EQUILIBRIO LIQUIDO-LIQUIDO: METANOL(1) - AGUAL(2) IDEAL ISOTERMICO

TORRES DE LA CRUZ JHYNO FREDY

ISOTERMICO DATOS EXPERIMENTAL
METANOL(1) AGUA (2) X exp Yexp P(Kpa)
VP_A -8.54796 -7.76451 0 0 19.953
VP_B 0.76982 1.45838 0.1636 0.5714 39.223
VP_C -3.1085 -2.7758 0.2167 0.6268 42.984
VP_D 1.54481 -1.23303 0.3039 0.6943 48.852
Pc (kpa) 8090 22120 0.3681 0.7345 52.784
Tc(K) 512.6 647.3 0.4461 0.7742 56.652
T(K) 333.15 333.15 0.5282 0.8085 60.614
0.6044 0.8383 63.9998
0.6804 0.8733 67.924
(METANOL)X= 0.350078033554 0.7255 0.8922 70.229
(AGUA)X= 0.485323652093 0.7776 0.9141 72.832
1 1 84.562
Pvp1 Pvp2 http://www.ciiq.org/varios/peru_2005/Trabajos/V/3/5.3.02.pdf
84.6540765 19.94065188829

X1 X2 Pvp1 Pvp2 P Y1 Y2 Y1+Y2

0.05 0.95 84.6540765 19.9406519 23.1763231 0.18263051 0.81736949 1
0.1636 0.8364 84.6540765 19.9406519 30.5277682 0.45366588 0.54633412 1
0.2 0.8 84.6540765 19.9406519 32.8833368 0.51487522 0.48512478 1
0.3 0.7 84.6540765 19.9406519 39.3546793 0.64531648 0.35468352 1
0.4 0.6 84.6540765 19.9406519 45.8260217 0.73891709 0.26108291 1
0.5 0.5 84.6540765 19.9406519 52.2973642 0.80935318 0.19064682 1
0.6 0.4 84.6540765 19.9406519 58.7687067 0.86427708 0.13572292 1
0.7 0.3 84.6540765 19.9406519 65.2400491 0.90830486 0.09169514 1
0.8 0.2 84.6540765 19.9406519 71.7113916 0.94438638 0.05561362 1
0.9 0.1 84.6540765 19.9406519 78.182734 0.97449481 0.02550519 1

0
0.2
0.4
0.6
EQUILIBRIO LIQUIDO-LIQUIDO: METANOL(1) - AGUAL(2) IDEAL ISOTERMICO

0.8
1
1.2

X vs Y
1
0.9
0.8
0.7
Y1

EXPERI
0.6 MENTAL
0.5 OBTENI
DOS
0.4
.
0.3
0.2
0.1
0
0 0.1 0.2 0.3 0.4 0.5
X1 0.6 0.7 0.8 0.9 1

Presion vs Xexp,Yexp

90
80
Presion

70
60
50
40 0 0
EXP 0.2 EXP 0.2
30
20 0.4 0.4
0.6 0.6
10 OBTE 0.8 OB 0.8
0 1 1
0 0.2 0.4 0.6 0.8 1 1.2
Xexp,Yexp
 ELV METHANOL(1) - CYCLOHEXANE(2) IDEAL ISOBARICO

METHANOL(1)CYCLOHEXANE(2)
TC 512.5 560.5
PC 80.9 43.4
VpA -8.54796 9.2041
VpB 0.76982 2813.53
VpC -3.1085 -49.98
VpD 1.54481

P(constante) 1.01

x1 x2 T X(1) Pvp1 Pvp2

0 1 356.00351469 0.3053589957198 2.00768677 1.01031688
0.05 0.95 354.44271347 0.3084044615247 1.90051715 0.96380396
0.1 0.9 352.94854504 0.3113199121216 1.80236933 0.92086521
0.15 0.85 351.64635746 0.3138607659222 1.72026742 0.88468083
0.2 0.8 350.40705977 0.3162789077623 1.64501402 0.85129053
0.25 0.75 349.24974234 0.3185370881248 1.57720806 0.82101168
0.3 0.7 348.1645333 0.3206545691797 1.51573686 0.79339586
0.35 0.65 347.14327741 0.3226472635814 1.45970728 0.76808113
0.4 0.6 346.17915895 0.3245284703329 1.40839292 0.7447715
0.45 0.55 345.2664225 0.3263094195038 1.36119609 0.72322223
0.5 0.5 344.40016274 0.3279996824601 1.31761987 0.70322881
0.55 0.45 343.57616366 0.3296074855356 1.27724721 0.68461882
0.6 0.4 342.79077402 0.3311399531318 1.23972511 0.66724567
0.65 0.35 342.04080956 0.3326032984178 1.2047525 0.65098379
0.7 0.3 341.29290252 0.3340626292298 1.17069438 0.63508087
0.75 0.25 340.59909109 0.3354164076273 1.13981756 0.62060512
0.8 0.2 339.93243007 0.3367172096253 1.11078878 0.60694368
0.85 0.15 339.29094721 0.3379688834957 1.08343857 0.59402465
0.9 0.1 338.67287839 0.3391748714377 1.05761818 0.58178473
0.95 0.05 338.07663937 0.3403382646353 1.03319651 0.5701679
1 0 337.50080224 0.3414618492907 1.01005746 0.55912441

X y TK
0.0083 0.2677 345.29
0.013 0.3247 342.95
0.0238 0.4093 338.99
0.0292 0.4488 336.94
0.0347 0.4901 334.77
0.0488 0.5215 333.12
0.068 0.5454 331.68
0.0868 0.5604 330.82
0.1248 0.5774 329.93
0.1658 0.5868 329.4
0.2344 0.595 328.96
0.2859 0.5992 328.78
0.3557 0.6022 328.7
0.4205 0.6064 328.67
0.4656 0.6098 328.62
0.5166 0.6127 328.54
0.5782 0.6163 328.51
0.635 0.6188 328.5
0.6934 0.6238 328.5
0.7497 0.6318 328.51
0.7916 0.6414 328.59
0.8342 0.6554 328.93
0.8804 0.6847 329.51
0.9137 0.7216 330.42
0.9476 0.7849 331.99
0.9656 0.8364 333.11
 DATOS EXPERIMENTALES
ISOBARICO
345.29
342.95
338.99
336.94
334.77
333.12
331.68
330.82
329.93
329.4
328.96
328.78
y1 y2 y1+y2 328.7
0 1.00031374 1.00031374 328.67
0.09408501 0.90654828 1.00063328 328.62
0.17845241 0.82057296 0.99902536 328.54
0.25548526 0.74453337 1.00001863 328.51
0.32574535 0.67428953 1.00003488 328.5
0.39039803 0.60966214 1.00006017 328.5
0.45021887 0.54987832 1.00009719 328.51
0.50583916 0.49430964 1.00014879 328.59
0.55777937 0.44243852 1.00021789 328.93
0.60647351 0.39383389 1.00030739 329.51
0.65228706 0.34813307 1.00042014 330.42
0.69553066 0.30502819 1.00055884 331.99
0.73647036 0.26425571 1.00072607 333.11
0.77533577 0.22558844 1.00092421
0.81137234 0.18863788 1.00001022
0.84639918 0.15361513 1.00001431
0.8798327 0.12018687 1.00001957
0.91180474 0.08822148 1.00002622
0.94243204 0.05760245 1.00003449
0.9718185 0.02822613 1.00004463
1.00005689 0 1.00005689