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Navneet Jethwani Geometrical Optics: Organic Chemistry
Navneet Jethwani Geometrical Optics: Organic Chemistry
REVISION
OF
ORGANIC CHEMISTRY
FOR JEE ADVANCED
BY
NAVNEET JETHWANI
GEOMETRICAL
OPTICS
ETOOSINDIA
INDIA’S NO. 1 ONLINE COACHING
Plot No. 38, Near Union Bank of India, Rajeev Gandhi Nagar,
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ETOOSINDIA F.T.R. BY N.J. SIR
INDIA’S NO. 1 ONLINE COACHING
(A) A > B > C (B) B > C > A (C) B > A > C (D) B > C > A
Ans. (C)
*
KH *
2. A + H2 ; (C = C14)
H2O
Major product
*
*
(A) (B) (C) (D) All
*
Ans. (D)
3. Among the isomeric amine select the one with lowest boiling point.
H CH3 NH2
N
N
(A) (B) NHCH3 (C) (D)
CH3
Ans. (C)
4. Which of the following, is the product of the reaction between AlCl3 and CH3OCH3?
Cl Cl
– + CH3 + – CH3
(A) Cl—Al— O (B) Cl—Al— O
CH3 CH3
Cl Cl
Cl Cl
+ + CH3 – +
(C) Cl—Al— O (D) Cl—Al— CH3OCH3
CH3
Cl Cl
Ans. (A)
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Kota, Rajasthan – 324005 Mob. : 9214233303
ETOOSINDIA F.T.R. BY N.J. SIR
INDIA’S NO. 1 ONLINE COACHING
–
O
Ans. (D)
Ans. (B)
7. In sets a – d, only one of the set is incorrect regarding basic strength. Select it :
NH2
H
N
(B) < <
N N
H
NO2 CH3
Ans. (C)
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Kota, Rajasthan – 324005 Mob. : 9214233303
ETOOSINDIA F.T.R. BY N.J. SIR
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H Br H Br H Br Br
H H H H H H H H
(A) (B)
+
(C) (D) H
+
H + H H H H H H H
+
:NH2 :NH2 NH2 :NH2
Ans. (C)
– – –
O O O O
Ans. (D)
O O O
O
O
(A) (B) (C) (D)
O
O
Ans. (A)
Ans. (C)
O O
+ +
NH NH +
12.
NH
A B C
Correct acidic strength :
(A) A > B > C (B) B > A > C (C) C > A > B (D) A > C > B
Ans. (D)
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ETOOSINDIA F.T.R. BY N.J. SIR
INDIA’S NO. 1 ONLINE COACHING
Ans. (A)
c
OH
The acidic strength order :
(A) Hc > Hb > Ha (B) Hb > Hc > Ha (C) Ha > Hb > Hc (D) Ha > Hc > Hb
Ans. (C)
15. In which case 2nd R.S. is more stable w.r.t. Ist R.S. :
–
+ O 2+ O
(A) CH3–N CH3–N
– –
O O
+
O + O
(B) CH2
+
(C) CH3–C–OCH3 CH3–C=OCH3
O –
O
+ – – +
(D) CH3–O=CH–CH–CH=CH2 CH3O–CH–CH–CH=CH2
Ans. (B)
16. Choose compound having highest pKb value :
NH
NH2 (a)
N
NH
NH2 (b)
N
NH
H2N (c)
N
(A) a (B) b (C) c (D) Both a & b
Ans. (C)
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ETOOSINDIA F.T.R. BY N.J. SIR
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O O
of marked bond length.
(A) p > q > r (B) q > p > r (C) r > q > p (D) p > r > q
Ans. (D)
+
+
+
(A) (B) (C) (D) +
CH3 CH3 CH3 CH3
Ans. (D)
19. Consider the following reaction involving two acids shown below : formic acid and HF. Which of the following
O O
+ – – +
KF + H OH H O K + HF
pKa = 3.8 pKa = 3.2
Ans. (D)
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Kota, Rajasthan – 324005 Mob. : 9214233303
ETOOSINDIA F.T.R. BY N.J. SIR
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H2
Ni H = –28.6 kcal mole–1
excess H2
(Ni) H = –116.2 kcal mole–1
Anthracene
Calculate the resonance energy of anthracene :
(A) 84 kcal / mol (B) 100 kcal / mol (C) 110 kcal / mol (D) 116 kcal / mol
Ans. (A)
H
N
HCl Product
N H 1 mole
–
Cl H
H + H N
N H
(A) (B)
N+ Cl
–
N H H
Cl H H
N N Cl
(C) (D)
N H N H
Ans. (B)
22. Rank the following substance in order of decreasing heat of combustion (maximum minimum) :
1 2 CH3 CH3
3 4
(A) 1 > 2 > 3 > 4 (B) 3 > 4 > 2 > 1 (C) 2 > 4 > 1 > 3 (D) 1 > 3 > 2 > 4
Ans. (C)
– + + –
O K + H2O OH + KOH
pKa = 15.7
t-butoxide pKa = 18
Plot No. 38, Near Union Bank of India, Rajeev Gandhi Nagar, Page # 7
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ETOOSINDIA F.T.R. BY N.J. SIR
INDIA’S NO. 1 ONLINE COACHING
Ans. (A)
24. For the following two acid base reactions, which statement is true ?
– –
(I) CH3CH2 + CH3NH2 CH3CH3 + CH3NH
pKa = 35 pKa = 50
– –
(II) F + H2O HF + HO
pKa = 15.7 pKa = 3.2
(A) It is favoured to the right, II is favoured to the left
(B) It is favoured to the lest, II is favoured to the right
(C) It is favoured to the right, II is favoured to the right
(D) It is favoured to the lest, II is favoured to the left
Ans. (A)
COOH HO
(Q)
25.
HO COOH HO COOH
(P) (R)
– O O
O
–
(p) (q) (r)
CH3
C C C
N N N–
(A) p > q > r (B) q > p > r (C) q > r > p (D) p > r > q
Ans. (D)
27. The heat of hydrogenation of 1-hexene is 126 kJ mol. When a second double bond in introduced in the molecule, the heat of
hydrogenation of the resulting compound is found to be 230 kJ mol–1. The resulting compound (diene) is :
(A) 1,5-hexadiane (B) 1,4-hexadiane
(C) 1,3-hexadiane (D) Cannot predict from the given information
Ans. (C)
Plot No. 38, Near Union Bank of India, Rajeev Gandhi Nagar, Page # 8
Kota, Rajasthan – 324005 Mob. : 9214233303
ETOOSINDIA F.T.R. BY N.J. SIR
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(A) x > y > z (B) y > x > z (C) z > y > x (D) z > x > y
Ans. (D)
H
(X)
N NH (Y)
30.
(Z)
O N O
H
The correct basicity order of atoms X, Y and Z is :
(A) X > Y > Z (B) Z > Y > X (C) Z > X > Y (D) Y > X > Z
Ans. (D)
Na
HOOC C CH=CH2 (x eq.)
Ans. (C)
(D) At low temperature –OH group and at high temperature toward –CO2H group
Ans. (C)
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ETOOSINDIA F.T.R. BY N.J. SIR
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– – + +
(C) CH2 CH CH O (D) CH2 CH CH O
Ans. (A)
(A) I > II > III (B) I > III > II (C) III > II > I (D) II > III > I
Ans (A)
NaHCO3
SO3H
14
(A) CO2 (B) SO2 (C) CO2 (D) SO3
Ans. (A)
OH OH CH3 OH
NO2
(A) (B) (C) (D)
NO2
Ans. (B)
OH COOH OH COOH
(A) I > IV > III > II (B) I > IV > II > III (C) IV > II > I > III (D) IV > I > II > III
Ans. (C)
Plot No. 38, Near Union Bank of India, Rajeev Gandhi Nagar, Page # 10
Kota, Rajasthan – 324005 Mob. : 9214233303
ETOOSINDIA F.T.R. BY N.J. SIR
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Ans. (B)
39. Among the following compounds, the most acidic is :
(A) p-nitrophenol (B) p-hydroxybenzoic acid
(C) o-hydroxybenzoic acid (D) p-toluic acid
Ans. (C)
40. Decide decreasing order of bond length of C–Cl bond x,y and z in the following structure :
Cl
y
Cl
z
Cl x
(A) x > y > z (B) y > z > x (C) z > x > y (D) y > x > z
Ans. (D)
41. Imidaole has pKa = 7 with respect to its conjugate acid. Which N is protonated in this conjugate acid and why ?
3
N
Imidazole
1
N
H
(A) N1 becuase imidazole is an aromatic heterocycle where n = 1 as per Huckel’s rule.
(B) N1 is protonated because it is sp3 hybridised
(C) N3 is protonated because it is sp2 hybridised and has localised lone pair
(D) N1 is protonated because the lone pair is part of the aromatic pi system
Ans. (C)
42. In each of the following pairs of ions, which ion is more stable ?
+ + + +
(a) C6H5–CH2 and CH 2=CH–CH2 (b) CH3–CH2 and CH 2=CH
(I) (II) (I) (II)
+ +
CH2 CH2 CH3–CH–CH3 CH 3–N–CH3
(c) and (d) and
CH3–C–CH3 CH 3–C–CH3
+ +
(I) (II) (II)
(I)
(A) a–I , b–I , c–II , d–II (B) a–II , b–II , c–II , d–II
(C) a–I , b–I , c–I , d–I (D) a–II , b–II , c–I , d–I
Ans. (A)
Plot No. 38, Near Union Bank of India, Rajeev Gandhi Nagar, Page # 11
Kota, Rajasthan – 324005 Mob. : 9214233303
ETOOSINDIA F.T.R. BY N.J. SIR
INDIA’S NO. 1 ONLINE COACHING
43. Which of the following two carbonium ions is more stable ? Explain why.
:
NH2
(a) + + (b) + +
Ans. (C)
45. Which of the following compounds are aromatic compounds ?
H H
N N O S
(I) (II) (III) (IV)
N
H
O S N
N
(V) (VI) (VII) (VIII)
N N
N H
H H O OH
N N N
(IX) (X) (XI) (XII)
N N
O OH
(A) I , II , III , IV , V , VI , VIII , X , XII (B) I , II , III , VI , VIII , X , XI , XII
Ans. (C)
46. A compound shows a large dipole moment. Which of the following resonance structures can be
Ans. (B)
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Kota, Rajasthan – 324005 Mob. : 9214233303
ETOOSINDIA F.T.R. BY N.J. SIR
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Ans. (D)
(i)
HO O
(ii) (iii)
HO OH
(A) ii > i > iii (B) ii > iii > i (C) i > iii > ii (D) iii > i > ii
Ans. (A)
+ +
NMe3 PMe3 CH3
H H H
(A) i > ii > iii (B) ii > iii > i (C) ii > i > iii (D) iii > i > ii
Ans. (C)
H H H
(A) iii > ii > i (B) ii > iii > i (C) i > iii > ii (D) iii > i > ii
Ans. (A)
Plot No. 38, Near Union Bank of India, Rajeev Gandhi Nagar, Page # 13
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ETOOSINDIA F.T.R. BY N.J. SIR
INDIA’S NO. 1 ONLINE COACHING
+ + +
C CH CH
OO O O O O
(i) (ii) (iii)
(A) i > ii > iii (B) ii > iii > i (C) i > iii > ii (D) iii > i > ii
Ans. (B)
O
(3)
(1)
C–N(C2H5)2
HN
(2)
N
CH3
Ans. (B)
(5)
H2N (4)
NH
:
(1) N (3)
:N
:
H2N N (2)
CH3
(A) 1 > 5 > 3 > 4 > 2 (B) 4 > 1 > 5 > 3 > 2 (C) 5 > 4 > 1 > 2 > 3 (D) 4 > 5 > 3 > 1 > 2
Ans. (B)
54. Which of the following acid gives evolution of CO2 with NaHCO3 ?
OH HO O
NO2 COOH
(I) HCl (II) (III) (IV)
COOH
HO O
NO2
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ETOOSINDIA F.T.R. BY N.J. SIR
INDIA’S NO. 1 ONLINE COACHING
COOH
(V)
COOH
Ans. (C)
Ans. (D)
56. Which of the following is most basic ?
N N
N N N
N N
(A) (B) (C) (D)
N
Ans. (C)
57. Which of the following is the most stabilised carbocation ?
Ans. (D)
–
– –
O O+ O + O
– +
(A) (B) (C) (D)
Ans. (B)
Plot No. 38, Near Union Bank of India, Rajeev Gandhi Nagar, Page # 15
Kota, Rajasthan – 324005 Mob. : 9214233303
ETOOSINDIA F.T.R. BY N.J. SIR
INDIA’S NO. 1 ONLINE COACHING
59. Which is the least likely protonation site in the conjugated alkene shown below ?
(c)
(d) (a)
(b)
Ans. (C)
60. Choose those that are resonance structures of protonated methyl vinyl ketone :
+ H
H :O
C C
H C CH3
H
Protonated methyl
vinyl ketone
H H H
:
:
:
H :O H :O H :O
+C C
(1) C C (2) (3) C + CH
H C + CH3 H C CH3 H C CH3
H H H
Ans. (D)
61. Which one of the following is the most basic compound :
(A) C6H5 – NH2 (B) C6H5 – NHCH3 (C) C6H5–N(CH3)2 (D) C6H5N(C2H5)2
Ans. (D)
62. Which of the following resonating structure is not possible for 2, 4, 6-trinitroiodo benzene
I I I
I
O2N NO2 + O O2N NO2 O2N NO2
O2N N
O
N N N
NO2
O O O O O O
(I) (II) (III) (IV)
Plot No. 38, Near Union Bank of India, Rajeev Gandhi Nagar, Page # 16
Kota, Rajasthan – 324005 Mob. : 9214233303
ETOOSINDIA F.T.R. BY N.J. SIR
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OH O
CH3 –C–COOH
COOH III
O OH II
I
Which of the above compounds reacts with NaHCO3 giving CO2
(A) I, II and III (B) I and III (C) II and III (D) I and II
Ans. (A)
Ans. (B)
2
H O
3 1
H N H
(A) 1 > 2 > 3 (B) 3 > 2 > 1 (C) 2 > 1 > 3 (D) 2 > 3 > 1
Ans. (C)
NH2
NH2 NMe2
N
N H N N
N H N
H
(II) (III)
(I)
(A) III > II > I (B) II > I > III (C) I > II > III (D) III > I > II
Ans. (A)
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Kota, Rajasthan – 324005 Mob. : 9214233303
ETOOSINDIA F.T.R. BY N.J. SIR
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O CH3 b CH3
N
H 2N C CH2 CH2 NH C CH3
c
NH
a
CH3 N
d
CH3
(A) b > d > a > c (B) a > b > d > c (C) a > b > c > d (D) a > c > b > d
Ans. (B)
68. Which of the following is the correct order of acidic strength.
COOH OH OH
NO2
(A) > > H2CO3 >
NO2
COOH OH OH
NO2
(B) > > > H2CO3
NO2
COOH OH OH
NO2
(C) > H2CO3 > >
NO2
(D) None
Ans. (A)
1 1 1
2 2 2
69. 3 3 3
4 4 4
These are three canonical structures of naphthalene. Examine them and find correct statement among the following:
(A) All C–C bonds are of same length (B) C1–C2 bond is shorter than C2–C3 bond
(C) C1–C2 bond is longer than C2–C3 bond (D) None
Ans. (B)
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ETOOSINDIA F.T.R. BY N.J. SIR
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70.
A B C D E
O +
O O O
+
N N
(I) (II)
NO2
5
1 3
NO2 NO2
Br
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Kota, Rajasthan – 324005 Mob. : 9214233303
ETOOSINDIA F.T.R. BY N.J. SIR
INDIA’S NO. 1 ONLINE COACHING
74. Examine the following two structures for pyrrole and choose the correct statement given below
+
N N
H H
(I) (II)
(A) II is not an acceptable resonating structure because carbonium ions is less able than nitride ion.
(B) II is not an acceptable resonating structure because there is charge separation.
(C) II is not an acceptable resonating structure because nitrogen has ten valance electrons
(D) II is an acceptable resonating structure
Ans. (C)
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ETOOSINDIA F.T.R. BY N.J. SIR
INDIA’S NO. 1 ONLINE COACHING
+
(A) (B) – +
(C) (D)
Ans. (B,C,D)
+ + + –
(A) H2N C NH2 (Urea) (B) CH2 CH C CH (Vinyl acetylene)
O
–
–
O + –
(C) CH3—N (Nitro methane) (D) CH2 CH Cl (Vinyl chloride)
–
O
Ans. (A,B)
(A) PhN2+ is more stable w.r.t. RN2+ because in PhN2+ +ve charge undergoes delocalisation in ring
– –
CH2 CH2
F Cl
(C) In PhSO3H, m position is relatively highly e– dense w.r.t. o/p position
(D) The e– movement with following compound HO–CH=CH–CO2H is towards –CO2H group
Ans. (A,B)
–
O O
4. Dianion of squaric acid
O O–
(A) 4-identical resonating structure (B) C–C bond lengths are identical
(C) C–O bond length = C–C bond length (D) Antiaromatic in nature
Ans. (A,B)
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ETOOSINDIA F.T.R. BY N.J. SIR
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5. Circle represent most acidic hydrogens in these molecules. Which of the following is correct representation
OH O
O
MeO2C
OH SH
(A) (B) (C) (D) None of these
HO
CF3 CO2H F
Ans. (A,B,C)
6. In the following acid base reaction, in which can forward reaction if favoured ?
–
(A) EtO + OH (B) KH + EtOH
O–
(C) – (D)
Me3CO + H2O + CH3OH
Ans. (A,B,C)
Me NO2 + NMe3
Ans. (A,B,D)
SO3Na
9. Which will give HaOOC–CH2 C ONa as a product ? (Assume that ions were not present in
ONa
reactant)
Ans. (A,B,D)
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ETOOSINDIA F.T.R. BY N.J. SIR
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N N
N N
(I) H (II) (III) H
(A) Basic strength order I > II > III
(C) III compound having all inductive, mesomeric & hyperconjugation effects
Ans. (A,B,C,D)
11. Which of the following option(s) has correct direction of dipole moment ?
Ans. (B,C,D)
12. Identify the binary mixture(s) that can not be separated into the individual compounds, by differential extraction,
NaOH (aq.)
Compoud-1 + Compoud-2
Binary mixture containing
compound 1 and compound 2
NaHCO3(aq.)
Compoud-2 + Compoud-2
OH OH CH2–OH OH
O2N NO2
(A) , (B) ,
NO2 SO3H
OH CH2–OH OH CH2–OH
NO2
(C) , (D) ,
COOH
Ans. (A,B,C)
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ETOOSINDIA F.T.R. BY N.J. SIR
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CH2
Ans. (B,C,D)
14. Hydrogen bonding is primarily responsible for which of the following observation :
(B) Dimethyl amine is more basic than trimethyl amine in aqueous medium
Ans. (A,B,C)
Ans. (A,B,C)
NH2 NH2
CH3
(A) is more basic than
COOH COOH
CH3
(B) is less acidic than
NMe2 NMe2
CH3
(C) is more basic than
NO2 NO2
CH3
(D) has shorter C–N bond length than
Ans. (A,B,D)
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ETOOSINDIA F.T.R. BY N.J. SIR
INDIA’S NO. 1 ONLINE COACHING
H
O O O–H
p s
u
t
–O q r
O
O
(A) s > p > t (B) u > q > r (C) p = q (D) p > t > r
Ans. (A,B,C,D)
O
18. Compound(s) having higher bond rotation energy barrier across C = C than compound is/are :
O
O
O
(A)
O O (B)
O
O
(C) (D) O
O
Ans. (A,B,C,D)
–
O O
(B) Squaric acid dianion have identical R.S.
O O–
(C) Squaric acid dianion have all C–O bonds identical
Ans. (A,B,C,D)
O + +
(A) O > + (B) >
+
O
+
(C) > (D) >
+
+ N + N
H H
Ans. (B,C)
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ETOOSINDIA F.T.R. BY N.J. SIR
INDIA’S NO. 1 ONLINE COACHING
Ans. (A,B,C)
+
+
(C) Order of stability of carbocation > >
N +
N
H
O
COH
(C) In H2C most acidic H is connected directly to oxygen not on carbon.
COH
O
(D) In urea both C–N bond length are identical
Ans. (A,B,C,D)
(A) (B)
(C) (D) HO OH
Ans. (A,B,C,D)
Plot No. 38, Near Union Bank of India, Rajeev Gandhi Nagar, Page # 26
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ETOOSINDIA F.T.R. BY N.J. SIR
INDIA’S NO. 1 ONLINE COACHING
O O O
O
>
(A) > Ph Ph (B)
Ph Ph
Ans. (A,B,D)
+ – –
O
(A) (B) (C) (D)
B
H
Ans. (A,B,C,D)
27. Identify the feasible reactions
COOH COONa
NH2 NHNa
OH ONa
(D) + +
NO2 NO2
Ans. (A, D)
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28. Select the number of compounds in which deprotonation gives aromatic anion :
O
HO CH2 O O
HN NH
O O
H
(A) (B) HO (C) (D)
O O
N O
Barbituric acid OH OH
Ascorbic acid H
(Vitamin - C)
Ans. (A, B, C, D)
29. Select correct statement :
(A) Carbon-oxygen bonds are equal length in acetate ion
(B) Resonating structures of acetate ion are equivalent
(C) Carbon-oxygen bonds are of unequal length in formate ion
(D) Resonating structures of formate ion are equivalent
Ans. (A, B, D)
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MISCELLANEOUS EXERCISE
Integer Type Questions
O
NaHCO3
1. Ph — C — O — H (A) gas
Na
Ph — C CH (B) gas
NaNH 2
Ph — OH (C) gas
NaH
R — O — H (D) gas
Sum of molecular mass of gas A + B + C + D is :
2. Analyse the following hydrogenation reactions and calculate resonance energy of ‘X’ in kcal/mole :
+ 2H2 H = – 58 kcal/mole
+ 5H2
H = – 94 kcal/mole
'X'
3. How many products will be aromatic ion when AgNO3 reacts with the following compounds ?
O
(a) Cl (b) Cl (c) (d)
Cl Cl
Cl
(e) CH2–Cl (f) CH2–Cl (g) (h) H–CC–Cl
OH OH COOH OH
H3C CH3 H3C
(a) (b) (c) (d)
+
– N CH3
O O
COOH O OH
HO OH HO O
(e) (f) (g) (h) H–CC–Cl
HO O N
O
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COOH OH
HO OH
H3C
(a) (b) (c) (d)
HO O
CH3
–
O O OH
OH
COOH N+ N+ OH
–
HO OH O O
(e) (f) (g) (h)
+ N
– N CN
O O
OH
OH
COOH
O
OH (c) H3C CH3
(a) (b) (d)
OH OH CH3
COOH O OH
HO OH O O
(e) (f) CH4 (g) (h)
OH OH
Cl
7.
X Y
OH OH OH
COOH
(i) (ii) (iii) (iv)
NO2
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O
O
(v) H–CC–H (vi) O (vii) (viii) CH2=CH2
HO
OH
(ix)
OH
OH
(e) (f) (g) (h) (i) NaOH
NO2
O
C
NH
[Provided N is the donor atom in all cases]
S
O O
O
C CH2 NH2
(iv) N H (v) (vi) N
C
O
11. Amongs the following, the total number of compounds soluble in aqueous NaOH is :
H3C CH3
N COOH OCH2CH3 OH
CH2OH
(a) (b) (c) (d)
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NH2 CH3
CH3
CH3
NO 2
NO 2
O
+
(g) —CCl3 (h) —PH3 (i) —OH
H2
Pt
(P)
Heat of hydrogenation
A
H2 C
Pt B
(Q)
H2
Pt
(R)
H2
Pt
(S)
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14. Give increasing order of C-H bond energy of various C-H bonds in following compounds, mentioned by a to g
H g H
a CH3
H–H2C
f H
b H
H d e
H–H2C H
H
c
15. In the given pair of compounds select the one in each pair having lesser resonance energy :
16. In which of the following pairs, indicated bond having less bond dissociation energy :
O
O
(c) CH2 CH CH CH2 and CH2 (d) and C
CH CH CH2 C
C CH3 NH2
C H2N NH2
CH2 CH2
O O O O
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(d)
(d) (e)
CH3 CH3
(iii) (a) (b)
CH3 CH3
O O
(iv) (a) (b)
CH3 CH3
(vi) (b) CH2 CH CH (b) CH2 C
CH3 CH2 CH3
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21. Statement - 1 : For the given two compounds - I is more acidic than compound - II.
NO2 CN
H3C CH3 H3C CH3
OH OH
(I) (II)
and
Statement - 2 : Due to presence of –CH3 group at ortho positions to –NO2 ; the plane of –NO2 deviates, w.r.t. plane of
ring.
(A) Statement - 1 is True, Statement - 2 is True ; Statement -2 is correct explanation for Statement -1.
(B) Statement - 1 is True, Statement - 2 is True ; Statement -2 is NOT a correct explanation for Statement -1.
(C) Statement - 1 is True, Statement - 2 is False.
(D) Statement - 1 is False, Statement - 2 is True.
and
Statement - 2 : Lone pair electrons on nitrogen in compound (I) does not participate in resonance.
(A) Statement - 1 is True, Statement - 2 is True ; Statement -2 is correct explanation for Statement -1.
(B) Statement - 1 is True, Statement - 2 is True ; Statement -2 is NOT a correct explanation for Statement -1.
(C) Statement - 1 is True, Statement - 2 is False.
(D) Statement - 1 is False, Statement - 2 is True.
Paragraph -1
CH3
(g)
(d) H
H–HN
H–CH2 (c)
(a) (e)
H H (b)
C C–H
OH
(f)
(A) a > b > c d > e (B) b > e > c > a > d (C) e > b > a > c > d (D) d > c > a > b > e
(A) e > f > g > b (B) f > e > g > b (C) b > g > e > f (D) b > g > f > e
25. What is the D.B.E. (Double bond equivalent) for the given compound :
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Paragraph -2
Aqueous Layer
Aqueous (Salt - B)
OH Organic Layer NaOH
COOH Aqueous
Organic Layer
NaHCO3
(Compound - C)
Aqueous Layer
(Salt - A)
Mixture of
3-compounds
in hexane
OH COOH OH
COOH
(Order) (Properties)
H H CHO
(D) > (S) Bond rotational energy barrier across (C=C)
H H
(T) Bond length of (C=C) bond
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Column-I Column-II
(Compounds) (Property)
Column-I Column-II
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Column-I Column-II
N
(A) (P) Aromatic
N
H
(T) Non-aromatic
Column-I Column-II
COOH
CH3
(A) (P) React with Na
OH
O2N NO2
(B) (Q) React with NaOH
NO2
OH
HO O
HO O
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(B) and (Q) (I) compound has more resonance energy that
(II) compound
than (I)
than (I)
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OH
OH
OH
OH
NO2
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