the cell Mg/Mg?* (0.2M) // Ag’ ( 1x10 2M) /Ag. What will be the effect on EMF if concentration of Mg? ion is decreased to 0.1M.ABU DHABI INDIAN SCHOOL, ABUDHABI WORK SHEET - ELECTROCHEMISTRY ‘What is SHE? 'b) What isthe E for Standard Hydrogen Elrod? ©) Can you store copper sulphate solaton in azine pot? Why? “Represent the galvanic cell a which the following rection taking place 201 +Fe" 200" + Fe Write individ reation at ach electrode? Calcite the E valve ofthe cll ‘A galvanic eal is repre by diping a copper ro in 1M CuSO. slaion and Ni rod in 1M 180. solution. 8) Whats the cell reason? 1b) Represent the et ©) Caleulte the standard em ofthe ell The emf of ell Ni/ Ni/Cu" Cw 18059. 1) Write the cel eaetion taking place in he cell, 1b) te emf the Cu clcoe is 0.34V, calelate he emf ofthe Ni electrode 3}Can Frees Cu ons? Why? ')Can we store AgNO in Copper vessel? ) Fou metals have the values -3.05V"-1.66V, OA0V and 0.80 V respectively, Which oe will be the strongest edcing agent? Arrange them aeording tthe ineeasing ode of reducing sharacterABU DHABI INDIAN SCHOOL -ABUDHABI ELECTRO CHEMISTRY ~ ELECTROCHEMICAL CELLS WORK SHEET 3 PRIMARY CELL 1) Write the anode and cathode reactions in dry cell 2) Mercury cell gives a constant voltage Why? 3) Dry cell do not have a long life Why ? 4) What are primary cells ? '5) What is the role of ZnCl, in dry cell ? 6) Name the electrolyte used in Dry cell ?cy ABUDHABI INDIAN SCHOOL - ABU DHABI SZ, WORKSHEET EQUILIBRIUM CONSTANT & GIBBS ENERSY 1. Under what conditions is Eqa =0 or AG =02, 2, What is meant by standard emf ofthe cell? Derive an expression between standard emf of the cell and equilibrium constant. 3. Define electric work done. 4, Caleulate the equilibrium constant fr the following reaction at 298 K Culs) #Ch ig) > CuC(aa.) (3.296%10") 5. Whats the relationship between Gibbs free energy ofa cell & emf of a cell? When will the maximum be obtained from a galvanic cel? 6. What the significance of Gibbs energy change? 7. Calculate the equilibrium constant for the following reaction at 298 K Z2n(s) +Cu*"(aq.) > Zn™(aq.) + Cu(s) (1.679x10") 8. Calculate the standard cell potential of galvanic cel in which the following reaction takes place (i) 2Cr{s) +3Cd"(aq.) > 2Cr*(aq.) + 3Cdls) (i Fe"(aq.) + Agaa.) > Fe (aq) + Ags) Calculate A ,G° and equilibrium constant for the reaction 9. Calculate standard Gibbs energy and equilibrium constant forthe following cell reaction 2Fe (aq) + 2laq) > 2Fe™(aq) +h{s) —_(-45.54Kimol', 9.69x107) 10. In the button cells used in watches the following reaction takes place Zn{s) + Ag,O(s) + H2O{l) > Zn"(aq.) + 2Aals) + 20H (2a) Determine standard cell potential standard Gibbs energy forthe reaction (+1.56, -301.08kimol")ABUDHABI INDIAN SCHOOL ABU DHABI WORKSHEET ~ CORROSION |. Define corrosion, ‘State and explain the factors which affect corrosion. \Write the reactions taking place at anode & cathode during rusting of iron. ‘What isa corrosion cell/ corrosion couple? How can we prevent corrosion? During the construction of buildings aluminium frames for windows & steel rallings are preferred over iron. Why? CO; is always present in natural water. Explain its effect on rusting of iron, Explain how rusting of iron is envisaged as setting up of an electrochemical cell 9. Rusting of iron is quicker in saline water than in ordinary water. Why is it 10, Alkaline medium inhibits the rusting of iron. ExplainABU DHABI INVDIAN SCHOOL, ABUDHA3I WORK SHEET - ELECTROCHEMISTRY 8) What is electrolysis? 'b) What ae the factors on whieh the quantity of substance deposited onthe electrode depends? ¢€) How isan electrolytic cll different fom Galvanic eel, 2) Define one Faraday. 'b) How many Faradays ae required to deposit 2 moles of Cu from CuSO solution? ‘)How much charge is required for reducing Imole of AP*to Al 1b) How much electricity in terms of Faraday required for producing 20g of Ca from cach? |. How many moles of mercury willbe produced by electrolyzing IM Hg(N0s) solution by ‘eure of 24 for 3 hours? . Chromium metal canbe placed out fom an scidie solution containing CrDs according to the equation CxO) (ay) + OH"(aq) + 66° ——-Cr{s) +3H0() 4) Calculate howmany grams of Chromium wil be plated out by 24,000 coum 'b)How long will take to plate out 15g of chromium by using 12.5 A curen{Cr=S2) 5. Three electrolytic cell A, B and C containing electrolytic Zn$04, APNOs, and CuSOx respectively were connected in series. steady curent of 1 5A was passed through them tnt L454 of Ag were deposited atthe cathode of cll B, Hox lng di the current flow? ‘What mass of copper and zine were deposited