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NMAT CHEMISTRY SIMULATIONS (MOCK 3R)

DIRECTIONS: Select the best answer to each of the following questions and blacken the appropriate space on your answer
sheet.

1. Given: F 2 ( g ) ↔2 F(g)
P → PH 3 + H 2 PO 2−¿¿ (alkaline) At a certain temperature is 7.3 x 10-13, what is KC for
When balanced, what will be the sum of the coefficients of 1
the products? F ( g ) ↔ F (g)?
a. 3 b. 4 c. 13 d. 14
2 2
a. 7.3× 10−13
√ c. 1.37 x 10-12
2. Which of the following is not a conjugate acid-base pair? b. 3.65 x 10-13 d. 7.3 x 10-13
a. NH 4 , NH 3
+¿¿ −¿¿
c. H 2 O , OH
NH 3, NH 2−¿¿ H 2 SO 4 , OH −¿¿ For numbers 10 and 11, consider this situation. Paul found a
b. d.
certain unknown compound to be 31.0% carbon, 5.2%
hydrogen, 27.6% oxygen, and 36.2% nitrogen. The
226
3. What nuclear process occurred if 88 X results from the molecular weight was experimentally determined to be
226 approximately 460.
emission of particle by 89 Y ?
Atomic Weights:
a.  decay b. - decay c. + decay d. K-electron capture H=1 C = 12
N = 14 O = 16
4. In the combustion of ethyne in oxygen, 8 g of O2 was
present. Ideally, what amount of ethyne could have reacted 10. What is the empirical formula of the compound?
with all that O2, and how much CO2 could have been a. C3H6O2N3 c. C6H10O5N5
produced? b. C5H2ON3 d. C10H20O7N10
a. 13 g ethyne; 11 g CO2
b. 2.3 g ethyne; 7.3 g CO2 11. Which is a possible molecular formula for the
c. 3.2 g ethyne; 6.4 g CO2 compound?
d. 2.6 g ethyne; 8.8 g CO2 a. C4H2O(NO)5(CO)2(NH2)5(CH)6(OH)2
b. C4(NO)4(CO)2(NH2)8(CH)6(OH)2
258
5. What kind of particle was emitted if 101 A underwent c. C18H2O2(CO)2(NH2)4(CH3)4(OH)2
254 d. C18H2(CO)2(NH2)6(CH3)4(OH)2
decay and the result was 99 B ?
a. alpha particle c. positron For numbers 12 and 13 consider this situation. A sample of
b. electron d. gamma ray 0.025 M KOH stands at 250C, where 100.4  2.5

6. Fusion is most likely to occur with the: 12. What is the pH of this sample?
a. Combination of 2 1H nuclei a. 1.6 c. 13
b. Combination of 2 2H nuclei b. 12.4 d. 13.6
244
c. Splitting apart of a single 95 Am nucleus
245 13. What is the pOH of this sample?
d. Splitting apart of a single 95 Am nucleus a. 1.6 c. 13
b. 12.4 d. 13.6
7. Mike can prepare methanol from bromomethane by
adding _____ to the latter. 14. Given this graph:
a. Hydrogen gas c. Sulfuric acid
b. Sodium hydroxide d. Heat energy and light

8. At 250C in the equilibrium

N 2 ( g )+ O 2 ( g ) ↔2 NO
Kp = 4.8 x 10-31
which species will dominate?
a. NO and O2 c. N2 and O2
b. N2 and NO d. None

9. If the equilibrium constant KC for

1
What type of reaction does the forward reaction represent?
a. Endothermic c. Both A and B
b. Exothermic d. Neither A nor B

15. NO2 is a gas whose density is 73.5 g/L. What pressure

will it exert at a temperature of 270C?
a. 43.05 atm c. 86.10 atm
b. 81.81 atm d. 1808.10 atm

25
16. If 13 Ky emits a gamma ray, then the daughter nucleus
is: 20. In which substance is the oxidation state of nitrogen
24 21
a. 13 Ky c. 11 Nc zero?
25 24 a. N2 c. NO2
b. 13 Ky d.14 Shf b. NH3 d. N2O
For numbers 17 and 18, refer to the following periodic table.

21. What happens to aluminium in the reaction:

2 Al +3∋ ( NO3 ) 2 → 2 Al ( NO 3 )3 +3∋¿

a. Reduced and its oxidation number increases

b. Reduced and its oxidation number decreases
c. Oxidized and its oxidation number increases
d. Oxidized and its oxidation number decreases

22. The Law of Multiple Proportions applies to what pair of

17. Which pair of elements below has the highest and compounds?
lowest electron affinities, respectively? a. KCl and KClO3 c. H2O and H2O2
a. He and Rn c. Ac and F b. MgSO4 and MnSO4 d. NaBr and NaCl
b. F and Fr d. Li and Nb
23. Which procedure is most likely to increase the solubility
18. Which of the following are all metalloids? of a gas in a liquid?
a. Sc, Lr, Zn, Uub c. Ge, As, Te a. Constant stirring c. Adding more solvent
b. B, O, F, Ne d. Ne, Ar, Kr b. Heating the solution d. Increasing the pressure
19. What will be the product of the following reaction? 24. Along a row in the periodic table, elements have the
same:
a. Energy level c. Atomic radius
b. Electronegativity d. Ionization energy

25. What is the correct identity of X in the reaction:

234
91 Pa → X + −10 β ?
234 234
a. 92 U c. 90 Th
235 232
b. 92U d. 90Th

2
26. The half-life, t1/2, of radioactive phosphorous, 32P, is 14 35. Exothermic is a term used to describe a reaction:
days. Given 1.0 mg 32P, how much will remain after 42 a. That occurs at a low temperature
days? b. For which heat is a reactant
a. 0.5 mg c. 0.125 mg c. For which heat is a product
b. 1.25 mg d. None d. That occurs at a high temperature

27. Which statement is NOT true? 36. Which type of reaction does the Haber process below
a. An element melts at a definite temperature. represent?
b. An element is changed into another substance by heat in N 2 ( g )+ 3 H 2 ( g ) →2 NH 3 ( g ) + Heat
the absence of air or another substance.
a. Exothermic, with an increase in entropy
c. An element may combine with another to form a
b. Exothermic, with a decrease in entropy
compound.
c. Endothermic, with an increase in entropy
d. An element is made of the same kind of atom.
d. Endothermic, with a decrease in entropy
28. Which of the following is a property of all metals?
37. Which change would most likely increase the rate of a
a. All are hard.
chemical reaction?
b. All are combined easily with oxygen.
a. Decreasing the reactants’ concentration
c. All are solids at room temperature.
b. Decreasing the reactants’ surface
d. All are conductors of heat and electricity.
c. Cooling the reaction mixture
d. Adding a catalyst to the reaction mixture
29. No two electrons in the same atom can have the same
set of quantum numbers is the statement of:
38. Given the reaction below at equilibrium.
a. Hund’s Rule of Multiplicity
b. Dalton’s Atomic Theory X 2 ( g ) +2 Y 2 ( g ) ↔2 XY 2 ( g )+ 80 kcal
c. Heisenberg’s Uncertainty Principle The equilibrium point will shift to the left if the pressure is:
d. Pauli’s Exclusion Principle a. Increased and the temperature is increased
b. Increased and the temperature is decreased
30. As you enter a building, you observe a beam of light c. Decreased and the temperature is increased
from the glass roof. What is the phenomenon? d. Decreased and the temperature is decreased
a. Brownian movement c. Tyndall effect
b. Peptization d. Adsorption

39. The molecular weight of a substance is 128 and its

equivalent weight in a particular reaction is 24. A 1.0 M
31. Which of the following substances will exhibit the solution of this substance will have a normality of:
highest boiling point? a. 5.33 N b. 0.50 N c. 2 N d. 0.25 N
a. CCl4 c. CH4
b. CO2 d. Cl2HCCHCl2 40. What volume of 0.1 M NaOH is needed to neutralize 25
mL of 0.1 M H2SO4?
32. Which of the following is/are true? a. 12.5 mL b. 25 mL c. 50 mL d. 100 mL
a. At 1 atm the boiling point of water is 100 0C.
b. The vapour pressure of 40 mL of water heated at 400C is 41. What is the normality of an acid solution if 50 mL of the
twice the vapour pressure of 20 mL of water heated at the solution requires 48.16 mL of 0.1879 N alkali for
same temperature. neutralization?
c. Generally, non-polar substances have higher boiling a. 0.4000 N c. 0.1827 N
points than polar substances. b. 0.2678 N d. 0.1274 N
d. Choices a and b are true.
42. Which is the conjugate base of H2SO4?
33. Which substance evaporates more rapidly at a given a. SO3-2 b. S-2 c. HSO3- d. HSO4-
temperature?
a. Substance that has high vapour pressure at room 43. Which statement best describes a solution with a pH of
temperature 3?
b. Substance with molecules having strong forces of a. It has an H+ concentration of 1 x 103 and is acidic.
attraction b. It has an H+ concentration of 1 x 10-3 and is acidic.
c. Substance with high boiling temperature c. It has an H+ concentration of 1 x 103 and is basic.
d. Substance with high heat of vaporization d. It has an H+ concentration of 1 x 10-3 and is basic.

34. What is the maximum number of grams of water at 100C 44. Which of the following will produce a solution with a pH
that can be heated to 300C by the addition of 40 calories of less than 7?
heat? a. KCN b. K2SO4 c. NH4Cl d. NaNO3
a. 1.0 c. 20
b. 2.0 d. 30 45. In any of the p, d, or f orbitals, electrons tend to occupy
separate orbitals before any orbital can have two electrons.
This principle is referred to as:
3
a. de Broglie’s Principle c. Aufbau’s Principle a. CH3CH(OH)CH2OH c. CH3CH2CH2OH
b. Pauli’s Exclusion Principle d. Hund’s Principle b. CH3CH2CH2MnO4 d. CH2(OH)CH(OH)CH2OH

46. If 75% of the isotopes of an element have a mass of 35 49. When propyne reacts with 2 moles of HBr, the major
amu and 25% of the isotopes have a mass of 37 amu, what product formed is :
is the atomic mass of the element? a. 1,1-dibromopropane c. 2,2-dibromopropane
a. 35 amu c. 36 amu b. 1,2-dibromopropane d. 1-bromopropane
b. 35.5 amu d. 37 amu
50. Which compound contains double bonds, does not
47. Which of the following molecules is the most acidic? decolorize bromine water, and reacts with chlorine in the
a. CH3COOH c. CHCl2CH2COOH presence of ferric chloride?
b. CH2ClCOOH d. CH3CCl2COOH a. Ethyl alcohol c. Benzene
b. Butane d. Cyclohexene
48. If propylene is shaken with cold neutral KMnO 4 solution,
the primary organic compound will be: