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Chapter 5 15.
The value of H0 for the reaction below is -72 kJ.
__________ kJ of heat are released when 1.0 mol of HBr is
formed in this reaction.
Thermochemistry H2 (g)  Br2 (g)  2HBr(g)
A) 144
B) 72
C) 0.44
D) 36
E) -72

General Chemistry-Problem 2

16. 17.
The value of H0 for the reaction below is -126 kJ. The value of H0 for the reaction below is -126 kJ. The
__________ kj are released when 2.00 mol of NaOH is amount of heat that is released by the reaction of 25.0 g of
formed in the reaction? Na2O2 with water is __________ kJ.
2Na 2O2 (s)  2H2O(l)  4NaOH(s)  O2 (g) 2Na 2O2 (s)  2H2O(l)  4NaOH(s)  O2 (g)
A) 252 A) 20.2
B) 63 B) 40.4
C) 3.9 C) 67.5
D) 7.8 D) 80.8
E) -126 E) -126

General Chemistry-Problem 3 General Chemistry-Problem 4

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38.
23.The enthalpy change for the following reaction is -483.6
kJ:
ΔH for the reaction IF5 (g)  IF3 (g)  F2 (g)
2H2 (g)  O2 (g)  2H2O(g) is __________ kJ, give the data below.

Therefore, the enthalpy change for the following reaction is IF(g)  F2 (g)  IF3 (g) ΔH = -390 kJ
__________ kJ:
2H2O (g)  2H2 (g) + O2 (g) IF(g)  2F2 (g)  IF5 (g) ΔH = -745 kJ
A) -483.6
A) +355
B) -967.2
B) -1135
C) 2.34 105
C) +1135
D) 483.6
D) +35
E) 967.2
E) -35
General Chemistry-Problem 5 General Chemistry-Problem 6

39. Given the following reactions 44. Given the following reactions
Fe2O3 (s)  3CO(s)  2Fe(s)  3CO2 (g) ΔH = -28.0 kJ H2O(l)  H2O(g) ΔH = 44.01 kJ
3Fe(s)  4CO2 (s)  4CO2 (g)  Fe3O4 (s) ΔH = +12.5 kJ 2H2 (g)+O2 (g)  2H2O(g)
ΔH = -483.64 kJ
the enthalpy of the reaction of Fe2O3 with CO the enthalpy for the decomposition of liquid water into
3Fe2O3 (s)  CO(g)  CO2 (g)  2Fe3O4 (s) gaseous hydrogen and oxygen
is __________ kJ. 2H2O(l)  2H2 (g)+O2 (g)
is __________ kJ.
A) -59.0 A) -395.62
B) 40.5 B) -527.65
C) -15.5 C) 439.63
D) -109 D) 571.66
E) +109 E) 527.65
General Chemistry-Problem 7 General Chemistry-Problem 8

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48.
The value of for the reaction below is -186 kJ. 50.
H2 (g)  Cl2 (g)  2HCl(g) Given the data in the table below, Horxn for the reaction
Ca(OH)2  2H3AsO4  Ca(H2AsO4 )2  2H2O
The value of Hof for HCl (g) is __________ kJ/mol.
is __________ kJ.
A) 3.72 102 A) -744.9
B) 1.27 102 B) -4519
C) -93.0 C) -4219
D) -186 D) -130.4
E) +186 E) -76.4

General Chemistry-Problem 9 General Chemistry-Problem 10

55. 6.The value of ΔE for a system that performs 111 kJ of

Given the data in the table below, for the reaction work on its surroundings and gains 89 kJ of heat is
2CO(g)  O2 (g)  2CO2 (g) __________ kJ.
is __________ kJ. A) -111
B) -200
A) -566.4 C) 200
B) -283.2 D) -22
C) 283.2 E) 22
D) -677.0
E) The of is needed for the calculation.

General Chemistry-Problem 11 General Chemistry-Problem 12

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7.The value of ΔE for a system that performs 13 kJ of work 8.

on its surroundings and loses 9 kJ of heat is When a system __________, ΔE is always negative.
__________ kJ.

A) absorbs heat and does work

A) 22 B) gives off heat and does work
B) -22 C) absorbs heat and has work done on it
C) -4 D) gives off heat and has work done on it
D) 4 E) none of the above is always negative.
E) -13

General Chemistry-Problem 13 General Chemistry-Problem 14

9. 13.
Which one of the following is an endothermic process? The internal energy can be increased by __________.
(a) transferring heat from the surroundings to the system
A) ice melting (b) transferring heat from the system to the surroundings
B) water freezing (c) doing work on the system
C) boiling soup
D) Hydrochloric acid and barium hydroxide are mixed at 25 A) a only
°C: the temperature increases. B) b only
E) Both A and C C) c only
D) a and c
E) b and c
General Chemistry-Problem 15 General Chemistry-Problem 16

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14. 18. Which one of the following statements is true?

A __________ ΔH corresponds to an __________ process.
A) The enthalpy change for a reaction is independent of the
A) negative, endothermic state of the reactants and products.
B) Enthalpy is a state function.
B) negative, exothermic
C) positive, exothermic C) H is the value of q measured under conditions of
constant volume.
D) zero, exothermic
D) The enthalpy change of a reaction is the reciprocal of
E) zero, endothermic the ΔH of the reverse reaction.

General Chemistry-Problem 17 General Chemistry-Problem 18

21. The reaction

4Al(s)  3O2 (g)  2Al2O3 (s) ΔH° = -3351 kJ 23.

is __________, and therefore heat is __________ by the The units of of heat capacity are __________.
reaction.
A) K/J or °C/J
A) endothermic, released B) J/K or J/ °C
B) endothermic, absorbed C) J/g-K or J/g- °C
C) exothermic, released D) J/mol
D) exothermic, absorbed E) g-K/J or g- °C/J
E) thermoneutral, neither released nor absorbed

General Chemistry-Problem 19 General Chemistry-Problem 20

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30. Which of the following is a statement of Hess's law?

31.

A) If a reaction is carried out in a series of steps, the ΔH for the For which one of the following reactions is Horxn equal to
reaction will equal the sum of the enthalpy changes for the the heat of formation of the product?
individual steps.
A) N2 (g)  3H2 (g)  2NH3 (g)
B) If a reaction is carried out in a series of steps, the ΔH for the
reaction will equal the product of the enthalpy changes for the B) (1/ 2)N2 (g)  O2 (g)  NO2 (g)
individual steps.
C) The ΔH for a process in the forward direction is equal in C) 6C(s)  6H(g)  C6 H6 (l)
magnitude and opposite in sign to the ΔH for the process in the P(g)  4H(g)  Br(g)  PH4 Br(l)
reverse direction. D)
D) The ΔH for a process in the forward direction is equal to the E) 12C(g)  11H2 (g)  11O(g)  C6H22O11 (g)
ΔH for the process in the reverse direction.
E) The ΔH of a reaction depends on the physical states of the
reactants and products.
General Chemistry-Problem 21 General Chemistry-Problem 22

15. 39.
For which one of the following equations is equal to Hf for For which one of the following reactions is the value of
the product? Hrxn equal to Hf for the product?
A) Xe(g)  2F2 (g)  XeF4 (g) A) H2O(l)  1/ 2O2 (g)  H2O2 (l)
B) CH4 (g)  2Cl2 (g)  CH2Cl2 (l)  2HCl(g) N2 (g)  O2 (g)  2NO(g)
B)
C) N2 (g)  O3 (g)  N2O3 (g) C) 2H2 (g)  O2 (g)  2H2O(l)
D) 2CO(g)  O2 (g)  2CO2 (g) D) 2H2 (g)  O2 (g)  2H2O(g)

E) C (diamond)  O2 (g)  CO2 (g)

E) none of the above

General Chemistry-Problem 23 General Chemistry-Problem 24