9) Calcular el valor de (−r A ), si:

Reacción:
A →2 R
(−r A )=2C A2SOLUCION:
$t =$ RV F R −$ A F A 0−$m V (1)

F R =F R 0 +2 F A X

X X
dX dX
V =F A 0 ∫ → V =F A 0∫ 2
0 r 0 K CA

F A0 X dX
V= ∫
F R =2 F A X K 0 1−X 2

[ ( )]
CA 0
1+εX
X
F A0 dX
V= ∫ 2
F R =400 X (2) K CA 0 1−X 2
0
[( ) ]
1+εX
(3)

F A 0=v 0 CA 0
FA 0
C A 0=
v0
200
C A 0= =1 M
200
Reemplazando datos en (3):
X
(1+ X)2
V =100 ∫ dX (4)
0 (1−X )2
En (1):
 X 2
( 1+ X )
$t =(1)( 400 X)−(1)(200)−( 0.04)(100∫ dX )
0 ( 1− X )2
( 1+ X )2
$t =400 X −200−4 ∫ 2
dX
( 1−X )
d $t ( 1+ X )2
=400−4 ( 2
)
dX ( 1−X )
( 1+ X )2
0=400−4 ( 2
)
( 1−X )
X =0.82
HALLAMOS C A:
N A 0 −N A 0 X
C A=
V 0 (1+εX )
1−X
C A=C A 0 ( 1+εX ) (5)

2−1
 ε= =1
1
En (5):
1−0.82
C A=1
( 1+1(0.82) )
C A=0.0989
En la ecuación:
(−r A )=2C A2
(−r A )=2(0.0989)2
(−r A )=0.0196

10. Para los siguientes datos calcular X , F R , $ t , $ RP , V

C A 0=1 M
V 0=35 L/ min $ RV =2/molR
$ A =1/molA $m =0,015/ L. min
 r =2CA 2 ( molg
L . hr )
$t =$ RV F R −$ A F A 0−$m V
F R =F RO +2 F A 0 X F R =2 F A 0 X
x x
x dx F dx
dx V =F A 0 ∫ = A0 ∫
V =F A 0 ∫ 0 KC A
2
K 0 1−X
2

0 r C A 0 ( )
1+ εX
molg
F A 0=V 0 C A 0=( 35 ) ( 1 )=35
min
¿> F R =F R 0 +2 F A 0 X=( 2 ) ( 35 )( X )=70 X
x
FA0 (1+ x)2
V=
K CA 02
∫
0
( )
(1−x )2
dx

x
35 (1+ x )2
V= 2∫ 2
dx
2 CA 0 0 (1−x )
x
(1+ x )2
$t =( 2 ) (70 X )−( 1 ) (35 )−(0,015) 17,5 ∫
[ 0 (1−x )2
dx
]
d $t (1+ x )2
=140−0,2625
dx (1−x)2
(1+ x )2
0=140−0,2625
(1−x)2
0=140(1−x )2−0,2625(1+ x )2
0=( 140 ) ( 12−2 x + x 2 )−0,2625 (12+ 2 x + x 2)
0=140−280 x +140 x2 −0,2625−0,5250 x−0,2625 x 2
0=139,7375 x 2−280,525 x +134,7375
X =0,917

F R =( 70 )( 0,9169 )=64,183
0,9169
(1+ x )2
V =17,5 ∫ dx=614,26
0 (1−x )2
$t =( 140 ) ( 0,917 )−35−( 0,015)(614,26)
$t =84,1521