Professional Documents
Culture Documents
Termo Cuantica
Termo Cuantica
Results in Physics
journal homepage: www.journals.elsevier.com/results-in-physics
a r t i c l e i n f o a b s t r a c t
Article history: The Heisenberg uncertainty relation, DxDpx P ⁄/2 (⁄ h/2p), is well known. The purpose of this paper is
Received 16 September 2016 to study a linkage between macroscopic thermodynamic quantities and the uncertainty relation. To sim-
Received in revised form 1 November 2016 plify matters, we consider one-dimensional harmonic oscillator model. The calculations are carried out
Accepted 3 November 2016
by two steps. First, the thermal average of the uncertainty relation is obtained for canonical system in
Available online 9 November 2016
thermal equilibrium at temperature T, which is denoted by ðDxÞT ðDpx ÞT . Second, the thermodynamic
quantities are expressed analytically as a function of ðDxÞT ðDpx ÞT within the harmonic oscillator model.
Finally, a connection between the energy fluctuations and the uncertainty relation is clarified for the
Einstein’s heat capacity model. The analysis is made on the basis of fluctuation theory. The uncertainty
relation is valid not only in quantum state but also at finite temperature.
Ó 2016 The Author. Published by Elsevier B.V. This is an open access article under the CC BY-NC-ND license
(http://creativecommons.org/licenses/by-nc-nd/4.0/).
http://dx.doi.org/10.1016/j.rinp.2016.11.007
2211-3797/Ó 2016 The Author. Published by Elsevier B.V.
This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).
S. Nagata / Results in Physics 6 (2016) 946–951 947
distinguish the properties between particle-like fluctuation and In the same way, ðDpx Þ2T becomes
wave-like fluctuation in energy. With increasing temperature, the
contribution to the dispersion in energy varies gradually and dis- ðDpx Þ2T < ðDpx Þ2 >T ¼< p2x >T < px >2T ¼< p2x >T ;
plays a crossover from particle to wave properties. The essential
1X 1
point is that both particle-like fluctuation and wave-like fluctuation ¼ < njp2x jn > ebEn ;
Z n¼0
in energy can be written as a function of (Dx)T(Dpx)T, respectively.
In addition, it is discussed that temperature is linked closely P1 ð9Þ
¼ mhx 1Z 1
2
þ n eb9nþ1=2Þhx ;
with (Dx)T(Dpx)T in the harmonic oscillator model. n¼0
¼ mhxf2 þ < n >g ¼ mhx 12 þ hx1
1
:
Thermal average of uncertainty relation ekB T 1
ðDxÞ2T < ðDxÞ2 >T ¼< x2 >T < x>2T ¼< x2 >T ;
1X 1
¼ < njx2 jn > ebEn ;
Z n¼0
1
h 1 X 1 ð8Þ
¼ þ n ebðnþ1=2Þhx ;
mx Z n¼0 2
! Fig. 1. The thermal average of the uncertainty relation, (Dx)T(Dpx)T/⁄, as a function
h 1 h 1 1 of x = kBT/⁄x in the one-dimensional harmonic oscillator model. Quantities (Dx)T
¼ þ<n> ¼ þ :
mx 2 mx 2 ekhBxT 1 and (Dpx)T indicate the root-mean-square deviations in thermal equilibrium of
canonical system at T.
948 S. Nagata / Results in Physics 6 (2016) 946–951
It is remarked that Eq. (10) has validity within the oscillator The mean internal energy in the canonical distribution is
model of canonical system in thermal equilibrium. For other 1 hx ðDxÞT ðDpx ÞT
canonical model systems, the formula concerned with Eq. (10) < E > E ¼ hx þ bhx ¼ hx ð13Þ
2 e 1 h
has not been found yet because of the mathematical difficulty. The value of <E> is in direct proportion to (Dx)T(Dpx)T/⁄. In Fig. 3
the variation of <E>/⁄x with (Dx)T(Dpx)T/⁄ is shown.
Linkage between thermal quantities and the uncertainty The Helmholtz free energy, F, can be written in the forms
relation F ¼ kB TlnZ ¼ h2x þ kB T lnð1 ebhx Þ;
hx <n>
The partition unction Z of individual oscillator, for the Einstein ¼ þ kB T lnð1 Þ;
2 8 < n > þ1 9
model of one-dimensional lattice vibration, can be written as a
function of (Dx)T(Dpx)T/⁄.
>
> >
>
>
>
>
>
>
> >
ebhx=2
< n > þ1
>
> ðDxÞT ðDpx ÞT 1 > >
> ð14Þ
1 >
<1 ln þ >
=
Z¼ ¼< n > exp ln ; h 2
1 ebhx 2 <n> ¼ hx 2 3 :
8 2 39 >
> 2 ð D xÞ ð D p Þ 1 >
>
<
ðDxÞT ðDpx ÞT 1 >
= ð11Þ >
>
> 6
T x T
þ 7> >
>
>
þ >
ðDxÞT ðDpx ÞT 1 1 6 h 27 >
> ln4
ðD
h
ðHp Þ
2 5>
>
>
¼ exp ln4 5 : >
: xÞ 1 >
h 2 >
:2 ðD xÞ ð D p Þ 1 > T x T
;
T x T
; h 2
h 2
Fig. 4 shows the Helmholtz free energy F. The value of F/⁄x
Inversely, (Dx)T(Dpx)T/⁄ has the form in terms of Z becomes 0.500 as (Dx)T(Dpx)T/⁄ goes to 0.500. The validity, of the
pffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffi minimum F in stable equilibrium situation, implicitly rests upon
ðDxÞT ðDpx ÞT 1 þ 4Z 2 the uncertainty relation (Dx)T(Dpx)T/⁄.
¼ ð12Þ
h 2 The entropy, S, is derived from F in the forms
The partition function Z becomes zero as T goes zero, hence @F hx 1
(Dx)T(Dpx)T goes to ⁄/2 as T goes zero. Fig. 2 shows the variation S ¼ ¼ kB lnð1 ebhx Þ þ ;
@T V kB T ebhx 1
of Z in the strength of (Dx)T(Dpx)T/⁄. Since Z is expressed in terms
¼ kB fð< n > þ1Þ lnð< n > þ1Þ < n > ln < n >g;
of (Dx)T(Dpx)T/⁄, thermodynamic quantities can be written analyt-
ically by using (Dx)T(Dpx)T/⁄, which are shown below. ðDxÞT ðDpx ÞT 1 ðDxÞT ðDpx ÞT 1 ð15Þ
¼ kB þ ln þ
h 2 h 2
ðDxÞT ðDpx ÞT 1 ðDxÞT ðDpx ÞT 1
kB ln :
h 2 h 2
Fig. 5 shows S/kB versus (Dx)T(Dpx)T/⁄. The value of S/kB
becomes zero as (Dx)T(Dpx)T/⁄ goes to 0.500.
The heat capacity at constant volume, CV, is given by
@<E> ebhx
¼ kB ðbhxÞ
2
CV ¼ ; ð16Þ
@T V ðe x 1Þ
b
h 2
2
< n > þ1
¼ kB ln < n > ð< n > þ1Þ ;
<n>
ðDxÞT ðDpx ÞT 1 ðDxÞT ðDpx ÞT 1
¼ kB þ
h 2 h 2 ð17Þ
8 2 39
> ðDxÞT ðDpx ÞT 1 >2
< þ 7=
6 h 25 :
ln4
>
: ð D xÞ ð D p Þ 1 >
T x T
;
Fig. 2. The partition unction Z for individual oscillator as a function of (Dx)T(Dpx)T/⁄. h 2
Fig. 3. The internal energy <E> as a function of (Dx)T(Dpx)T/⁄. The value of <E> has Fig. 4. The Helmholtz free energy, F, as a function of (Dx)T(Dpx)T/⁄. The highest
no upper bound but has a certain lower bound because of the uncertainty relation. value of F/⁄x is 0.500.
S. Nagata / Results in Physics 6 (2016) 946–951 949
On the other hand, it is noted that the heat capacity, CV, can be The mean square deviation, <(DE)2>, which means the disper-
decomposed into two contributions, which is written as sion in energy, is defined as <(DE)2> = <E2> <E>2. The fluctuation
qffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffi
( ) in energy is < ðDEÞ2 > which means the root-mean square devi-
CV hx 2 1 1
¼ þ ; ation in energy. A general formula of <(DE)2> for the canonical sys-
kB kB T ebhx 1 ðebhx 1Þ2
tem is given by [7]
ð18Þ
hx 2
¼ ð< n > þ < n>2 Þ ;
kB T < ðDEÞ2 >¼ kB T 2 C V : ð21Þ
CV ðpÞðFirst termÞ þ C V ðwÞðSecond termÞ ;
This Eq. (21) has the validity, regardless of whether zero-point
8 2 39 energy exists or not. From Eq. (18), the dispersion in energy <
> ðDxÞT ðDpx ÞT 1 >2
< þ = ðDxÞ ðDp Þ (DE)2> for the Einstein model becomes
6 h 27 1
C V ðpÞ ¼ ln4 5 T x T
; ð19Þ
>
: ðDxÞT ðDpx ÞT 1 > h 2 < ðDEÞ2 > 1 1
; ¼ þ ¼< n > þ < n>2 ;
h 2 ðhxÞ
2 ebhx 1 ðebhx 1Þ2
2
8 2 39 ðDxÞT ðDpx ÞT 1
> ðDxÞT ðDpx ÞT 1 >2 2 ¼ ; ð22Þ
< þ = ðDxÞ ðDp Þ h 4
6
h 27 x T 1
C V ðwÞ ¼ ln4 5 T
: ð20Þ 2
>
: ðDxÞT ðDpx ÞT 1 > h 2 ðDxÞT ðDpx ÞT 1 ðDxÞT ðDpx ÞT 1
; ¼ þ ;
h 2 h 2 h 2
The first term CV(p) of Eq. (19) arises from the particle-like fluctua-
tion in energy and the second term CV(w) of Eq. (20) originates from DE2 ðpÞðFirst termÞ þ DE2 ðwÞðSecond termÞ : ð23Þ
Fig. 6. Heat capacity at constant volume, CV/kB, as a function of (Dx)T(Dpx)T/⁄, for Fig. 7. The dispersion in energy for the Einstein model of one-dimensional lattice
the Einstein model of one-dimensional lattice vibration. The heat capacity has two vibration as a function of (Dx)T(Dpx)T/⁄. The dispersion in energy, <(DE)2>,
components: CV/kB CV(p + w) = CV(p) + CV(w). The behavior of CV(p) and CV(w) normalized by (⁄x)2 has two components: <(DE)2>/(⁄x)2 DE2(p + w) = DE2(p)
originates from particle-like and wave-like properties of dispersion in energy. The + DE2(w). The behavior of DE2(p) and DE2(w) comes from particle-like and wave-
crossover point is found to be (Dx)T(Dpx)T/⁄ = 1.500 and CV(p) = CV(w) = 0.480. At like properties of dispersion in energy. The crossover point is given at (Dx)T(Dpx)T/⁄
lower values, (Dx)T(Dpx)T/⁄ 1.500, CV(p) contributes dominantly to the heat = 1.500. At lower values, (Dx)T(Dpx)T/⁄ 1.500, DE2(p) contributes dominantly to
capacity. the dispersion in energy.
950 S. Nagata / Results in Physics 6 (2016) 946–951
Fig. 9. Schematic illustration showing the linking bridges in canonical system for
Fig. 8. The dispersion in energy as a function of (Dx)T(Dpx)T/⁄ over a range of 0.50 to harmonic oscillator model. (a): Connection is mediated by means of <n>. They are as
10.00. follows: dispersion in energy <(DE)2>, thermal uncertainty relation (Dx)T(Dpx)T, and
the thermodynamic quantities such as mean energy E, the Helmholtz free energy F,
entropy S, and heat capacity at constant volume CV. (b): The dispersion in energy
<(DE)2> and the thermodynamic quantities S, E, F, and CV are mediated by
The dispersion in energy <(DE)2> is linked to the strength of (Dx)T(Dpx)T.
(Dx)T(Dpx)T in Eq. (22). The essential point is that <(DE)2> contains
two components due to wave-particle duality in energy. In the
same way as for the heat capacity, the labels are assigned as Eq.
Eqs. (24) and (25) indicate a close connection of T with (Dx)T
(23). The first term of Eq. (23) shows particle-like fluctuation,
(Dpx)T/⁄. In fact, Fig. 1 shows a simple linear dependence over a
and the second term shows wave-like fluctuation in energy. The
temperature region kBT/⁄x > 1.
interpretation of this particle-wave duality is quite a long story
In statistical mechanics, the temperature has been introduced
and was originally considered by Einstein [8]. The explanation of
to the canonical system as a parameter or index which determines
the duality is omitted in the present paper. We quote here the ref-
the distribution to the each energy level. Hence this distribution
erences in Ref. [9].
leads magnitudes of many thermodynamic quantities. In this
Figs. 7 and 8 show the variations of <(DE)2>/(⁄x)2. The cross
framework, the temperature does not directly connect with a
point is found to be (Dx)T(Dpx)T/⁄ = 1.500, and DE2(p) = DE2(w)
specific dynamical variable. Nevertheless, it is worth discussing
= 1.000. This is a crossover from the particle property to wave
the relationship between T and (Dx)T(Dpx)T/⁄.
property in dispersion with increasing (Dx)T(Dpx)T/⁄. The value of
The temperature is an intensive variable and the quantity
<(DE)2>/(⁄x)2 decreases monotonically with decreasing (Dx)T
(Dx)T(Dpx)T is also an intensive variable. The absolute temperature
(Dpx)T/⁄. It goes to zero as (Dx)T(Dpx)T/⁄ ? 0.500. At high values,
has the minimum value T = 0, and in the same manner the lowest
(Dx)T(Dpx)T/⁄ 1.00, DE2(w) causes mainly <(DE)2 > /(⁄x)2.
value of (Dx)T(Dpx)T/⁄ is bounded by 0.500. If the two separated
Incidentally, another analysis has been reported [9]. Although it
systems are characterized by the same temperature, then the sys-
is not dealt with here, the temperature dependence of <(DE)2> is
tems will remain in equilibrium when brought into thermal con-
calculated for the harmonic oscillator model. From this analysis,
tact with each other. In this sense, the same temperature in the
the graphical representation by using y = <(DE)2>/(⁄x)2 vs.
two systems holds the same value of (Dx)T(Dpx)T/⁄ with each other.
x = kBT/⁄x, the crossover point from the particle- to wave-like fluc-
The figures from 2 to 8 represent the characteristic behaviors of
tuations was found to be x = 1.443 with increasing temperature.
thermal properties as a function of (Dx)T(Dpx)T/⁄, where the
horizontal x-axis signifies (Dx)T(Dpx)T/⁄. In these figures x-axis
Discussion
seems to play a role just like temperature, over the region of
(Dx)T(Dpx)T/⁄ > 1.00.
Temperature and the thermal uncertainty relation
Here the author would like to mention some speculative
remarks, regardless of whether the description is adequate or
By using Eq. (10), temperature as a function of (Dx)T(Dpx)T/⁄ can
not. An activity of the uncertainty relation may drive substantially
be written in the forms
the canonical system to the thermal equilibrium state. Even if at
hx 1 low temperatures, the most canonical systems can attain to the
T¼ ;
kB < n > þ1 proper equilibrium state by changing and adjusting the distribu-
ln
<n> tion. The zero-point energy due to the uncertainty relation can
x
h 1 ð24Þ
shuffle and mix extremely low energy in the system. Presumably
¼ 8 9 tunneling effect, arisen from the overlap of the wave functions
kB >ðDxÞT ðDpx ÞT 1>
< þ = between adjacent oscillators, also helps the system to draw into
ln h 2
:ðDxÞT ðDpx ÞT 1>
> ; the thermal equilibrium in the harmonic oscillator model.
h 2
Inversely, (Dx)T(Dpx)T/⁄ is expressed in terms of T as given in Eq. Linking bridges by the thermal uncertainty relation
(10). In the region of (Dx)T(Dpx)T/⁄ 0.500 and hence kBT ⁄x,
we have Fig. 9 shows schematic illustrations from a perspective view
hx ðDxÞT ðDpx ÞT 1 point. These illustrations specify the connections between thermo-
T¼ ; kB T hx : ð25Þ dynamic quantities and the thermal uncertainty relation for har-
kB h 2
monic oscillator model. The present work exemplifies that the
S. Nagata / Results in Physics 6 (2016) 946–951 951
validity of macroscopic thermodynamics rests implicitly upon the Vol. 2(1976), Vol. 6(1970) (Tokai University Press, Tokyo) edited
uncertainty relation in quantum-mechanical laws in the micro- by Physics History Kankokai: T. Tsuji, T. Hiroshige, S. Nisio, E. Yagi,
scopic world. T. Ogawa, and A. Taniguchi.
Summary References