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Pecutan Akhir Kimia BHGN B & C 2018 + Skema PDF
Pecutan Akhir Kimia BHGN B & C 2018 + Skema PDF
BAHAGIAN B
F4: CHEMICAL BONDS: JOHOR SET 1
1. Diagram 7 shows the chemical symbols which represent three elements P, Q and R. These
letters are not the actual symbols of the elements.
Rajah 7 menunjukkan simbol kimia yang mewakili tuga unsur P, Q dan R. Huruf ini bukan simbol
sebenar bagi unsur.
(a) State which elements that can form ionic and covalent compound when combined.
Nyatakan unsur-unsur yang manakah boleh membentuk sebatian ionik dan kovalen apabila ia
berpadu. [2 marks]
(b) Based on Diagram 7, explain how two compounds in question 7(a) can be formed from these
elements. The two compounds should have different type of bonds.
Berdasarkan Rajah 7, terangkan bagaimanakan dua sebatian dalam soalan 7(a) ini boleh
terbentuk. Dua sebatian ini sepatutnya mempunyai ikatan yang berbeza. [10 marks]
(c) Compare and explain the physical properties between the ionic compound and covalent
compound. Your answer should consist of the following:
Bandingkan dan jelaskan ciri-ciri fizikal antara sebatian ion dengan sebatian kovalen. Jawapan
anda perlu mengandungi perkara berikut:
• Melting point and boiling point
Takat lebur dan takat didih
• Electrical conductivity
Kekonduksian elektrik [8 marks]
Diagram 8 / Rajah 8
Compound P is a highly volatile, flammable organic liquid with petroleum like odour. Compound
P is insoluble in water and less dense than water.
Uses: formulation of glue and leather products.
Sebatian P mudah meruwap, cecair organik yang mudah terbakar dengan bau serupa petroleum.
Sebatian P tidak larut dalam air dan kurang tumpat daripada air.
Penggunaan: bahan untuk membuat pelekat dan bahan-bahan dari kulit.
Compound Q is a colourless, highly volatile, flammable organic liquid with petroleum-like odor. It
is insoluble in water and less dense than water.
Uses: solvent and chemical antiseptic.
Sebatian Q merupakan cecair tidak berwarna, mudah meruwap, cecair organik yang mudah
terbakar dengan bau serupa petroleum. Sebatian Q tidak larut dalam air dan kurang tumpat
daripada air.
Penggunaan: pelarut dan antiseptik kimia.
Compare and contrast these two hydrocarbons based on their structure formulae.
Banding dan bezakan kedua-dua hidrokarbon ini berdasarkan formula strukturnya. [4 marks]
(b) Table 8 shows the properties of four organic compounds. Each compound has three carbon
atoms per molecule.
Jadual 8 menunjukkan sifat empat sebatian organik. Setiap sebatian mempunyai tiga atom
karbon per molekul.
Based on table, state the names for the homologous series for compounds W, X, Y and Z.
Berdasarkan jadual, nyatakan nama bagi siri homolog untuk sebatian W, X, Y and Z. [4 marks]
(c) Diagram 8.2 shows the conversion of an organic compound from one homologous series to
another.
Rajah 8.2 menunjukkan penukaran sebatian organik daripada satu siri homolog kepada yang
lain.
3. Diagram 7.1 shows eight test tubes containing lead(II) chromate(VI) precipitate. The
experiment was carried out to construct an ionic equation for the formation of lead (II)
chromate(VI).
Rajah 7.1 menunjukkan lapan tabung uji mengandungi mendakan plumbum(II) kromat(VI).
Eksperimen tersebut telah dijalankan untuk membina persamaan ion bagi pembentukan
plumbum(II) kromat(VI).
Dengan menggunakan isipadu yang diperolehi, hitungkan bilangan mol bagi ion plumbum(II) dan
ion kromat(VI) yang diperlukan untuk pembentukan plumbum(II) kromat(VI).
[4 marks]
(ii) Write the ionic equation for the formation of lead(II) chromate(VI).
Tulis persamaan ion bagi pembentukan plumbum(II) kromat(VI) [2 marks]
(c)
(iii) Copper(II) salt is a soluble salt. Describe briefly a chemical test to verify the cation and
anion present in aqueous solution of the salt.
Garam kuprum(II) adalah garam terlarutkan. Huraikan secara ringkas ujian kimia untuk
mengesahkan kehadiran kation dan anion yang hadir dalam larutan akueus garam tersebut.
[5 marks]
(b) One of the method used to prevent iron from corrosion is tin plating. Diagram 8.2 shows a
food can that is electroplated with tin.
Salah satu kaedah digunakan untuk menghalang besi daripada terkakis adalah penyaduran timah.
Rajah 8.2 menunjukkan satu tin makanan yang disadurkan dengan timah
(c) Diagram 8.3 shows the apparatus set-ups and observations for redox reaction involving
metal X.
Rajah 8.3 menunjukkan susunan radas dan pemerhatian bagi tindak balas redoks yang
melibatkan logam X.
(a)(i) Based on article shown in Diagram 7.1, mothballs are commonly used as the main
insecticide to repel cockroaches.
Name the process involved and explain how the mothballs vapour act as insecticide by using
Kinetic Theory of Matter.
Berdasarkan artikel dalam Rajah 7.1, ubat gegat kebiasaannya digunakan sebagai insektisid
untuk menghalau lipas.
Namakan proses yang terlibat dan terangkan bagaimana wap ubat gegat bertindak sebagai
insektisid menggunakan Teori Kinetik Jirim. [4 marks]
(ii) Solid mothballs melt into liquid when heated in water bath.
Diagram 7.2 shows the heating curve of the solid mothballs.
Pepejal ubat gegat melebur menjadi cecair apabila dipanaskan dalam kukus air.
Rajah 7.2 menunjukkan lengkungan pemanasan pepejal ubat gegat.
Based on Diagram 7.2, describe the curve from the region of P to Q and the region of R to S. In
your description include:
Berdasarkan Rajah 7.2, huraikan lengkung dari bahagian P ke Q dan dari bahagian R ke S.
Dalam huraian anda sertakan:
• state of matter
keadaan jirim
• movement of the particles
pergerakan zarah-zarah
• diagram of particles arrangement
gambarajah susunan zarah-zarah [6 marks]
(b) Diagram 7.3 shows subatomic particles in the nucleus of three carbon atoms.
Rajah 7.3 menunjukkan zarah subatom di dalam nukleus bagi tiga atom karbon.
(ii) Compare and contrast the three carbon atoms in terms of:
Banding dan bezakan ketiga –tiga atom tersebut dari segi:
• Number of proton
Bilangan proton
• Number of neutron
Bilangan neutron
• Number of electron
Bilangan elektron
• Physical properties
Sifat fizikal
• Chemical properties
Sifat kimia [5 marks]
The following are three examples of salts that can be prepared using either Method I or Method
II.
Berikut adalah tiga contoh garam yang boleh disediakan sama ada menggunakan Kaedah I atau
Kaedah II.
(ii) From the given examples, identify the salts that can be prepared by using the methods as
shown in Diagram 8.1.
Daripada contoh-contoh yang diberikan, kenalpasti garam-garam yang boleh disediakan melalui
kaedah-kaedah seperti di dalam Rajah 8.1. [2 marks]
(ii) State the reactants for the preparation of salt in Method II.
Nyatakan bahan tindak balas bagi penyediaan garam dalam Kaedah II. [2 marks]
(b) Diagram 8.2 shows the graph of the height of precipitate against the volume of potassium
iodide solution used to construct the ionic equation for the formation of lead(II) iodide through
continuous variation method using 0.2 mol dm-3 potassium iodide solution and 5 cm3 of 0.1 mol
dm-3 salt P solution.
Rajah 8.2 menunjukkan graf tinggi mendakan melawan isipadu larutan kalium iodida yang
digunakan untuk membina persamaan ion bagi pembentukan plumbum(II) iodida melalui
kaedah perubahan berterusan menggunakan larutan kalium iodida 0.2 mol dm-3 dan 5 cm3
larutan garam P 0.1 mol dm-3.
(ii) Describe a chemical test to verify the cation and anion in solution Y.
Huraikan ujian kimia untuk mengesahkan kehadiran kation dan anion di dalam larutan Y.
[6 marks]
7. (a) A group of students carry out an electrolysis of ethanoic acid solution, CH3COOH by
using carbon electrodes.
Sekumpulan pelajar menjalankan suatu elektrolisis larutan asid etanoik, CH3COOH,
menggunakan elektrod karbon.
By using your knowledge of factors affecting the selective discharge of ions at the electrodes,
Dengan menggunakan pengetahuan anda tentang faktor-faktor yang mempengaruhi pemilihan
ion untuk dinyahcaskan di elektrod,
(i) Identify the ion that is selectively discharge at anode and cathode.
Kenal pasti ion yang dipilih menyahcas di anod dan katod.
(ii) Write half equation for the reactions occurred at anode and cathode.
Tuliskan persamaan setengah yang berlaku di anod dan katod.
(b) Table 3.1 shows the apparatus set-up to electroplate iron spoon.
Jadual 3.1 menunjukkan susunan radas bagi menyadurkan sudu besi.
Observation on
iron spoon
Set Apparatus set up
Pemerhatian
Set Susunan radas
terhadap sudu
besi
A
Silver
Iron spoon Argentum No changes
II Sudu besi Tiada perubahan
Silver nitrate
solution
Larutan
argentum nitrat
Based on the observation in Table 3.1, explain the differences in Set I and Set II.
Berdasarkan pemerhatian dalam Jadual 3.1, terangkan mengapa terdapat
perbezaan dalam Set I dan Set II.
[4 marks]
(c) Table 3.2 shows the apparatus set-up and observation for four different of cells using
1.0 mol dm-3 copper(II) sulphate solution
Jadual 3.2 menunjukkan susunan radas dan pemerhatian bagi empat sel yang
berbeza menggunakan larutan kuprum(II) sulfat 1.0 mol dm-3.
Electrolyte:
Copper(II) su lphate Elektrolit:
solution The intensity of blue
Larutan kuprum ( II ) colour of copper(II)
sulfat sulphate solution remain
Keamatan warna biru
larutan kuprum(II) sulfat
kekal
III Anode:
Anod:
V
Magnesium plate
becomes thinner
Kepingan magnesium
Copper menipis
Mag nesium Kuprum
Mag n esium Electrolyte:
Elektrolit:
Copper(II) sulphate The intensity of blue
colour of copper(II)
solution
sulphate solution
Larutan kuprum ( II )
decreases
sulfat
Keamatan warna biru
larutan kuprum(II) sulfat
berkurang
Anode:
IV V Anod:
8 (a) Diagram 7 shows the apparatus set-up and the observations of three sets of the
experiments to study the displacement of halogen. The products formed are then added
with 1,1,1-trichloroethane.
Rajah 7 menunjukkan susunan radas dan pemerhatian bagi tiga set eksperimen untuk
mengkaji penyesaran halogen. Kemudian, hasil yang terbentuk ditambah dengan
1,1,1-trikloroetana.
Set
I II III
Set
(ii) By using the reaction in set I, explain the meaning of redox reaction in terms
of the oxidation number. Write the chemical equation for the reaction.
Dengan menggunakan tindak balas dalam set I, terangkan maksud tindak
balas redoks dari segi nombor pengoksidaan. Tuliskan persamaan kimia bagi
tindak balas itu. [5 marks]
(b) Table 4 shows the results of two experiments to study the effects of metals P and Q
on the rusting of iron.
Jadual 4 menunjukkan keputusan bagi dua eksperimen untuk mengkaji kesan
logam P dan logam Q terhadap pengaratan besi.
Experiment Observation
Eksperimen Pemerhatian
I Hot agar solution containing
potassium hexacyanoferrate(III)
and phenolphthalein
Larutan agar-agar panas
mengandungi larutan kalium Dark blue spots formed.
heksasianoferat(III) dan Tompok biru tua
fenolftalein terbentuk.
Iron nail
Paku besi
Metal P
Logam P
Table 4 / Jadual 4
(i) Explain why there is a difference in observations in both experiments and
include the half equations.
Terangkan mengapa terdapat perbezaan pemerhatian dalam kedua-dua
eksperiment dan sertakan setengah persamaan. [8 marks]
9 (a) Food stored in a refrigerator last longer than food stored in a kitchen cabinet.
Explain why.
Makanan yang disimpan di dalam peti sejuk tahan lebih lama daripada makanan
yang disimpan dalam kabinet dapur. Terangkan mengapa.
[4 marks]
(b) Table 7 shows the information for three sets of experiment to investigate factors
affecting the rate of reaction between calcium carbonate and hydrochloric acid.
Jadual 7 menunjukkan maklumat bagi tiga set eksperimen untuk menyiasat faktor-
faktor yang mempengaruhi kadar tindak balas antara kalsium karbonat dengan asid
hidroklorik.
Tuliskan persamaan kimia bagi tindak balas antara kalsium karbonat dengan
asid hidroklorik. Hitungkan isipadu maksimum bagi gas karbon dioksida yang
terhasil dalam Set I.
[Diberi isipadu molar bagi gas ialah 24 dm3 mol-1 pada keadaan bilik] [5 marks]
10. (a) Diagram 8 shows the apparatus set-up for redox reactions involving electron
transfer at a distance.
Rajah 8 menunjukkan susunan radas bagi tindak balas redoks yang melibatkan
pemindahan elektron pada satu jarak.
(b) The Prime Minister of Malaysia, YAB Tun Dr.Mahathir Bin Mohamad had visited to
Japan on 10-12 June 2018. In his visit, he has suggested to produce national car
2.0.
You are selected to work at the car factory.
Suggest the way to control the rusting and give a reason for your answer of the
following parts of cars:
• Gear and engine
• Car body
• Tire rim
Perdana Menteri Malaysia, YAB Tun Dr. Mahathir Bin Mohamad telah membuat
lawatan ke negara Jepun pada 10-12 Jun 2018. Dalam lawatan itu beliau telah
mencadangkan untuk mengeluarkan kereta nasional 2.0.
Anda telah dipilih untuk bekerja di kilang kereta itu.
Cadangkan cara untuk mengawal pengaratan dan berikan satu sebab bagi jawapan
anda pada bahagian-bahagian kereta berikut:
• Gear dan enjin
• Badan kereta
• Rim tayar [6 marks]
(c) Table 8 shows the apparatus set-up and observation of two set of experiments, Set
I and Set II for the reaction between metal X and metal Y with copper(II) oxide.
Jadual 8 menunjukkan susunan radas dan pemerhatian dua set eksperimen, Set I
dan Set II bagi tindak balas antara logam X dan logam Y dengan kuprum(II)
oksida.
Apparatus set up Observation
Set
Susunan radas Pemerhatian
Mixture of metal X and A glow spreads to the whole
copper(II) oxide. mixture.Black solid change
Campuran logam X dan to brown solid.
Kuprum(II) oksida
I Baraan merebak ke
seluruhan campuran.
Pepejal hitam bertukar ke
pepejal perang
Table 8 / Jadual 8
BAHAGIAN C
F4: SALT: JOHOR SET 1
1. Salts played an important part of human life. Salts is used in many areas such as fertilizers in
agricultural, painting, industry, medicine and cooking.
Garam memainkan peranan penting dalam kehidupan manusia. Garam digunakan dalam pelbagai
bidang seperti baja dalam pertanian, mengecat. industry, perubatan dan memasak.
(b)
The displacement of iodine, I2 from potassium iodide, KI
solution by halogen Y is a redox reaction.
Penyesaran iodin, I2 daripada larutan kalium iodida oleh halogen Y
adalah tindak balas redoks.
Based on the above statement, design an experiment to verify the reaction that occurred is a
redox reaction. In your description, include the following.
Berdasarkan penytaan di atas, rancangkan satu eksperimen untuk mengesahkan bahawa tindak
balas yang berlaku adalah tindak balas redoks. Dalam penerangan anda, sertakan yang berikut
• Name of suitable halogen Y
Nama halogen Y yang sesuai
• Procedure
Prosedur
• Test to identify the ion that is produced
Ujian untuk mengenalpasti ion yang terhasil
• Explanation on oxidation and reduction process
Penerangan berkaitan proses pengoksidaan dan penurunan
• Ionic equations
Persamaan ion
[10 marks]
(a) The sting of a jelly-fish is alkaline and can cause pain. Suggest one substance that can be
applied to the skin to relieve the pain without causing further injury. Give three reasons for your
suggestion.
Sengatan obor-obor adalah beralkali dan boleh menyebabkan kesakitan. Cadangkan satu bahan
yang boleh disapu pada kulit untuk mengurangkan rasa sakit tanpa menyebabkan kecederaan
yang seterusnya. Beri tiga sebab bagi cadangan anda. [4 marks]
Acid P Q
Asid
Uses of acid
Kegunaan asid
pH value 5 1
Nilai pH
Table 9.2 / Jadual 9.2
By naming an example for each acid, explain why the pH values are different.
Dengan menamakan satu contoh bagi setiap asid, terangkan mengapa nilai pH adalah berbeza.
[6 marks]
Diagram 9.3
Rajah 9.3
Zinc sulphate salt can be prepared by adding solid X into acid Y solution. Suggest a suitable
solid X and acid Y.
Describe how you can prepare a dry zinc sulphate salt by using solid X and acid Y.
Garam zink sulfat boleh disediakan dengan menambahkan pepejal X ke dalam larutan asid Y.
Cadangkan pepejal X dan larutan asid Y yang digunakan.
Huraikan bagaimana anda dapat menyediakan garam zink sulfat yang kering dengan
menggunakan pepejal X dan larutan asid Y. [10 marks]
4. Diagram 10.1 shows the conversion of few carbon compounds with less than four carbon
atoms.
Rajah 10.1 menunjukkan penukaran beberapa sebatian karbon yang mempunyai atom karbon
kurang daripada empat.
(ii) By using suitable number of carbon atom, draw the structural formula of compound P,
carboxylic acid Q and alkene W.
Dengan menggunakan bilangan atom karbon yang sesuai, lukiskan formula struktur bagi
sebatian P, asid karbosilik Q dan alkena W. [6 marks]
(iii) By using compound P and alkene W that obtained in 10(a)(ii), describe how to conduct
reaction II in the laboratory. In your description, include:
Labeled diagram
Procedure
Chemical equation
Chemical test to proof the product
Dengan menggunakan sebatian P dan alkena W yang diperolehi di 10(a)(ii), huraikan
bagaimana tindak balas II dijalankan dalam makmal. Dalam huraian anda, sertakan:
Gambar rajah berlabel
Prosedur
Persamaan kimia
Ujian kimia untuk mengesahkan hasil tindak balas [10 marks]
Suggest the carboxylic acid and a reagent that can be used to produce carboxylic acid Q from
compound P. Write the chemical equation involved in this conversion.
Cadangkan nama asid karboksilik tersebut. Nyatakan suatu bahan yang boleh digunakan untuk
menghasilkan asid ini. Tulis persamaan kimia yang terlibat. [4 marks]
5. (a) Edham telah diarahkan oleh gurunya supaya menjalankan ujian ke atas dua jenis
hidrokarbon yang mempunyai kumpulan berfungsi yang berbeza iaitu sebatian hidrokarbon X dan
Y. Sehubungan dengan itu, beliau telah menjalankan tiga tindak balas untuk membezakan sifat
kimia bagi dua hidrokarbon tersebut.
Jadual 9.1 menunjukkan pemerhatian hasil daripada ujian yang telah dijalankan.
(i) Berdasarkan maklumat dalam Rajah 9.1, sebatian X dan Y masing-masing mempunyai enam
atom karbon, cadangkan sebatian X dan sebatian Y.
Nyatakan formula molekul sebatian X dan sebatian Y seterusnya lukis formula struktur bagi
kedua-dua sebatian X dan Y. [6 markah]
(ii) Pembakaran sebatian X menghasilkan lebih banyak jelaga berbanding sebatian X. Jelaskan.
[ Jisim Atom Relatif : H = 1C = 12 ] [4 markah]
(b) Faqihah sangat menggemari kuih traditional iaitu tapai pulut. Pada suatu hari, Faqihah
meminta ibunya menyediakan makanan tersebut untuk jamuan hari raya di sekolahnya.
Berdasarkan situasi itu, nyatakan nama tindak balas yang berlaku bagi menyediakan kuih
tradisional itu.
Sebagai seorang murid, huraikan penyediaan etanol dalam makmal sekolah yang
mengandungi perkara yang berikut:
(i) senarai bahan
(ii) susunan radas
(ii) prosedur
(iii) persamaan tindak balas [10 markah]
Berdasarkan rajah 10.1, terangkan perbezaan nilai haba pembakaran bagi butana dan oktana.
[4 markah]
(c) Bioetanol (C2H5OH) merupakan salah satu bahan bakar alternatif yang lebih mesra alam dan
mudah diperoleh dari tumbuhan seperti pokok tebu dan ubi kayu.
Rajah 10.2 menunjukkan bioetanol digunakan sebagai bahan api.
7. Diagram 9.1 shows the three element cards, X, Y and Z. X and Y can react with Z to form
different type of compounds.
Gambarajah 9.1 menunjukan tiga kad unsur, X, Y dan Z. X dan Y boleh bertindakbalas dengan
Z membentuk sebatian yang berbeza.
(ii) Based on Diagram 9.1, suggest any two suitable elements that can react to form a
compound.
State the type of bond formed and explain the formation of the compound.
Berdasarkan Rajah 9.1, cadangkan dua unsur yang sesuai bertindak balas membentuk suatu
sebatian.
Nyatakan jenis ikatan yang terbentuk dan terangkan pembentukan sebatian tersebut.[7 marks]
(b) Diagram 9.2 shows the arrangement of particle for two types of compound.
Rajah 9.2 menunjukkan susunan zarah dua jenis sebatian.
THERMOCHEMICAL EQUATION
PERSAMAAN TERMOKIMIA:
(a) Based on Diagram 10.1, verify the heat of combustion of methane by using the following
formula, Energy change, ΔH = Ex - Ey and identify the type of reaction.
Berdasarkan Rajah 10.1, tentusahkan haba pembakaran metana menggunakan formula,
Perubahan tenaga, ΔH = Ex - Ey dan kenalpasti jenis tindak balas tersebut. [4 marks]
(b) Diagram 10.2 shows the cross section of apparatus set-up for two sets of experiment to
determine the heat of reaction.
Rajah 10.2 menunjukkan keratan rentas susunan radas bagi dua set ekperimen untuk
menentukan haba tindakbalas
(ii) Based on Diagram 10.2, compare Set I and Set II in terms of:
Berdasarkan Rajah 10.2, bandingkan antara Set I dan Set II dari segi:
• Heat change in the reaction
Perubahan tenaga haba dalam tindakbalas
• Change in total energy content of reactants and total energy content of products
Perubahan jumlah kandungan tenaga bagi bahan tindakbalas dan hasil tindakbalas.[2 marks]
(ii) Hydrochloric acid in Set I is replaced with 100 cm3 of 1.0 mol dm-3 of copper(II) sulphate
solution. The initial temperature of solution recorded is 28.0 °C and the highest temperature of
the mixture is 40.0 °C.
Calculate the heat of reaction in this experiment.
[Specific heat capacity of solution, c = 4.2 J g-1 °C-1]
Asid hidroklorik didalam Set I digantikan dengan 100 cm3larutan kuprum(II) sulfat 1.0 mol dm-3.
Suhu awal larutan direkodkan adalah 28.0 °C dan suhu tertinggi campuran adalah 40.0 °C.
Hitung haba tindakbalas bagi eksperimen ini.
[Muatan haba tentu bagi air, c = 4.2 J g-1 °C-1] [4 marks]
(c) A student carried out an experiment to determine the heat of precipitation of zinc carbonate.
Describe an experiment to determine the heat of precipitation of zinc carbonate.
Your answer should include the following:
Seorang pelajar menjalankan satu eksperimen untuk menentukan haba pemendakan zink
karbonat.
Huraikan eksperimen untuk menentukan haba pemendakan zink karbonat.
Jawapan anda perlu mengandungi perkara berikut:
• Suggest the suitable reactants required
Cadangkan bahan tindak balas yang sesuai
• Procedure
Prosedur
• Chemical equation
Persamaan kimia [10 marks]
9 The following equation represents the reaction between magnesium and acid P. Acid P is
a monoprotic acid.
Persamaan berikut mewakili tindak balas antara magnesium dengan asid P. Asid P
adalah asid monobes.
Mg + Acid P → Salt Q + H2
Mg + Asid P → Garam Q + H2
(ii) From your answer in 9(a)(i) , write the chemical equation for the reaction.
Daripada jawapan anda di 9(a)(i) , tulis persamaan kimia bagi tindak balas itu.
[2 marks]
(b) Diagram 8 shows a flow chart of magnesium salts.
Rajah 8 menunjukkan carta alir bagi garam magnesium
MgSO 4
+ Solution R
Lauran R Salt
MgCl 2
MgCO 3 + Garam
Reaction I
Mg(NO 3) 2 Tindak balas I
Reaction II + Acid W
Tindak balas II + Asid W
Magnesium salt
Garam magnesium
Diagram 8 / Rajah 8
All the three salts, MgSO4, MgCl2 and Mg(NO3)2 in Diagram 8 can be converted to MgCO3
by reaction I, then MgCO3 reacts with acid W to form a Magnesium salt through
reaction II.
Ketiga-tiga garam, MgSO4, MgCl2 dan Mg(NO3)2 dalam Rajah 8 boleh ditukar kepada
MgCO3 melalui tindak balas I, kemudian MgCO3 bertindak balas dengan asid W
membentuk satu garam magnesium melalui tindak balas II.
(i) By choosing one of the three salts in Diagram 8, suggest solution R to prepare
magnesium carbonate, MgCO3.
Write the chemical equation involved and describe a laboratory experiment to
prepare magnesium carbonate, MgCO3.
Dengan memilih satu garam di Rajah 8, cadangkan larutan R untuk menyediakan
(ii) Suggest acid W to prepare any one of the three magnesium salt in Diagram 8.
Write a chemical equation involved and describe a laboratory experiment to
prepare the salt.
Cadangkan asid W untuk menyediakan salah satu daripada tiga garam
magnesium di Rajah 8.
Tulis persamaan kimia yang terlibat dan huraikan eksperimen makmal untuk
menyediakan garam itu. [8 marks]
10. Mr. Ali is a rubber plantation entrepreneur. Rubber factory A wants to buy latex in liquid
form while rubber factory B wants to buy latex in solid form to produce tyres.
En. Ali adalah seorang pengusaha ladang getah. Kilang getah A mahu membeli lateks
dalam bentuk cecair manakala kilang getah B mahu membeli lateks dalam bentuk
pepejal untuk pembuatan tayar.
Diagram 9 shows a flow chart to prepare the rubber for rubber factory A and rubber factory
B by Mr. Ali.
Rajah 9 menunjukkan carta alir untuk menyediakan getah bagi kilang getah A dan kilang
getah B oleh En. Ali.
(a) (i) Based on the Diagram 9, suggest solution X, solution Y and process Z.
Berdasarkan Rajah 9, cadangkan larutan X, larutan Y dan proses Z. [3 marks]
(ii) Explain
Terangkan
1. why physical state of latex different when solution X and solution Y are added into
fresh latex.
kenapa keadaan fizikal lateks berbeza apabila larutan X dan larutan Y ditambahkan
ke dalam lateks segar.
Describe an experiment to verify the above statement by listing the materials and
apparatus.
Huraikan satu eksperimen untuk menentusahkan pernyataan di atas dengan
menyenaraikan bahan dan radas. [8 marks]
BAHAGIAN B
Q and R
1. Electron arrangement of Q atom is 2.4 and R atom is 2.6
2. To achieve stable octet electron arrangement
3. Q atom contributes 4 electrons for sharing and R atom contributes 2 electrons for sharing
4. One Q atom and two R atoms share electrons
5. A compound with the formula QR2 is formed
6.
(c)
(b) 1. When food can dent, the tin plate is crack and form small hole and the ion is exposed.
2. Iron atom will donates/releases 2 electrons to form iron(II) ions
3. Fe → Fe2+ + 2e
4. In food can also have water and some oxygen gas. The water and oxygen gas gain electron
to formed hydroxide ion
5. Iron(II) ion will combine with hydroxide ion to form iron(II) hydroxide.
6. Fe2+ + 2OH- → Fe(OH)2
7. Fe(OH)3 are oxidized by oxygen to form brown solid which is iron(III) oxide /rust.
(ii)
(ii)
7.
(a)(i) Anode: OH-
Cathode: H+
(ii) Anode : 4OH- → O2 + H2O + 4e
Cathode : 2H+ + 2e → H2
(iii) Insert a lighted wooden splinter into the mouth of the test tube.
A pop sound is produced
(b) In Set I :
- Iron spoon is connected at cathode
- The position of Ag+ ion is lower than H+ ion in electrochemical series. Ag+
ion is selectively discharged to form silver atom // Ag+ + e → Ag
In Set II :
- Iron spoon is placed at anode
- No silver atom formed
(c)(i) In Cell I
- OH- is discharged at anode because the position of OH- is lower than NO3- in
ECS
- Oxygen gas is formed // 4OH- → O2 + 2H2O + 4e
In Cell II
- copper anode ionises to form Cu2+ ion because copper is active
electrode// Cu →Cu2+ + 2e
In Cell IV
- Copper is more electropositive than silver
- Copper atom ionises to form Cu2+// Cu→ Cu2+ + 2e
- The concentration of Cu2+ increases because copper ionises to form Cu2+
at copper electrode (negative terminal) // Cu → Cu2+ + 2e
8 (a)(i) X: Iodine
Y: Bromine
Z: Chlorine
Z→Y → X
(b)(i) Set I:
1. Iron rusts.
4. Fe → Fe2+ + 2e
Set II:
8. O2 + 2H2O + 4e → 4 OH–
Q → Iron → P
9.
(a)
Food stored in a refrigerator Food stored in a kitchen
Makanan disimpan dalam cabinet
peti sejuk Makanan disimpan dalam
kabinet dapur
1.The temperature is lower 1.The temperature is higher
Suhu lebih rendah Suhu adalah lebih tinggi
2. Bacterial activity is lower 2.Bacterial activity is higher.
Aktiviti bakteria adalah lebih Aktiviti bakteria lebih tinggi
rendah
3. Less toxin is produced by the 3. More toxin is produced by
Bacteria. bacteria
Kurang toksin dihasilkan oleh . Lebih toksin dihasilkan oleh
bakteria bakteria
(ii) Set II
Average rate of reaction = 40
45
= 0.889 cm3 s-1
10.
(a) Fe2+ ion release electron to form Fe3+ //
Ion Fe2+ membebaskan elektron membentuk ion Fe3+
Fe2+ ion undergoes oxidation //
Ion Fe2+ mengalami pengoksidaan
MnO4 – ion accept electron to form Mn2+ ion //
Ion MnO4 – menerima elektron membentuk ion Mn2+
MnO4 – ion undergoes reduction //
Ion MnO4 – mengalami penurunan
(b)
Part The way Reason
Bahagian Cara Sebab
Gear and Put grease// Moving parts or engine//bahagian enjin
engine// Letak gris yang bergerak
Gear dan
enjin
Paints // Prevent water and air from reaching
Car body// Cat the surface of iron//
Badan kereta Mencegah air dan udara sampai ke
permukaan besi
Set I
3. The reaction occurred // Tindak balas berlaku
Set II
10. The reaction did not occur because metal Y below copper in the reactivity
series.//
Tindak balas tidak berlaku sebab logam Y dibawah kuprum dalam siri
kereaktifan
BAHAGIAN C
1. (a) Salt is a substance formed when hydrogen ion from acid is replaced by metal ion or
ammonium ion
(b) 1. React excess magnesium oxide with nitric acid or hydrochloric acid
2. MgO + 2HCl → MgCl2 + H2O
Correct chemical formula for reactants and products
Balanced chemical equation
3. Filter out the mixture to remove excess magnesium oxide powder.
4. Add sodium carbonate solution into the filtrate containing magnesium chloride solution.
Double decomposition reaction occurs and insoluble magnesium carbonate is precipitated
5. MgCl2 + Na2CO3 → MgCO3 + 2NaCl
Correct chemical formula for reactants and products
Balanced chemical equation
6. Filter the mixture. The insoluble magnesium carbonate is collected in filter paper
7. Rinse magnesium carbonate with distilled water
8. The magnesium carbonate is dried by pressing between two filter papers.
2. (a)
Cell A Cell B
Ions in electrolyte Cu2+ , H+ , SO4 2-, OH ̅
Ion selectively None. OH ̅ ion
discharged Because copper is Because position of OH ̅ ion
at anode active electrode. is lower than SO42- ion in
electrochemical series
Observation at anode Anode P: Copper Anode X: colourless gas
becomes thinner bubbles released
Half equation Anode P: Anode X:
Cu → Cu2+ + 2e 4OH ̅ → O2 + 2H2O + 4e
Reaction at anode Anode P: Copper Anode X: OH ̅ ion release
release electron to electrons to form Oxygen
form Cu2+ ion // gas and water // Oxidation
Copper atom is oxidised to occur
Cu2+ ion // oxidation occur
Procedure
2. Pour 2 cm3 of potassium iodide into test tube
3. Add 2 cm3 of chlorine water // bromine water into the test tube.
4. Add 1,1,1 – trichloroethane // tetrachloromethane to the test tube and shake the test tube
5. Put a stopper to the test tube
6. Observation : The purple layer formed at the bottom of the test tube.
Labeled diagram
1. Functional diagram
2. Label: glass wool, ethanol, porcelain chip//alumina//other
substance, water, boiling tube
Procedure
3. Some glass wool is placed in a boiling tube
4. Using a dropper, some ethanol is added into the boiling tube to wet the glass wool
5. The boiling tube is clamped horizontally and unglazed porcelain chip are placed in the mid-
section of boiling tube.
6. The boiling tube is closed with a stopper fitted with a delivery tube and the other hand of
delivery tube is placed under an inverted test tube filled with water.
7. The unglazed porcelain chips are heated strongly. When the porcelain chips are hot, the
flame is shifted to gently heat the glass wool to vaporize the ethanol.
Chemical equation
8. C2H5OH → C2H4 + H2O
Chemical test to proof the product
9. Flow the gas produced in a test tube contain bromine water // acidified potassium
manganate(VII) solution.
10. If ethene produced then brown bromine water /purple acidified potassium manganate(VII)
solution turns colourless
P4 : Peratus kandungan karbon mengikut jisim bagi heksena lebih tinggi berbanding heksena
Prosedur
P5 : 200 cm3 air suling disukat dan dituang ke dalam kelalang kon
P6 : 20 g glukosa ditimbang dan dimasukkan ke dalam kelalang kon
P7 : 10 g yis ditimbang dan dimasukkan ke dalam kelalang kon
P8 : Kelalang kon ditutup dan dibiarkan selama tiga hari ditempat hangat / pada suhu 35oC
Persamaan tindakbalas
P9 : Betul bahan dan hasil
P10 : Persamaan seimbang
Kenaikkan suhu
Ɵ = Q / mc
= 20170 / ( 200 x 4.2)
= 24.0 ⁰C
(ii)
(b)
Butana Oktana
Nilai haba pembakaran 2900 kJ mol-1 5500 kJ mol-1
Saiz molekul / Bilangan Kecil / mengandungi bilangan Lebih besar / bilangan atom
atom karbon dan atom karbon & hidrogen kurang karbon & hidrogen lebih banyak
hidrogen berbanding oktana berbanding butana
semasa pembentukan haba dibebaskan kurang
haba dibebaskan lebih banyak
ikatan berbanding oktana
Haba pembakaran Lebih rendah Lebih tinggi
(c) Prosedur
1. Sukat [50 – 250] cm3 air dan tuangkan ke dalam tin kuprum.
2. Rekodkan suhu awal air.
3. Timbang dan catat jisim awal pelita dan bioetanol.
4. Letakkan pelita dibawah tin kuprum dan nyalakan sumbu.
Keputusan
Bilangan mol
= M1 – M2 // M1 – M2 = n
Jisim molar 46
ΔH = - ----------------------------- = q kJmol-1
M1 – M2
46
OPTION 1
P1. X and Z formed ionic bond
P2. To achieve [stable] octet electron arrangement
P3. X atom release/donate one [valence] electron to form X+ ion.
P4. Z atom gain/receive one electron to form Z ¯ ion
P5. X+ ion and Z ¯ ion are attracted by strong electrostatic force
P6 & P7. Diagram
• Correct number of shells and electron
• Labeled nucleus and charge of ions
OPTION 2
P1. Y and Z form covalent bond
P2. To achieve [stable] octet electron arrangement
P3. One atom Y contribute 4 electrons while
P4. each atom Z contribute 1 electron
P5. One atom Y share 1 pair of electrons each with four atom Z
P6 & P7. Diagram
• Correct number of shells and electron
• Labeled nucleus and correct number of atom
Conclusion:
Compound T is ionic compound and compound V is covalent compound.
(b)(i)
(c) P1.Soluble salt 1: suitable carbonate salt solutions to produce precipitate/ insoluble salt
Sample Answer:
Sodium carbonate solution/ ammonium carbonate solution/potassium carbonate solution.
P2. Soluble salt 2: suitable zinc salt solutions to produce precipitate/ insoluble salt
Sample answer:
Zinc nitrate solution/zinc sulphate solution/zinc chloride solution
Procedure:
P3. Measure [25-200] cm3 of [0.1-2.0] moldm-3 zinc nitrate solution.
P4. Pour into a polystyrene cup.
P5. Measure [25-200] cm3 of [0.1-2.0] moldm-3 sodium carbonate solution.
P6. Pour into a different polystyrene cup.
P7. Measure the initial temperature of both solutions.
P8. Pour sodium carbonate solution quickly into zinc nitrate solution.[a: vice versa]
P9. Stir the mixture.
P10. Record the highest/maximum temperature.[r: final temperature]
P11. Zn(NO3)2 + Na2CO3 → ZnCO3 + 2NaNO3
9.
(a)(i) Hydrochloric acid //nitric acid // ethanoic acid
magnesium chloride// magnesium nitrate // magnesium ethanoate
(ii) Mg + 2HCl → MgCl2 + H2 //
Mg + 2HNO3 → Mg(NO3)2 + H2 //
Mg + 2CH3COOH → Mg(CH3COO)2 + H2
- Correct formula of reactants and products
- Balance chemical equation
(b)(i) Sample answer:
Magnesium chloride, MgCl2
Solution R : sodium/potassium/ammonium carbonate
Sample answer:
MgCl2 + Na2CO3 → MgCO3 + 2NaCl
Procedure :
1. [20-100] cm3 of MgCl2 solution [0.5 - 2.0] mol dm-3 is
poured into a beaker
2. [20-100] cm3 of Na2CO3 solution [0.5 - 2.0] mol dm-3 is
added into MgCl2 solution
3. The mixture is stirred
4. The mixture is filtered
5. The residue is rinsed and dried.
Sample answer :
H2SO4 + MgCO3 → MgSO4 + CO2 + H2O
Procedure:
1. [50-100] cm3 of sulphuric acid [0.5-2.0] mol dm-3 is poured into a
beaker .
2. Magnesium carbonate is added bit by bit into the acid until excess
4. Hang a natural rubber strip to the retort stand by using two clips