03 “TRIBHUVAN UNIVERSITY. INSTITUTE OF ENGINEERING Examination Control Division 2074 Ashwin Engineering Chemistry (811403) Y Candidates are required to give their answers in their own words as far as practicable, Y Attempt All questions. Y The figures in the margin indicate Fult Marks. Y Assume suitable data if necessary. 1. What is meant by Normal Hydrogen Electrode? Discuss its use to measure standard electrode potential of copper electrode. Calculate Emf of the following cell at 20°C. Al(s) / A1P(0.2M) 1 Cu"(0.1M) / Cu(s) Given: Faia? = +1.66V and E%cy/0,"7 = 0.34 V 415125] 2. What is meant by ‘buffer solution’ and bufler action? A litre of solution containing 0.5 mole of CHsCOOH and 0.5 mole of CHsCOONa provides a buffer of pH 4.74. Caleulate the pH of solution after the addition of 0.02 mole NaOH [K,~ 1.8x10°] (243) 43, Define Heterogenous catalysis. What are the general characteristics of a catalyst? Explain adsorption theory of catalysis. (242) 4, Write short notes on: 25125] a) Global warming ) Acid Rain 5. What is soil pollution? Point out major soil pollutants, their effects and possible remedies? 4] 6. a) Why do the transition elements form complexes? 23) b) Why do the transition metals exhibit variable valency? 25] 7. a) What are transition elements? Which of the d-block elements are not considered as typical elements and why? 2] b). Write the electronic configuration and group of the following elements Cr, Fe, Cu and Zn. P 8 [Fe(CN)s]* and [FeFq” , both are octahedral complexes. Explain the difference between these two complexes on the basis of VBT. (3) 9. a) How do you distinct a double salt from a complex salt? b) Write the IUPAC names of the following co-ordination compounds. @_[Co(H20),(OH)s) i) INKCN). (iii) Ks[AKC200)3} (vi) [Cu(NH5),]8Ox G2] 10. Define the following terms with example. [es] 2) pigment b) thinner c) solid lubricant d) varnishes €) lacquers 11, Write the differences between organic and inorganic polymers. Write the piepayation and applications of polyphosphazines. +3]12. Write the method of preparation and two important uses of Bakelite and polyurethane. [2.5+2.5] 13, Write preparation and two important uses of a)INT b) ING 125125] 14, How do enantiomers differ from diagleromers? Write all the possible stereoisomers of a ‘compound that contain two asymmetric carbon atoins.~ BH) 15, What is - elimination reaction? Explain the reaction mechanism for the dehydrohalogenation of pritoary alkyl halide. ty 16. What are the factors affecting Sy! and Sy? reactions, Explain SN* reaction mechanism swith reference to hydrolysis of alkyl halide. 25125]0 ‘TRIRHUVAN UNIVERSITY INSTITUTE OF ENGINEERING Examination Control Division 2074 Chaitra engineering Chemistry (SH#03) % Candidates are required to give theit answers in their own words as far as practicable Y Aitempt AU questions. Y The figures in the margin indicate Full Marks. ¥ Assume suitable data if necessery. ‘What is an electrochemical series? How does an electrolytic cell differ from a galvanic cell? Calculate the emf of the following cell at 25°C [242] ZniZn"*(0.IM)#Cu™ (0.05M)/Cu Given, B°Zn™ /Zn=~0.76V.E°Cu* /Cu=034V 2. a) How does am acidic buffer solution containing acetic acid and sodium acetate resist the change im p" in in spite of the addition of the small amount of acid or base? Explain it 2 b) Calculate the pH of resulting solution when 0.01 mole of NaOH is added to 500ml of 0.1M acetic acetic acid (p* for acetic is 4.74) BI 3, What is homogeneous catalyst? How does a catalyst alter the rate of reaction? Explain with example. [14] 4. What is water polivtion? Write down the major sources of water pollution and mention the possible measure to control. How does the oxides nitrogen make the water acidic? [1+3+1] 5. Write short nates on: 2.52.5) {) Ozone layer depletion ii) Global warming due to air pollution 6. What is conducting polymer? Describe the preparation and uses of polyurethane and Epoxy resin, [242] 7, a) Write down the structure of cyelic and cross linked silicones and also give the ‘engineering applications of silicones. tay 'b) What are the general characteristic of inorganie polymer? Write the preparation and uses of polymeric sulphur. U2} 8. Give reasons: 15] 8) Transition elements are mostly paramagnetic ») Transition clements and their compounds show catalytic behavior ©) Feq(SOq)s is more stable then FeSO, d) Compound of Ti” are coloured but those if Ti" are colourless ©) Zn in 3d series is called typical transition clement9. Write the expected and actual electronic configuration of Cr in box notation. Why the actual electronic configuration of Cr is different from expected electronic configuration? [In the 3-d transition series the size of atom decreases from Sc to Cr but the size remains almost similar ftom Cr to Zn. Explain, (414143) 10. How does valence bond theory explain the geometry and magnetic behavior of a complex? Explain with suitable example, 15] LL. a) Explain the formation of [FeF«]* on the basis of VBT and predict its geometry as well as magnetism, B) ') Write UPAC names of the given examples. 2] i) EN{CO}q ii) KelFe(CN)e} iii) NafAg(CN)s] iv) Ko[Heh] 12, What primary explosives, low explosives and high explosives? Write the preparation and uses of nitroglycerine. 132) 13.) What is tubricant? In what situation grease and solid lubricant are used? (142) b) What are the characteristics of good paints? rey 14, Explain enantiomers, racemic mixture and meso compounds with examples, Draw the structures and specify Z and E configuration of 4-methyl hept 3-ene and 2-chiori pent 2- ene. 32] 15. Describe the bimolecular nuclephilic substitution reaction in haloalkane with suitable example, What type of solvent is favour for this reaction? Write down the differences between Sy, anid Sy, reactions? [+142 16, Explain the reaction mechanism of dehydrohalogenation of tertiary buty] bromide by aleoholie caustic soda. Mention the factors governing the mechanism of El reaction. [342]03 TRIBHUVAN UNIVERSITY = INSTITUTE OF ENGINEERING — | Level Examination Control Division e | 2073 Shranan ‘Year /Part ‘Subject: i Candidates are required to give their answers in their own words as far as practicable Attempt All questions. ‘The figures in the margin indicate Full Marks, Assume suitable data if necessary. ingineering Chemistry SSR ‘What is sat bridge? Write its functions. Write electrode reaction, net cell reaction, EMF of the cell at 25°C and cell notation of the following electrode couple and also predict the spontaneity of the cell reaction, 0143) E°Fe/Fe"* =0.44V, E°Ag/Ag' =-0.80V [Fe'*]=-0.01M, [Ag*}=0.1M 2. What is buffer capacity? Write the characteristics of buffer solution. 200 ml of 0.1M CsHs COONa is mixed with 400 ml of 0.2 M CsHsCOOHa at 30°C dilute solution. Calculate the pH of solution. (04242) 3. Explain the terms: (a) Acetocatalyst (b) Catalytic poisoining and (¢) Promoters 1243] 4. Explain the mechanism of ozone layer depletion. Write its preventive measures and secondary pollution effects in troposphere. (24.541.5] 5. Define soil pollution, Write the major sources of soil pollution, their negative effects and control measures. 14242] 6. Write short notes on: [2.5%2] 3) Polyphosphazine ii) Chaleogenide glasses 7. 2) Give an account for biodegradable and non biodegradable polymer with suitable example, b) What are fibers reinforced plastics? Write dawn the characteristics and its application [2.5+2.5] 8. What are transition clements? How do they show: (j) catalytic behaviour (ji) coloured ions and (ii) variable oxidation states? [0S+15+1.5+1.5] ‘9. Explain the formation of [NiCl,]~ and [Ni(CN),]” on the basic of VBT of coordination compounds. 2.5") 10.a) Write the formula of the following IUPAC name: R] i) Potassium penta cyano nytrosyl ferate (TIT) ii) Pentaammine chloro cabalt (11) ion iii) Tetracarbonyl cabalt (O) iv) Pentamminenitrito cobalt (III) sulphate b) “[Fe(CN),]* is diamagnetic but [Fe(CN),]~ is paramagnetic" justify. [1.5415]11. What are lubricants? What are the characters of good lubricants? What is emuilsm paint? ‘Write its applications? j (28s 12. Define explosive. How it is used for defense purpose? What are the uses ‘of TNT, ING and cellulose nitrate? U+H1e+1] 13. What are geometrical isomers? Geometrical isomer is not possible in the compound (CHCH = CH, explain. Why are trans isomers more stable than Tis-isomers? T4242) 14. What is @ nucleophilic substitution reaction? Differentiate between SN? and SN! reactions, Write the factors affecting SN? and SN! reactions. [1+242) 15. Explain reaction mechanism for dehydrohalogenation of tertiary butyl bromide, What solvent favours the reaction mechanism’? 4] 16. ‘Write ground state electronic configuration of 3d transition series, How do you explain the formation of complexes by 3d transition elements? [243]03 _-TRIBHUVAN UNIVERSITY INSTITUTE OF ENGINEERING Examination Control Division 2073 Chaitra Candidates are required to give their answers in thei own words as far as practicable Attempt All questions. The fleures in the margin indicate Full Marks Assume suitable data if necessary, A688 Define Butfer. Write the mechanism of acidic buffer. Calculate the pH of the solution formed by edding 0.2 g of sodium acetate in 200 mL 0.1 M acetic acid. pKa or newt acid = 4.74, [14242] > What is standard bydcogen electrode? How is it used to measure the single electrode Potential? Why is salt bridge used in construction of galvanic cell? Calculate the emf of the following cell at 25' [+143] IF" -0.24V and Ep ""pq=-0.22V) Nis) /Ni™(aq) (1M)//Pb™aq) {4M)/Pofs) 3+ Explain with an example the mechanism of adsorption theory of catalysis. Write the differences between homogenous and heterogenous catalysis, [sy ‘4. Define soil potion. Write the major sources of soil pollution, their negative effects and ‘contro! ineasuxes, [11243] Write the formation, effects and remedies of SOx and NOx 2542.5] & What are biodegradable polymers? Give the proparation and uses of Nylou 6,6 and polyurethane, [9249] 7 Describe the preparation and uses of polymeric sulphur (PS), and pelyphosphazines, 2542.5] Give an account for the following: (14143) a) Cu (3d) is more stable than Cu* Ga, Justify the statement. b) Why Zinc is cafled non-typical transition element? ©) Explain magnetic properties of transition elements 9. Explain with reasons: 2) Transition metals ean form most of the complex compounds 5) Zine (I) compounds are white and diamagnetic while copper (I) compounds ere colored and paramagnetic. [2,542.5] 10. Explain the formation of [Co(NHs)e}" and [CoF¢f” on the basis of Valence Bond Theory and also predict their magnetic property, R24] 11. Write the basic assumptions of Wemer’s theory of co-ordination ‘compounds, GoCLANHG gives a precipitate with AgNOs solution. Explain it onthe basis of Wemer, theory. (342) 12. What are plastic explosives? Write the advantages of plastic explosives. Write the Preparation of TNT, TNG and nitrocellulose, [313.0) What are lubricants? Show your famiiaity with application of different types of lubricants. ») Explain the method of application of paints in galvanized iron. [14243] 14.a) Explain geometrical isomerism with examples, [15] }) Write all possible stereoisomers of 2,3-dibromopentane. Identify all possible enantiomers and diastereomers from the stereoisomers, 5 15, What are the differences between ! and E? reactions? Explain the reaction mechanism for the reaction of primary alkyl halide with alcoholic NaOH. Res] 16. Why does SN’ reaction give both retention and inversion isomers but SN? gives only inversion isomer? Write the mechanism for the reaction between bromocthane and aq.NaOH. [283]Examination Control Division | Programme | 8cé. BM A446 10. 03 TRIBHUVAN UNIVERSITY [Exam, INSTITUTE OF ENGINEERING [Level [BE Full Marks | 80 BGE | Pass Marks) 32 a SEL 2072 Kartik (Year: Pert [TT Candidates are required to give their answers in their own words as far as practicable. Attempt All questions. ‘The figures in the margin indicate Full Marks, Assume suitable data if necessary. Derive the equation required to calculate the emf of cell at non-standard condition, What are the factors that affect the single electrode potential value? Calculate the oxidation electrode potential of given half cell reaction at 20°C. 2142] Fe‘*(0.1M)+e~» Fe" (0.2M),E° = 40.77V . What are the criteria for buffer system? Calculate the change in pH of buffer system having 200 ce of 0.1 m-CH;COOH and 0.1 M CHyCOONa when | millimole NaOH is added into it. (Ky = 1.810") 3] ‘What is autocatalysis? Explain the mechanism of adsorption theory of catalysis with example, (+4 What are the major pollutants responsible for water pollution? How do the oxides of sulphur and nitrogen make water acidic? . (243) What is meant by ozone depletion? Write its eauses and consequences. 243] 8) What are chalcogenide glasses? Give an account of preparation and uses of chaleogenide glasses in the engineering field. (14242) b) Write down the preparation of cyclic silicones. 8) Give an account for the biodegradable and non-biodegradable polymers with suitable examples, [2.5%2} b). What are fibers-reinforved plastics? Write down its applications. Explain the origin of the adsorption spectra of transition elements with do d transitions. [5] ‘Mention the main applications of 3d elements and give main causes of variable oxidation states shown by transition elements. (32) ) Describe the simple test to distinguish between the following pairs of compounds on the basis of Werner's theory. [Co(NH, },Cl]SO, snd {Co(NH,),S0, }Cl 2H] ‘b) Name the following complexes by IUPAC system. ) KAR) fi) [Cofen),]Bs, ii) [Cr(7,0), CI}CI, iv) PONH,),CL,]CI, ©) State EAN rule.11, Using VBT, predict the possible number of unpaized number in the following complex compounds, K,[Fe(CN),} and [Fe] (2.5125) 12, Write the mechanism for the conversion of Bromomethane into methanol in presence of ‘aqueous alkali. Also explain the stereochemistry of the redetion. (342) 13, What do you mean by Elimination reactions? Explain the reaction mechanism for the dchydrohalogenation of tertiary alkyl halide (243) 14. Write down the possible geometrical isomer of but-2-ene-1, 4-dioie acid. Why does this ‘compound exhibit geometrical isomerism? Explain the difference between enantiomer and diastereoisomer giving an example of 3-bromo-2-butanol. [+143] 15, What is the requisite of good explosive? How can you prepare TNT form benzene? Why does detonator required for the explosion of TNT? [21] 16. a) Show your acquaintance with liquid and semi-tiquid lubricants. Under what situations greases are used? [+2] +b) What do you understand by paints? Mention the requisites of good paint.03 mupNUvan university | Exam. INSTITUTE OF ENGINEERING | Levet Full Marks | 80 Examination Control Division | Programme 2072 Chaitra Candidates are required to give their answers in their own words as Attempt All questions. The figures in the margin indicate Full Marks Assume suitable data if necessary. as practicable. R444 What is buffer solution? Detive Henderson's equation for bsic buffer. Calculate pH of a mixture of 10 mf of 0.1M ammonium chloride solution and same volume of 0.2 M ammonia solution. (pKb for ammonia solution = 4.74), [14143] 2. How does a galvanic ceil generate electricity? Construct a cell with the following cell teaction, write its notation and calculate standard emf of the cell (HH+142] 2Ai+3Z,80, + Al,(SO,); +Z, at 298K aM) aM) Given, standard reduetion potential of Al and Zn are -1.66V and 0.76 V respectively 5. What is catalysis? Explain intermediate compound formation theory and an industeial application of catalysis. [142.5413] 4. What are the parameters of water pollution? Explaii its causes and adverse effects, [3+141] 5. Write the functions of lubricant, Show your acquaintance with fluid film lubrication and its role in engineering. Give an example each of (2) semi solid lubricant and (b) emulsion [1524141] 6. Write short notes on: (any two) [2,542.5] i) Global warming ji) Formation and depletion of ozone layer iti) Acid rain and its effects % What is conducting polymer? Give an account of polyphosphazines and chalcogenide galsses. Also write their applications in engineering field. [14242] 8. Explain the following: 23] i) 3d- transition series show variable axidation states 4) Completely filled 3-d transition series are unable to form coloured compounds 9. What is a complex ion? Give example of a (i) complex cation and (ii) complex anion, with their IUPAC name. Also calculate EAN of central metal of these ions, (iste 10. Show your acquaintance on the basis of hydbridisation with inner orbital and outer orbital complexes with example, [2,542.5] Ni Differentiate between high explosive and low explosives, Write the preparation and applications of TNT. B42) 12, Write the method of preparation and uses of (a) polystyrene (b) Bakelite (2.42.5) 15. Distinguish between enantiomers and diastereomers. Show all optical isomers of (2) 3-Bromo 2-butanol and (b) Tartaric acid, Also show optically inactive meso form of {erfarie acid. Explain why 3-Bromo 2-butanol doesn't exist in meso form. [1-1 5+141+0,5 1} '4. Explain E2 and B reactions with referance to dehydrohalogenation of haloalkane and point out the factors affecting these mechanism. [LS#1.542] 1S. Why does haloalkane favour Sy reaction? Explain why there is only inversion product in 8x2 and both inversion and retention products in Syl path, (14242) Se ee ee 7if w 03 TRIBHUVAN UNIVERSITY INSTITUTE OF ENGINEERING Fall Marks Examination Control Division | Programme SCE, BME, BOE PassMarks 32} 2071 Shawan (Wear? Par it i Engineering Chemistry (SH#03) Subject Y Candidates are required to give their answers in their own words as far as practicable, ¥. Attempt All questions. The figures in the margin indicate Full Marks. Y Assume suitable data if necessary. 1. What is buffer solution? Calculate the pH of 500 cc of 0.2 M CHsCOOH solution when 2. gof sodium acetate is added. [K, for CHyCOOH is 1.810] (144) ” 2. What és Daniell cell? Answer the following question using equation (a) and (b) 14g (al Fe" [0.2M)= Fr € (0.6), €=-0.771, (b) Ca(0.M) -2e = Cu", £=-0.34Y (net cell reaction (ii) spontaneity of redax reaction (iii) cell notation (iv) emf of cell 3./ What are catalytic promoter and catalytic poison? Explain their activity on the basis of adsorption theory of catalysis. 24) 4, 8) What are chlorofluorocarbons? Explain their photolysic reactions in the upper atmosphere ol ) Discuss about the air pollution caused by oxide of nonmetals? a |S. What are the major water pollutants? Point out their adverse effet and the possible measures to control water pollution. 14243] 6. Write the preparation and uses of Teflon and epoxy resin. What are conducting polymers? Point out their applications in engineering field (e141) 7. a) Give preparation and uses of the nonmetallic super conductor. Be b) Write down the main characteristic of inorganic polymers. 8. Give an account for the followings: i) Transition metals aze well known to form complexs. a) ii). Copper (1) compounds are white and diamegnetic where as copper (If) compounds are colored and paramagnetic. a iil) Zine is nontypical tanstion metal. n 9._ 4) Explain the variable oxidation states of transition elements, Which divalent metal has ‘maximum paramagnetic character among the first trénsition metals? (2541415) b) -A transition metal forms alloys with other transition metals easily. Why? Explain. 10. Explain how the two complexes of Ni, (Ni(CN).)” and [Ni(CO)}]° have different Structures but do not differ in their magnetic behavior (Ni = 28). 15] 11, 3) Write the FUPAC name of the following eompoundsfions pH) 1) Co{NHA).NO3 Ch 2 1 Fe (GOda” 1 [eetent Ch” IN) Nii fer (H.0) (NCS) 1b) What is complex compound? What do you understand by principal and auxiliary valency of the central ion in complex eompound? Illustrate them in [Co (NH5)JC\s03 TRIBHUVAN UNIVERSITY Exam, SE ee ae INSTITUTE OF ENGINEERING = [Level BE ‘ull Marks | $0 Examination Control Division Programme (BCE, BME, BGE | Pass Marks 32 2071 Shawan (Ner/Pan 0/1. Time (3s ‘Subject: - Engineering Chemistry (SH403) Y Candidates are required to give their answers in their own words as far as practicable, Y. Attempt AU questions, Y The figures in the margin indicate Full Marks, Y Assume suitable data if necessary. : 1, What is buffer solution? Calculate the pH¥ of 500 oc of 0.2 M CHsCOOH solution when 2 gof sodium acetate is added. [K, for CHyCOOH is 1.810] f+4 > 9. wihacis Daniell coll? Answer the following question using equation (a) and (b) a4 {a Fe (0.284) = F"+ © (0.10), = -0.77V, (b) Cu{0.3M)-2e = Cu", E=-0.34V, (i net cell reaction (i) spontanelty of redox reaction (i) cell notation (iv} emf of cel 3) What are catalytic promoter and catalytic poison? Explain their activity on the basis of adsorption theory of catalysis, 243] 4, a) What are chlorofluococarbons? Explain their photolytic reactions in the upper atmosphere a b) Discuss about the air pollution caused by oxide of nonmetals? a 3. Whai are the major water pollutants? Point out their adverse efficr and the possible measures to control water pollution. (124) 6. Write the preparation and uses of Teflon and epoxy resin, What are conducting polymers? Point out their applications in enginecring field. Be] 7. a) Give preparation and uses of the nonmetallic super conductor. GI 1b) Write down the main characteristic of inorganic polymers. 8 Give an account for the followings: i) Transition metals are well known to form complexs. 2) ii) Copper (1) compounds are white and diamegnetic where as copper (I!) compounds are colored end paramagnetic. 2 iif) Zinc is nontypicel transtion metal. 0 9, a) Explain the variable oxidation states of transition elements. Which divalent metal has maximuin paramagneti¢ character among the frst transition metals? 251415) b) A transition mictal forms alloys with other transition metals easly. Why? Explati 10. Explain how the two complexes of Ni, [Ni(CN)J* and (Ni(CO)|* have different structures but do not differ in their magnetic behavior (Ni = 28). (1 11, 2 Write the TUPAC name of the following compounds/ions (24142), 1) [COAINOS Ch in tFe (Goa tu) fcr fen) ach)” V] NBg [er (HL,0} ANCS) J 8) What is compléx compound? What do you understand by principal and auxiliary valency of the central ion in complex compound? Illustrate thert in [Co (NH3)JCh.examples. 1) Write (is, Trans and Z, 6 no Weite the difference between enantiomers and di “What are lubricating oils? Indicate its application in engineering work. ‘Show your familiarity with the types of paint rigisomers ing appropriate forthe possible isomes of but-2-endioe acid. \4. a) Explain the mechanism involved in the reaction between bromomethane and aqueous NaOH, b) How do nucleophile and solvent affect this type oF reaction? 15.a) Differentiate between B and E? reaction. +) Explain the reaction mechanism forthe deby drohalogination of 3lky/ halide 16. What are low explosives? Write the preparation and uses of GTN and TNT. (142 2 (342) GB) @ (243) (4)05 TRIBHUVAN UNIVERSITY { _ eT E 1 2 INSTITUTE OF ENGINEERING —_ | Level BI Ful Mars_| ACE, BME, BGE | Pass. tt Timi Candidates are required to give their answers in their own words as far as practicable, Attempt All questions. ‘The figures in the margin indicate Full Marks. ‘Assume suitable data if necessary. Examination Control Division | Programme Year / A464 | 1. What is SHE? Calculate the emf of, electrode couple of EY, =~14Vand FF | =-0.77V.. Where the concentration of Sn'*,Fe"and Fe" are 0.2M 0.1M and | M respectively, 23] 2. Explain the mechanism of buffer aston with a suitable example, Calculate the weit dean of NH,CI required to prepare buffer sotution having phi = 9.35 in 200 ce of 02% ‘ammonia solution. (PRO = 4.74) Bel 44, What is heterogeneous catalysis? How does a catalyst alter the rate of reaction? Give a brief account on the intermediate compound formation theory of catalysis. (+183) 4 8) What is ezone depletion? Write the chemical reactions involved in the stratospheri ‘ozone depletion by nitric oxide? (42+2] 'b) How does earbon dioxide cause atmospheric pollution? 5, What are the major water pollutants and their harmful effect? Mention the possible measures to control water pollution. 243) 6. a) Write the engineering applications of Silicone and give the structure of cyclic and cross Tinked silicons. (1 b) Write the preparation of pelyphosphazine and its uses. 7. What are biodegradable polymers? Write down the preparation and uses of Nylon 6.6 and Teflon. Lie] 8. a) Why do transition metals form complex compound? G2) 1) Explain why the 3d transition series having completely filled d-orbital cannot form coloured compounds. 9, What are transition elements? Why does the presence of unpaired clectrons make a substance paramagnetic in nature? Explain it with magnetie moment measurement tea) 10. Name the following complexes by TUPAC system: 23 {Cr (HO), (NHS)2] Bra fi) [CuCh(CH)NH)2) fit) NiPICh iv) [Cr (NIG)aP* State and explain EAN rule as applied to metal complexes. L1Differentiate between inner and outer orbital complexes, Magnetic measurement on Ky[Fe(CN),) indicates the presence of one unpaired electron, predict on the basis of VBT whether the given complex is inner oF outer complex. (23)12, Define explosives. Why are the primary explosives called "detonators"? Write the reaction oftoluene forming an explosive. Mention the important uses of GTN and plastic explosives(1+1+1+2] 13.a) What are solid lubricants? Mention the types and function of lubricants with examples.[1*+2+2] 'b) Explain the method of application of paint in galvanized iron. 14.) What isomerism is shown by tartaric acid and why/? R03) b) Define enantiomers with examples. Differentiate between racemic mixture and mesocompound. 15. Explain the reaction mechanism for the hydrolysis of tertiary alkyl halide by aqueous NaOH. What solvent favours the reaction mechanism? UH 16. What is Saytzeffs rule? Describe the mechanism for the reaction of 3alky! halide in alcoholic alkali 23]INSTI TE OF ENGINEERING Level Examination Control Division | Programme 2070 Ashad 7 Year /Part Full Marks | 30 PassMarks 3 Time a Subject: - Engineering Chemistry (S403) Candidates are required to give their answers in their own words as far as practicable. Altempt All questions. The figures in the margin indicate Assume suitable data if necessary. ll Marks. 7 v v v ‘What is buffer and buffer capacity? To 100 ml of 0.1 M acetic acid, 0.1 gm of sodium hydroxide is added. Find the pH of the resulting solution. (pk, for acetic acid is 4.74) 243) 2. How does a galvanic cell differ from an electrolytic cell? Calculate the EMF of the cell: Znlén™ (0.001M) // Ag” (0.1M) / Ag. The standard potential of Av/Ag” half cell is 0.080 Vand Zn/Zn™ is - 0.76 V [243] 3. a) What are promoters? Mention the action of promoters. (4) b) Describe the adsorption theory of catalysis with a suitable example. BI 4. a) Write down the sources and defects of sulphur oxides BI b) Explain the causes and effects of ozone layer depletion Q] 5. What are the major water pollutants and their harmful effect? Mention the possible measures to control water pollution +2] 6. Write short notes on (i) Sulphur based polymers (ii) Chaleogenide glass, [342] 7. a) Give preparation and uses of Nylon.6,6 and polyurethane. [4] b) What are engineering applications of conducting polymer? fa] 8. a) Write the important characteristics of transition elements. [2.5] b) Explain the magnetic properties of the transition elements. (2.5] 9. Explain the following: (2.5+2.5] a) Complexes of transition elements are generally coloured. b) Most of the transition elements are paramagnetic. 10. What are primary and secondary valencies of metal? Explain the structure of Kj {Fe (CN)]s on the basis of Werner's theory. * [243] 11. a) With the valence bond concept, explain the geometry and magnetic character of the complex [Ni (CO).). Write down one of the limitations of valence bond theory, p+) b) Write the IUPAC name of the following co-ordination compounds, 2 ) K. (Pt) fi) Ks [Al (C204)s] iii) [Co (NH3)804] Br iv) [Pt (NH).Ch] SOx 12. Explain the reaction methanism for the hydrolysis of tertiary butyl bromide by aquéous ‘NaOH. Differentiate between SN' and SN* mechanism. [3+2] 13. @) How do enantiomers differs with diasteoisomers? Illustrate with an example, [142] b) What isomerism is shown by 2-bromo 1-chloropropéne? Mention Z and E notation for the compound. (21 14, What are secondary explosives? Give preparation and properties and uses of GTN and TNT. [233] 15. What do you mean by Elimination reactions? Explain the reation mechanism for the reaction between primary alkyi halide and alcoholic NaOH R83] U6. a) What are lubricating oils? Indicate their importance. +2} by Show your familiarity with types of paints Qhpila ak 05 TRIBHUVAN UNIVERSITY INSTITUTE OF ENGINEER Candidates are required to pive their answers in their own words as far as practicable, Attempt All questions. The figures in the margin indicate Full Marks Assume suitable data if necessary. RRAM |. Derive Henderson equation for buffer solution. What is the pH of resulting mixture obtained by mixing of 100 ec of 0.2 N HCL and 50 cc of 0.5M ammonia solution, Ki for ammonia is 1.810% [4] 2. How can you measure the standard reduction potential of Zn electrode? Hydrogen electrode at 1 atm is connected with Zn electrode in which the emf of the cell is found to be 0.61 V at 25°C. If [Zn] = 1.0 M, calculate H” in hydrogen clectrode, ey] 3. What is heterogeneous catalysis? Giving a suitable example, explain the mechanism of heterogeneous catalysis. Write any two criteria for choosing a catalyst for industrial purpose. [34 4, a) What do you mean by CFC? Mention their photolytic reactions in high altitude at stratosphere, b) How do the oxides of sulphur and nitrogen make water acidic? (1259 5. Write major sources of water pollution, How does CO act as pollutant of the atmosphere? Explain. Ie+3] 6. Give an account on chalcogenide glasses and polysulphur nitride. [2542.5] 7. Explain about the biodegradable and non-biodegradable polymers with suitable examples (2.5%2] 8. Explain giving reasons. a) Transition metals and their compounds show paramagnetic behavior. 23) b) Zine (11) Compounds are white and diamagnetic while copper (111) Compounds sre colored and paramagnetic. 25] 9. Transition elements formed colored compounds. Explain this on the basis of d to d transition, vg le PEF 10. Compare the magnetic beltivior of the complex entities [F.(CN)s]* and [FeFs]” using ‘volence bond theory. [2,542.5] 11), Write the IUPAC name of the following co-ordination compounds. 1 i) [Co(NER)E" * - ii) (PRONE)Ch) it) Nas fC, (C20.}] iv) (Co (NE).CH] CI b) What is EAN? How would you. explain the stability and magnetic behavior of ‘‘iiatinaremeiaicnsed bey Tiel ran. e ny) aSie eiectiialhla ae 12-0), Write the characteristics of a good paint and explain the method of application of paint in galvanized iron ———— +b). Mention the types and fonetions of lubricants with examples. pea] 13.) What isomerism is shown by 1b) What do you mean by racemic mixture? Explain chemical resolution of « racemic mixture. 12) 14,2) Descgibe SN! reaction mechanism in haloalkane shown stereochemistry. 'b) Why does nucleophile attack the substrate molecule from backside in SN? reaction sic acid? Weite its possible isomers py ‘mechanism? (ay 15. Discuss B! reaction with reference to the debydrohalogenation of alkyl halide. How does ! differs from E” reaction, 342) 16. What are plastic explosives? Write down the characteristios of explosives. Give the preparation and uses of explosive obtained from toluene, (19242)63 aRIBHUvAN UNIVERSITY [i INSTITUTE OF ENGINEFRING Level Examination Control Division, | | 2069 Ashad h ‘ngineering Chemistry (St 403) ~ ¥ Candidates are required to give their answer Y Attempt All questions. % The figures in the margin indicate Full Marks, Y Assume suitable data if necessary, What is meant by buffer capacity? A chemist desires to Prepare one liter of a solution buffered at pH 9.00. How many grams of ammonium chloride have to be added to one liter of | 020M NH to make such buffer. pKa value of ammonia is 4 75 (ita) 2, How does.an electrolytic cell differ from a galvanic cell? Calculate the ‘emf of the cell, (243) Zn/Zn°"(0.001MY//Ag'(0.IMV/Ag. The standard potential of Ag/Ag’ half cell is +0.80V and Zal2n* is -0.76V >. Explain the terms: (a) Heterogeneous estalysis (b) Catalytic poisoning and promoters, [243] 4.” What is meant by ozone depletion? Mention its causes and consequences, [243] Nhat are the major water pollutants and their harmful eects? Mention the possible measures to ‘control water pollution (342) &. Write short notes on: (a) Polyphosphazines (b) Chaleogenide glasses, [2.5x2 7. a) Give an account for the biodegradable and non-biodegradable polymers with suitable ‘examples. (2.5x2] 5) What are fiber-reinforced plastics? Write down the applications. 8. What are transsition elements? Point out the applications of these elements and their complexes, [5] % Compare ionisation potential and oxidation state of transition elements with representative elements. What is the effect of lanthanide contraction in Properties of transition elements? Explain how colour is originated in transition metal complexes. [+1+t42) 10. Weite assumptions of valence bond theory of complexes. Explain formation of spin paired ‘complex on the basis ofthis theory. Mention its magnetic behavieur [242+1) {1- What is a Chelate complex? Show Wemer's representation and TUPAC name of the following complexes. (a) (Cu(NH;)x]S0, (b) K[Ptel,(NH,)] 114242) 22. Give an account of low and high explosives. Write the preparation and Uses of TNa, B+] 13. a) Show your acquaintance with lubricants? Under what situations greases are used? 42) ) What do you understand by paints? Mention the requisites ofa 004 paint. 4. a) What isomerism is showm by butenedioic acid and why? R43] ») Define enantiomers with examples. Differentiate betwoon racemic mixture and ‘™meso-compound. . 15. Explain the reaction mechanism for the hydrolysis of 3° alkyl halide by aqueous NaOH, What solvent favours the reaction mechanism? (+1) 16. What do you mean by Elimination reactions? Explain the reaction méchanism for the dehydrohalogenation of tertiary alkyl halide. [243]. ig 03 TRIBKUWAN UNIVERSITY INSTITUTE OF ENGINEERING Level BE Full Marks | 80 ee C 1 Divi BCE, BME, A amination Control Division | programme BGE Pass Marks , 32 2069 Chaitra Year/Part (1/1 | Time Shi ~ Subject: - Engineering Chemistry (SH403) Y Candidates are required to give their answers in their own words as far as practicable ¥ Attempt All questions Y The figures in the margin indicate Full Marks. Y Assume suitable data if necessary. * 1. Define a galvanic cell. What are functions of salt bridge in a galvanic cell? Predict the feasibility of the following reactions, i) Zn+Agt > Zntteag ji) Zn** + Ag > Zn+Ag* Given, E° zn**/zn= - 0.76V, Eg" /ag = 0.80V (24143) 2. What Is a buffer solution? Discuss the mechanism of buffer action with suitable examples. z (144) 3. What Is meant by catalysis? Point out its importance. Discuss intermediate compound formation theory of catalysis. (14143) 4. @) Point out the sources of radioactive substances responsible for environmental pollution. Give their adverse effects and protective measures. [2.5] b) Briefly discuss any two sources of organic and inorganic substances responsible for water pollution. Point out their possible remedies. [2.5] 5.a) How do exhausts of internal combustion engine pollute air? Give the possible remedies. (3) b) What is the photochemistry behind ozone layer depletion? (21 G. a) What are Chalcogenide glasses? Give their uses, (2.5) b) Give the preparation and applications of silicone rubbers. [2.5] 7. ) Give the preparation and applications of polystyrene and polyurethanes. [4] b) What are the advantages of conducting polymers? 0) 8. Why do transition elements form complexés? List the Industrial application of 3d transition elements in engineering. “(3+2] 9. Explain the following features of transition elements with reference to 3d. transition series; ‘ (2.542.5] a)" Variable oxidation state b) Formation of Colored compounds 10. Differentiate between complex salts and double salts. How does Werner's theory explain the bonding In complex salts? [144]Va) Write the IUPAC name of following; i) Ks {fg Md fi) KeLFe(CN)s} ili) {Co (NHL) s ef” iv) LifAlHa) b) How -does-valence bond theory explain its magnetic behaviour, de ny anee seal 12. What are primary explosives, preparation and applications 2,4,6-Trinitrotoiuene (TNT). 13. a) Show your familiarity with liquid, sémi solid and solid lubricants giving examples. b) Discuss any two types of pal works. 14, a) What are geometrical isomers? Give an example b) Show your familiarity with diastereomerism. ¢) Draw the structure of 2-Chlorobutane specifying & and S configuration. ints showing their applications in engineering 15. Discuss the unimolecular nucleophilic substitution reaction mechanism in al halide showing the stereochemistry. 16. What is meant by'elimination reaction? Discuss Et and £2 reaction mechanism. gw exdlosives and plastic explosives? Givé the {2} the formation of (Ni(NH3)6]""? Predict (3t (342) Gl a (2] i2i @ (11 kyl 5] +4]03 —_tmtuvan usivensiry a INSTITUTE OF ENGINEERING | Tevel Examination Control Division | Progr: 2068 Chaitra (Year/ ‘Subject: - Engineering Chemistry (SH 403) Y Candidates are required to give their answers in their own words as far as practicable. Y Attempt All questions Y The figures in the margin indicate Full Marks, ¥ ‘Assume suitable data if necessary. 1. What is meant by normal hydrogen electrode? Calculate the emf of the following cell at 25°C MgiMg™ (0.1M\/Ag (MY/Ag. Given EM -2.37V, E*AgiAg’ --0.80V. [2+3] 2. Explain the mechanism of basic buffer, Write the equation for acidic buffer, 0.005gm equivalent of KOH is added to 400ml of 0.1N acetic acid, calculate the pl] of the mixture, (Ka for acetic acid = 1.8107). [1.5 + 0.543] 3. Define heterogeneous ¢: lysis. Point out some characteristics of catalytic reactions and mention its industrial applice (vay 4, a) Define soil pollution. What are its sources? [143] b). Explain cause and effect of Ozone layer depletion. {4} ©) Give averse effects of (i) pb (ii) phosphates in water. 2} 5, What are the general churacteristics of inorganie polymer? * What do’ you measi by cross - linked? What are the engineering uses of chaleagenide polymer? [24142] 6. Write short tiote on fibre reinforced resin. . (31 7. a) Explain variable oxidation states of transition metals, along with nature of oxides. 4] b) Explain the colour of [Ti(H0),[ ion, . (4) c) Transition metal complex ions with d° or d!? configuration are colourless. Why’? 2 8. a) Explain the formation of [Ni (CO}.]° Complex on the basic of VBT. Also predict its geometry and magnetism with reason. (2+y b). Write the formula of the following co-ordination compounds. [0.54] i) Dichloro-tetra-aqua chromium (Ill) cation ii) Dicyano argentate (1) ion— — iii) Sodium hexa nitrito cobaltate (IID) iv) Hexa-cyanofernate (III) ion 9. a) What are primary explosives and plastic explosives? Give the methods of preparation of TNT and uses. (4143) b) Explain hubricating oils with types. 13) ©) What are requisites of good paint? Gi 10.) Define: (i) Optical isomers (ii) Racemic mincture (iii) Chirality (iv) Optical activity. 14) b) Get differences in between enantiomers and di-stereomers. 3) ©) How many meso-forms are possible for CH,OH (CHOH); CH;OH? Write their Fischer projection. Ry 11. a) Define lubricant and lubrication and explain the main purpose of lubricant. [sy b) What is paint? What are the requisites of a good paint? [142] 12a) Deseribe the mechanism involved in the reaction between a tertiary alkylhalide and aqueaus caustic potash. : [15415] What type af solvent favours the unimolecular nucleophilic’ substitution reaction * »)CE 03 TRIBKUVAN UNIVERSITY Exam, i INSTITUTE OF ENGINEERING Level | BE Examination Control Division [es 2068 Baichakh Subject: ~ Engineering Chemistry Y Candidates are required to give their answers in their own words as far as practicable. Y. Atiempt AU questions. The figures in the riargin indicate Y Assume suitable data if necessary. ul Marks, (7 Whats galvanic cell? Write electrode reaction, net cell reaction, EMF of the cell and cell notation of given electrode couple and also predict the spontaneity ofthe eell reaction. [144] NU" Be Zn/Zn"* = 0.76V, E° Ag'/Ag = 0.80V [Zn] =0.01M, [Ag"]=0.1M 2, How does an acidic buifer solution reserve its PH value on the addition of strong acid or sirong base? 10¢ml of 0.2M CH,COONa is mixed with 200ml of 0.3M CH3COOH, which is 2.1% ionised ia dilute solution. Find out the PH of the resulting solution. [2.5+2.5] 3. Write the adsorption theory to describe the mechanism of heterogeneous catalysis with a suitable example, How docs « promoter enhance the catalytic action? List any two criteria of catalysed reactions applicable for the industries, G++) 1 4 Write short notes on:(any two) (2.5425) 2) Green house effect b) Formation end depletion of ozone layer ©) Acid rain 5. List out four major pollutants of air, their adverse effects on human health and also write their possible remedies [14242 Write the method of preparation and two important uses of each of polyurethane and iamine epoxy resin [25425] 7. What is biodegradable polymer? Describe the contribution of csrbon fibre reinforced __ “polymer and chalcogenide glass in engineering (ay 8. 8) What are transition elements? Which of the 34 series elements is not a transition clement and why? [142] b) Explain why compounds of V*S are cdlourless but those of V"? aré colourful, < * Q 9. a), Explain the causé of origin of paramagnetism in transition elements, Bl 'b) Explain why are transition élements good for alloy formation, a 10.4), What is meant by effective atomie number of metal ion in the complex sale What = inférmation does it convey? “ (21 ) Explain the formation of (Ni(CO),}* complex on the basis of VBT. Also predict its geometry and magnetism with reason B) Ll.8) Write the basic assumptions of Wemes’s theory of co-ordination compounds B61 z, Ag nes ag a pe ae faeb) Write the TUPAC names ofthe following co-ordination compounds, 1 i)’ [Co(NHE)2 (endsICLs ii) [AMOH) (Hi20)s)" iit) KalFe(CN}e} “ivy K[AR(CN)2] 12,.Whatjs.plastic.explosive? Howelo you prepare dynamite and gusrbatton? 13.) What is paint Write characteristics of 4 good paint and expliin the method of application of paint in galvanised iron. (ost+]) ). What is lubricant? Give an example of emulsicin and solid lubricant. Mention their specific functions, (osH+i] 14, a) Distinguish between enantiomers and diasteromers. Write all possible stersoisomers of a compound that contain two asymmetric carbon atoms but eannot exist in meso ¢ forms. uy 'b) Write the cis and trans isomers of butencdioic avi. oh 15. a) What is resolution? Explain the method of chemical resolution of a racemate 6) ) Determine B or Z configuration in the following molecules 2 ce CH,CH LACH, y Te-c C H,C cH, HO, cn \ woe one ce \cx,on 16. What is @ nucleophlic substition reaction? Briefly explain SN” and SN paths of such zeaction in haloalkane. Mention the factors governing these paths. (14247 “pated. [eazy03 TarBHAIVAN UNIVERSITY CesT Regataviiack INSTITUTE OF ENGINEERING “Teva! BE. Full Marks. 80 Examination Control Division , Programme | BC 2057 Askadh Year Part 17] BME | PassMarks 32 2 Shr Subji Candidates are required to give their answers in their own words as far as practicable i Attempt All questions, | The figures in tne margin indicate Full Marks, Assume suitable data if necessary. gineering Chemistry R586 How does electrode potentiaf dflginate? Define standard clectrode potential? Write the cell notation, and eell reaction for Za-Cu cell [2H142} What is buer solution’? Calculate the pF of resulting golution when 0.005,mole of KOI, is added to 200 mil of 0.1N acetic acid solution, (pK, = 4.74). tsa) 2 What is meant by Homogeneous catalysis? Describe the intermediate compound formation theory of catalysis with a suitable example, List the eritetia for choosing a catalyst for industrial application, fase & 4) What are chlorofluorocarbons? Give their photolytic reactions in the upper atmosphere, B b) Why oxides of sulphur and nitrogen are assumed as air pollutants? py Poine out four major pollutants of water, their adverse effect on human health ang also | ‘mention theit possible remedies, [asa] 3 | 6, Describe the preparation and uses of polyphosphazines and polymeric sulphur (PS)n 5] 7. What are double and complex salts? Write the formulae of the follwing co-ordination compounds, 243) 3 4), Dibromotetraaquochromium (III) chloride ) Potassium hexacyanocobaltate (I) ©) Tetrabromocuparate (I) 4) Tetsaamminedichloracobalt (111) ©) Hexacysnoferrate (11) ion Sodium trioxalato aluminate (IN) 8. a) What are principal and auxiliary valencies of the metal ion in the complex compound? Mlustrate them jn [Co (NH)s] Cos. @ ss b) Show yout familiarity with clectrotic interpretation of complexés, bo. a a ¥ 4 we : Cc sin the followings B49) ey ) Transition elements are good in forming complexes 5) Show your acquaintance with application of 3-d transition elements. opt bo What are transition elements? Explain the following features of transition elements; [14242] 9 ‘) Variable oxidation state pe Maat opejes? Give the preparation, ps wu initrotoluene (7), plastic explosives? Define hubs and i sation their functioas. Name different pes of liquid lubricants miliary with types of paint 3a) What are metrical isomers? Draw the siructure of 2-Chlon and specify Z and E configuration, CPrraseees antiomerism with an example. Mention a typieal organic molecule which YP’ exhibits cstoreomeriom 14. Deseribe the mec -3-methylpent-2-ene 1 involved in the reaction between a tertiary alkyl halid sausous castle potash, How does $2 reaction differ from Sul i its stereochemistry? [441] BF Wrete the mectanism of bimolecular climinaton reaction ~ [2 b) Mention the effect of nucleophile, substrate and solvent on nucleophilic substitmion reaction mechanisms, GB ‘6. Wiha ara bio-degradable and nonbiodegradable polymers? Mention the uses of epoxy resin and fibre reinforced polymer. (23) x 4