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MSDS Atren FK
MSDS Atren FK
SEAL: FEDERAL STATE UNITARY ENTERPRISE MOSCOW / ALL-RUSSIAN SCIENTIFIC RESEARCH CENTER OF STANDARDIZATION,
INFORMATION AND CERTIFICATION OF RAW MATERIALS AND SUBSTANCES
NAME:
technical (according to Atren FK A Drilling Mud Lubricant
regulatory document)
chemical (according to Not available
IUPAC)
Atren FK A Drilling Mud Lubricant
trade
synonyms Not available
ARPC Code code: FEACN Code:
2 4 5 8 6 1 3 4 0 3 1 9 9 9 0 0
2 1
2
Symbol and name of basic standard, technical or information document for products
(GOST, SPECIFICATIONS, OST, STO, (M) SDS etc.)
DANGER DESCRIPTION:
Signal word: DANGER
Short (verbal): a slightly hazardous substance according to extent of exposure to the organism (Hazard
Class 3 according to GOST 12.1.007). The product causes irritation of upper respiratory airways, has an
irritation effect on eye mucosa, causes slight irritating of skin. Flammable substance. Pollutes the
environment.
Detailed: in 16 attached sections of Safety Data Sheet.
MAC w.z. – Maximum allowable concentration of chemicals in the working zone area,
mg/m3 (maximum single/shift-average)
2. Hazard identification
2.1. Hazard level of chemicals in the mass: Classification according to GOST 12.1.007: acute (oral,
(Data about hazard classification according to the legislation dermal, inhalation) toxicity – class 4 (slightly hazardous
of the Russian Federation (GOST 12.1.007) and GHS) substance)
Classification according to GHS [26,2]:
- Corrosion/ irritation of eyes, class 2B
- Corrosion / irritation of skin, class 3;
- Dangerous if inhaled, class 1;
- Harmful to aquatic life with long-lasting effects, class
3;
Note: + special protection for skin and eyes is required. 1- according to the document “Hygienic criteria for
substantiation of the necessity of elaboration of maximum allowable concentration of and SRLI (AAL) of
hazardous substances in the working zone air, atmospheric air of inhabited localities, water of dangerous facilities”
it is not necessary to establish standards in in the working zone air and atmospheric air of inhabited localities in
view of physical/chemical properties and low toxicity of the substance.
4.2.4 Poisoning via peroral route: Abundant water drinking, keep the injured person at
rest, warming, fresh air, apply for medical aid if
necessary. Upon vomit stoop a head to prevent vomit
entry into lungs. [29, 30, 24]
5.1. General description of fire and explosion hazard: Combustible liquid, burns forming toxic gases and
dense smoke, containers can explode if heated. Fire
can cause injuries and burns, in case of contact with
hot product thermal burns are possible. Reasons of
ignition: effect of flame. [29-32,21,23,25]
5.3. Hazard caused by Products of combustion and/or When heated may decompose with formation of
thermal destruction: carbon oxides and nitrogen oxides affecting central
nervous and cardiovascular systems, blood, liver,
kidneys. [29-31]
5.4. Recommended fire-fighting equipment: Sand, sprayed water, generated mechanical foam, dry
powders. [21,23,25,29,30]
5.5. Forbidden fire-fighting equipment: Do not apply straight streams of water.
[21,23,25,29,30]
5.6. PPE for fire-fighting: Fire-fighting suit complete with a self-rescue device
(PPE of firemen) SPI-20 or according to the main source. [22]
5.7. Specificity upon fire-fighting: Enter the fire zone with protective clothes on. The
product emits toxic substances in the seat of fire.
Dispose fire-fighting subdivisions on a windward
side, limit access of oxygen. Cool down and combat
from the maximum distance. Packaging can be
damaged in the seat of fire. Containers may explode
when heated. [21,24,29,30]
6. Measures for prevention and elimination of
emergencies and consequences of them.
6.1. Prevention of hazardous imact
on people, environment, buildings, constructions
etc. in case of emergency.
6.1.1. Necessary general actions: Stop work, send off strangers, keep a windward side,
avoid low places, move the vehicle to a safe place.
Isolate the hazardous zone within a radius of not less
than 50 m, correct the specified distance according to
results of chemical survey. Enter the emergency zone
with complete protective clothes on, observe fire
safety measures, eliminate sources of fire and sparks.
Render first medical aid to injured persons, send
people from the emergency zone for a medical
checkup, call emergency services. [22]
6.1.2. PPE: Protective suit L-1 and L-2 completed with industrial
(of emergency crews and personnel) gas mask and A and B cartridges. Special clothing.
Oil and petrol resistant gloves, special footwear.
[22,1]
6.2. Operational procedure for elimination of
emergencies.
6.2.1. Actions in case of leak, spill, spreading: Stop work, use personal protective equipment,
(including precautionary measures providing protection of empty the content into a good container. In case of
environment) spilling in rooms collect to the container, wipe the
contaminated place, wash and ventilate the area. In
case of spill on the open ground, fence the place of
spill with an earth mound, cover up with sand.
Collect and send for liquidation to the landfill of
hazardous industrial wastes. Avoid the product entry
into water basins, sewerage and soil. Observe fire
safety regulations, do not smoke, eliminate sources of
fire and sparks. For spreading (laying, isolation) of
vapors use sprayed water. Measure MAC for
conformity if necessary, call neutralization
specialists. Burn out territories (its parts) upon
possibility of entry of the product to ground waters;
plow over the soil. [22]
6.2.2. In case of fire: Inform fire protection service, surrounding people
about the fire, leave the hazardous zone, tell to
firemen the place and the object of burning when
they arrive. Organize evacuation of people from
nearby buildings subject to a direction of movement
of toxic combustion products, do not approach
burning containers. [1,18,20,21,22,23]
7. Storage regulations for chemicals and
handling of them upon loading-unloading operations.
7.1. Safety measures upon handling of
chemicals.
7.1.1. Safety measures and collective protective Hermetic sealing of equipment, communication lines
measures: and containers, avoid spilling, forming of vapors,
(including system of fire and explosion safety measures) direct contact of a personnel to the product. Provide
limited access to the product, production control of
harmful factors. Use personal protective equipment,
suction-and-exhaust ventilation. Provide control of
technological processes and equipment condition.
Observe requirements in accordance with GOST
12.1.004, PPB 01-93 and GOST 12.1.018, use
explosion-proof equipment, illumination and
sparkproof tools, protect from a static electricity;
provide with emergency firefighting equipment,
exits, entrances and exits should be free. Do not pour
the product to containers close to sources of open
fire. Avoid strokes when you close the hatches of the
tanks and barrels, upon connecting of hoses and other
equipment, pour the product without spilling it.
The rooms should be equipped with washstands,
medical kits, emergency PPE, water supply and
industrial sewage. The floor in production rooms
should be easily cleaned with water and should be
with slopes and drains. [1,9, 12,13,14,21,29-32]
7.1.2. Measures for environment protection: Avoid entry of the product into the working zone and
the environment. Provide control of concentration of
hazardous substances in the air of a working zone,
sanitary protection zone, industrial effluents.
Observe requirements of accumulation, collection,
placements, disposal and utilization of industrial
wastes. Do not discharge the product to municipal
collectors, sewage systems, natural water basins,
rivers and soil, do not store containers, in which the
product was or is, directly on the ground, do not burn
waste in earth mounds, do not perform unauthorized
placement of waste, importing of the wastes to the
landfill of industrial wastes with further burying.
[1,9,12,13,14,21,29,30].
7.1.3. Recommendations for safe transfer and Continuity and tightness of packing, exclude
carriage: inflammability, unauthorized access, spillage, entry
into the environment. Do not use fire and sparking
equipment. Do not perform loading-unloading
operations with the product if containers do not
comply with requirements or are improper, if there is
no marking on them. Do not transport with oxidizers,
explosive substances, the substances capable of
forming explosive mixtures flammable upon contact
to air and water, alkalis and acidic-type materials,
compressed and liquefied gases, acids. Observe
requirements on securing and disposition of loads.
Avoid external mechanical effect - damage to the
package. Do not throw; do not turn over.
[1,19,20,21,22]
7.3. Security measures and storage rules in a life: Do not apply in household use. [1]
8. Control devices for hazardous exposure and
PPE.
8.1. Parametres of a working zone, Health standards are given for
subject to compulsory control (MAC w.z. or SRLI mineral (hydrocarbon) oil: maximum one-time
w.z.): MAC of work. zone: 5 mg/m3, aerosol, special
protection of skin and eyes is required [29,3]
8.2. Provision measures for hazardous substances in Operability of the ventilation system. Provide hermetic
allowable concentration: sealing of production equipment, containers, avoid
forming of vapors. Use the product in well-ventilated
premises, provide control of product component
concentration in air of a working zone, sanitary and
hygienic control of ventilation systems. Laboratory works
shall be performed only in the exhaust fume hood with
ventilation switched on, periodical wet cleaning of
premises. [1,8,13,14,21]
8.3. PPE of the personnel:
8.3.1. General recommendations: Avoid direct contact with the product; do not eat,
drink or smoke in the working zone. Use PPE. Make
periodical hygienic cleaning of personal protection
equipment. Availability of PPE spare sets. Observe
HSE. Availability of fire-fighting equipment. Persons
aged 18 are allowed by results of medical checkups.
Labour protection briefing. [13]
8.3.2. Respiratory protective equipment (RPE types): Half-mask with BKF cartridges according to GOST
TR TS 019/2011. [29, 17]
8.3.3. Protective clothes (material, type): Acid and alkali resistant rubber gloves, type I-II,
(special clothes, special footwear, hand protection, eye according to GOST 20010. Acid-resistant suit
protection): according to GOST R 12.4.248 or a chemical
protective overall according to TR TS 019/2011,
apron according to GOST 12.4.029 is recommended
for use. Leather, rubber or compound boots
according to GOST 12.4.137. Mask-type goggle
according to GOST 12.4.230.1. [29,17]
8.3.4. PPE for household used: Do not apply in household use. [1]
11.6. Acute toxicity equivalents: DL50 10000 mg/kg, intragastric route, mice (by the
(DL50, routes of entry (intragastric, epicutaneous), animal type; method of V. B. Prozorovsky). [2]
CL50, exposition time (h), animal type) DL50 > 2500 mg/kg, epicutaneous, rabbits.
CL50 > concentration is not achieved, 2 hours.
[29,30]
C 16-18 fatty acids : Not determined Not determined Not determined Not determined
Note:
1 – emulsified and dissolved oil and oil products
2 - according to the document “Hygienic criteria for substantiation of the necessity of elaboration of
maximum allowable concentration of and SRLI (AAL) of hazardous substances in the working zone air,
atmospheric air of inhabited localities, water of dangerous facilities” it is not necessary to establish standards
in in the working zone air and atmospheric air of inhabited localities in view of physical/chemical properties
and low toxicity of the substance.
1
LHI – limiting harmful index (tox. – toxicological; s. – sanitary-toxicological; org. - organoleptic; refl. – reflexory; rez. -
resorptive; refl.-res. – reflexory and resorptive, fisheries (change of market conditions of field aquatic organisms); gen. – general
sanitary)
2
Water of water bodies of household and cultural and general water use
3
Water of water bodies for fishery purpose (including off-shore facilities)
12.4.2. Ecotoxicity parametres: Acute toxicity for fish according to GHS
(СL, EU for fishes, daphnias magna, seaweed etc.) recommendations makes CL50 10-100 mg/l, fishes,
96 hours, is defined by action of mineral
(hydrocarbon) oil CL50>10 mg/l, fishes, 96 h.
Acute toxicity for fishes and bioaccumulation
properties were determined, is defined by the action
of mineral (hydrocarbon) oil. The substance is not
soluble in water, capable of accumulating in the
water, forms a stable oily film on the surface of the
water, Log pow=6 [26,28,29]
A threshold concentration limit of its influence on
the organoleptic properties of water was not studied
regarding the product. [29,30]
12.4.3. Migration and transformation in Biodeterioration and biodissimilation are poor. The
environment owing to biodeterioration and other product is transformed in the
processes (oxidation, hydrolysis etc.): environment.[28,29,30]