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Composite Structures: Dora Foti
Composite Structures: Dora Foti
Composite Structures
journal homepage: www.elsevier.com/locate/compstruct
Use of recycled waste pet bottles fibers for the reinforcement of concrete
Dora Foti ⇑
Polytechnic of Bari, Department ICAR, Via Orabona, 4 – 70125 Bari, Italy
a r t i c l e i n f o a b s t r a c t
Article history: In the present paper the results of some tests performed on concrete specimens reinforced with fibers
Available online 9 October 2012 made from waste polyethylene terephthalate (PET) bottles are reported. The fibers have been obtained
by simply cutting the bottles; the fibers are then added to the mix concrete or they are used as discrete
Keywords: reinforcement of specimens and little beams in substitution of steel bars. The tests are to be considered as
Waste PET bottles an approach to a more extensive investigation on the use of PET as a reinforcing material for concrete and
Fiber-reinforcement masonry structures. The results that have been obtained are very interesting, especially regarding the
Concrete ductility and durability
adherence between PET and concrete, suggesting a possible use of this material in the form of flat or
round bars, or networks for structural reinforcement.
Ó 2012 Elsevier Ltd. All rights reserved.
0263-8223/$ - see front matter Ó 2012 Elsevier Ltd. All rights reserved.
http://dx.doi.org/10.1016/j.compstruct.2012.09.019
D. Foti / Composite Structures 96 (2013) 396–404 397
Table 1
Uses of virgin and recycled PET.
Name of plastic Description Some uses of virgin plastic Some uses for plastic made from recycled waste plastic
Polyethilene Clear tough plastic, may be Soft drink and mineral water bottles, Soft drink bottles, detergent bottles, clear film for packing, carpet
terephthalate (PET) used as a fiber textile fibers fibers, fleecy jackets
shrinkage cracks, which could trigger the most visible cracking with the important result to avoid corrosion problems and reduce
phenomena. the deterioration of concrete structures.
For the reasons outlined above, fibers in the concrete mix do not The novelty of this research respect to similar studies on con-
increase the compressive and tensile strength significantly; how- crete that utilizes PET fibers is, principally, that PET has been uti-
ever, they are still useful to limit the cracks, especially those lized in two different ways, not found in previous authors:
caused by shrinkage, and also to give the concrete more ductility. circular fibers added in the concrete mix and long strips for the
The fibers exert an action of sewing the surfaces where the cracks reinforcement of structural elements or specimens in substitution
occur. In other words, they prevent the brittle and sudden fracture of steel reinforcement. In previous studies waste PET has never
of a material that, depending on the type and quantities of fibers been utilized in these shapes, but only as short strips or filaments
used, may show a further post-peak deformation. in the concrete mix. In addition, in this research PET has never been
This effect is also present in concrete added with PET fibers. The subjected to complicate chemical and manufacturing processes,
use of PET fibers falls in the attempt to suitably and profitably re- but fibers and strips have been obtained by simply cutting the
cycle a waste material, produced now in large quantities, obtaining waste PET bottles.
the fibers directly from the bottles, by means of simply cuts, with-
out subjecting them to any special and costly chemical process
[6,7]. 2. Experimental program and results
Studies have been developed to get the mechanical characteris-
tics of concrete reinforced with PET fibers [2]. The density, work- Studies on the use of PET fibers for the reinforcement of con-
ability, compressive and tensile strengths and the modulus of crete have been developing at the Department of Civil and Environ-
elasticity of the mixture added with PET fibers have been investi- mental Engineering of the Polytechnic of Bari since the mid-
gated [8–10]. Impact resistance has been investigated as an influ- nineties. Both short strips of fibers and circular fibers have shown
ence on concrete of polypropylene fibers [11] and recycled a good sewing effect in the post-cracking phase of concrete.
plastics [3] showing an improvement of the impact resistance of In the present paper the results of further studies on the use of
concrete. PET as a reinforcing material of concrete are reported. In particular,
Another interesting aspect is the thermal conductivity of con- bending tests have been performed to obtain the ultimate tensile
crete reinforced with PET fibers. It has been noticed that there is stress of specimens in concrete reinforced with PET fibers. The load
an increment in the thermal insulation of the concrete both adding has been applied in the middle of the specimen according to the
pieces of waste rubber of tires and plastic fibers [12] or simply add- static scheme of Fig. 1. The specimens have been subjected to
ing plastic fibers alone [13]. In [13] PET filaments have been ex- bending tests by an Instrom L.T.D. equipment, under the same con-
truded by an industrial process; the concrete added with these ditions described in Foti [7].
fibers has shown a better behavior both for its mechanical strength Previously to the tests on the specimens, a series of tensile tests
and ductility. on fibers of PET have been performed following the modalities
Anyway, in all the studies cited above, PET has been utilized in shown in Fig. 2a. In Fig. 2b the force–displacement plot referred
the concrete mix in the shape of short strips. Sometimes the fibers to one specific test is reported.
have been obtained after a long and expensive extruding process The tensile tests on PET fibers furnished an average value of the
from the waste bottles [14], or the surfaces of the fibers have been tensile strength equal to 160 N/mm2 high enough and comparable
coated with maleic anhydride grafted polypropylene and then with the other fibers on the market for fiber-reinforced concrete
chopped into the desired fiber length [15]. (FRC) (Table 2).
Foti [7] has observed a better behavior of the circular shaped The testing program consisted of three parts:
PET fibers; they are obtained without any manufacturing, but with
simple transversal cuts of the bottles deprived of the top and bot- (1) Tests on concrete specimens reinforced with circular fibers
tom parts. The circular fibers perform better than the lamellar ones of PET (1% by weight of concrete), and added with super-
because they guarantee a higher concrete-fiber adherence also for plasticizers.
high stresses. The lamellar fibers, on the contrary, for high stresses
tend to slip off.
In this paper the results of a research on the use of PET as a rein-
forcing material of concrete is reported. It is part of a wider re-
search in the field of fiber-reinforced concrete obtained with the
use of PET fibers. Differently from previous studies of other
researchers, the specimens are made with a concrete mix added
with circular fibers the last obtained cutting waste bottles orthog-
onally to their longitudinal axis. The fibers have a width of about
5 mm and are added in higher quantity (1% by weight of concrete)
respect to previous tests. Another series of tests has been per-
formed on little concrete beams reinforced with long PET strips
positioned similarly to reinforcement bars in concrete beams. Re-
sults show a high adherence level between PET fibers and concrete
with the further aim to utilize round or flat PET bars (or networks
in case of plates and slabs) in substitution of steel reinforcement Fig. 1. Static scheme of the tests.
398 D. Foti / Composite Structures 96 (2013) 396–404
Fig. 2. (a) Test set-up for the characterization of the fibers; and (b) force–elongation plot of the tensile test on one fiber.
Table 2
Mechanical characteristics of different fibers for FRC.
Fiber type Equivalent diameter (lm) Specific weight (103 kg/m3) Elastic modulus (N/mm2) Tensile strength (N/mm2) Ultimate elongation (%)
Steel 5–500 7.84 200,000 500–2000 0.5–3.5
Glass 9–15 2.60 70,000–80,000 2000–4000 2–3.5
Polypropylene 20–200 0.90 5000–7000 500–750 8
Nylon – 1.10 4000 900 13–15
Carbon 9 1.90 230,000 2600 1
Acrylic 18 1.18 14,000–19,500 400–1000 3
(2) Tests on concrete specimens that have the same size of 1) The tests firstly confirmed the results already obtained showing
and have been reinforced with strips of PET obtained with the ‘‘sewing’’ effect and a larger post-peak behavior before collapse
two overlapping layers of half bottles. (see Figs. 4 and 5); secondly, the tests have shown that dosages of
(3) Tests on larger concrete specimens reinforced with four fibers greater than 1% by weight of the concrete are hardly practi-
overlapping layers of PET obtained cutting longitudinally cal, even with the use of superplasticizers, because the material be-
waste bottles in four parts. comes no longer easily workable.
Fig. 5 shows the results of the tests previously performed on
The samples were carefully prepared and stored for aging in PET 0.50% and PET 0.75% together with the results obtained in
accordance with UNI EN 12390:2009. the present study on a mixture with PET 1%. The concrete mixtures
utilized are different: for PET 0.5% and 0.75% Composite Portland
2.1. Test (1): Specimens in concrete with the addition of circular fibers concrete of Type II/A-LL (SN EN 197-1:2000) was utilized, while
for PET 1% an industrial ready-made mix concrete was utilized.
Tests on the samples in concrete reinforced with circular PET fi- Therefore the comparisons obtained in Fig. 5 are interesting
bers (Fig. 3) were performed both to control their effectiveness regarding only the recovery of the load as it is not possible to com-
(comparing the results to the tests performed in Foti [7]) and to pare the peak values because the concrete mixtures are different.
determine the influence of their dosage on the increment of con- It is possible to notice that the recovery of the load, in percent-
crete ductility. age respect to the peak, is faster for the mix with 1% of PET. The
D. Foti / Composite Structures 96 (2013) 396–404 399
Fig. 4. Loading test on specimens with annular fibers and detail of the crack.
drop of the load is about 70% respect to the cracking load for PET principally absorbs the stresses produced by the applied load.
0.50%, 55% for PET 0.75% and about 35% for PET 1%. The results con- When the specimen cracks for bending in the most stressed sec-
firm, as expected, that in case of PET 1%, the fibers are present in tion, the load is then transferred to the fibers that are able to
quantities larger than in the other tested specimens and take up sew the fracture and to deform in the plastic range. lD is therefore
more easily the load transfered by the cracked concrete. an index of the ductile behavior of concrete reinforced with PET
A measure of the ductility of the different types of concrete is fibers.
evaluated through the following coefficient: Fig. 6 shows the values of lD for the different weight percent-
ages of fibers. The value of lD varies from a minimum of 11.73
Du
lD ¼ for PET 1% to a maximum of 37.88 for PET 0.75%. It means that a
Dy
high percentage of fibers improves the concrete behavior but it
where Du is the maximum deformation at the centerline; Dy is the cannot be highly incremented because the circular fibers loose
deflection at the peak load. their adherence with the concrete as it becomes less workable,
The last corresponds to the maximum deflection of the concrete even adding superplasticizers (that is the case of the tested speci-
specimen because, before cracking, concrete is the material that mens with 1% of PET).
400 D. Foti / Composite Structures 96 (2013) 396–404
Fig. 7 shows the peak values of the applied load, Pmax. However,
it must be noticed that specimens with 1% by weight of PET fibers
have been prepared with a different concrete mix.
Table 3 shows the characteristics of the concrete mixtures uti-
lized to make the specimens with different PET percentages.
Table 3
Components of the concrete mixtures.
Fig. 5. Load–deformation plot on specimens with circular fibers (1%, 0.75% and Fibers (wt.%) Concrete Portland Superplasticizers Water
0.5%). + Aggregate (kg) (wt.%) (l)
PET 0.5% and PET 0.75% 24 – 2.8
PET 1% and half bottle 25 0.8 2.7
PET strips
PET for little beams 43 1.4 3.0
specimens
Fig. 6. Values of lD for the three different fiber contents. Laminated fibrous
reinforcement.
Fig. 7. Peak load at cracking for three different fiber contents. Positioning of the
fibrous reinforcement. Fig. 9. Positioning of the half bottle reinforcement.
D. Foti / Composite Structures 96 (2013) 396–404 401
This is a type of reinforcement that does not fall within the has been cut longitudinally into two equal parts to obtain strips
parameters prescribed by CNR-DT 204/2006 for fiber-reinforced having a ‘‘C’’ section, with a base equal to about 8 cm and two side
concrete, as it is a continuous reinforcement, not arranged in a uni- elevations of about 4 cm. These strips were assembled using the
form manner within the cement matrix, but concentrated in the variation in section of the bottles and subsequently, after an appro-
position where high levels of tensile stresses are expected, simi- priate overlap, fixed together with staples. The reinforcement con-
larly to the case of concrete reinforced with steel bars. sisted of four of the abovementioned elements and therefore, at the
As regards the practical realization, the reinforcement has been bottom and the middle of the specimens to be tested, there were
obtained from waste PET bottles of water, with a capacity equal to four layers of PET, each of a thickness of 0.2 mm, while in the side
1.5 l, having a square section with rounded corners and marked sections there are only two layers (Figs. 8 and 9).
surface undulations due to grooves useful for improving the grip Two specimens have been made as described in the following:
of the bottles themselves by the user. The bottles have been de- first it was realized a thin layer of concrete on which the reinforc-
prived of the bottom and the upper parts, while the central part ing elements were lying and, subsequently, the empty side was
filled with concrete up to the complete saturation of the formwork.
The main purpose of the tests described hereinafter is to assess
the adhesion between PET and concrete and the attitude of the
strips of PET to behave similarly to concentrate reinforcement.
Therefore a standard test was performed on the specimens up to
a maximum deflection of 20 mm (Fig. 10).
The crack pattern shown at the end of the tests is extremely
interesting. In fact, unlike the specimens reinforced with circular
fibers, which detects a single vertical cracking concentrated in
the middle and sewn by the fibers, in the specimens reinforced
with PET half bottles, after the appearance of a first vertical crack
in the middle, inclined shear cracks appeared and subsequently
the detachment of the bottom area occurred while continuing to
exist a good adhesion between concrete and PET strips (Fig. 11a–c).
The load–deflection plots, in addition to the peak in correspon-
dence of the crack, then showed a fairly hardening trend with a
subsequent recovery of the load and increase of the deformation.
The tests have shown, therefore, the possibility of using strips of
PET as concentrate reinforcement for structures, or secondary
structural elements. PET fibers, in fact, not only confer a certain
Fig. 10. Load–deflection plot for specimen no. 2.
tensile strength to the concrete as a consequence of the good Fig. 14 shows the energy dissipated during the bending test for
adherence between the two materials, but also they increase sig- each specimen. It is possible to notice the large amount of energy
nificantly the ductile behavior of structures. dissipated if compared to the beam without fibers.
The highest value of energy dissipation is obtained for speci-
2.3. Test (3): Beam-specimens with a bigger dimension and reinforced mens 3 and 4. This result was quite expected as the latter show
with PET strips a more ductile behavior with displacements higher than 12 mm.
Fig. 15 shows the amount of energy dissipated at a displace-
From the results obtained from Test 1 and Test 2 it was decided ment of 6 mm in the centerline of each specimen.
to test the behavior of larger elements; to this aim four little beam This plot indicates the specimen with the fastest recovery of
specimens of dimensions 100 200 1100 mm were prepared, load from concrete to the PET fibers. It could be attributed to beam
reinforced with four long overlapping layers of PET strips cut from 3, even if the energy dissipated is more or less the same: it is al-
waste bottles. In particular the strips were disposed in the middle most 30–35% higher if compared to the total energy dissipated
along one longitudinal side of each specimen. Each strip had a by the not-reinforced specimen.
dimension of approximately 45 0.2 300 mm, and they were Fig. 16 shows the crack pattern of a beam reinforced with PET
suitably overlapped and connected together with staples. Fig. 12 strips.
shows a photo of the strips utilized as a reinforcement of the beam
specimens.
The little beams, after curing, were subjected to bending tests
with a concentrated load applied at the centerline.
Fig. 13 shows the load–deflection plots for a non-reinforced
beam and for those reinforced with strips of PET. The comparison
shows a ductile behavior of the beams reinforced with PET.
The ductile behavior in the post-cracking phase is evidenced by
the diagrams of Fig. 13: the low value of recovery of resistance
after cracking is due to the limited amount of resistant area of
PET fibers, equal to about 36 mm2.
Fig. 13. Load–deflection plot for little beams reinforced with PET sheets. Fig. 15. Energy dissipated up to a displacement of 0.6 mm.
D. Foti / Composite Structures 96 (2013) 396–404 403
Table 4
Mechanical characteristics of the concrete utilized in the tests without PET fibers.
create networks, flat or round bars good to replace, in special cases, [2] Siddique R, Khatib J, Kaur I. Use of recycled plastic in concrete: a review. Waste
Manage 2008;28:1835–52.
the current metallic reinforcement. The advantages of PET fibers
[3] Soroushian P, Plasencia J, Ravanbakhsh S. Assessment of reinforcing effects of
compared to the use of welded wire mesh made of steel or adding recycled plastic and paper in concrete. ACI Mater J 2003;100(3):203–7.
glass or carbon fibers are evident especially from economic and [4] Allievi E, Pola M. Calcestruzzi per pavimenti industriali: i calcestruzzi
ecological points of view. Compared to steel, moreover, the advan- fibrorinforzati con fibre in filo d’acciaio. In Concreto 66; 2005 [in Italian].
[5] Galbiati A, Grandini L, Macchia C. I calcestruzzi fibrorinforzati. Produzione e
tages are also related to the increase of structural durability that Applicazione. In: Maggioli Editore; 1996 [in Italian].
can be achieved. [6] Donatone G, Foti D, Paparella F. Soluzioni innovative nel campo dei
Summarizing, the use of PET fibers and strips as proposed in the calcestruzzi fibrorinforzati: analisi preliminare su un calcestruzzo rinforzato
con fibre di PET. In Concreto 95. lug/ago; 2010. p. 36–44 [in Italian].
present paper shows the following important advantages: [7] Foti D. Preliminary analysis of concrete reinforced with waste bottles PET
fibers. Constr Build Mater 2011;25:1906–15.
– Reduction of the plastic waste. [8] Choi Y-W, Moon D-J, Chung J-S, Cho S-K. Effects of waste PET bottles aggregate
on the properties of concrete. Cem Concr Res 2005;35(4):776–81.
– Reduction of the production costs. [9] Marzouk OY, Dheilly RM, Queneudec M. Valorization of post-consumer waste
– Reduction of structural degradation due to steel corrosion. plastic in cementitious concrete composites. Waste Manage 2007;27:310–8.
[10] Pereora de Oliveira LP, Castro-Gomez JP. Physical and Mechanical Behaviour of
recycled PER fibre reinforced mortar. Constr Build Mater 2011;25:1712–7.
In addition, possible predictive models that could fit the results [11] Bayasi Z, Zeng J. Properties of polypropylene fiber reinforced concrete. ACI
obtained so far and future experimental results could be studied, Mater J 1997;90(6):605–10.
such as energetic approaches to crack-bridging effects [16–18]. [12] Yesilata B, Isiker Y, Turgut P. Thermal insulation enhancement in concretes by
adding waste PET and rubber pieces. Constr Build Mater 2009;23:1878–82.
The models would give the possibility of a better interpretation
[13] Fraternali F, Ciancia V, Chechile R, Rizzano G, Feo L, Incarnato L. Experimental
of the mechanical behavior of concrete reinforced with PET. study of the thermo-mechanical properties of recycled PET fiber-reinforced
concrete. Compos Struct 2011;93:2368–74.
Acknowledgments [14] Ochi T, Okubo S, Fukui K. Development of recycled PET fiber and its application
as concrete-reinforcing fiber. Cem Concr Compos 2007;29:448–55.
[15] Kim SB, Yi NH, Kim HY, Kim JHJ, Song Y-C. Material and structural performance
The author gratefully acknowledge Francesco Paparella for the evaluation of recycled PET fiber reinforced concrete. Cem Concr Compos
help in performing the tests, ‘‘Calcestruzzi San Giorgio’’, and espe- 2010;32:232–40.
[16] Bourdin B, Francfort GA, Mario JJ. Numerical experiments in revisited brittle
cially Mr. Lombardozzi, for the collaboration to make the speci- fracture. J Mech Phys Solids 2000;46(8):797–826.
mens and Mapei Italia Group for furnishing the ready-made mix [17] Bourdin B. Numerical implementation of the variational formulation of brittle
concrete. fracture. Interfaces Free Bound 2007;9:411–30.
[18] Fraternali F, Negri M, Ortiz M. On the convergence of 3D free discontinuity
models in variational fracture. Int J Fracture 2010;166(1–2):3–11.
References
[1] Batayneh M, Marie I, Asi I. Use of selected waste materials in concrete mixes.
Waste Manage 2007;27(12):1870–6.