Test ID : 512

E- mail : gpccnamakkal@gmail.com Website : www.gpccnamakkal.com

.VOLUME TEST - II (Batch – A))

Std : Long Term Max. Marks: 500

Test Date : 29.03.2020 CHEMISTRY Time : 3.00 Hrs.

Note :
For every correct answer four marks will be awarded. For every wrong answer one mark will
be reduced. For unanswered questions zero mark.
Choose the correct answer : 125 x 4 = 500
1. Which of the following does not give The product (B) in this reaction is
iodoform test 1)
1) ethanol 2) propanone
3) aceto phenone 4) benzo phenone
2. In the given reactions [X] will be 2)
CH3 – CH2 – COOH  Cl2 /Red P

O 3)
1) ||
CH3  CH 2  C  O  C2 H5 4)
O 5. Which of the following Halide is most reactive
|| for SN2 reaction?
2) CH  CH  C  O  CH 2 Cl
3 2
1) CH2 = CH – CH2 – Br
3) CH3  CH  COOH 2)
|
Cl O
4) ClCH2 – CH2 – COOH ||
3) CH 3  C  CH 2  Br
3. The reaction of 
4) CH3  O CH 2  Br
with HBr gives 

6. Which one of the following give

1) predominently SN1 reaction
1) C6H5CH2Cl
2) 2)

3)
3)
4)
4) 7. The order of ease of dehydration of the
  A     B

KMnO4 /OH /  following is
4. C6H5Cl 
HCHO/con.HCl
Anhy ZnCl2
 2 Test ID : 512
2) potassium formate
3) methanal
a) 4) methanol
12. Carbyl amine test is given by
1) Isobutyl amine 2) Sec butyl amine
b) 3) 1-amino propane 4) all of these

13. on dehydration with con H2SO4.

c)
Predominantly forms

d) 1) 2)

1) a > b > c > d 2) a > c > b > d

3) d > c > b > a 4) a > d > b > c
3) 4)
8.


CH3I(2moles)
 A 
H2O2
 B 


 C + D, D is a compound containing 14. 
NaBH 4


nitrogen then ‘C’ is
1) 2)
1)
3) 4)

9. For obtaining ethyl methyl ketone from acetyl 2)

chloride which of the following reagent can be
employed?
3)
1) Grignard reagent
2) reaction with HI
3) H 2 , Pd / BaSO4 4)
4) reaction with  C2H5 2 Cd in the presence
of dry ether 15. Which of the following compound is used to

10. The reaction (CH3)3CBr + HC  CNa   distinguish between phenol and benzoic acid
1) (H3C)2 C = CH2 1) Aqueous NaOH
2) (H3C)2 CHCH = CH2 2) Tollens reagent
3) (H3C)3 C – C  CH 3) Molisch reagent
4) (H3C)3 C – CH = CH2 4) Neutral FeCl3
11. Chloroform on treatment with aq KOH gives 16. C6H6 H2SO4
360o
 A 
Alkali
fusion
 B 
Br2
H2O
C
1) dichloro carbene
In this reaction ‘C’ is
 3 Test ID : 512
3) LiAlD4/H2O 4) NaBD4/H2O
21. CH3CHO + HCHO
1) 2) 
Dil.NaOH

  A  
HCN
H O
  B The structure of
3

compound B is
OH
|
1) CH 2  CH  CH  COOH
3) 4) 2) CH2 = CH – CH2 – CN
3) CH3  CH 2  CH  COOH
|
OH
17. In the reaction for nitration 4) Both (2) and (3)
22. The major product of the following reaction is


con
 X The major product R CH2OH
 
HNO3 H  anhyd 

OH 1) a hemiacetal 2) an acetal
O2N NO2 3) an ether 4) an ester
1) 2) 23. Which of the following gives addition product
with Benzaldehyde
CH3
1) CH3 – CHO 2) CH3 – CH2 – NO2
3) CH3 – CH2 – CN 4) All of these
24. Rosenmunds reduction cannot be used for the
3) 4)
preparation of

1) 2) CH3CHO
18. Consider the following reactions
CH 3  CH  CHO O

SOCl2 3) | 4) ||
ether
CH 3 HCH
25. Arrange the compounds in the decreasing
In this reaction what will takes place order of reactivity for the nucleophilic
1) inversion 2) retention addition
3) racemisation 4) epimerization i) Acid chloride ii) Aldehyde
19. Which of the following combination can be iii) Ketone iv) Amide
used for the preparation of Cis, Vic diol? 1) i > ii > iii > iv 2) iv > iii > ii > i
1) Alkene, Baeyer’s reagent 3) iii > ii > i > iv 4) i > iv > ii > iii
2) Alkene OSO4
3) Alkene, m-CPBA and H2O/H+
26. compound on aldol
4) Both of (1) and (2)

20.
condensation followed by heating gives.
[X] will be
1) LiAH4/H2O 2) LiAlD4/D2O
 4 Test ID : 512

3) 4)
1) 2)

31.
 3
i H O

 ii   P
3) 4)

In the above P is

27. Which of the following cannot reduce

Fehling’s solution
1) HCOOH 2) CH3CHO 1) 2)
3) HCHO 4) CH3COOH
28. 3-hydroxy butanal is formed when X reaction
with Y in dilute Z, what are X,Y, Z
X Y Z
3) 4)
1) CH3 CH2CHO (CH3)2CO NaOH
2) CH3CHO CH3CHO NaCl
3) (CH3)2CO (CH3)2CO HCl 32. In the given reaction [A] and [B] are
4) CH3CHO CH3CHO NaOH
29. In the reaction :
O    A  
 ii  H 2O2 /OH   
 3
 B
NaBH 4 i BH
H2 C

A and B are

1) and HO CH2OH

2) and
3) and
O

4) and O
1) CH2OH CH2 CH2 CH CH2OH and
30. In the given reaction
OH
OH
Zn Hg/ConHCl/ 
 Y [Y] will be
.

2)

1) 2)
 5 Test ID : 512

NH3
|
3) R  CH  COOH
1) 7 2) 14
3) 0 4) 12
36. A tripeptide contains three amino acids A, B
4) Both are CH 2OH  CH 2  CH 2  CH  CH 2OH
|
and C (one mole each) how many tripeptides
OH are possible
33. In the given sequence 1) 3 2) 6
CH 2  COOH 3) 9 4) 12
| 
  A  
CH3  CH 2  NH 2
  B 37. The correct statements about the following
CH 2  COOH disaccharide is
[B] will be
O
||
1) CH 2  C  NH  C2 H 5
|
CH 2  C  NH  C2 H 5
|| 1) Ring (a) is pyranose with -glycosidic link
O 2) Ring (a) is furanose with -glycosidic link
3) Ring (b) is furanose with -glycosidic link
2) 4) Ring (b) is pyranose with -glycosidic link
38. An antibiotic contains nitro group attached to
aromatic nucleus, it is
1) penicillin 2) streptomycin
3) CH 2  COOH 3) tetracycline 4) chloramphenicol
| 39. Paracetamol is
CH 2  COOH 1) methyl salicylate
O 2) phenyl salicylate
|| 3) acetyl salicylate acid
4) CH 2  C  NH  C2 H5 4) N-acetyl-p-amino phenol
|
CH 2  COOH 40. The drug valium is a
1) antiseptic 2) anesthetic
34. 3) analgesic 4) tranquilizer
41. Which of the following is a polyamide?
1) Teflon 2) Nylon-6, 6
The above reaction is 3) Terylene 4) Bakelite
1) Nucleophilic substitution 42. Three dimensional cross links are formed in
2) Electrophilic substitution case of a ______ polymers
3) Free radical substitution 1) Thermoplastic 2) Thermosetting
4) Addition reaction 3) Both (1) and (2) 4) Elastomers
35. The given structure of -amino acid will exist 43. Which of the following is a Biodegrade
at which pH polymer
1) celluloses 2) Polyethylene
3) PVC 4) Nylon – 6
 6 Test ID : 512
44. The monomer units in terylene are 4) CH2 = CH – CH = CH2 and CH2 = CH – Cl
CH 2  OH 50. The number of nitrogen atoms is one unit of
1) | only monomer melamine
CH 2 OH 1) 3 2) 6
3) 9 4) 2
CH 2 OH 51. Novolac on heating with formaldehyde forms
2) | + 1) Bakelite 2) Glyptal
CH 2 OH 3) Melamine 4) Neoprene rubber
52. -D-(+) glucose and -D-(+) glucose are
1) Enatiomers 2) Conformers
CH 2 OH
3) Anomers 4) None of these
3) | +
CH 2 OH 53. Artificial sweetner which is stable under cold
conditions only is
1) Saccharin 2) Sucralose
4) 3) Aspartame 4) Alitame
54. Poling process is used for
1) The removal of Cu2O from Cu
2) The removal of Al2O3 from Al
45. Which of the following is not a bactereocidal 3) The removal of Fe2O3 from Fe
1) pencillin 2) amino glycosides 4) All of these
3) ofloxacin 4) tetracycline
55. Method which is based on difference in
46. Which of the following is main functional solubility of impurities in molten metal and
group in amino acid (from IUPAC) solid state of metal
1) phenol 2) alcohol 1) Parke’s process
3) amide 4) carboxylic acid 2) Bessemerisation
47. Morphine and heroin both are narcotic 3) Zone refining
analgesics heroin may be obtained from 4) Electrolytic refining
morphine by 56. Following reaction is not involved in thermite
1) Nitration 2) Acetylation process
3) Chlorination 4) Hydroxylation 1) 3Mn3O4 + 8Al  9Mn + 4Al2O3
48. Butyl hydroxyl anisole is a 2) Cr2O3 + 2Al  Al2O3 + 2Cr
1) Antifertility drug 2) Tranquilizer 3) 2Fe + Al2O3  2Al + Fe2O3
3) Antioxidant in food preservative 4) B2O3 + 2Al  2B + Al2O3
4) All of these 57. The crystal field stabilization energy for Cr+3
49. Buna-N contains which of the following ions in octahedral field increases for ligands,
monomer units I-, H2O, NH3 and CN-, In which of the
1) CH2 = CH – CH = CH2 and CH2 = CH – CN following order
1) I- < H2O < NH3 < CN-
2) CH 2  C  CH  CH 2 and CH2 = CH – CN
| 2) I- < NH3 < H2O < CN-
CH 3 3) NH3- < I- < CN- < H2O
3) CH 2  C  CH  CH 2 and CH2 = CH – Cl 4) H2O < NH3 < I- < CN-
| 58. When aqueous KCN is added to ‘AlCl3’
CH 3 solution which one of the following results
 7 Test ID : 512
1) Al(OH)3 is precipitated 4) at face centres only
2) [Al(CN)6]-3 is formed 67. Polonium crystal in a simple cubic structure
3) [Al(CN)3] is formed the edge length of unit cell is 0.236 nm, what
4) None of these is the radius of polonium atom
59. The metal carbon bond in metal carbonyl 1) 0.144 nm 2) 0.156 nm
possess 3) 0.118 nm 4) 0.102 nm
1) only -character 68. Which of the following has voids space and
2) only -character packing efficiency equal to hexagonal close
3) ionic character packing structure
4) both and  character 1) simple cubic
60. In the combinations, all the ligands are 2) body centered cubic
ambidentate in nature? 3) face centered cubic
1) NO2-, SCN-, CN- 2) EDTA, NH3, CN- 4) None of these
3) H2O, NH3, CO 4) All of these 69. If the ratio of coordination number of A to
61. Which complex is most stable that of B is x : y, then the ratio of number of
atoms of A to that number of atoms of B in
1) [Cu(CN)2]- Kd = 1 x 10-16
unit cell is
2) [Fe(CN)6]4- Kd = 1 x 10-37
1) x : y 2) y : x
3) [Fe(CN)6]-3 Kd = 1 x 10-44 2
3) x : y 4) y : x2
4) [Ag(CN)2]-1 Kd = 1 x 10-20
70. Which of the following figures represents the
62. An excess of AgNO3 is added to 100ml of
cross – section of octahedral site?
0.01M solution of dichlorotetraaqua chromium
(III) chloride. The number of moles of AgCl 1) 2)
precipitated would be
1) 0.001 2) 0.002
3) 0.003 4) 0.01
63. Which of the following complex ion is
expected to absorb visible light 3) 4)
1) [Ti(en)2(NH3)2]+4
2) [Cr(NH3)6]3+
3) [Zn(NH3)4]+2 71. The number of octahedral void in bcc structure
4) [Sc(H2O)3(NH3)3]+3 is
64. Graphite is an example of 1) 0 2) 1
1) Ionic solid 2) Covalent solid 3) 2 4) 4
3) Metallic crystal 4) Molecular solid 72. For a binary ideal liquid solution, the total
65. In hexagonal crystal vapour pressure of the solution is given as
1)  =  = γ  90o ; a = b = c 1) Ptotal  PAo   PAo  PBo  XB
2)  =  = γ = 90o ; a = b  c 2) Ptotal  PBo   PAo  PBo  XA
3)  =  = γ = 90o ; a  b  c
4)  =  = 90o, γ = 120o a = b  c 3) Ptotal  PBo   PBo  PAo  XA
66. The face centered unit cell the lattice points 4) Ptotal  PBo   PBo  PAo  XB
are present at the
73. For an ideal binary liquid solution with
1) corners of unit cell only
2) corners and centre of unit cell PAo  PBo , which relation between XA (mole
3) corners and face centre of unit cell
 8 Test ID : 512
fraction of A in liquid phase) and YA (mole 1) [Co(NH3)6]Cl3 2) [Co(NH3)5Cl]Cl2
fraction of A in vapour phase) is correct? 3) [Co(NH3)4Cl2]Cl 4) None of these
1) YA < YB 2) XA > XB 80. In a 0.5 molal solution of KCl, KCl is 50%
Y X Y X dissociated. The freezing point of solution will
3) A  A 4) A  A
YB XB YB X B be (kf = 1.86 k. kg mol-1)
74. In a mixture of A and B, components show 1) 274.674 K 2) 271.60 K
negative deviation when 3) 273 K 4) none of these
81. The experimentally determined molar mass of
1) Vmix > 0, Hmix > 0
a non-volatile solute, BaCl2 in water by
2) Vmix = 0, Hmix > 0 cottrells method is
3) A – B interaction is weaker than A – A and 1) Equal to the normal molar mass
B – B interaction 2) More than the normal molar mass
4) A – B interaction is stronger than A – A and 3) Less than the normal molar mass
4) Double of the normal molar mass
B – B interaction
82. Incorrect statement regarding the complex
When 1 mole of solute is dissolved in 1kg of
K3 Co  C2O4 3  is
75.
H2O, boiling point of solution was found to be
100.5oC Kb for H2O is 1) The complex can’t display optical
1) 0.5 2) 100 isomerism.
3) 100.5 4) 95.5 2) It is a low spin complex
76. The boiling point elevation constant for 3) It has t 62g ego type arrangement of electrons
toluene is 3.32 k.kg mol-1. The normal boiling 4) Its magnetic moment is 0 BM.
point of toluene is 110.7oC. The enthalpy of 83. A 5% (w/v) solution of cane sugar (molecular
vaporization of toluene would be nearly mass = 342) is isotonic with 1% (w/v) solution
1) 17.0 kJ mol-1 2) 34.0 kJ mol-1 of a substance X (non electrolyte) The
3) 50.1 kJ mol-1 4) 68.0 kJ mol-1 molecular mass of X is
77. In the following reaction A and B are 1) 34.2 2) 71.2
NaOH + Cl2 → (A) + side product 3) 68.4 4) 136.8
(Hot con) 84.
+3
One gm of metal M was discharged by the
Ca(OH)2 + Cl2 → (B) + side product passage of 1.81 x 1023 electrons. What is the
(Cold, dil) atomic mass of metal?
1) NaClO3 and Ca(ClO3)2 1) 33.35 2) 133.4
2) NaOCl and Ca(OCl)2 3) 66.7 4) 10
3) NaOCl and Ca(OCl3)2 85. Total charge required for the oxidation of two
4) NaClO3 and Ca(ClO)2 moles Mn3O4 to MnO42- in presence of
78. Which one of the following aqueous solutions alkaline medium is
will exhibit highest boiling point? 1) 5F 2) 10F
1) 0.015 M urea 2) 0.01 M KNO3 3) 20F 4) none of these
3) 0.10 M Na2SO4 4) 0.015 M glucose 86. A dilute aqueous solution of CuSO4 is
79. A complex is represented as CoCl3 xNH3 its electrolyzed using platinum electrodes. The
0.1 molal solution in water shows ∆Tf = products at the anode and cathode are
0.568K. Kf for H2O is 1.86 K molality-1. 1) O2, H2 2) H2, O2
Assuming 100% ionization of complex and 3) O2, Cu 4) S2O82-, H2
co-ordination number of Cobalt is six, 87. How many grams of Cr are deposited in the
calculate formula of complex electrolysis of solution of Cr(NO3)3 in the
 9 Test ID : 512
same time that it takes to deposit 0.54g of Ag 3) second order 4) third order
in a silver coulometer arranged in series with 95. In the first order reaction the concentration of
the Cr(NO3)3 cell? (Atomic mass : (r = 52.0 ; reaction is reduced to 25% in one hour. The
Ag = 108) half life period of the reactions is
1) 0.0866 2) 0.088 1) 2 hrs 2) 4 hrs
3) 0.173 4) 0.220 3) 1/2 hr 4) 1/4 hr
88. Saturated solution of KNO3 with agar-agar is 96. A substance reacts with initial concentration
used to make ‘salt bridge’ because of a mol dm-3 according to zero order kinetics
1) size of K+ is greater than that of NO3- the time it takes for the completion of reaction
2) velocity of NO3- is greater than that of K+ is : [k = rate constant]
3) velocities of K+ and NO3- are nearly the k a
1) 2)
same a 2k
4) both velocity and sizes of K+ and NO3- ions a 2k
are nearly same 3) 4)
k a
89. If EoAu /Au is 1.69 V and EoAu3 /Au is 1.40 V, then 97. In first order reaction A  D, the ratio of a/(a-
EoAu /Au3 will be x) was found to be 8 after 60 minutes. If the
concentration is 0.1M, then the rate of reaction
1) 0.19 V 2) -2.945 V
in moles of A reacted per minute is
3) -1.255 V 4) None of these
1) 2.226 x 10-3 mol liter-1 min-1
90. Which of the following has highest
2) 3.466 x 10-3 mol liter-1 min-1
malleability and ductility
3) 4.455 x 103 mol liter-1 min-1
1) Cu 2) Zn
4) 5.532 x 10-3 mol liter-1 min-1
3) Na 4) Mn
98. The experimental data for the reaction 2A+B2
91. Resistance of a decimolar solution between
 2AB is
two electrodes 0.02 meter apart and 0.0004m2
Expt No. [A] [B2] Rate [Ms-1]
in area was found to be 50 ohm. Specific
conductance (k) is 1. 0.50M 0.50M 1.6 x 10-4
1) 0.1 Sm-1 2) 1 Sm-1 2. 0.50M 1.00M 3.2 x 10-4
3) 10 Sm-1 4) 4 x 10-4 Sm-1 3. 1.0M 1.00M 3.2 x 10-4
The rate equation for the above data is
92. The half-life of a certain reaction A  product
is 1 hour, when the initial concentration is 1) rate = k[B2] 2) rate = k[B2]2
2 mole lit-1. Find the time does it take for its 3) rate = k[A]2[B]2 4) rate = k[A]2[B]
concentration to come from 0.50 to 0.25 mole 99. The rate constants k1 and k2 for two different
lit-1, if it is a zero order reaction reactions are 1016 e-2000/T and 1015 e-1000/T,
1) 0.25 h 2) 1 h respectively the temperature at which k1 = k2
3) 4 h 4) 0.5 h is
93. In the first order reaction, the concentration of 1000
1) 2000 K 2) K
reactant decreases from 1.0M – to 0.25M in 20 2.303
minutes. The value of specific rate is 2000
3) 1000 K 4) k
1) 69.32 2) 6.932 2.303
3) 0.6932 4) 0.06932 100. The flocculation value of HCl for Arsenic
94. The hydrolysis of ethyl acetate is given as sulphide sol is 30 m mol L-1. If H2SO4 is used

CH3COOC2H5 + H2O  H
 CH3COOH + for the flocculation of Arsenic sulphide, the
C2H5OH, the order of this reaction is amount is grams of H2SO4 in 250ml required
1) zero order 2) first order for above purposes is
 10 Test ID : 512
1) 0.72 2) 0.18 2) The refractive indices of dispersed phase
2) 1.44 4) 0.37 and dispersion medium differ greatly in
101. Which of the following is not a characteristic magnitude, it is observed
of chemisorptions? 3) Tyndal effect is more for lyophobic sols
1) Adsorption is irreversible generally than lyophillic sols
2) ∆ H is of the order of 40 kJ 4) All of these
3) Adsorption is specific 107. In freuncllich absorption isotherm, the value
4) Adsorption increases with increase of 1
of is
surface area n
102. Which of the following reactions is not used 1) 1 in case of physical absorption
for the preparation of colloidal solution 2) 1 in case of chemisorptions
1) 2AuCl3 + 3SnCl2  3SnCl4 + 2Au 3) between 0 and 1 in all cases
2) FeCl3 + 3H2O  Fe(OH)3 + 3HCl 4) between 2 and 4 in all cases
3) 2Mg + CO2  2MgO+C 108. The number of d-p and p-p bonds in SO3
4) 2H2S + SO2  2H2O + 3S molecule is
103. The number of moles of lead nitrate needed to 1) 2, 1 2) 1, 2
coagulate 2 mole of colloidal [AgI]I- is 3) 1, 1 4) 2, 2
1) 2 2) 1 109. Dry bleaching is done by
1 5 1) Cl2 2) SO2
3) 4)
2 2 3) O3 4) H2O2
104. Which is the incorrect pair 110. Which reaction can be used to prepare
1) starch solution : sol phosphoric acid?
2) Aq. NaCl : true solution
1) P2O3 + H2O  
o
20 C

3) milk : emulsion
2) P2O3 + H2O  
o
80 C
4) Aq.BaSO4 : true solution
3) P2O3 + H2O  
o
25 C
105. At which one of the following condition, a
reducing agent is suitable for reducing a metal 4) P + Conc. HNO3  
oxide 111. The fertilizer named ‘Nitrolim’ is prepared by
1) sum of the ∆G values for oxidation of metal the use of
and oxidation of reductant should be 1) CaO + N2 2) CaC + N2
negative 3) CaCO3 + N2 4) CaC2 + N2
2) sum of the ∆G values for oxidation of metal 112. Which of the following statements regarding
and oxidation of reductant should be halogens is not true?
positive 1) Halogens act as strong oxidizing agents
3) sum of the ∆G values for reduction of metal 2) Fluorine oxidizes water to oxygen and ozone
oxide and oxidation of reductant should be 3) Chlorine oxidizes water to oxygen
negative 4) Bromine disproportionate in water producing
4) sum of the ∆G values for oxidation of metal HBr and HOBr
and reduction of reductant should be 113. Oxidation states of chlorine in the products
negative when chlorine reacts with cold and dil NaOH
106. True statements for tyndal effect are
1) It is observed when diameter of dispersed 1) 0, -1 2) -1, +1
particles is not much smaller than wave 3) -1, +3 4) -1, +5
length of light used
 11 Test ID : 512
 2 
114. The metal that has the lowest boiling point 3) MnO  Cr2 O  VO
4 7 2
among the following is
4) Cr2 O72  VO2  MnO4
1) Ti 2) Zn
3) Cu 4) Fe 120. When K2Cr2O7 is heated with KCl and
115. In which pair, both ions are coloured in
conc.H2SO4, the product formed is
aqueous medium 1) CrCl3 2) CrO2Cl2
1) Sc+3, Zn+2 2) Cu+2, Ti+4 3) CrOCl2 4) CrCl2
3) Ti+3, Co+3 4) Cd+2, Mn+2 121. The electronic configuration of cerium is
116. The ratio of magnetic moments of Fe(III) and 1) [Xe] 4f1 5d06s2 2) [Xe] 4f1 5d1 6s2
Co(II) is 3) [Xe] 4f2 5do 6s2 4) Both (2) and (3)
1) 5: 7 2) 35 : 15 122. Which of the following metal is leached by

3) 7 : 3 4) 24 : 15 Cyanide process
117. Zinc gives H2 gas with H2SO4 and Conc. HCl
1) Ag 2) Na
but not with Conc. HNO3 because 3) Al 4) Cu
1) NO3- ion is reduced in preference to 123. In the extraction of copper, the slag formed in

hydronium ion the blast furnace is

2) Conc. HNO3is a weaker acid than Conc. 1) CaSiO3 2) FeSiO3
H2SO4 and Conc. HCl 3) Ca3(PO4)2 4) MnSiO3
3) Conc. HNO3 acts as a reducing agent 124. Which method of purification is represented

4) Zinc is more reactive than hydrogen by the equations?

118. Zn and Cd do not show variable valency Ti + 2I2 
500K
 TiI4 
1675K
 Ti + 2I2
because? (Impure) (Pure)
1) They have only two electrons in the 1) Cupellation 2) Poling
outermost sub shells 3) van Arkel 4) Zone refining
2) Their d-subshells are completely filled 125. Which of the following set of elements mostly
3) Their d-subshells are partially filled occur as suphide ores
4) They are relatively soft metals 1) Zn, Cu, Na 2) Zn, Cu, Pb
119. Select the correct order of oxidizing power in 3) Fe, Al, Ti 4) Cu, Ag, Au
acidic medium
1) VO2  Cr2 O72  MnO4
2) VO2  Cr2 O4  Cr2O72

*** All The Best ***