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Date: 25th August 2019 Bakliwal Tutorials-IIT

Comprehensive 2021 B-Test 3 YOUR STRATEGIC MOVE

Total Time: - 3 hrs. Sub: - Physics, Chemistry & Math Max. Marks: -360

SET-A
Rules & regulations for BTEST

1. Immediately fill in the particulars on this page of the Test Booklet with Ball Point Pen.

2. The Answer Sheet (OMR) is provided separately. Please fill in the particulars carefully with Ball Point Pen.

3. The test is of 3 hours duration.

4. The Test Booklet consists of 90 questions. The maximum marks are 360.

5. There are three parts in the question paper consisting of Physics, Chemistry and Mathematics having 30 questions
in each part of equal weightage. Each question is allotted 4 (four) marks for correct response.

6. Candidates will be awarded marks as stated above in instruction No. 5 for correct response of each question. ¼
(one-fourth) marks of the total marks allotted to the question (i.e. 1 mark) will be deducted for indicating incorrect
response of each question. No deduction from the total score will be made if no response is indicated for an item in
the answer sheet.

7. There is only one correct response for each question. Filling up more than one response in any question will be
treated as wrong response and marks for wrong response will be deducted accordingly as per instruction 6 above.

8. No candidate is allowed to carry any textual material, printed or written, bits of papers, pager, mobile phone, any
electronic device, etc. except the Admit Card inside the examination room/hall.

9. Rough work is to be done on the additional sheets provided

11. On completion of the test, the candidate must immediately hand over the Answer Sheet to the Invigilator on duty
in the Room/Hall. However, the candidates are allowed to take away this Test Booklet with them.

12. The CODE for this Booklet is A. Make sure that the CODE is marked properly on the answer sheet.

13. Do not fold or make any stray mark on the Answer Sheet.

Name of student

Roll No

Exam Hall

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BT Tests Bakliwal Tutorials - IIT
PHYSICS
SECTION - I
Single Correct Answer Type
This section contains 30 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of
which ONLY ONE is correct.

Q.1 A rescue plane is flying horizontally at a speed of 30 m/s and at an altitude of 125 m when it drops a
warning flare. Neglecting air resistance and assuming that the plane does not change its course, speed,
altitude, how far from the plane is the flare when it hits the ground?

(A) 146 m (B) 195 m (C) 125 m (D) 150 m

Solution: (C)

Since horizontal velocity of both are same so plane will always remain vertically above packet. Hence it
will be 125 m.

Q.2 A particle starts from the origin at t = 0 and moves in the x-y plane with constant acceleration a in the y-
direction. Acceleration of particle in x direction is zero. Its equation of motion is given by y  bx 2 . The
x-component of its velocity is

 2a  a a
(A) Variable (B)   (C) (D)  
 b  2b b

Solution: (C)

y  bx 2
dy dx
 2bx
dt dt

On differentiating again, we get

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2 2
d y  d x  dx  dx  
2
 2b  x 2    
dt  dt  dt  dt  
d2y   dx 2  d 2 x
 2b 0     as 2  0
dt 2   dt   dt
2
 dx 
a  2b  
 dt 
dx a
v 
dt 2b

PARAGRAPH FOR QUESTION NO. 3 & 4

An inclined plane makes an angle   45 with horizontal. A stone is projected normally from the inclined
plane, with speed u m/s at time t = 0 the x and y axis are drawn from the point of projection along and normal to
inclined plane as shown in the Figure. The length of incline is sufficient for stone to land on it and neglect air
friction.

Q.3 The instant of time at which velocity of stone is parallel to x-axis

2 2u 2u 2u u
(A) (B) (C) (D)
g g g 2g

Solution: (C)

vy  0
 u y  dyt  0
 u  g cos  t  0,
u u 2
t 
g cos  g

Q.4 The instant of time at which velocity of stone makes an angle   45 with positive x-axis is

2 2u 2u 2u u
(A) (B) (C) (D)
g g g 2g

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Solution: (D)

v y  vx
 u  g cos  t  g sin 6t
u u
t  
g(cos   sin ) g 2

Q.5 A particle is projected from a point O with a velocity u in a direction making an angle  with the
horizontal. At point P particle is moving at right angles to its initial direction. Its velocity at point P is

(A) u tan  (B) u cot  (C) u cos ec  (D) u sec 

Solution: (B)

v cos (90   )  u cos 


v  u cot 

Q.6 A ball is projected from a point at two different angles with same speed u and land at the same point in
both the cases. Then

(A) the difference between two angles of projection is 90

(B) The maximum height attained by the ball in both the cases is equal

(C) the sum of maximum heights for the two cases is u 2 /  2g 

(D) the maximum height attained by the ball in one case must be twice of the maximum height attained
by the ball in second case

Solution: (C)

(a) sum of angle is 90° not difference

(b) Max. height ∝ sin

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2 2
u sin 
(c) H1 
2g

 
u 2 sin 2     2 2
H2  2   u cos 
2g 2g
 H1  H 2  u 2 / (2g)

Q.7 At time t = 0 a particle leaves the origin with a velocity of 6 m/s in the positive y direction. Its
acceleration is given by ⃗ = 2 ̂ − 3 ̂ / . The x and y coordinates of the particle at the instant the
particle reaches maximum y coordinate are

(A) 2 m, 3m (B) 4 m, 6 m (C) 1 m, 3 m (D) 2 m, 6 m

Solution: (B)

Q.8 Jai is standing on the top of a building of height 25 m, he wants to throw his gun to Veeru who stands on
top of another building of height 20 m at a distances 15 m from the first building. For which horizontal
speed of projection, it is possible

(A) 5ms 1 (B) 10 ms 1 (C) 15ms 1 (D) 20 ms 1

Solution: (C)

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Q.9 In a rescue attempt, a stationary helicopter in air drops a life preserver to a drowning man (Velocity of
man with respect to river is zero) being swept downstream by a river current of constant velocity v. The
helicopter is at a height of 45 m. The man is 6.0 m upstream from a point directly under the helicopter
when the life preserver is released. It lands 3.0 m in front of the man. How fast is the current flowing?
Neglect air resistance.  g  10 m / s 2 

(A) 1m / s (B) 2m / s (C) 3m / s (D) 4m / s

Solution: (A)

2h
t  3s
g
x  vt
3  v3
 v  1m / s

Q.10 Two guns on a battleship simultaneously fires two shells with same speed at enemy ships. If the shells
follow the parabolic trajectories as shown, which ship will get hit first?

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(A) A (B) B (C) Both at same time (D) Need more information

Solution: (B)

Time of flight depends upon maximum height and maximum height for A is large in comparison to B.

Q.11 A student is standing on a train travelling along a straight horizontal track at a speed of 10 m/s. The
student throws a ball into the air along a path, that he sees to make an initial angle of 60 with the
horizontal along the track. The professor standing on the ground observes the ball to rise vertically, the
maximum height reached by the ball with respect to professor is

(A) 15 / 4m (B) 15 3 (C) 5 3 (D) 15 m

Solution: (D)

Vbt cos 60  10


Vbt sin 60  Vbg
Vbg  10 3
Vbg2 100  3
H   15 m
2g 20

Q.12 A swimmer swims in still water at a speed = 5 km/h. He enters a 200-m-wide river, having river flow
speed = 4 km/h, at a point A and proceeds to swim at an angle of 127  sin 37  0.6  with the river flow
direction. Another point B is located directly across A on the other side. The swimmer lands on the other
bank at a point C, from which he walks the distance CB with a speed = 3 km/h. The total time in which
he reaches from A to B is

(A) 5 min (B) 4 min (C) 3 min (D) None of these

Solution: (B)

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Given: Vbr  5km / h

v r  4 km / h
d  0.2 km
0.2
t
4
 0.05 h  3 min

BC  1km / h  0.05 h
0.05
t2   60
3
 1min
t1  t 2  4 min

Q.13 A boat having a speed of 5 km/h in still water crosses a river of width 1 km along the shortest possible
path in 15 min. The speed of the river in km/h is.

(A) 1 (B) 3 (C) 4 (D) 41

Solution: (B)

Vbr  5km / h
vr
sin  
5
d 4
t  cos  
v br cos  5
   37
vr
sin 37 
5
 v r  3km / h

Q.14 A river flows with a speed more than the maximum speed with which a person can swim in still water.
He intends to cross the river by the shortest possible path (i.e., he wants to reach the point on the opposite
bank which is directly opposite to the starting point). Which of the following is correct?
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(A) He should start normal to the river bank

(B) He should start in such a way that he moves normal to the bank, relative to the bank

(C) He should start in a particular (calculated) direction making an obtuse angle with the direction of
water current

(D) The man cannot cross the river in the desired way

Solution: (D)

We know that to cross the river by the shortest path,

u
sin  
v

But u  v  sin   1 , which is not possible

PARAGRAPH FOR QUESTION NO. 15 & 16

A car is moving towards south with a speed of 20 ms 1 . A motorcyclist is moving towards east with a speed
of 15ms 1 . At a certain instant, the motorcyclist is due south of the car and is at a distance of 50 m from the car.

Q.15 The shortest distance between the motorcyclist and the car is

(A) 10 m (B) 20 m (C) 30 m (D) 40 m

Solution: (C)

Taking N as + y-axis and E as + x Axis

Imagine yourself as an observer sitting inside the car. You will regard the car as being at rest (at C).
Relative to you, the speed of the motorcyclist is obtained by imposing the reversed velocity of the car on
motorcyclist as shown in Figure

vm  15ms1 , vc  20ms 1

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v mC  152  202  25 ms 1

Q.16 The time after which they are closest to each other

(A) 1/3 s (B) 8/3 s (C) 1/5 s (D) 8/5 s

Solution: (D)

 20 
  tan 1    15 with x  axis
 15 

The motorcyclist appears to move along the line MP with speed 25

The shortest distance = perpendicular distance of MP from

 C  d  d  50cos53  d  30 m

Time taken to come closest = time taken by motorcyclist to reach B

MB 50 sin 53
t   t  1.6 s
v mc 25

Q.17 For a man moving on a horizontal road at a uniform speed of 6 km/hr, rain appears to fall vertically
downwards. When he increases his speed to 12 km/hr rain appears to make 30 with vertical. Find speed
of rain with respect to ground

(A) 12 km/hr (B) 14 km/hr

(C) 16 km/hr (D) 10 km/hr

Solution: (A)

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Q.18 The acceleration of a particle is increasing linearly with time t as a   t . If the particle starts from the
origin with initial velocity u, the distance travelled by it in t second is

1 1 1  t3
(A) ut   t 3 (B) ut   t 3
2
(C) ut   t 3 (D) ut 
2 2 3 6

Solution: (D)

a  t
dv  t.dt
t
v  t2 
 vu   
 2 0
t 2
vu 
2
t 2
v u
2
 t 2 
dx    u  .dt
 2 
 t 3 
x  ut 
 6 

Q.19 The position-time graph of a moving particle is shown in the figure. Shape of curves from t=0 to t=1 and
t=1 to t=2 is parabolic. The velocity-time graph is best given by

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(A) (B)

(C) (D)

Solution: (A)

From figure

For time interval t = 0 to t = 1s

Slope of x-t graph is negative and increasing, so velocity increases in negative direction

For t = 1 to 2 s

The slope is +ve and decreasing, so velocity is decreasing in +ve direction and become zero at t = 2

Q.20 The acceleration-time graph of a moving particle is shown in the figure. The velocity-time graph is given
by

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(A) (B)

(C) (D)

Solution: (A)

As acceleration is increasing slope of v-t curve continuously increases with velocity increasing as
acceleration is decreasing but velocity is increasing though slope is decreasing.

Q.21 The time when relative motion between the blocks will stop is

(A) 1 s (B) 2 s (C) 3 s (D) 4 s

Solution: (A)

Q.22 A block of mass 2 kg is on a horizontal surface. The co-efficient of static and kinetic frictions are 0.6 and
0.2. The minimum horizontal force required to start the motion is applied and if it is continued, the
velocity acquired by the body at the end of the 2nd second is  g  10 ms 2 

(A) 8ms 1 (B) 4 ms 1 (C) 2 ms 1 (D) Zero

Solution: (A)

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F  s mg  12N
f k  4N
F  fk
a  4ms 2
m
v  at  8 m / s1

Q.23 A given object takes m times as much time to slide down a 45 rough incline as it takes to slide down a
perfectly smooth 45 incline. The coefficient of kinetic friction between the object and the incline is
given by

1 1 1 1
(A)  k  (B)  k  1  (C)  k  1  (D)  k 
1  m 2  m2 m2 1  m2

Solution: (B)

1 g  2
S  t ;
2 2
1 g g  2
S    (t m )
2 2 2
1
1  1   k  m 2   k  1 
m2

Q.24 A particle is moving along x-axis with v  t 2  7t  10 . The distance it covers between t = 1s and t = 3s is

(A) 3m (B) 1.5m (C) -1.5m (D) 0m

Solution: (A)

Q.25 Acceleration of a particle moving along a straight line is given by a = 2t – 1. If its velocity at t = 1s is -
20m/s then its velocity at t = 6 s is

(A) -10 m/s (B) 10 m/s (C) 35 m/s (D) 46 m/s

Solution: (B)

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Q.26 The velocity-time graph of a body moving in a straight line is shown in the figure. The ratio of
displacement to the distance travelled by the body in first 6 second is :

(A) 1 : 1 (B) 1 : 2 (C) 1 : 3 (D) 1 : 4

Solution: (B)

Q.27 Two particles 1 and 2 are moving with velocities ⃗ = (4 ̂ − 3 ̂) / and ⃗ = ( ̂ − ̂) /


respectively. The position vectors of the particles at time t = 0 are ⃗ = (5 ̂ + 2 ̂) and

⃗ = (−4 ̂ − 4 ̂) . If they collide at t = 3s, the value of b is:

10
(A) (B) 5 (C) -1 (D) 7
3

Solution: (D)

⃗ +⃗ = ⃗ +⃗

(5 ̂ + 2 )̂ + (4 ̂ − 3 ̂)(3)

= (−4 ̂ − 4 ̂) + ( ̂ − ̂)(3)

17 ̂ − 7 ̂ = (−4 + 3 ) ̂ − 7 ̂

So, (3 − 4) = 17 ⇒ =7

Q.28 A man throws a ball making an angle of 60 with the horizontal. He runs on a level ground with constant
velocity and catches the ball at the same horizontal level as it was thrown. If he had thrown the ball with
speed 4 m/s, then his speed of running must be

(A) 4 m/s (B) 2 m/s (C) 8 m/s (D) 2 3 m / s

Solution: (B)

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Vmax  Vballin horizontal
 Vball cos 60
 4 cos 60
 2 ms -1

Q.29 Two trucks are moving on parallel tracks. A person on one truck projects a ball vertically upward then
path of the ball as seen by four observers : from the ground, from the second truck moving with same
velocity as that first truck, from the second truck moving with speed greater than first one in same
direction and from the second truck moving with speed less than the first truck in same direction are:

(A) Parabola, parabola, parabola and parabola

(B) straight line, straight line, parabola and parabola

(C) parabola, straight line, parabola and parabola

(D) None of the above

Solution: (C)

For the first, third and fourth observer velocity ball and g are neither parallel or anti-parallel so that the
path will be parabola. For the second observer velocity of the ball and g are parallel so that the path will
be straight line

Q.30 An airplane flies northwards from town A to town B and then back again. There is a steady wind blowing
towards the north so that for the first stage of the trip, the airplane is flying in the same direction as the
wind and for the return half of the journey, the airplane is flying directly into the wind. The total trip time
Tw , as compared to the total trip time in the absence of any wind To , obeys:

(A) Tw  To (B) Tw  To (C) Tw  2To (D) Tw  To

Solution: (D)

d d 2du
Tw    2
v  u v  u v  u2
v  speed of plane
u  speed of wind
2d 2d
Tw  2
TO  Clearly
 2 u  v
v  
 v 
Tw  TO

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CHEMISTRY
SECTION - I
Single Correct Answer Type
This section contains 30 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of
which ONLY ONE is correct.

Q.1 The vapour density of a mixture containing equal number of moles of methane and ethane at STP is

(A) 11.5 (B) 11.0 (C) 23 (D) 12.0

Solution: (A)

Molar mass of mixture will be

n  Molar mass of CH 4  n  Molar mass of C 2 H 6


M mix 
nn
n 16  30 
M mix   23
2n
M 23
Vapour density  mix   11.5
2 2

Q.2 Which of the following has maximum ionic character?

(A) LiCl (B) NaCl (C) KCl (D) CsCl

Solution: (D)

Cl is common hence larger the cation more will be the ionic character (Fajan’s rule). Hence CsCl
will have highest ionic character.

Q.3 In which of the following reactions hybridization of underlined species is not changing?

(A) NH 3  H   NH 4 (B) BF3  F   BF4 (C) C2 H 2  H2  C2 H6 (D) All of these

Solution: (A)

NH 3  H   NH 4
sp3 sp3

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Q.4 A partially dried clay mineral contains 8% water. The original sample contains 12% water and 45%
silica. The % of silica in the partially dried sample is nearly.

(A) 50% (B) 49% (C) 55% (D) 47%

Solution: (D)

Let original sample weighs  g

12 45
water  , silica  x
100 100
43
Im purities  x
100

Partially dried sample weight y g

8
Water  y
100

Since no evaporation of silica & impurities. So,

45 43 92 92
 x yx  y
100 100 100 88

45
x
% of silica in partially dried sample  100  100  47%
y

1 1
Q.5 If the mole fraction of a solute is changed from to by adding some solute in the 800 g of H 2 O
4 2
solvent, then the ratio of molality of two solutions will be:

(A) 1 : 3 (B) 1 : 4 (C) 2 : 3 (D) 1 : 2

Solution: (A)

x A 1000
Molality 
1  x A  mB
0.25 1000
First solution’s molality 
0.75 18

0.5 1000 1
Second solution’s molality   Molality ratio 
0.5 18 3

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Q.6 Which electronic level would allow the hydrogen atom to absorb a photon but not to emit a photon
(A) 3s (B) 2p (C) 2s (D) 1s

Solution: (D)

Fact based.

Q.7 Which does not favour the formation of ionic compound:

(A) the ionization energy of the metal atom should be low

(B) the lattice energy of the compound formed must be low

(C) the electron affinity of the non-metal should be high

(D) the lattice energy of the compound formed must be high

Solution: (B)

Q.8 In C3 O2 the hybridization state of carbon is:

(A) sp (B) sp 2 (C) sp3 (D) Both sp and sp 2

Solution: (A)

OCCCO

Q.9 A particle initially at rest having charge q coulomb. & mass m kg is accelerated by a potential difference
of V volts, what would be its K.E. & de-broglie wavelength respectively after acceleration

h h h h
(A) qV, (B) , qV (C) qV, (D) , qV
2qVm 2qVm mV mV

Solution: (A)

Fact based.

Q.10 The electron affinity of a hypothetical element ‘A’ is 3eV per atom. How much energy in kcal is
released when 10g of ‘A’ is completely converted to A  ion in a gaseous state?

( 1ev per atom  23 kcal mol 1 , Molar mass of A = 30)

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(A) 23 kcal (B) 46 kcal (C) 50 kcal (D) 52 kcal

Solution: (A)

A  e  A   3eV
30 3  23kcal

3  23
 Energy released for conversion of 10g gaseous A into A  ions  10  23kcal
30

Q.11 Which of the following is paramagnetic?

(A) O 2 (B) CN  (C) CO (D) NO

Solution: (A)

It has one unpaired electron.

Q.12 The distance between 4th and 3rd Bohr orbits of He  is:

(A) 2.645 1010 m (B) 1.322 1010 m (C) 1.8511010 m (D) None

Solution: (C)

n2 
r  0.529 A
Z
 16 9  
r4  r3  0.529    A  1.851 10 10 m
 2 2

Q.13 First, second & third ionization energies are 737, 1045 & 7733 KJ/mol respectively. The element can be:

(A) Na (B) B (C) Al (D) Mg

Solution: (D)

Mg has two electrons in its s-subshell after removing these electrons it will obtain inert gas configuration.
So, a big jump in I.E. will be there

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2
Q.14 The correct order of hybridization of the central atom in the following species NF3 , BF3 , PF5 and SiF6 
is:

(A) sp 2 ,sp3 , sp3d 2 ,sp3d (B) sp3 , sp 2 ,sp3d,sp 3d 2

(C) sp 2 ,sp3 ,sp3d,sp 3d 2 (D) sp3 ,sp 2 ,sp3d,sp 3d 3

Solution: (B)

Q.15 Which of the following arrangements is correct on the basis of the increasing p-character of the hybrid
orbitals of the central atoms in the following:

(I) CIO 2 (II) CS2 (III) SnCl2

(A) I > III > II (B) II > I > III (C) I > II > III (D) III > I > II

Solution: (A)

Q.16 Which of the following are isostructural?

(I) NO3 (II) CO32  (III) CIO3 (IV) SO 3' (V) XeO3

(A) (I) and (IV) (B) (II) and (V) (C) (III) and (IV) (D) (IV) and (V)

Solution: (A)

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Q.17 Which of the following is a planar molecule?

(A) XeO 2 F2 (B) XeOF3 (C) XeF4 (D) XeF6

Solution: (C)

Q.18 Which one of the following represents the INCORRECT decreasing order of bond angles?

(A) CO 2  BF3  CH 4  H 2 O (B) NO 2  NO 2  NO 2

(C) BCl3  PCl3  AsCl3  BiCl3 (D) IO3  BrO3  CIO3

Solution: (D)

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Q.19 Which set does not show correct matching?

(A) Sc3  Ne 3s 2 3p6 zero group (B) Fe2  Ar  3d6 8th group

(C) Cr  Ar  3d5 4s1 6th group (D) All of the above

Solution: (A)
18 18
21 Sc3 ;  Ar  3d 0 4s 0 and 21 Sc;  Ar  3d1 4s 2

As last electron enters in d-subshell so it belongs to d-block and thus its group number = 2 + 1 = 3

Sc3 belong to 3rd group of d-block, not zero group.

Q.20 Among the following, the pair in which the two species are not isostructural is

(A) IO 3 and XeO 3 (B) AlH 4 and PH 4 (C) AsF6 and SF6 (D) SiF4 and SeF4

Solution: (D)

Q.21 The maximum number of atoms which lie in the same plane in B2 H 6 molecule is:

(A) 5 (B) 6 (C) 4 (D) 8

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Solution: (B)

Four terminal hydrogen atoms and the two boron atoms lie in one plane in B2 H 6 .

Q.22 Arrange the following compounds in increasing order of their ionic character

SnCl2 ,SnCl 4 ,SiCl 4 ,SnF4 ,SnF2

(A) SnF2  SnCl2  SnF4  SnCl 4  SiCl 4 (B) SnF2  SnCl2  SnF4  SiCl 4  SnCl 4

(C) SiCl4  SnCl4  SnF4  SnCl 2  SnF2 (D) SnCl4  SnF4  SnCl 2  SnF2  SiCl 4

Solution: (C)

As the size of the cations increases in the order Si 4  Sn 4  Sn 2 and the size of anions, F  Cl

So, the order of increasing ionic character is, SiCl4  SnCl4  SnF4  SnCl 2  SnF2 .

Q.23 Which of the following statements are correct?

(I) In ICl2 , CIF3 and TeCl4 , the number of lone pair(s) of electron on central atoms are 3, 2 and 1
respectively.

(II) Amongst CO, CO 2 , CO 32  , CH 3OH , the correct order from the weakest to the strongest

carbon-oxygen bond is CH 3OH  CO 32  CO 2  CO

(III) The hybridization of boron in BF3 is the same which nitrogen has in CINO molecule.

(A) Only I and III (B) II (C) Only I & II (D) I, II & III

Solution: (D)

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Q.24 The correct order of strength of H-bond in the following compound:

(A) H 2 O  H 2 O 2  HF  H 2S (B) HF  H 2 O 2  H 2 O  H 2S

(C) HF  H 2 O  H 2S  H 2O 2 (D) HF  H 2 O  H 2O 2  H 2S

Solution: (D)

Strength of H-bonding is higher in H 2 O , than H 2 O2 because the amount of formal negative charge on
oxygen atom in case of water is more than that of H 2 O2 .

Q.25 Give the correct order of initials T or F for following statements. Use T if statements is true and F it is
false:

(I) The order of repulsion between different pair of electrons is lp  lp  l p  b p  b p  b p

(II) In general, as the number of lone pair of electrons on central atom increases, value of bond angle
from normal bond angle also increases

(III) The number of lone pair on O in H 2 O is 2 while in N in NH 3 is 1

(IV) The structures of xenon fluorides and xenon oxy fluorides could not be explained on the basis of
VSEPR Theory.

(A) TTTF (B) TFTF (C) TFTT (D) TFFF

Solution: (B)

(II) (F) In general as the number lone pair of electrons on central atom increases, value of bond angle
from normal bond angle decreases due to lp – lp > lp – bp.

(iv) (F) Structure of xenon fluorides and xenon oxy fluoride are explained on the basis of VSEPR theory

Q.26 In a molecule, the ionic charge is 4.8 × 10 esu. If the interionic distance is 1 unit, then the dipole
moment is

(A) 0.48 debye (B) 4.18 debye (C) 4.8 debye (D) 41.8 debye

Solution: (C)

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Q.27 Two types of carbon – carbon covalent bond lengths are present in

(A) Carbonate Ion (B) (C) Propene (D) Benzene

Solution: (C)

Q.28 Which of the following atomic orbitals overlapping are not allowed for bonding?

(A) All (B) (i) (ii) (iii) (C) (i)(iii)(v) (D) (ii) only

Solution: (B)

Fact based.

Q.29 The mole fraction of the solute in the 12 molal solution of Na 2 CO3

(A) 0.822 (B) 0.177 (C) 1.77 (D) 0.017

Solution: (B)

m Na 2CO3  12
n Na 2 CO3  12
1000
n H 2O   55.55
18
12
x Na 2CO3   0.177
12  55.55

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Q.30 Number of electrons having + value equal to zero in 26 Fe may be

(A) 13 (B) 18 (C) 7 (D) 12

Solution: (A)

MATHS
SECTION - I
Single Correct Answer Type
This section contains 30 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of
which ONLY ONE is correct.


be the set of integers. If A  x  Z : 2  x  2  x 
 B   x  Z: 3  2x 1  9 , then the
2
5 x  6
Q.1 Let  1 and

number of subsets of the set ∪ , is:

(A) 2 (B) 2 (C) 2 (D) 2

Solution: (C)

n 10
1
Q.2 If Sn   Tr  n  n  1 n  2 n  3, then  T is equal to:
r 1 r 1 r

(A) 65 (B) 75 (C) 65 (D) 58


1056 1056 528 528

Solution: (A)

3 13 5  1  2  7  1  2  3 
3 3 3 3 3

Q.3 The Sum 2


 2 2
 2 2 2
 ....... up to 10th term, is
1 1 2 1  2 3

(A) 680 (B) 600 (C) 660 (D) 620

Solution: (C)

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Q.4 Let , be positive real numbers and , positive integers. The maximum value of the expression
m n
x y
1  x 1  y 2 n 
2m

(A) 1 (B) 1 (C) 1 (D) m  n


2 4 6mn

Solution: (C)
3 3 3 3
3  1  1  3
Q.5 If the sum of the first 15 terms of the series     1    2   33   3   ...... is equal to 225 ,
4  2  4  4
is equal to:

(A) 108 (B) 27 (C) 54 (D) 9

Solution: (B)

Q.6 The sum of the solutions of the equation x 2  x  


x  4  2  0,  x  0  is equal to:

(A) 9 (B) 12 (C) 4 (D) 10

Solution: (D)

Q.7 Let and be the roots of the quadratic equation x 2sin   x  sin  cos    cos     0    o  , and
 n  1n 

< . Then    n  is equal to:
n 0
  

1 1 1 1
(A)  (B) 
1  cos  1  sin  1  cos  1  sin 

1 1 1 1
(C)  (D) 
1  cos  1  sin  1  cos  1  sin 

Solution: (C)

Q.8 If three distinct numbers a, b, c are in G.P. and the equations ax 2  2bx  c  0 and dx 2  2ex  f  0
have a common root, then which one of the following statements is correct?

(A) d , e , f are in A.P. (B) d, e, f are in A.P.


a b c
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(C) d, e, f are in G.P. (D) d , e , f are in G.P.
a b c

Solution: (A)

Q.9 The number of integral values of m for which the quadratic expression,
1 2m x2  2 1  3m x  4 1 m , x  R , is always positive, is:
(A) 3 (B) 8 (C) 7 (D) 6

Solution: (C)

such that sum of the squares of the roots of the quadratic equation , x   3  x  2  
2
Q.10 The values of
has the least value is:

(A) 15 (B) 1 (C) 4 (D) 2


8 9

Solution: (D)

Q.11 Let f k  x   1  sin k x  cos k x  for = 1, 2, 3, …. Then for all xR , the value of f4  x  f6  x  is equal
k
to:

(A) 1 (B) 1 (C) 1 (D) 5


12 4 12 12

Solution: (A)

Q.12 If cos       3 , sin       5 and 0      then tan  2 is equal to:


5 13 4

(A) 63 (B) 63 (C) 21 (D) 33


52 16 16 52

Solution: (B)

Q.13 The least value of the expression 2log10 x  logx 0.01, for x  1, is _______.

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(A) 10 (B) 4 (C) 2 (D) −2

Solution: (B)

Q.14 If sin   cos ec   2, the value of sin 10   cos ec 10  is

(A) 10 (B) 2 (C) 2 (D) 2

Solution: (D)

Q.15 Evaluate log5 log2 log3 log2 512

(A) 1 (B) 0 (C) 2 (D) −1

Solution: (B)

Q.16 The value of cos15 o  sin 15 o is equal to

1 1
(A) (B) 1 (C)  (D) 0
2 2 2

Solution: (A)

Q.17 If 1, log 9  31 x  2  , log 3  4.3x  1 are in A. P. then equals

(A) log3 4 (B) 1log3 4 (C) 1 log4 3 (D) log4 3

Solution: (B)

cos17o  sin17o
Q.18 
cos17o  sin17o
(A) tan 62 o (B) tan 56 o (C) tan 54 o (D) tan 73 o

Solution: (A)

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3 1
Q.19    , then 2cot   is equal to
4 sin 2 

(A) 1  cot  (B) 1  cot  (C) 1  cot  (D) 1  cot 

Solution: (B)

sin 3  sin 5   sin 7   sin 9 


Q.20 is equal to
cos 3  cos 5   cos 7   cos 9 

(A) tan3 (B) cot3 (C) tan 6 (D) cot6

Solution: (C)

Q.21 The value of tan27o  tan18o  tan27o tan18o , is

(A) An irritational number

(B) Rational which is not integer

(C) Integer which is prime

(D) Integer which is not a prime

Solution: (D)

Q.22 If tan A and tan B are the roots of the quadratic equation x2 ax b  0, then the value sin2  A  B is:

a2 a2 a2 a2
(A) (B) 2 2 (C) (D)
a 2  1  b 
2
a b b  a 
2
b 2 1  a 
2

Solution: (A)

Q.23   
Let P   : sin   cos   2 cos  and Q   : sin   cos   2 sin  be two sets. Then:
(A) P  Q Q  P   (B) Q  P (C) P  Q (D) P  Q

Solution: (D)

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tan A cot A
Q.24 The expression  can be written as:
1  cot A 1  tan A

(A) sin A cos A  1 (B) sec A cos ec A  1 (C) tan A  cot A (D) sec A  cos ec A

Solution: (B)

Q.25 If      and      , then tan equals


2

(A) 2  tan   tan   (B) tan   tan  (C) tan    tan  (D) 2 tan   tan 

Solution: (C)

Q.26 Let        . Suppose 1 and 1 are the roots of the equation x 2  2x sec   1  0 and 2 and 2
6 12
are the roots of the equation x 2  2x tan      . If 1 1 and 2 2, then 1 2 equals

(A) 2  sec   tan   (B) 2 sec  (C) 2 tan  (D) 0

Solution: (C)

such that f  x   x  px  q has a factor x 2  3x  2 is


4 2
Q.27 The value of and

(A) = 4, = 5 (B) = −1, = −4 (C) = −5, = −4 (D) = 5, =4

Solution: (D)

Q.28 If   are the roots of ax 3  bx  c  0 , then the equation whose roots are          is

(A) ax 3  bx  c  0 (B) ax 3  bx  c  0 (C) cx 3  bx  c  0 (D)  ax 3  bx 2  c  0

Solution: (B)

such that  n  2 x  8x  n  4  0 x  R where n  N .


2
Q.29 The least value of

(A) 5 (B) 6 (C) 4 (D) 7


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Solution: (A)

Q.30 Number of solutions of log4  x 1  log2  x  3 is

(A) 3 (B) 1 (C) 2 (D) 0

Solution: (B)

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