4/19/2015

Chapter 7 4) Consider the following reaction:

A  2C
The average rate of appearance of C is given by C t .
Kinetic Comparing the rate of appearance of C and the rate of
disappearance of A, we get C t  _____ (A t) .

A) +2
B) -1
C) +1
D) +1/2
E) -1/2
General Chemistry -Problem 2

17*) At elevated temperatures, dinitrogen pentoxide 21) If the rate law for the reaction
decomposes to nitrogen dioxide and oxygen: 2A  3B  products
N2O5 (g) 4NO2 (g)+ O2 (g)
is first order in A and second order in B, then the rate law is
When the rate of formation of NO2 is5.5  104 M/s, the rate rate = __________.
of decomposition of N2O5 is __________ M/s.
A) k  A   B
2 3
B) k[A] [B]
A) 2.2  103 2
C) k[A][B]
B) 1.4  104 2
D) k[A] [B]
C) 10.1 104 2 2
E) k[A] [B]
D) 2.8  104
E) 5.5  104

General Chemistry -Problem 3 General Chemistry -Problem 4

1
 4/19/2015

A  B P 33) A first-order reaction has a rate constant of0.33 min

1

. It takes __________ min for the reactant concentration

to decrease from 0.13 M to 0.088 M.

A) 1.2
B) 1.4
27) The order of the reaction in A is __________. C) 0.51
28) The order of the reaction in B is __________ D) 0.13
29) The overall order of the reaction is __________. E) 0.85

General Chemistry -Problem 5 General Chemistry -Problem 6

34) The initial concentration of reactant in a first-order 35) The rate constant for a second-order reaction is 0.13M -
reaction is 0.27 M. The rate constant for the reaction is0.75 s1 1s-1 . If the initial concentration of reactant is 0.26mol/L it
. What is the concentration (mol/L) of reactant after 1.5s takes __________ s for the concentration to decrease to
0.13mol/L
A) 3.8
B) 1.7 A) 0.017
2
C) 8.8 10 B) 0.50
2
D) 2.0  10 C) 1.0
E) 0.135 D) 30
3
E) 4.4 10

General Chemistry -Problem 7 General Chemistry -Problem 8

2
 4/19/2015

38) The reaction below is first order in [H2O2]:

36) The half-life of a first-order reaction is 13 min. If the 2H2O2 (l)  2H2O(l)  O2 (g)
initial concentration of reactant is 0.085M it takes ____
for it to decrease to 0.055 M. A solution originally at 0.600 M is found to be 0.075 M after
54 min. The half-life for this reaction is __________ min.
A) 8.2
B) 11 A) 6.8
C) 3.6 B) 18
D) 0.048 C) 14
E) 8.4 D) 28
E) 54

General Chemistry -Problem 9 General Chemistry -Problem 10

7) The rate law of a reaction is rate = k[D][X]. The units of

the rate constant are __________.

1 1
A) mol L s
B) L mol1s1
C) mol2 L2s1
1 2
D) mol L s
2  2 1
E) L mol s

General Chemistry -Problem 11 General Chemistry -Problem 12

3
 4/19/2015

45). 45).

General Chemistry -Problem 13 General Chemistry -Problem 14

45). 45).

General Chemistry -Problem 15 General Chemistry -Problem 16

4
 4/19/2015

45). 45).

General Chemistry -Problem 17 General Chemistry -Problem 18

45).

General Chemistry -Problem 19