Final Exam Review Answers 2007

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FINAL EXAM REVIEW

Unit 1 – Matter and Chemical Bonding

1) See bulletin board.

2) a) alkali metals b) halogens c) Noble gases

3) Francium

4) Fluorine

5) Magnesium has the largest atomic radius because they all have the same number of
energy levels, but Mg has less protons to attract the electrons.

6) Oxygen has the largest ionization energy because it has the least number of energy
levels, so there is less shielding of the positive nucleus and it can attract its electrons
more tightly, making them difficult to remove.

7) Oxygen has the largest ionization energy because it has the least number of energy
levels, so there is less shielding of the positive nucleus and it can attract electrons
from other orbits more readily.

8) a) Ca  2e - + Ca2+ b) N + 3e-  N3-

9) a) ionic solids – hard, no odour, soluble in H2O, high melting point, good conductor of
electricity when dissolved in water.
b) Covalent solid – opposite of ionic

10) Covalent – a, b, d polar covalent – e, f ionic – c

11) See bulletin board.

12) A) LiBr b) Ca3N2 c) CO d) PF5

13) a) silicon (IV) chloride


b) barium sulphide
c) magnesium fluoride
d) lithium phosphide

14) a) Mg(NO3)2
b) CuO
c) K2SO4
d) CaCO3

15) a) calcium hydroxide


b) sodium chlorate
c) iron (II) oxide
d) ammonium nitrate
16) a) H2SO3
b) Ba(NO2)2
c) SnBr4
d) Fe2O3

17) a) phosphoric acid


b) calcium sulphite
c) iron (III) nitrate
d) copper (II) carbonate

18) a) NaClO2
b) K2SO4
c) Cu(NO3)2
d) NH4ClO4

19) a) nitrous acid


b) iron (III) hydroxide
c) potassium hypochlorite
d) hydrochloric acid

20) a) barium nitrite


b) hydrosulphuric acid
c) lithium bicarbonate (or lithium hydrogen carbonate)
d) nitrogen (III) oxide

21) a) 2, 13, 8, 10
b) 2, 6, 5, 1, 6, 5
c) 1, 1, 1, 4
d) 4, 11, 2, 8
e) 1, 3, 2, 3
f) 1, 1, 2
g) 1, 3, 2, 3
h) reaction a represents the combustion of a hydrocarbon

22) synthesis reactions – b, f


decomposition – g, i
combustion – k
single displacement – d, e
double displacement – a, c, h, j

Unit 2 – Quantities in Chemical Reactions

1) a) 148.33 g./mol b) K2CO3, 138.21 g/mol


2) 2.30 mol
3) 2.6 x 102 g
4) 2.41 x 1024 molecules
5) 113 g
6) 40.91% C, 4.59% H, 54.50% O
7) CH4O
8) Na2C8H4O4
9) a) 62.97 % b)ZnSO4 . 7H2O
10) 2.31 g
11) a) 55.1 g b) 19.0%
12) 0.329 g

Unit 3 – Solutions and Solubility

1) 23%
2) 23g
3) 26ppm
4) 0.412 mol/L
5) 12 mol/L
6) a) 0.125 L b) 9.9 L
7) a) Fe(NO3)3 (aq) + 3NaOH (aq)  Fe(OH)3 (s) + 3NaNO3 (aq)
Fe3+ (aq) + 3OH-(aq)  Fe(OH)3 (s)
b) Pb(NO3)2 (aq) + 2KI (aq)  PbI2 (s) + 2KNO3 (aq)
Pb2+ (aq) + 2I- (aq)  PbI2 (s)

8) 68.9 mL
9) a) NH4NO3 (aq)  NH4+(aq) + NO3-(aq)
b) HClO3 (aq) + H2O (l)  H3O+ (aq) + ClO3- (aq)

10) a) 3.176 b) acidic


11) a) H3PO4 (aq) + 3NaOH (aq)  3H2O (l) + Na3PO4 (aq)
b) H2SO4 (aq) + K2CO3 (aq)  CO2 (g) + H2O (l) + K2SO4 (aq)
12) 0.133 mol/L

Unit 4 – Gases

1) a) 258 K b) 302oC c) 99.0 kPa d) 0.981 atm


2) 9.0 L
3) 13 L
4) 7.4 x 102 oC
5) 2.1 L
6) 1.46 x 104 kPa
7) 1.7 L
8) 48.0 kPa Ar, 24.0 kPa Ne, 8.00 kPa Kr
9) 0.58 mol
10) 44.0 g/mol
11) 6.4 x 102 g
12) 144 L
13) 2.5 L
14) 5.00 L
15) 0.245 L

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