EQUILIBRIO LIQUIDO-VAPOR

DIAGRAMA x -y
BENCENO(1)-TOLUENO(2)
760 mm Hg
1

0.9

0.8

0.7

0.6
Raoult
exp
y

0.5

0.4

0.3

0.2

0.1

0
0 0.1 0.2 0.3 0.4 0.5
x 0.6 0.7 0.8 0.9 1
 EQUILIBRIO LIQUIDO-VAPOR
DIAGRAMA x,y - T
BENCENO(1)- TOLUENO(2)
760 mm Hg
390

380

x-T Raoult
y-T
370
Raoult
x - T exp
y - T exp
T

360

350

340

330
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
x, y
 ELV BENCENO(1) - TOLUENO(2) IDEAL ISOBARICO
343 400
BENCENO(1)TOLUENO(2)
TC 562.2 591.8
PC 48.9 41
Tb 353.2 383.8
VpA -6.98273 -7.28607
VpB 1.33213 1.38091
VpC -2.62863 -2.83433
VpD -3.33399 -2.79468

Patm 1.01325
PHI 1

0 x1 x2 TOC TK x1 ln(Pvp/Pc) pvp

1 0 1 110.708388 383.858388 0.31722094 -3.02348012 2.37808913
2 0.05 0.95 108.421133 381.571133 0.32128934 -3.08190846 2.24312265
3 0.1 0.9 106.228598 379.378598 0.32518926 -3.13867913 2.11932632
4 0.15 0.85 104.157646 377.307646 0.32887292 -3.19300111 2.00727139
5 0.2 0.8 102.194189 375.344189 0.33236537 -3.24514359 1.9052892
6 0.25 0.75 100.327205 373.477205 0.33568622 -3.29531312 1.81205992
7 0.3 0.7 98.5486679 371.698668 0.33884975 -3.34364971 1.72655429
8 0.35 0.65 96.852012 370.002012 0.34186764 -3.39026413 1.64791898
9 0.4 0.6 95.231429 368.381429 0.34475022 -3.43525495 1.57542086
10 0.45 0.55 93.6816386 366.831639 0.34750687 -3.47871358 1.50842161
11 0.5 0.5 92.1752307 365.325231 0.35018636 -3.52136786 1.44543387
12 0.55 0.45 90.7648203 363.91482 0.35269509 -3.56167769 1.38832739
13 0.6 0.4 89.4068706 362.556871 0.35511051 -3.60083458 1.33501539
14 0.65 0.35 88.098852 361.248852 0.35743712 -3.63887737 1.2851816
15 0.7 0.3 86.8095968 359.959597 0.35973035 -3.67669131 1.23749117
16 0.75 0.25 85.6242692 358.774269 0.36183872 -3.71173815 1.19487221
17 0.8 0.2 84.4245016 357.574502 0.36397278 -3.74748956 1.15290845
18 0.85 0.15 83.3100865 356.460086 0.36595502 -3.78095073 1.11496907
19 0.9 0.1 82.2301283 355.380128 0.36787597 -3.8136126 1.07914039
20 0.95 0.05 81.1832328 354.333233 0.36973811 -3.84549805 1.04527431
21 1 0 80.1961671 353.346167 0.37149383 -3.8757649 1.01411113

X y TC T K
0 0 110.05 383.2
0.1 0.208 105.31 378.46
0.2 0.372 101.46 374.61 0
0.3 0.507 98 371.15 1
0.4 0.619 95.05 368.2
0.5 0.713 92.3 365.45
0.6 0.791 89.74 362.89
0.7 0.857 87.29 360.44
0.8 0.912 84.99 358.14
 0.9 0.959 82.68 355.83
0.95 0.98 81.43 354.58
1 1 80.13 353.28
x2 ln(pvp/pc) pvp y1 y2 y1+y2
0.35137143 -3.70121662 1.0124321 0 0.99919279 0.99919279
0.35523634 -3.76661321 0.94834099 0.1106895 0.8891428 0.9998323
0.3589412 -3.83016514 0.88994726 0.20916125 0.79047869 0.99963994
0.36244061 -3.89098519 0.83743375 0.29715343 0.70251043 0.99966385
0.36575838 -3.94937307 0.78993786 0.37607485 0.62368644 0.99976129
0.36891314 -4.0055587 0.74677852 0.44709102 0.55275982 0.99985085
0.37191844 -4.05969773 0.70742359 0.51119298 0.48872096 0.99991394
0.37478538 -4.11191322 0.67143293 0.56922935 0.43072431 0.99995366
0.37752378 -4.16231474 0.63843036 0.6219278 0.37804907 0.99997687
0.38014255 -4.21100396 0.6080903 0.66991337 0.33007616 0.99998953
0.38268802 -4.25879574 0.5797121 0.71326616 0.28606568 0.99933184
0.38507127 -4.3039639 0.55411012 0.75359493 0.24608888 0.99968381
0.38736588 -4.34784297 0.530322 0.79053465 0.20935485 0.9998895
0.38957612 -4.39047608 0.5081879 0.82444415 0.17553986 0.99998402
0.39175465 -4.43285503 0.4871014 0.85491618 0.14421951 0.99913569
0.39375757 -4.47213475 0.46833909 0.88443539 0.11555369 0.99998908
0.39578489 -4.51220592 0.44994323 0.91026574 0.08881189 0.99907763
0.39766798 -4.54971168 0.43338031 0.93533058 0.06415697 0.99948755
0.39949286 -4.58632287 0.41780068 0.95852589 0.04123372 0.99975961
0.40126186 -4.62206495 0.40313133 0.98002526 0.01989298 0.99991825
0.40292976 -4.6559937 0.38968302 1.00084987 0 1.00084987

0
1