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    LGC Certificate

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    LGC Certificate

    Copyright:

    © All Rights Reserved
    Download as PDF or read online from Scribd
    Flag for inappropriate content
    Download as pdf
    23 views10 pages

    TAN LGC Hydrocarbon Oil

    Uploaded by

    Purwito Sigit
    LGC Certificate

    Copyright:

    © All Rights Reserved
    Download as PDF or read online from Scribd
    Flag for inappropriate content
    Download as pdf
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    Vig CERTIFICATE OF ANALYSIS Petrochemical Test CRM Acid Number (AN) - 1.5 mg KOH/g Matrix: Hydrocarbon Oil Product #: VHG-AN-.5-1006 Loti: 9290814 peated Certified Value & Uncertainty ASTM DEE 163 0:12mg KOHG ASTM D974 1.56 + 0.12 mg KOH/g Intended Use: This solution i intended for use as acetid reference mater in the determination of Acid Number (AN of petrceum products in ‘2ccordance wih ASTM Method D864 (ptentcmetic talon, andor ASTM Method DS74(colorndcatr tration). As dened in those methods, ‘2c number is equal othe quantiy of base, expressed in moras of potassium hydroxide per gram of sample thats required to trate a sample <2 specied endpoint Certification & Traceabilty: VHG CRMs are manufactured and certied under a quality management system that is accredited o ISO 8001, 180 Guide 34 and ISOEG 17025. This CRM was prepared tothe nominal value of 15 mg KOHI9 using gravimetric methods. The balances sed in the preparation of VHG CRMs are caltrated regulary with traceability to NIST. The oartiied values were determined by VHG Labs in ‘coordance wih ASTM Method D6S4 and ASTM Method D974, The ant used to assay the cafied values was standardizes agaist NIST SRM ‘84L (potassium hydrogen palate). The uncertany assocsted wih each ceifid value reoresens the expanded uncertainty atthe $5% confidence level using a coverage face fk Instructions for Use: We recommend thatthe solution be thoroughly mized by repeated shang or swing ofthe bot immediatly prior o use The cetied values were determined folloing exact ASTM methods, so any modification tothe methods may affect your resus. To achieve the highest acuracy the analyst should: (1) falow the exact ASTM methods, (2) use only re-cleaned containers and transfenwar, (3) not ppete rect from the CRMs rigna container, () use the recommended subsample size specified in the ASTM metheds, and (5) never pour used product back ilo the rg container. The soliton shoud be Kent hy capped and store under nomal laboratory condtions. Do no eeze, heat or expose to det sunight. Minimize exposure to meistue or high humid, Period of Validity: VG ensures the accuracy cf this solution for 12 Months from the Certification date shown below, provided the instucton fr Use ae flowed. During he period of vty, the purchaser wil be noted this prac is recaled due to any significant changes inte stabity ofthe saluion. ‘VAG Labs, ine. An ee ss -watages «=S(tssCS YMG Labs ne, was repens for any damages resting fom he sane adr npementatn the rod esc heen, Page 4 of2 276 Abby Road, Manchester, NH 03103 USA (603) 622-7660 Fax: (603) 622-5180 www.vhglabs.com Su Page 1/9 Safety Data Sheet ace. to OSHA HCS Printing date 07/19/2016 Reviewed on 07/19/2016 Product identifier Product name: Acid Number 1.5 mgKOH/g Reference Standard in Hydrocarbon Oil Part number: VHG-AN-1.5-100G Application of the substance / the mixture Reference material for laboratory use only ‘Manufacturer/Supplier: VHG Labs, Inc Tel +1 (603) 622-7660 LGC Standards Fax: +1 (603) 622-5180 276 Abby Road Manchester, NH 03103 eMail : custsve@vhglabs.com UNITED STATES OF AMERICA Web : www.vhglabs.com Information department: Product safety department eMail: sds-request@lgcgroup.com Emergency telephone number: INFOTRAC 24-hour Emergency telephone number: 800-533-5053 (US & Canada); 352-323-3500 (International) Classification of the substance or mixture (GHS08 Heath hazard Repr. 2 H361 Suspected of damaging fertiliy or the unborn child Asp. Tox. 1 H304 May be fatal if swallowed and enters airways. Label elements GHS label elements The product is classified and labeled according to the Globally Harmonized System (GHS). Hazard pictograms GHSO8 Signal word Danger Hazard-determining components of labeling: White mineral oil Hazard statements H361 Suspected of damaging fertility or the unborn child, H304 May be fatal if swallowed and enters airways. + Precautionary statements P280 Wear protective gloves/protective elothing/eye protection/face protection. P301+P310 IF SWALLOWED: Immediately call a POISON CENTER doctor. (Com. on page 2) Page 29 Safety Data Sheet ace. to OSHA HCS Printing date 07/19/2016 Reviewed on 07/19/2016 Product name: Acid Number 1.5 mgKOH/g Reference Standard in Hydrocarbon Oil (Contd. of page 1) ?.308+P313 IF exposed or concerned: Get medical advice/attention P331 Do NOT induce vomiting, P4035 Store locked up P501 Dispose of contents/container in accordance with local/regional/national/international regulations. Classification system: NEPA ratings (scale 0 - 4) Healt Fire Reactivity = 0 HMIS-ratings (scale 0- 4) OMS] Heath = 0 | Fire - 1 REACTIMTY[o] Reactivity = Other hazards Results of PBT and vPvB assessment PBT: Not applicable, vPyB: Not applicable. a] Chemical characterization: Mixtures Description: Also contains substances at levels not considered to be hazardous ‘Dangerous components: CAS: S01-F7-3__| White mineral oi! RTECS: PY8047000) S Asp. Tox. 1, W304 [> 99% De See] Description of first aid measures After inhalation: Supply fresh air: consult doctor in case of complaints. After skin contact: Immediately wash with water and soap and rinse thorough After exe contact: Rinse opened eye for several minutes under running water. After swallowing: Rinse mouth. Do not induce vomiting. Seek immediate medical advice. Information for docti ‘Most important symptoms and effects, both acute and delayed No further relevant information available Indication of any immediate medical attention and special treatment needed ‘No further relevant information available. (Contd. on page 3) Page 39 Safety Data Sheet ace. to OSHA HCS Printing date 07/19/2016 Reviewed on 07/19/2016 Product name: Acid Number 1.5 mgKOH/g Reference Standard in Hydrocarbon Oil (Com. oF page 2) Extinguishing media ‘Suitable extinguishing agents: Use fire fighting measures that suit the environment. Special hazards arising from the substance or mixture Formation of toxic gases is possible during heating or in case of fire. Advice for firefighters Protective equipment: Wear self-contained respiratory protective device. Personal precautions, protective equipment and emergency procedures Wear protective clothing. Environmental precautions: Do not allow to enter sewers surface or ground water. © Methods and material for containment and cleaning up: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust) Dispose contaminated material as waste according to item 13. Ensure adequate ventilation Reference to other sections No dangerous substances are released. See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information. Handling: Precautions for safe handling Ensure good ventilationexhaustion at the workplace. ‘Store in cool, dry place in tightly closed receptacles. Prevent formation of aerosols. Information about protection against explosions and fires: The product is not flammable. Conditions for safe storage, including any incompatibilities Storage: Requirements to be met by storerooms and receptacles: Store in a cool location, Please refer to the manufacturers certificate for specific storage and transport temperature conditions. Store onty in the original receptacle. Keep container in a well-ventilated place. Keep away from sources of ignition and heat. Information about storage in one common storage facility: Siore away from foodstuffs. Further information about storage conditions: None. ‘Specific end use(s) No further relevant information available, (Contd. on page 4) Page 49 Safety Data Sheet ace. to OSHA HCS: Printing date 07/19/2016 Reviewed on 07/19/2016 Product name: Acid Number 1.5 mgKOH/g Reference Standard in Hydrocarbon Oil (Com. of page 3) Additional information about design of technical systems: No further data; see item 7. Comrol parameters Components with limit values that require monitoring at the workplace: The product does not contain any relevant quantities of materials with critical values that have 10 be ‘monitored at the workplace. Additional information: The lists that were valid during the creation were used as basis. Exposure controls Personal protective equipment: General protective and hygienic measures: Keep away from foodstuffs, beverages and fed. Wash hands before breaks and atthe end of work Breathing equipment: {In case of bref exposure or low poltution use respiratory filter device. In case of imensive or longer exposure tse respiratory protective device that is independent of circulating air. Follow the OSHA respirator regulations fourd in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded o if irritation or other symptoms are experienced Protection of hands: The glove material has to be impermeable and resistant to the product’ the substance’ the preparation. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation The protective gloves 10 be used must comply with the specifications of EC Directive 89/686/EEC and the related standard EN374 Protective gloves Material of gloves Natural rubber, NR Penetration time of glove material The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed, Eye protection: Safety glasses Information on basic physical and chemical properties General Information Appearance: Form: oly Color: Colorless Odor: Odorless Odor threshold: Not determined, (Contd on pase) Page 59 Safety Data Sheet ace. to OSHA HCS Printing date 07/19/2016 Reviewed on 07/19/2016 Product name: Acid Number 1.5 mgKOH/g Reference Standard in Hydrocarbon Oi (Com. of paged) ‘pH-value: ‘Not determined. ‘Change in condition Melting point/Metting range: Not determined. Boiling poiny Boiling rang 218°C (424 °F) Flash point: 115°C 239 °F) ‘Flammability (solid, gaseous): ‘Not determined. Ignition temperature: Decomposition temperature: Not determined. Auto igniting: Product is not selfigniting. Danger of explosioy Not determined. Explosion limits: Lower: Not determined. Upper: Not determined. Vapor pressure: Not determined. Density at 20 °C (68 °F); 0,862 gem! (7.193 lbs/gal) Relative density Not determined. Vapor density Not determined. Evaporation rate Not determined. ‘Solubility in / Miseibility with Water: Not miscible or difficult 0 mix. Partition coefficient (n-octanol/water): Not determined. Not determined. Kinematic Not determined. ‘Solvent content: VOC content: 10% Other information No further relevant information available. Reactivity Stable under normal conditions. Chemical stability Stable under normal conditions. Thermal decomposition / conditions to be avoided: Formation of toxic gases is possible during heating or in case of fire. Possibility of hazardous reactions No dangerous reactions know. Conditions to avoid Heat. Incompatible materials: Strong oxidizing agents (Com. on page 6) Page 69 Safety Data Sheet ‘ace, to OSHA HCS Printing date 07/19/2016 Reviewed on 07/19/2016 Product name: Acid Number 1.5 mgKOH/g Reference Standard in Hydrocarbon Oil (Contd. of pase 8) Hazardous decomposition products: Formation of toxic gases is possible during heating or in case of fire. Information on toxicological effects May be fatal if swallowed and emers airw Acute toxicity: TD/LC30 values that are relevant for classification: 8042-47-5 White mineral oll Oral] LD30|> 3000 mayke (rat) Primary irritant effect: ‘on the skin: No irritant effect. ‘on the eye: No irritating effect. Sensitization: No sensitizing effects known. Additional toxicological information: The product shows the following dangers according to internally approved calculation methods for reparations: Careinogenic categories TARC (International Agency for Research on Cancer) None of the ingredients isTisied. NIP (National Toxicology Program) None of the Ingredients is listed. (OSHA-Ca (Occupational Safety & Health Administration) ‘None of the ingredients is listed. Toxicity Aquatic toxicity: No further relevant information available. Persistence and degradability No further relevant information available, Behavior in environmental systems: Bloaccumulative potential No further relevant information available Mobility in soil No further relevant information available. Additional ecological information: General notes: Water hazard class I (Selfrassessmen: slightly hazardous for water Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system. Results of PBT and vPvB assessment “PBT: Not applicable. vPvB: Not applicable. (Contd on page 7) Page 79 Safety Data Sheet ace, to OSHA HCS- Printing date 07/19/2016 Reviewed on 07/19/2016 Product name: Acid Number 1.5 mgKOH/g Reference Standard in Hydrocarbon (Comd. of page 6) Other adverse effects No further relevant information available, Waste treatment methods Recommendation: Must not be disposed of together with household garbage. Do not allow product to reach sewage system. Uncleaned packagings: Recommendation: Dispose in accordance with national regulations. ‘UN-Number DOT, ADR, ADN, IMDG, IATA Not applicable DOT, ADR, ADN, IMDG, IATA Not applicable Transport hazard class(es) DOT, ADR, ADN, IMDG, IATA Class Not applicable “Packing group DOT, ADR, MDG, IATA Not applicable Environmental hazards: Marine pollutant: No ‘Special precautions for user Not applicable. Transport in bulk according to Annex Hof MARPOL73/78 and the IBC Code Not applicable. UN "Model Regulation”: Not applicable ‘Safety, health and environmental regulationsegislation specific for the substance or mixture Sara ‘Section 335 (extremely hazardous substances): ‘None of the ingredients is listed. ‘Section 313 (Specific taxte chemical listings): None of the ingredionis is listed. TSCA (Toxte Substances Control Act): All ingredients are sted. Tonid- on pase Page 89 Safety Data Sheet ‘acc. 1o OSHA HCS Printing date 07/19/2016 Reviewed on 07/19/2016 Product name: Acid Number 1.5 mgKOH/g Reference Standard in Hydrocarbon Oil (Cond oF page?) Proposition 65 Chemicals known to cause cancer: None ofthe ingredients is listed. Chemicals known to cause reproductive toxicity for females: None of the ingredients is Tisted [[ Ghemicals known to cause reproductive toxicity for mal None of the ingredients is listed. ‘Chemicals known to cause developmental toxicity: TA9-37-3]2-Euhyhexole acid Carcinogenic categories EPA (Environmental Protection Agency) None of the Ingredients is listed TLV (Threshold Limit Value established by ACGIH) ‘None of the ingredients is listed. ‘NOSH-Ca (National Institute for Occupational Safety and Health) None of the ingredients is sted. GHS label elements The product is classified and labeled according to the Globally Harmonized System (GHS). Hazard pictograms GHSos Signal word Danger Hazard-determining components of labelin; White mineral oil Hazard statements H361 Suspected of damaging fertility or the unborn child H304 May be fatal if swallowed and enters airways Precautionary statements 7280 ‘Wear protective gloves/protective clothing/eve protectioniface protection. P301+P310 IF SWALLOWED: Immediately call a POISON CENTER’ doctor P308+P313 IF exposed or concemed: Get medical advice/attention 331 DoNOT induce vomiting P405 Store locked up. PS01 Dispose of contents/eontainer in accordance with local/regional/national/international regulations. (Chemical safety assessment: A Chemical Safety Assessment has not been carried out ‘(Com on page 9) Page 99 Safety Data Sheet ace. to OSHA HCS: Printing date 07/19/2016 Reviewed on 07/19/2016 Product name: Acid Number 1.5 mgKOH/g Reference Standard in Hydrocarbon Oil (Coma. of page 8) The information in this Safety Data Sheet meets the requirements of the United States OCCUPATIONAL SAFETY AND HEALTH ACT and regulations promulgated thereunder (29 CFR 1910,1200 et. seq.) This document is intended onty as a guide to the appropriate precautionary handling of the material by a person trained in, or supervised by a person trained in, chemical handling. The user is responsible for determining ‘he application. Depending on usage, protective clothing including eye and face guards and respirators must be used 10 avoid contact with material or breathing chemical vapors/fumes, Exposure to this product may have serious adverse health effects. This chemical may interact with other substances. Since the potential uses are so varied, we cannot warn of all of the potential dangers of use or interaction with other chemicals or ‘materials. We warrant that the chemical meets the specifications set forth on the label. We (LGC/VHG/ARMI) disclaim any other warranties, expressed or implied with regard to the product supplied hereunder, its ‘merchamability or its fimess for a particular purpose. The user should recognize that this produet can cause severe injury and even death, especially if improperly handled or the known dangers of use are not heeded. Read all precautionary information. Date of preparation /tast revision 07/19/2016 Abbreviations and acronyms: ADR: Accord exropen sur le transport des marchandises dangerenses par Rowe (European Agreemen concerning the International Carriage of Dangerous Goods by Road) MDG: Internrional Maritime Code for Dangerows Goods DOT: US Department of Transportation ATA: Inernational dir Transport sociation ‘ACGIH: American Confrence of Governmental Industral Hygienists EINECS: European mentor of Eusting Commercial Chemical Substances EELINCS: European List of Notified Chemical Substances (CAS: Chemical Abstracts Service (dteison ofthe merican Chemical Socke) NEPA: National Fire Proction

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