PUNJAB GROUP OF COLLEGES

CHEMISTRY 1st Quarter Book Test INTER PART-II

(Objective Type)
MCQ Correct Option Reference in Textbook
(i) B Chapter # 1, Exercise Q # 3 ( i)
(ii) D Chapter # 1, Exercise Q # 3 (iv)
(iii) C Chapter # 1, Exercise Q # 3 (iii)
(iv) A Chapter # 4, Exercise Q # 3 (x)
(v) C Chapter # 4, Exercise Q # 3 (iv)
(vi) B Chapter # 4, Exercise Q # 3 (ix)
(vii) C Chapter # 7, Exercise Q # 3 (vii)
(viii) A Chapter # 7, Exercise Q # 3 (v)
(ix) C Chapter # 7, Exercise Q # 3 (iv)
(x) B Chapter # 12, Exercise Q # 3 (i)
(xi) D Chapter # 12, Exercise Q # 3 (iii)
(xii) B Chapter # 12, Exercise Q # 3 (v)

(Subjective Type)

SECTION-I

Q.2 Short answers of the questions.

(i) Give the similarities and dissimilarities between hydrogen and alkali metals?
Ans. Chapter # 1, Page # 14
The position of hydrogen (1st paragraph)
(ii) What is Shielding effect? Give its periodicity.
Ans. Chapter # 1, Page # 7 ionization energy (Variation within group)
Key Points: Definition + Shielding effect increases down the group due to increase in number of shells and in
period decreases from left to right.
(iii) How AIF3 is conductor while AlI3 is insulator at room temperature?
Ans. Chapter # 1, Topic is Halides (Last paragraph)
Key Words: AlF3 is ionic solid and conductor in molten state but AlI3 is covalent compound so it is non-conductor.
(iv) Why is SO3 dissolved in H2SO4 and not in water?
Ans. Chapter # 4, Page # 71, Topic is Contact Process, Absorption Unit
H2SO4 + SO3  H2S2O7 (Oleum)
SO3 is not dissolve in water due to highly exothermic process.
(v) How ortho phosphoric acid converted into different forms at different temperatures?
Ans. Chapter # 4, Page # 68
240C 316C
2H3PO4  H4P2O7  2HPO3
H2O H2O
Orthophosphoric Pyrophosphoric Metaphosphoric
acid acid acid
(vi) How aqua regia dissolves Gold?
Ans. Chapter # 4, Page # 63
Key Points: (Complete equations)
HNO3 + 3HCl  NOCl + Cl2 + 2H2O
2NOCl  2NO + Cl2
3Au + 3Cl2  2AuCl3
(vii) What are Fossil fuels?
Ans. Chapter # 7, Page # 120
Heading: Sources of Organic Compounds
(viii) Explain the tetra valency of Carbon atom?
Ans. Key Point: Valence shell electronic configuration
6C = 2s2, 2p2 (2px1,2py1,2pz0)
After excitation of electrons
6C = 2s1, 2p3 (2px1,2py1,2pz1)
(ix) What is catalytic cracking?
Ans. Chapter # 7, Page # 122
Key Words: Catalyst SiO2 and Al2O3 at 500C, for obtaining better quality gasoline.
(x) What is chemistry of Silver Mirror test?
Ans. Chapter # 12, Page # 244
R  CHO + 2[Ag(NH3)2]OH  R  COONH4 + 2Ag + 2NH3 + H2O
(xi) Give the polymerization reaction of formaldehyde and acetaldehyde?
Ans. Chapter # 12, Page # 239
Equations:
O

H2SO4 CH2 CH2

3HCHO 
O O

CH2
Metaformaldehyde
O

H2SO4
CH3  CH CH  CH3
3CH3  CHO 
O O

CH
Paraldehyde
(xii) Differentiate between butanone and 3-pentanone by iodoform test?
Ans. Chapter # 12, Exercise Question # 17 (v)
This can be distinguished by iodoform test (give equation)
O
||
CH3  C  CH2  CH3 + I2 + NaOH  No reaction
(xiii) What is meant by Lanthanide Contraction?
Ans. Chapter # 1, Topic: Atomic size, Page # 6 (Definition)
(xiv) Why phosphorous form five bonds while nitrogen not?
Ans. Chapter # 1, Page # 9 (Oxidation State)
Key Point: Valence shell electronic configuration
15P = 3s2, 3p3, 3d0
After excitation of electrons
3s1, 3p3, 3d1
7N = 2s2, 2p3
No excitation of electron due to absence of d-orbital
(xv) Why there is free rotation across single bond while restricted rotation across double bond?
Ans. Chapter # 7, Exercise Question # 15
Key Words: Rotation could happen only if the -bond breaks. This ordinarily costs too much energy.
(xvi) What is Formalin? How it is prepared?
Ans. Chapter # 12, Page # 230
Preparation of Formaldehyde, Mixture of 40% formaldehyde, 8% Methanol and 52% water
O
Pt-asbestos ||
2CH3OH + O2  2H  C  H + 2H2O
300C

SECTION-II

Q.3 (a) Write a detail note on Ionization energy.

Ans. Chapter # 1, Page # 6
Key Points: Definition + Example with value of H, give reason that 2nd I.E > 1st I.E
Discuss variation in group and period.
Q.3 (b) Explain the Brikeland and Eyde’s process for the manufacture of nitric acid.
Ans. Chapter # 4, Page # 6
Manufacturing of Nitric Acid
Key Points: Complete equations
Q.4 (a) What is meant by Functional group? Name typical functional groups containing oxygen?
Ans. Chapter # 7, Page # 125 + 126
Definition and examples, give the names of functional groups and their structures.
Alcohol R  OH , Ether ROR
Aldehyde R  CHO , Ketones R  CO  R etc
Q.4 (b) What is disproportionation reaction? Give the mechanism of Cannizzaro’s reaction. Which type of carbonyl
compounds give this test?
Ans. Chapter # 12, Page # 237
Definition + Equation and complete Mechanism.