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Studying The Production Process and Mechanical Properties of Reactive Powder Concrete: A Hong Kong Study
Studying The Production Process and Mechanical Properties of Reactive Powder Concrete: A Hong Kong Study
Studying The Production Process and Mechanical Properties of Reactive Powder Concrete: A Hong Kong Study
9, September, 647–654
doi: 10.1680/macr.9.00063
Reactive powder concrete is a relatively new cementitious material. Its main features include a high percentage
ingredient of Portland cement, very low water-to-binder (cement + silica fume) ratio, a high dosage of super-
plasticiser and the presence of very fine crushed quartz and silica fume. Coarse aggregate in normal aggregate
concrete is completely replaced by fine quartz sand with particle sizes ranging from 150 to 600 ìm. Reactive
powder concrete is characterised by ultra-high performance in mechanical properties, particularly in compressive
strength; and this could be of tremendous interest to construction practitioners. However, production of reactive
powder concrete is not yet available in Hong Kong and limited research is available in this area. This study is an
attempt to produce reactive powder concrete using local materials under laboratory conditions. Concrete designed
from reactive powder concrete and high-performance concrete is experimentally conducted and compared. The
results show that the compressive strength, splitting tensile strength and static modulus of elasticity are found to be
significantly higher than that of high-performance concrete using the same water-to-binder ratio. It is noted that
the rate of strength development of the reactive powder concrete samples is greater than that of high-performance
concrete. The difference in strength at a later age is even bigger. Compressive strength of about 200 MPa could
even be achieved in 3 days for the reactive powder concrete samples when the samples were heat-treated at a
temperature of about 2508C for 16 h, which can be explained by the formation of xonotlite under scanning electron
microscopy investigation.
of very-high-strength concrete (Long and Wang, 2002). Richard and Cheyrezy, 1995; Shaleen and Shrive, 2006;
An experiment on shear strength test found that the Washer et al., 2004).
ultra-high-performance concrete beams (total length of
8.6 m and a total depth of 650 mm) were observed to Mixing sequences
crack in the web regions in an average shear force of The conventional mixing method is based on BS
230 kN (Voo and Poon, 2008). The beams then under- 1881: part 125 (BSI, 1986). However, since RPC is
went strain hardening in the web regions and numerous composed of very fine materials, the conventional mix-
smear diagonal cracks appeared. The average ultimate ing method is not appropriate and thus the selected
shear carrying capacity was measured to be 350 kN. It mixing method cannot be the same. The focus of this
is reported that the ultra-high-performance concrete can study is to compare the mechanical properties of both
be used as structural members for many engineering types of concrete made using the same water-to-binder
applications. ratio. The following sequence in mixing RPC is based
Despite these attractive properties, RPC has not re- on previous studies (Bonneau et al., 1997; Chan and
ceived much attention in Hong Kong owing probably to Chu, 2004; Feylessoufi et al., 2001; Lee and Chisholm,
the complicated production process, and its unknown 2005; Morin et al., 2002; Shaleen and Shrive, 2006), as
and unconfirmed properties when made using local well as the current authors’ own trial-and-error ap-
materials. In fact, there are many examples of innova- proaches
tive RPC bridges existing around the world, such as the
(a) dry mixing powders (including cement, quartz
world’s first RPC pedestrian bridges, Sherbrooke Foot-
sand, crushed quartz and silica fume) for about
bridge in Canada, Sakata-Mirai Footbridge in Japan
3 min with a low speed of about 140 r/min
and more recent highway bridges in the United States
(b) addition of half volume of water containing half
of America (Rebentrost and Cavill, 2006). Apart from
amount of superplasticiser
the applications of RPC in constructing bridges, it can
(c) mixing for about 3 min with a high speed of about
be used as a reliable container for radioactive waste
285 r/min
from disused nuclear plants because of the excellent
(d ) addition of the remaining water and superplastici-
strength and durability (Collepardi et al., 2003).
ser
This paper aims to study the current development of
(e) mixing for about 10 min with a high speed of
RPC in construction, investigate the production process
about 285 r/min.
of RPC, examine its mechanical properties, including
compressive strength, splitting tensile strength and sta- The entire mixing process takes about 15 min. The
tic modulus of elasticity by making comparison to HPC RPC mix is compacted using a vibrating table and hand
made by local materials, and explore the effects of tamping using a square tamping rod. The specimens
heat-treatment for RPC. are demoulded 24 h after casting. Some samples are
placed in a water tank at 278C and cured for a specific
number of days for testing; some samples are placed in
Experimental programme an oven at 2508C for 16 h and taken out for testing.
disperse silica fume fully, breaking up any agglomer- curing days. In general, the compressive strength of the
ated particles, and allowing superplasticiser to develop RPC is higher than that of the HPC over the entire
its full potential (De Larrard et al., 2004; Lee and curing period using the same water-to-binder ratio of
Chisholm, 2005). about 0.24. This is attributable to the enhancement of
homogeneity of RPC by elimination of coarse aggre-
Mechanical properties gates (Richard and Cheyrezy, 1995). This also leads to
The test results of compressive strength, splitting a high packing density of solid particles of the RPC
tensile strength and static modulus of elasticity for the mix (Wong and Kwan, 2008). The homogeneity and
RPC and HPC samples are summarised in Table 2. high packing density of fine particles of RPC can be
supported by the scanning electron microscopy (SEM)
Compressive strength. Figure 1 shows the compres- observations as shown in Figure 2, in which no distinct
sive strength of the RPC and HPC samples at different interfacial transition zone (ITZ) is observed and minute
Concrete mix Temperature: Duration: Compressive strength: Splitting tensile strength: Static modulus of
8C days MPa MPa elasticity: GPa
8
Splitting tensile strength, ft: MPa
6
Cement paste
5
Aggregate
4
2 RPC
HPC
1
0
7 14 28 56
Age: days
Figure 3. Scanning electron micrograph of the HPC samples Figure 4. Splitting tensile strength of the RPC and HPC
at 28 days samples at different curing days
650 Magazine of Concrete Research, 2010, 62, No. 9
Studying the production process and mechanical properties of reactive powder concrete
50
45
Effect of temperature on mechanical properties of RPC
Elastic modulus, E: GPa
40
35 From Table 2, it is found that the compressive
30 strength of RPC increases rapidly with temperature,
25 from 1008C to 2508C. When the RPC samples are heat-
20 treated at temperature of about 1008C for 16 and 48 h,
15 compressive strengths of about 120 MPa are achieved in
10 RPC 3 days. However, compressive strengths reach about
HPC
5 200 MPa when the RPC samples are heat-treated at a
0
7 14 28 56
temperature of approximately 2508C for 16 and 48 h in
Age: days 3 days, a very high strength value. The increase is about
Figure 5. Static modulus of elasticity of the RPC and HPC 67%. Increased heat-treatment temperature leads to long
samples at different curing days calcium–silicate–hydrate (C–S–H) chains and this phe-
nomenon could be attributed to the progression of ce-
ment hydration as well as pozzolanic activity of both
160
silica fume and crushed quartz (Zanni et al., 1996). The
140 microstructure of RPC changed at a high temperature of
Compressive stress: MPa
Xonotlite
Cement paste
Figure 8. Scanning electron micrograph of cement paste and Figure 10. Scanning electron micrograph of toberorite found
xonotlite at a lower magnification at 2508C for 16 h
References
Appa Rao G (2003) Investigations on the performance of silica fume
incorporated cement pastes and mortars. Cement and Concrete Re-
search 33(11): 1765–1770.
Behnood A and Ziari H (2008) Effects of silica fume addition and
water to cement ratio on the properties of high strength concrete
Figure 11. Scanning electron micrograph of xonotlite after exposure to high temperatures. Cement and Concrete Compo-
secondary particles found at 1008C for 16 h sites 30(2):106–112.
Bonneau O, Lachemi M, Dallaire E, Dugat J and Aitcin PC (1997)
Mechanical properties and durability of two industrial reactive
0.058 and 0.058 for 7, 14, 28 and 56 days respectively, powder concretes. ACI Materials Journal 94(4): 286–290.
BSI (British Standards Institution) (1986) BS 1881: part 125. Method
which are higher than those of HPC at 0.063, 0.060, for mixing and sampling fresh concrete in the laboratory is adopted
0.059 and 0.0553 for 7, 14, 28 and 56 days respectively. for mixing HPC. BSI, London.
Although the ratios at the early age are quite different Chan YW and Chu SH (2004) Effect of silica fume on steel fiber
between RPC and HPC, the ratios are merging and bond characteristics in reactive powder concrete. Cement and Con-
have similar values at 28 days, showing that the rela- crete Research 34(7): 1167–1172.
Cheyrezy M, Maret, V and Frouin L (1995) Microstructural analysis
tionships between splitting tensile strength and com- of reactive powder concrete. Cement and Concrete Research 25(7):
pressive strength are comparable for concrete at the 1491–1500.
matured curing age. After 28 curing days, the ratios for Collepardi M, Collepardi S, Troli R and Coppola L (2003) Innovative
RPC become stable; however, the ratio for HPC is still concretes (SCC, HPC and RPC) in the field of architectural, civil
varied. This shows that both splitting tensile strength and environmental engineering. Proceedings of the Workshop on
New Technologies and Material in Civil Engineering, Milan, pp.
and compressive strength are constantly developing for 1–8.
RPC after 28 curing days, but not for HPC. De Larrard F, Chopin D and Cazacliu B (2004) Why do HPC and
For the ratio of static modulus of elasticity to com- SCC require a longer mixing time? Cement and Concrete Research
pressive strength, results of 0.43, 0.36, 0.33 and 0.32 34(12): 2237–2243.
have been recorded for RPC and 0.34, 0.38, 0.41 and El-Hemaly SAS, Mitsuda T and Taylor HFW(1977) Synthesis of
normal and anomalous tobermorite. Cement and Concrete Research
0.38 for HPC for 7, 14, 28 and 56 days respectively. 7(4): 429–432.
Gradually increasing ratios from 7 to 56 curing days Feylessoufi A, Cohen Tenoudji F, Morin V and Richard P (2001)
for RPC have been recorded; however, the ratios for Early ages shrinkage mechanisms of ultra-high-performance ce-
HPC are reduced for a greater number of curing days. ment-based materials. Cement and Concrete Research 31(11):
This explains the fact that the rate of strength develop- 1573–1579.
Ji WY, An MZ, Yan GP and Wang JM (2008) Study on Reactive
ment of the RPC samples is greater than that of HPC. Powder Concrete Used in the Side Walk System of the Qinghai-
The development of RPC is still relatively new com- Tibet Railway Bridge. Schmitz Ready Mix Inc., China.
pared with HPC and other types of concrete. Therefore, Lee NP and Chisholm DH (2005) Study report reactive powder con-
it is necessary to provide more in-depth research stud- crete. BRANZ 1(1): 146.
ies for RPC to ensure consistent cause and effect rela- Long G and Wang XYX (2002) Very high performance concrete with
ultra fine powders. Cement and Concrete Research 32(4): 601–
tions. 605.
Ma JX and Schneider H (2002) Properties of ultra high performance
concrete. Leipzig Annual Civil Engineering Report (LACER 2002)
7(1): 7.
Conclusion Mehta PK and Monteiro JM (1993) Concrete: Structure, Properties,
and Materials. Prentice Hall, Upper Saddle River, NJ.
This paper has investigated the production process, Mindess S, Young F and Darwin D (2003) Concrete. Prentice Hall,
mechanical properties and effects of heat-treatment of Upper Saddle River, NJ.
RPC by making comparisons with HPC. Tests to con- Morin V, Choen-Tenoudji F, Feylessoufi A and Richard P (2002)
crete samples were experimentally conducted. It was Evolution of the capillary network in a reactive powder concrete
during hydration process. Cement and Concrete Research 32(12):
found that compressive strength, splitting tensile
1907–1914.
strength and static modulus of elasticity of the RPC are Rebentrost M and Cavill B (2006) Reactive powder concrete bridges.
higher than those of the HPC over the entire curing Austroads 6th Bridge Conference: Bridging the Gap, Perth, Wes-
period for the same water-to-binder ratio. The rate of tern Australia, 1–11.
Richard P and Cheyrezy M (1995) Composition of reactive powder Wong HHC and Kwan AKH (2008) Packing Density: a Key Concept
concretes. Cement and Concrete Research 25(7): 1501–1511. for Mix Design of High Performance Concrete. Hong Kong Pro-
Shaleen E and Shrive NG (2006) Optimization of mechanical proper- ductivity Council, Hong Kong.
ties and durability of reactive powder concrete. ACI Materials Yazici H (2007) The effect of curing conditions on compressive
Journal 103(6): 444–451. strength of ultra high strength concrete with high volume mineral
Shaw S, Clark SM and Henderson, CMB (2000) Hydrothermal admixtures. Building and Environment 42(5): 2083–2089.
formation of the calcium silicate hydrates, tobermorite Zanni H, Cheyrezy M, Maret V, Philippot S and Nieto P (1996)
(Ca5Si6O16(OH)2 .4H2 O) and xonotlite (Ca6Si6O17(OH)2 ): an in Investigation of hydration and pozzolanic reaction in reactive pow-
situ synchrotron study. Chemical Geology 167(1): 129–140. der concrete using 29Si NMR. Cement and Concrete Research
Voo YL and Poon WK (2008) The world first portal frame building 26(1): 93–100.
(Wilson Hall) constructed using ultra-high performance concrete.
The 33rd Conference on Our World in Concrete and Structures,
Singapore, vol 1, 493–500.
Washer G, Fuchs P, Graybeal BA and Hartmann JL (2004) Ultrasonic
testing of reactive powder concrete. IEEE Transaction on Ultra- Discussion contributions on this paper should reach the editor by
sonic, Ferroelectrics and Frequency Control 51(2): 193–201. 1 March 2011.