GravEiens EDUservices Pvt Ltd( Chemistry).

1. Which of the following oxidation-reduction reactions will be spontaneous

in the direction written? Select all that apply. Fe2- (aq) Pb (s)-- Fe (s)Pb2
(aq) .2+ Zn2 (aq)Cu (s)- Zn (s)Cu2 (aq) Cu2 (aq)Hg ()-Cu (s)Hg2 (aq)
Cu2 (aq)Pb (s)-Cu (s)+Pb2 (aq) Be2 (aq)+Mg (s)-Be (s)Mg2 (aq).

2. A 585−g piece of copper tubing is heated to 89.5°C and placed in an

insulated vessel containing 159 g of water at 22.8°C. Assuming no loss of water
and a heat capacity for the vessel of 10.0 J/°C, what is the final temperature of
the system (c of copper = 0.387 J/g·°C)?

3.A pycnometer weighs 25.60 g empty and 35.55 g when filled with water at
20°C. The density of water at 20°C is 0.9982 g/ml. When 10.20 g lead is placed
in the pycnometer and the pycnometer is again filled with water at 20°C, the
total mass is 44.83 g. What is the density of the lead in grams per cubic
centimetre?

4.Determine the electron geometry, molecular geometry, and idealized bond

angles for each molecule. In which cases do you expect deviations from the
idealized bond angle? b. NF a. CF4 d. H2S c. OF2 Which species has the
smaller bond angle, H3O or H2O? Explain. Explain why CO2 and CC14 are
both nonpolar even though they contain polar bonds. CH&F is a polar
molecule, even though the tetrahedral geometry often leads to nonpolar
molecules. Explain.

5. If you have a sample of water in a closed container, some of the water will
evaporate until the pressure of the water vapor, at 22.0°C is 19.8 mm Hg. How
many molecules of water per cubic centimeter exist in the vapor phase?

6. Calculate the pH of a solution created by placing 2.0 grams of yttrium

hydroxide, Y(OH)3, in 2.0 L of H2O. Ksp for Y(OH)3 is 6.0x10-24.
7.How many collisions does a single A atom, with collision cross section
σ=0.36nm2, make in 1.0 s when the temperatre is 25 degree centigrade and the
pressure is (a) 10 bar, (b) 100 kpa, (c) 1.0 pa?

8. What is the freezing point of a 50.0 mosM/kg salt solution after 30.0 g of
glucose (167 mosM/kg) is added.

9.Draw the two stereoisomers of 1,3-dibromocyclobutane Refer to the structure

below to answer the following questions:
4. Which of the labeled bonds in the structure are equatorial bonds?
5. Which of the labeled bonds are trans to bond b?
6. Which labeled bonds have a 1,3-diaxial interaction with each other?

10.Phosphorus pentachloride decomposes according to this equation. PCl5(g)

equilibrium reaction arrow PCl3(g) + Cl2(g) An equilibrium mixture in a 5.00 L
flask at 245°C contains 4.27 g of PCl5, 9.31 g of PCl3, and 2.86 g of Cl2. How
many grams of each will be found if the mixture is transferred into a 2.00 L
flask at the same temperature