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Welcome Address

On behalf of the Organizing Committee, it is my great pleasure to welcome you to the 1st
International Conference on Chemistry and Science Education (ICChSE). The theme of the conference
is “Accelerating and fostering research’s innovations in chemistry and Science Education to meet the
challenges of the 5th industrial revolution ”. This conference is organized by Department of Chemistry,
Universitas Negeri Padang in collaboration with Faculty of Sciences and Mathematics of Universiti
Pendidikan Sultan Idris, Malaysia. The main objective of this conference is to provide opportunity for
academics, researchers, professionals, practitioners, observers, teachers and students to present their
current research in chemistry and related fields as well as current issues in science education (chemistry,
biology and physics).
The conference spans a broad area of research in the field of chemistry and science learning
including but not limited to organic chemistry, inorganic chemistry, physical chemistry, analytical
chemistry, biochemistry, and science instruction. The conference will feature invited plenary talks by
prominent speakers in the field of chemistry and chemistry learning from national and overseas
researchers. All papers presented in 1st ICChSE 2020 will be reviewed and selected for publication in a
proceeding and journal indexed by Scopus.

Best Regards,

Fitri Amelia, M.Si., Ph.D.


(General Chair)

i
ii
Rundown

iii
iv
CONTENTS

Welcome Address………………................……………………………………………………………………i
ICChSE 2020 Program……..........……………………………………………………………………………..ii
Rundown…………………..............……………………………………………………………………………..iii
Abstract of Keynote Speaker 1………………………………………………………………………………….1
Abstract of Keynote Speaker 2………………………………………………………………………………….2
Abstract of Keynote Speaker 3………………………………………………………………………………….3
Abstract list of Room A………………………………………………………………………………………......4
Abstract list of Room B…………………………………………………………………………………………..16
Abstract list of Room C…………………………………………………………………………………….........32
Abstract list of Room D……………………………………………………………………..……….................46
Abstract list of Room E……………………………………………………………………………....................58
Abstract list of Room F……………………………………………………………………………....................71

v
Keynote Speaker 1

Sustainable Aviation Biofuels and the Impact to Climate Change

Y.H. Taufiq-Yap1,2*, G. Abdulkareem-Alsultan1 and N. Asikin-Mijan3

1ChancelleryOffice, Universiti Malaysia Sabah, 88400 Kota Kinabalu, Sabah, Malaysia 2Catalysis
Science and Technology Research Centre (PutraCAT), Faculty of Science, Universiti Putra Malaysia,
43400 UPM Serdang, Selangor, Malaysia
3Department of Chemical Science, Faculty of Science and Technology, Universiti Kebangsaan

Malaysia, 43600 UKM, Bangi, Selangor, Malaysia.

Abstract. Over 2.2 billion passengers flew all over the world with about 15 thousand aircrafts for many
reasons. Aviation industries created many jobs worldwide and contributed nearly 8% to world gross
domestic product. Even though air transportation become so important, unfortunately it gave a significant
impact to The environment. Projections anticipate 5% annual growth in airline passengers up to 2050,
with emissions reaching 3,100 Mt annually in a high growth scenario. Aviation sector has to play a bigger
role in order to reduce the global greenhouse gas (GHG) emissions. Air transportation become important.
Aviation industry generates 32 million jobs worldwide and contributes nearly 8% to world gross domestic
product. However, the aviation industry gave impact on climate change. As the aviation skies continue to
crowd so does the impact of CO2 emissions. This lecture will review the challenges facing for the
sustainable aviation biofuels industry and how the catalytic manufacturing process can be reducing
carbon footprint.

1
Keynote Speaker 2

Implementing active learning


strategies in university science

Mauro Mocerino
School of Molecular and Life Sciences, Curtin University, Australia

2
Keynote Speaker 3
Overview of Inulin as Prebiotic and Inulin Hydrolyzing Enzymes

Minda Azhar

Biochemistry Laboratory, Faculty of Mathematics and Natural Sciences, Universitas Negeri Padang,
Jl. Prof. Hamka, Air Tawar, Padang 25131, Indonesia

E-mail: minda@fmipa.unp.ac.id
Abstract. Inulin is a natural polysaccharide that is the second largest carbohydrate group in nature.
Inulin is a polymer with monomer of fructose. Glucose can be attached to the end of inulin polymer.
Hence, the general formula of inulin can be written as either Fn or GFn. Inulin is a good prebiotic that
can increase the amount of Bifidobacteria and Lactobacilli bacteria to generate short chain fatty acids
(SCFA), decreases pH of colon, decreases the growth of pathogenic bacteria, prevents intestinal
cancer and enhances the absorption of Ca, Mg, and Fe. Hydrolyzing of inulin can use inulinase
enzymes. Inulin hydrolysis using an exo-inulinase can produce fructose, whereas using endo-inulinase
produces Fructooligosaccharides (FOS). The tertiary structure of exo-inulinase and endo-inulinase as
a whole fold to form two domains, namely β-propeller in the N-terminal domain (Domain 1) and β-
sandwich in the C-terminal domain (Domain 2). These two domains are connected by loops. The article
is overview of inulin as prebiotic and inulin hydrolyzing enzyme, especially inulinase.

3
International Conference on Chemistry and Science Education 2020
(ICChSE 2020) Parallel Seminar

Science Education Topics


Name List
Room A
Meeting Link:
https://us02web.zoom.us/j/81051980178?pwd=YXUxU3BSMHVORWtDamp1alRMYmxjdz09
Meeting ID: 810 5198 0178
Passcode: 214409
Time (Westren
No Indonesia Time Name Abstract Title
UTC: +7)
1 13.30-13.40 Agustini, S.Pd The Development and Validity of CPS-
Based Assessment Instrument for
Critical Thinking Ability on
Stoichiometry Materials
2 13.40-13.50 Yandriani, S.Si The Development and Validation of
Assessment Instruments to Measure
Students’ Analytical Thinking Ability
and Chemical Literacy on Colligative
Properties
3 13.50-14.00 Vina Septiani, S. Pd. Development of a Test Instrument to
Measure HOTS and Cognitive
Knowledge in Biology
14.00-14.15 QnA presenter 1-3
4 14.15-14.25 Eka Yusmaita Test Item analysis of chemical literacy:
a validity and reliability assessment
5 14.25-14.35 Dr. FRANCISCA DIANA Correlation between Cumulative
ALEXANDRA,M.Sc Achievement Index (GPA) of
Undergraduate And Professional
Programs with the Medical Student
Profession Program of Medical Faculty
score of FK UPR
6 14.35-14.45 Nurul Jannah Yuliani, Challenges towards the implementation
S.Pd. of ICT in biology learning: a review
study
14.45-15.00 QnA presenter 4-6
7 15.00-15.10 Rody Putra Sartika The improvement of students'
conceptual understandings through the
PQ4R aided the 5E learning cycle
model on the topic of salts hydrolysis.
8 15.10-15.20 Anna Juniar The Difference of Students’ Science
Process Skills and Learning Activities in
Guided Inquiry and Direct Instruction

4
with Practicum
9 15.20-15.30 Dr. Rusmansyah, M. Pd. Training Of Scientific Literation And
Self Efficacy Of Students Using
Scientific Critical Thinking (Sct) Models
15.30-15.45 QnA presenter 7-9
10 15.45-15.55 Zonalia Fitriza, M.Pd. Cross-Sectional Approach for
Diagnosing Student’s Learning
Progression in
Relation to Pre-requisite Knowledge of
Buffer Solution
11 15.55-16.05 -
12 16.05-16.15 -
16.15-16.30 QnA presenter 10-12
13 16.30-16.40 -
14 16.40-16.50 -
15 16.50-17.00 -
17.00-17.15 QnA presenter 13-15

5
ID ICC00029

The Development and Validity of CPS-Based Assessment Instrument for Critical Thinking Ability
on Stoichiometry Materials
Agustini1, R U Rery2 and L Anwar 3
1Postgraduate Study of Chemical Education, FKIP, Universitas Riau
Pekanbaru, 28293, Riau, Indonesia

*E-mail: agustinihusniwan@gmail.com

Abstract. Education at schools, especially high schools, has not been handled so well that critical
thinking skills of the high school graduates are still relatively low. An assessment is necessary to find out
whether the on-going teaching and learning process has achieved the stated learning objectives. Thus,
it is necessary to develop an instrument that can evaluate the students’ critical thinking abilities. This
study aimed to determine the validity of CPS-based assessment instrument for students' critical thinking
skills on stoichiometry materials. The method of development utilized in this study was Research and
Development (R&D) adapted from Borg & Gall Model which consists of 10 development steps. However,
this study was conducted only in three stages, namely preliminary research and information gathering,
planning, and development of the initial product. The results of this study indicated that the CPS-based
assessment instrument fulfilled the validity requirements, not only material validity but also language and
construct validity. This study was expected to produce a valid instrument so that it could be used to
assess the students’ critical thinking ability.

Keyword: Development, validity, assessment instruments, critical thinking, CPS

6
ID ICC00030

The Development and Validation of Assessment Instruments to Measure Students’ Analytical


Thinking Ability and Chemical Literacy on Colligative Properties
Yandriani 1, Usman Rery2 and Maria Erna3
1,2,3 Chemistry Education, Postgraduate of Universitas Riau

*E-mail: yaniyandriani@gmail.com

Abstract. This study aimed to develop and validate assessment instruments to measure students’
analytical thinking ability and chemical literacy on the material of colligative properties. The method of
this study was research and development (R&D) implementing ADDIE model (analysis, design,
development, implementation, and evaluation). However, this study was limited to the validation of
products. The assessment instrument was developed based on indicators of analytical thinking ability
and chemical literacy and contained 15 items of questions as the result. Based on the validation result
conducted by 3 validators, it was found that the average score of validation was 94% for the material;
91% for the language, and 91% for the construction. Moreover, the validation of the assessment of
analytical thinking ability and chemical literacy was 93.33%. Thus, it can be concluded that this
assessment instrument was valid and feasible to be used in order to measure students' analytical thinking
and chemical literacy skills in the material about the colligative properties.

Keyword: Assessment Instruments, Analytical Thinking, Chemical Literacy, Validity

7
ID ICC00068

Development of a test instrument to measure HOTS and Cognitive Knowledge in Biology


Vina Septiani1* and Paidi2
1Post-graduate Student of Biology Education, Yogyakarta State University, Yogyakarta, Indonesia
2Biology Education Department, Yogyakarta State University, Yogyakarta, Indonesia

*E-mail: vina11septiani@gmail.com

Abstract. SKL of primary and secondary education set each graduate have HOTS (analysis, evaluation,
and create) and cognitive knowledge (conceptual and procedural). The aim of this research is to develop
test instrument of multiple choice for measuring how the ability to HOTS and cognitive knowledge of
biology of senior high school students on the subject of digestive system. The type of this research is
Research and Development (R&D) that based on the development model of Oriondo & Dallo-Antonio
and Wilson. The field testing was be done in Januari-Februari 2020 involving 280 around the five senior
high school in Yogyakarta. The data based on analysis measurement Rasch Model and use Quest
program to find out validity and reliability of the instrument items, including the goodness of fit, difficulty
index, and reliability estimate. Result of validity shows that from 10 HOTS and cognitive knowledge
evaluation items, one of them are not valid. INFIT MNSQs for the item ranged 0,89 to 1,14. Difficulty
indexes for the item ranged -3,44 to +1,36. Reliabilities of item estimate were 0,99.

Keyword: multiple choice test item, HOTS, cognitive knowledge, biology

1
To whom any correspondence should be addressed.

8
ID ICC00153

Test Item analysis of chemical literacy: a validity and reliability assessment


Yusmaita E1*, Gazali F2 and Nasra E3

1,2,3 Universitas Negeri Padang


*E-mail: ekayusmaita@fmipa.unp.ac.id

Abstract. Chemical literacy test serves as measurement instrument capable of measuring student’s
understanding of chemical concepts, attitude, and the application of chemistry in life. The measurement
of chemical literacy skill requires good test instrument with valid and reliable criteria. This research aims
to analysis chemical literacy instruments in senior high school. Some of the topics in questions include:
the fundamental law of chemistry, reaction rates, and thermochemistry. The type of question used was
an essay. The student’s answer are grouped into five levels, known as scientific illiteracy, nominal,
functional, conceptual, and multi-dimensional. This research method is quantitative descriptive study with
a sample number of 72 students. The Instruments analysed using an ANATES software. The acquisition
of reliability questions are 0.89 and 32 questions in valid category.

Keyword: chemical literacy, validity, reliability, assesment

9
ID ICC00142

Correlation between Cumulative Achievement Index (GPA) of Undergraduate And Professional


Programs with the Medical Student Profession Program of Medical Faculty score of FK UPR

Francisca Diana Alexandra, Agnes Fretehernety, Indria Augustina


Medical Faculty, Palangka Raya University

Abstract. Implementation of Medical Education aims to produce doctors who have competence in
carrying out primary health services. The Grade Point Average (GPA) can be used as an indicator to
measure the success of the teaching and learning process of student learning achievement. The
government guarantees the quality of higher education in the health sector through Law No.12 of 2012,
one of the central policies of conducting a national competency test. This study uses a correlation
research method to determine the relationship between the Bachelor GPA and Professionals programs
towards the graduation results of UKMPPD FK UPR Students. The target population limit used in this
study is FK UPR students who took the Doctor Professional Program Student Competency Examination
period of May 2016 - November 2019. Data obtained in this study were processed statistically, and then
the data were analyzed using the Spearman correlation test. The CBT passing rate is 90.9% (120 out of
132 people), while the OSCE 100% (132 people) have passed. The results p-value of 0,000 shows the
correlation between the GPA of the Undergraduate Medical Program and the value of CBT and OSCE.
Spearman's correlation value of 0.638 indicates a positive correlation with the strength of a strong
relationship between GPA and CBT, while between GPA and OSCE of 0, 292, which shows a positive
association with weak power. The results p-value of 0,000, which shows that the correlation between the
Professional GPA and the value of CBT and OSCE. Spearman correlation value of 0.451, which shows
a positive relationship with the strength of moderate correlation between GPA and CBT, while between
GPA and OSCE of 0, 209, which shows a positive association with the weak force. These results indicate
that the GPA of Bachelor and Professional Programs can use as an indicator of learning outcomes to
determine cognitive test results.

Keywords: Assessment of Competency, CBT, GPA, OSCE

10
ID ICC00131

Challenges towards the implementation of ICT in biology learning: a review study


Nurul Jannah Yuliani1) and Ixora Sartika Mercuriani 2)
Yogyakarta State University, Indonesia

Corresponding author email : nuruljannah.2018@student.uny.ac.id 1)

Abstract. The implementation of ICT in biology learning is not optimal because there are challenges that
influence it. This study aims to determine the challenges of ICT implementation in biology learning. This
research is a research that uses meta-analysis method. Sampling in this study using purposive sampling
technique. Data collection is done by downloading written documents in Science Direct, Eric, Research
Gate, Google Scholar, and NDLTD (Networked Digital Library on Theses and Disertations). The results
showed that there were various challenges towards the implementation of ICT in biology learning. The
most common challenges found in the research results is the lack of ICT infrastructure with a percentage
of 12.73%. The results of this study are expected to be a reference to minimize the challenges that have
been found so that the implementation of ICT in biology learning can be maximized in the future.

11
ID ICC00132

The improvement of students' conceptual understandings through the PQ4R aided the 5E
learning cycle model on the topic of salts hydrolysis.

Rody Putra Sartika1 and Lukman Hadi2*


1Chemistry education, Tanjungpura University,
2Chemistry education, Tanjungpura University,

*E-mail: rody.putra.sartika@fkip.untan.ac.id

Abstract. Conceptual understanding is essential for students to be gained during classroom activities.
There are various methods to achieve it. This study was conducted to describe the improvement of
students' conceptual understanding of the topic of salt hydrolysis after being taught with the PQ4R aided-
5E learning cycle model. To achieve the goal, one shot study was implemented as a study design. As
participants, first semester students of the chemistry education department of Tanjungpura University
were selected. Data were collected through an achievement test, which comprised two indicators. The
indicators used were identifying acid-base properties of salts and determining the pH of salts solutions.
The results showed that the improvements were 3.23%, 77.42%, and 19.35%, which was categorized as
poor, average, and excellent, respectively. In conclusion, PQ4R aided the 5E learning cycle model
successfully improved students' conceptual understandings.

Keyword: conceptual understandings, learning cycle, hydrolysis.

12
ID ICC00155

The Difference of Students’ Science Process Skills and Learning Activities in Guided Inquiry
and Direct Instruction with Practicum

Anna Juniar1*, Ratih Dwi Fardilah2 and Pravil Mistryanto Tambunan3


1Department of Chemical Education, Faculty of Mathematic and Science, State University of Medan,
Medan City
2Department of Chemical Education, Faculty of Mathematic and Science, State University of Medan,
Medan City
3Department of Pharmacy, University of Tjut Nyak Dhien, Medan City, Indonesia

Abstract. Improving the quality of chemistry learning can be achieved by emphasizing mastery of the
scientific process to students. The fact in the field show the chemical knowledge of students still low for
the reason that learning activities tend to be teacher-oriented, it causes students feel chemistry is not
only difficult but also monotonous. For this reason, a learning approach that develops knowledge
acquisition process skill is needed. Mastery of the process in learning science requires a scientific
attitude that is included in the “Science Process Skills”. The purpose of this research was to determine
the type of learning model which was able maximize the students' scientific processes skills. The results
of the application can be observed in student learning activities during observation. A quasy-
experimental control group pretest-posttest design was performed in this study. The sample in this study
were students in XII MIA-1 in SMAN 5 Binjai that applied by Guided Inquiry learning model and XII MIA-
2 which was applied by Direct Instruction. The results showed that the Science Process Skills in both
experimental classes obtained an average score of 93.78 and 75.32 respectively so that they were
categorized as "Very Good" and "Good" on 6 (six) aspects: observing, grouping, applying concepts,
interpreting, conducting experiments, formulating hypotheses. While learning activities obtained an
average score of 90.27 and 79.29 respectively, so that they were categorized as "Very Good" and
"Good" on the five indicators: Readiness to learn, skills for using tools, actively providing opinion,
working in group and making conclusion.
Keywords: Direct Instruction, Guided Inquiry, Science Process Skill, Learning Activities.

13
ID ICC00008

TRAINING OF SCIENTIFIC LITERATION AND SELF EFFICACY OF STUDENTS USING SCIENTIFIC


CRITICAL THINKING (SCT) MODELS

1Rusmansyah, 2M. Isra’i Rahman, 3Almubarak, 4Masniah


1,2,3,Pendidikan Kimia, Universitas Lambung Mangkurat, Indonesia
4SMAN Negeri 6 Banjarmasin, Indonesia

* E-mail: 1rusmansyah@ulm.ac.id

Abstract: The ability of scientific literacy and self-efficacy is an essential part of learning chemistry in
schools within the framework of preparing students to enter the industrial era 4.0 and the era of society
5.0. The Scientific Critical Thinking (SCT) model is one model that can be used to practice the scientific
literacy skills and self-efficacy of students in learning the concept of buffer solution. This study uses a
type of pre-experiment design with one group pretest-posttest design. The sample of this study were
students of class XI MIPA 3 of SMAN 6 Banjarmasin in 2019/2020. The independent variable is the SCT
model, and the dependent variable is the ability of scientific literacy and self-efficacy. Data collection uses
test and non-test techniques. Data analysis techniques used descriptive and inferential analysis
techniques. The results of this study indicate (1) there is a significant difference in scientific literacy ability
between the results of the pretest and posttest with tcount> ttable ie 13.2> 2, 00, (2) there is a significant
difference in students' self efficacy with tcount <ttable ie 8.53> 2 , 00, (3) students respond with criteria
both for learning with the SCT model. Thus, the Scientific Critical Thinking model can train the scientific
literacy ability and self-efficacy of students of XI MIPA 3 students at SMAN 6 Banjarmasin.

Keywords: scientific literacy, self-efficacy, SCT models

14
ID ICC00028

Cross-Sectional Approach for Diagnosing Student’s Learning Progression in Relation to Pre-


requisite Knowledge of Buffer Solution
Zonalia Fitriza1*, Faizah Qurrata Aini2, and Putri Handayani3
1,2,3Chemistry Department Universitas Negeri Padang

*E-mail: zonaliafitriza@fmipa.unp.ac.id

Abstract. Buffer Solution is one of the complex concepts in chemistry since it involves many prerequisite
concepts such as acid and base, chemical equilibrium, and stoichiometry. These concepts also need
sequent students’ understanding of the chemical equation, chemical nomenclature, and atomic symbol.
Their difficulty in comprehending prerequisite knowledge will affect the learning progression. This
research aims to diagnose learning progression and the causes of the learning progression block of
senior high school students on the buffer solution. Learning progression of 82 X grade, 80 XI grade, and
80 XII grade students were identified by a structured diagnostic test of chemistry using a cross-sectional
approach. This research figure out that the learning progression of the student was not as expected since
they cannot mastering buffer solution well particularly in buffer solution component, pH of buffer solution,
and pH maintaining mechanism because of their difficulty in understanding chemical equilibrium and
ionization reaction.

Keyword: buffer solution; cross-sectional approach; learning progression; misconception; pre-requisite


knowledge

15
International Conference on Chemistry and Science Education 2020
(ICChSE 2020) Parallel Seminar

Science Education Topics


Name List
Room B

Meeting Link:
https://us02web.zoom.us/j/88660147064?pwd=Q05RYXl0WDVOZW1kdmtUcTJGSVBBdz09
Meeting ID: 886 6014 7064
Passcode: 604459
Time (Westren
No Indonesia Time Name Abstract Title
UTC: +7)
1 13.30-13.40 Ria Almareta Biology teachers used Learning Management
System (LMS) for collaborative learning
2 13.40-13.50 Akram La Kilo Mol-Basketball: Learning of Mole Concept
based on Basketball Game in Boarding
School
3 13.50-14.00 Fefri Perrianty VALIDATY AND PRACTICALITY OF
MODULE SOLUBILITY AND SOLUBILITY
RESULTS BASED ON DISCOVERY
LEARNING WITH PROBING PROMPTING
TECHNIQUES
14.00-14.15 QnA presenter 1-3
4 14.15-14.25 Zulfiati Rahmi Permata Improving Students' Critical Thinking Skills
Sari, S.Si Through LKPD of Colloid Systems Based on
Discovery Learning and Multiple
Representations at SMAN Pariaman
5 14.25-14.35 Indah Cahyani VLOG DEVELOPMENT (VIDEO BLOG)
YOUTUBE CHANNEL STEM BASED ON
REACTION RATE CLASS XI SMA/MA
6 14.35-14.45 Wilda Yanti The development of interactive learning
media based on augmented reality on
molecular shape material
14.45-15.00 QnA presenter 4-6
7 15.00-15.10 Nahadi Development of an electronic portfolio
assessment model in learning chemistry to
develop the habits of mind and reasoning of
Indonesian students
8 15.10-15.20 Hidayati Kardena, S.Pd The Development of Guided Inquiry-Based
Student Worksheet of Chemical Equilibrium
Towards Student Activities
9 15.20-15.30 Arip Erlangga, S.Pd THE DEVELOPMENT OF WHO WANTS TO

16
BE A GREAT BIOLOGY GAMES AS A
COMPUTER LEARNING MEDIA BASED ON
HUMAN RESPIRATORY SYSTEMS AT
CLASS VIII MIDDLE SCHOOL STUDENTS
15.30-15.45 QnA presenter 7-9
10 15.45-15.55 Annisatul Qaidah, S.Pd Development of Salt Hydrolysis Module
Based on guided Inquiry to Increase The
Critical Thinking Ablility of 11th Grade High
School Students
11 15.55-16.05 Rusdani Development of Discovery Learning Based
Learning Modules with Probing Prompting
Techniques Redox to Improve Critical
Thinking Ability of Class X High School
Students
12 16.05-16.15 Nova Putri The Development of PowerPoint-iSpring
Multimedia on Topic of Buffer Solution for
Senior High School Learning
16.15-16.30 QnA presenter 10-12
13 16.30-16.40 Fauzana Ghazali, M.Pd Validity Testing of a Contextual Approached
with REACT Components-Based Module on
Topic of Salt Hydrolysis for Class XI Senior
High School students
14 16.40-16.50 Effendi, M.Sc Development of STEM-PjBL Integrated LKPD
(Science, Technology, Engineering and
Mathematics - Project Based Learning) on
Acid and Base Materials
15 16.50-17.00 -
17.00-17.15 QnA presenter 13-15

17
ID ICC00078

Biology teachers used Learning Management System (LMS) for collaborative learning
Ria Almareta1* and Paidi2

1,2 Biology Education, Post Graduate School, Universitas Negeri Yogyakarta, Jl. Colombo No. 1,
Yogyakarta, Special Region of Yogyakarta Province, 55281, Indonesia.

*Corresponding author: riaalmareta.2018@student.uny.ac.id

Abstract. Learning Management System (LMS) provides a new perspective in the education system in
the 21st century. The use of LMS by biology teachers is dominated by developing countries, as many as
67% of teachers have implemented LMS in biology learning.. LMS can be used by biology teachers to
conduct collaborative and conceptual learning through existing media in online-based learning system.
Moodle is a learning Managemnt System (LMS) with the most popular and most used system in the world,
because of its flexibility, open source capabilities, and a learning management system that is free to
download, and can load 1000 subjects in its system. This literature study aims to illustrate that the use of
LMS to support collaborative learning in biology and science subjects. This research methodology using
Review and Meta-Analysis There are interactive features that can support collaboration between students
and teachers or between students.

Keyword: biology teachers, learning management system, collaborative learning

18
ID ICC00119

Mol-Basketball: Learning of Mole Concept based on Basketball Game in Boarding School


Astin Lukum1, Elyas Nusi1, Lukman A. R Laliyo1, Jafar La Kilo1, Akram La Kilo1*

1Department of Chemistry Education, Faculty of Mathematics and Natural Sciences, State University of
Gorontalo, Jl. Habibie, Desa Moutong, Kec. Tilongkabila, Bonebolango Gorontalo
*E-mail: akram@ung.ac.id

Abstract. The purpose of this study was to determine the understanding and activeness of students on
the topic of mole concepts through basketball-based learning. Three of the six ball passing techniques in
basketball are used as mathematical operation. This research was carried out in boarding school of SMA
Terpadu Wira Bakti Gorontalo, with 24 samples from 48 populations taken by simple random sampling
technique. Data collection techniques in this descriptive research were through test, observation, and
interview. The test was carried out in two ways, namely through a written test in class as a preliminary
test and through a game in the basketball court. Written test result was low, with an average score of 30
and only 5% of students achieving mastery learning. While the test results in the court obtained an
average value of 93.12. This learning can activate students so as to prevent the drowsiness that was
common in boarding school students. In addition, this learning was able to arouse thought of analysis,
openness, cooperation, and harmonizing thought and movement.

Keyword: Game based-learning; basketball, mol concept, boarding school, mencegah rasa kantuk

19
ID ICC00086

VALIDATY AND PRACTICALITY OF MODULE SOLUBILITY AND SOLUBILITY RESULTS BASED


ON DISCOVERY LEARNING WITH PROBING PROMPTING TECHNIQUES

Fefri Perrianty1, Hardeli2


1,2Departement of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Negeri
Padang, Padang Utara, Padang 25131 West Sumatera, Indonesia
fefriperrianty3@gmail.com

Abstract. The solubility module and the solubility results based on discovery learning with probing
prompting technique is one of the teaching materials. This study aims to produce solubility modules and
solubility results based on discovery learning with probing prompting techniques that are valid and
practical. This research is a development study using the Plomp model with three stages, namely the
initial investigation stage, the prototype stage and the assessment stage. The evaluation method used is
formative evaluation consisting of self-evaluation, expert review, individual evaluation, and evaluation of
small groups of validation sheets. The research instruments used were interview sheets, questionnaires
in the form of validity and practicality sheets. The validation results obtained a high level of validity (k =
0.75). The results of the practicality of students in small groups and in the field test obtained very high (k
= 0.83), while the level of practicality of teachers was obtained high (k = 0.73). The results showed that
the solubility module and the solubility product based on discovery learning with probing prompting
techniques met valid and practical.
Keywords: module, solubility and solubility product, discovery learning, probing prompting technique.

20
ID ICC00089

Improving Students' Critical Thinking Skills Through LKPD of Colloid Systems Based on
Discovery Learning and Multiple Representations at SMAN Pariaman

Zulfiati Rahmi Permata Sari, Alizar, Ananda Putra, Rahadian Zainul

Chemistry Department, Faculty of Mathematics and Natural Science


Padang State University
Jl. Prof. Dr. Hamka Air Tawar, Padang, 25131, Indonesia

Abstract. This study aims to produce colloidal systems LKPD-based discovery learning and multiple
representations to improve the critical thinking skills of learners valid, practical, and effective. This
research is a development study using the Plomp development model. Sampling was done using a
purposive sampling cluster technique. Research instrument used is the questionnaire, a questionnaire in
the form of sheet validity and practicalities, about objective and about the critical thinking skills. The
validation results obtained a very high level of validity (k = 0 , 83 ). The results of the practicality of small
group students is very high k = 0.834. In the field test results obtained very high student practicality (k =
0.815) while the practicality by high teachers (k = 0 , 74 ). Hypothesis testing of learning outcomes shows
that there are significant differences between the learning outcomes of experimental class students and
control class students . The results of the critical thinking skills of hypothesis testing showed that there
are significant differences between the critical thinking skills of learners Kela 's experimental and control
classes. The results showed that LKPD had fulfilled the valid, practical and effective criteria.

Words key : Worksheets learners, the colloidal system, discovery learning , critical thinking skills.

21
ID ICC00105

CHANNEL YOUTUBE VLOG DEVELOPMENT


STEM-BASED ON XI HIGH SCHOOL / MA REACTION RATE MATERIALS

Cahyani, Indah
Jurusan Tadris Kimia Fakultas Tarbiyah dan Ilmu Keguruan IAIN Batusangkar
Icahyani957@gmail.com

Abstract. The use of instructional media is one of the innovations for students in understanding each
subject matter so that they are motivated to always follow the learning process without experiencing
boredom. The teacher can choose appropriate and efficient learning media to achieve educational goals.
The development of information technology has influenced the world of education, from conventional
face-to-face education to more open education. The development of increasingly modern and highly
sophisticated era makes individuals dependent on technology, especially smart phones. Where this tool
is often used by many people, ranging from adults to children. However, in reality it is often found in the
field that in using various technologies for teacher learning activities still have limitations. This limitation
is seen in the minimal use of technology-based learning media in the learning process. The research
aims to develop a vlog (video blog) on YouTube channel as an alternative to learning chemistry based
on STEM. The type of research used is research and development (Research and Development) with a
4D design model. This study consists of four stages, namely: defining (defining), design (design), stage
of development (development) and the stage of dissemination (disseminate). But in this study only
reached the stage of development (development) due to time and cost limitations. Product viability is
done by validating the media expert and material expert. After that, the researchers conducted a limited
practicality test on the product using 10 students. Based on the results of product validation, a percentage
of 80% was obtained with valid criteria, and the percentage of STEM-based vlog practicality seen from
the student response questionnaire was 96.13%, while from the teacher response questionnaire obtained
a percentage of 90%.

Kata Kunci: Vlog, STEM and Reaction Rate.

22
ID ICC00106

The development of interactive learning media based on augmented reality on molecular shape
material

Wilda Yanti
Jurusan Tadris Kimia Fakultas Tarbiyah dan Ilmu Keguruan IAIN Batusangkar

Abstract. A good learning process must contain aspects of interactive, fun, challenging, motivating and
giving more space for students to be able to develop creativity and independence, in accordance with
students' talents and interests. An interesting learning media is also very necessary for students, one of
them is in the subject of chemistry, because the subject of chemistry prioritizes practice. The problem in
this study is the lack of student interest in learning because teachers do not use interactive media so that
when learning takes place students pay less attention to the teacher. The media used by students are
also limited, and they do not help students to learn independently. Based on this, the researchers
conducted research into the development of interactive learning media based on Augmented Reality.
Augmented Reality is a technology that combines 3D virtual objects into a real three-dimensional
environment at the same time. Augmented Reality technology has been diplomatic in various diverse
fields, including in the field of education. Augmented Reality can be built using the software vuforia and
unity 3D. The final result is an interactive learning media using Augmented Reality technology. One
chemical that uses Augmented Reality technology is molecular shape material. Molecular material is
material that requires 3D visualization. The results showed that the results of the validity of Augmented
Reality-based interactive learning media obtained were 82.577% with a very valid category. With this it
can be concluded that the interactive learning media based on Augmented Reality that was designed
was valid.

Keyword: Learning Media, Interactive, Augmented Reality, Validity

23
ID ICC00129
Development of an electronic portfolio assessment model in learning chemistry to develop the
habits of mind and reasoning of Indonesian students
Nahadi11, P. Purnawarman22, and W. Siswaningsih33*
1,2,3 Universitas Pendidikan Indonesia,
*1e-mail: nahadi@upi.edu

Abstract. This research aims to develop an electronic portfolio assessment model in learning chemistry.
The development of the model is intended to build students' habits of mind and reasoning. Research on
the development of this model is carried out with a research & development method that begins with a
preliminary study, development, validation, and application. Research instruments in the form of
questionnaires, interview guides, validation sheets and documents as a tool to explore various
information needed at each stage. Research respondents consisted of chemistry educators or teachers,
high school students, and related stakeholders. In the preliminary study and development phase, a
number of research data have been produced. The preliminary study data are in the form of a number of
habits of mind and reasoning indicators that form the basis of developing assessment instruments. The
data from the development study are in the form of a package of test and non-test assessment
instruments constructed from 3 main indicators of habits of mind and 5 indicators of reasoning in
chemistry learning. Initial instrument data developed in the form of 50 items generated from related
indicators, after theoretically validated 48 items were obtained with a CVI index of 0.89 in the good
category and all items having a CVR index met valid criteria. Based on the results of the study, the items
produced were declared valid and could be used as content to build the electronic portfolio assessment
framework and model.

Keyword: electronic portfolio assessment, chemistry, habits of mind, reasoning

24
ID ICC00133

The Development of Guided Inquiry-Based Student Worksheet of Chemical Equilibrium


Towards Student Activities

Hidayati Kardena1 ,Mawardi Mawardi2*


1UniversitasNegeri Padang,
2UniversitasNegeri Padang
*E-mail: hkardena@gmail.com

Abstract. This study aims to produce a worksheet of chemical equilibrium which based on guided inquiry
in order to measure the validity, practicality and effectiveness of the worksheet on student learning
activities. Learning activities are assessed in the form of listening activities, visual activities, mental
activities, oral activities, writing activities and motor activities. This research method was a research
development using the Plomp model. The research subjects were students majoring in chemistry in 2019.
The research instruments used were validation sheets, practicality sheets and observation sheets of
learning activities.This research found that the students’ worksheets have a very high level of validity
(k=0,91) and very high level of practicality by students (k=0,87) and high by the lecturer (k=0,79). The
results showed that in general, the average student learning activity was 81,18% which was included in
the very high category. It shows that the students’ worksheets which have been produced can be used
as one of the teaching materials in the learning process on chemical equilibrium material

Keyword: student worksheet, guided inquiry, chemical equilibrium, student activities

25
ID ICC00165

THE DEVELOPMENT OF WHO WANTS TO BE A GREAT BIOLOGY GAMES AS A COMPUTER


LEARNING MEDIA BASED ON HUMAN RESPIRATORY SYSTEMS AT CLASS VIII MIDDLE
SCHOOL STUDENTS
Series: Journal of Physics

Arip Erlangga
Pendidikan Biologi, Program Pascasarjana, Universitas Negeri Yogyakarta
*Coressponding Author. Email: Ariperlangga.2018@student.uny.ac.id

Abstract. This study aims to determine the quality and feasibility of learning media games who want to
be a great computer-based biology. This research refers to the Research and development (R&D)
procedureADDIE development model is carried out through five stages, namely Analysis, Design,
Development, Implementation and Evaluation. The instrument used in assessing the media was a
questionnaire sheet that used a Likert measurement scale with descriptive analysis techniques.
The results of research into the development of media games who want to be a great biology
material on the human respiratory system obtain an average overall evaluation criteria of 60% of media
experts, 87% of material experts, very good quality, 93% natural science teachers, very good quality, in
class trials small based on an average rating of 74%, large class trials 84% with very good quality. Based
on the results of the assessment and questionnaire responses of these students, the media games who
want to be a great biology material of the human respiratory system can be categorized as very
appropriate to be used as teaching media in schools.
Keywords: Who Wants To Be A Great Biology, Human Respiratory System, Teaching Media.

26
ID ICC00172
Development of Salt Hydrolysis Module Based on guided Inquiry to Increase The Critical
Thinking Ablility of 11th Grade High School Students

Annisatul Qaidah
Magister of Chemical Education FMIPA Padang State University

Abstract
Abstract. This study aims to produce a guided inquiry-based salt hydrolysis module to improve students'
critical thinking skills by determining the level of validity, practicality and effectiveness of the module. The
type of research used is research development or Research and Development (R&D). The sampling
technique uses cluster purposive sampling. The number of samples is 57 students from both schools.
The development model used is the Plomp development model which has three stages namely the initial
investigation phase (preliminary research phase), the prototype phase (prototyping phase) and the
assessment phase (assessment phase). The research instruments used were interview sheets,
questionnaires in the form of validation and practicality sheets, objective questions, and critical thinking
questions. The data analysis technique used SPSS 16 software. The results obtained by N-gain
experimental class were higher than the control class, namely experimental classes 1 and 2 had N-gain
64.65 and 59.46, while control classes 1 and 2 had N-gain 60 , 83 and 58.6 with significant differences.
Hypothesis test results show a significant difference between the critical thinking skills of the experimental
class and the control class, both in schools with high and low student abilities.

Keywords: modules, salt hydrolysis, guided inquiry, Critical thinking, Plomp Development Model

27
ID ICC00183
Development of Discovery Learning Based Learning Modules with Probing Prompting
Techniques
Redox to Improve Critical Thinking Ability
of Class X High School Students

Rusdani1 , Hardeli2*
1Master Student of Chemistry Education Universitas Negeri Padang,
2 Chemistry lecturer Universitas Negeri Padang

*E-mail: Rusdanidani567@gmail.com

Abstract. The purpose of this to produce discovery learning redox chemistry modules with probing
techniques and determine the level of validity, practicality and use of modules. This research includes
education development research using the Plomp development model which has three stages, namely
the initial research stage,the prototype making stage, and the renewal stage. When making prototypes
self-evaluation (self-evaluation), expert evaluation (expert review), individual evaluation (one-to-one
evaluation), small group evaluation (small group evaluation), while testing is done through the field test
(field test) in 2 schools namely SMAN 9 Padang and SMAN 15 Padang.The research instrument used
was a questionnaire in the form of validity and practicality sheets, multiple choice questions and critical
thinking descriptions. The results of practicality by students in small groups with an average of 0.93 and
practicality by teachers on average 0.86 on the field test is very high. Hypothesis test results show a
significant difference between the learning outcomes of experimental class students and the control class
in schools with low ability, Hypothesis test results also show a significant difference between the thinking
ability of the experimental class and the control class, both in schools with moderate to low student
abilities .

Keyword: module, solubility and solubility product, guided inquiry, probing prompting technique, critical
thinking.

28
ID ICC00190

The Development of PowerPoint-iSpring Multimedia on Topic of Buffer Solution for Senior High
School Learning

N Putri1 and Guspatni2*


1,2 Chemistry Department, Faculty of Mathematics and Natural Sciences, University Negeri Padang
*guspatni.indo@gmail.com

Abstract. Understanding buffer solution topic requires explanations and visual representations of the
concepts at macroscopic, sub-microscopic and symbolic ones (chemical multiple representations). This
Research and Development (R&D) study aims to develop PowerPoint-iSpring multimedia on buffer
solution topic to help students understand the concepts through the integration of chemical multiple
representations and prompting questions accompanying the representations. Define, design and develop
stages of 4-D developmental model were performed. Validation of the multimedia developed was done
to six expert validators and the data were analysed with Kappa Cohen formula. The result showed that
PowerPoint-iSpring multimedia had moment kappa of 0.86 showing a very high degree of validity. To
consider of developing and using the multimedia in further researches and practices, other descriptions
of this study are described in this paper as well.

Keyword: PowerPoint-iSpring, Multimedia, Buffer Solutions, 4-D Developmental Model

29
ID ICC00121

Validity testing of a contextual approached with REACT components-based module on topic of


Salt hydrolysis for Class XI Senior Highs school students
Fauzana Ghazali
Chemistry Department, Faculty of Mathematics and Natural Sciences, University Negeri Padang

Abstract. A contextual approach-based module that consists of five components namely Relating,
Experiencing, Applying, Cooperating, and Transferring (REACT) can help students find concepts. This
Research and Development (R&D) aims to develop a contextual approach-based module that contains
critical thinking skills indicators on salt hydrolysis topic. The developmental model used was 4-D model
that consists of Define, Design, Development, and Disseminate. Research instruments were a construct
validity questionnaire analyzed with kappa moments (k) formula and a content validity questionnaire
analyzed with CVR approach. The questionnaires were filled by 3 chemistry lecturers and 2 chemistry
teachers at SMA 9 Padang. It was found that kappa moment value of construct validity was 0.82 showing
a very high level of validity, while the CVR and CVI values of content validity were 0.98 and 1 respectively
showing valid categories.Therefore, it can be concluded that the salt hydrolysis module which is based
on a contextual approach with REACT components for class XI learning is valid.

Keywords :Module, contextual approach, REACT, critical thinking skills, salt hydrolysis, 4-D model

30
ID ICC00375

Development of STEM-PjBL Integrated LKPD (Science, Technology, Engineering and Mathematics -


Project Based Learning) on Acid and Base Materials

Effendi1* and Syuhaibatul Islamiah1


Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Negeri Padang,
Kampus UNP, Jalan Prof. Dr Hamka Air Tawar Padang, Sumatera Barat, 25131, Indonesia
*E-mail: fernando_00id@yahoo.com

Abstract. Chemistry education and learning currently requires students to have chemical skills and
critical thinking skills. One effort that can be taken is through the development of learning and its
integration with certain approaches. In this study, an integrated learning STEM-PjBL is outlined in the
form of teaching materials in the form of LKPD on Acid and Base material. Therefore, this study aims to
produce STEM-PjBL Integrated Science (Technology, Technology, Engineering and Mathematics-
Project Based Learning) on Acid and Base Material and determine the validity and practicality of the
developed LKPD. This type of research is Research and Development (R&D) using the 4D model. The
research instrument was a validation sheet and practicality questionnaire. The validity and practicality of
the data were analyzed using the Cappa Cohen Formula. The average Kappa Moment is 0.85 with a very
high validity category. The results of the practicality test data analysis for teachers obtained Kappa
Moment of 0.83 and the practicality of students of 0.88 with very high category category. The results of
the data show that the LKPD developed is valid and practical for use in learning Acid and Base in schools.

Keyword: Keywords: LKPD, STEM, PjBL, acids and bases

31
International Conference on Chemistry and Science Education 2020
(ICChSE 2020) Parallel Seminar

Science Education Topics


Name List
Room C
Meeting Link: https://us02web.zoom.us/j/88422577786?pwd=RFhhdFhreG83RlpnS0NETSt4T1NhQT09
Meeting ID: 884 2257 7786
Passcode: 499428
Time (Westren
No Indonesia Time Name Abstract Title
UTC: +7)
1 13.25-13.45 Dr. Paed Nurma Yunita Reshaping a sustainable chemistry
Indriyanti (invited Speaker) education through a tetrahedral
chemistry approach
13.45-14.00 QnA invited speaker
2 14.10-14.20 Ani Latifatun Naj'iyah , S.Pd Design Learning Strategies to
Improve Scientific Reasoning and
Performance Argumentation and
Reduce Differences Learning Styles
and Prior Knowledge
3 14.20-14.30 Ismi Yohana, S.Pd. Toward an Education for
Sustainable Development with
RADEC (Read, Answer, Discuss,
Explain, and Create) Learning
Model in Chemistry Education
4 14.30-14.40 Restiana Effectiveness of learning models for
improving science process skills: A
review study.
14.40-14.55 QnA presenter 2-4
5 14.55-15.05 Meida Wulan Sari, S.Pd., The Effectiveness of Integration
M.Pd. Conceptual Change Learning Model
with Cognitive Conflict Strategy
Toward Student’s Conceptual
Understanding
6 15.05-15.15 Mahardika Himas Nugraeni, Instructional Designs to Promote
S.Pd Scientific Literacy on Students and
Teachers: a Review Study
7 15.15-15.25 Mera Afriyanti, S.Pd. Design of e-modules to stimulate
HOTS on static fluid materials with
the STEM approach
15.25-15.40 QnA presenter 5-7
8 15.40-15.50 Arief Muttaqiin, M.Pd. Is Integrated Science Book with
Ethno-STEM Approach needed by

32
Secondary School Students?
9 15.50-16.00 Andriani Dotimineli, S. Si Development of STEM-Based PBL
Student Worksheets in Energetic
Materials of First Year Students
10 16.00-16.10 Suha Kamilah Development pf Guided Inquiry
learning Module using Promting
Probing Technique in Electrolite and
Non- Electrolite Solution to Increase
Thingking Ability Critical
16.10-16.25 QnA presenter 8-10
11 16.25-16.35 Dra. Iryani, MS Effect of Using Guided Inquiry-
Based Chemical Bonding Modules
on Student Learning Outcomes
12 16.35-16.45 Masykuri Strengthening Buffer Solution
Learning Activities with Numbered
Head Together Models Equipped
with a Combined Hand Out -
Augmented Reality
13 16.45-16.55 -
16.55-17.10 QnA presenter 11-13
14 17.10-17.20 -
15 17.20-17.30 -
16 17.30-16.70 -
17.40-17.55 QnA presenter 14-16

33
Invited Speaker

Reshaping a sustainable chemistry education through a tetrahedral chemistry approach

Nurma Yunita Indriyanti*


1Department of Chemistry Education
Faculty of Teacher Training and Education
Universitas Sebelas Maret, Indonesia

*E-mail: nurma.indriyanti@staff.uns.ac.id

Abstract. The more challenges in 21st-century chemistry learning are students grasp knowledge from
more ‘’windows’’. In the last decade, the X and Z chemistry generation learn by representing three levels;
macroscopic, sub-microscopic, and symbolic from the planar triangles, particularly the triangle of thinking
levels. The pandemics as uncertainty, forces a significant change in the way of teaching and learning.
Teachers found the new normal is a barrier. Therefore investing powerful chemistry teachers with
comprehensive knowledge and skills are the main objectives. The tetrahedral chemistry approach
emphasizes the human element in and outside the classroom. It focuses on the human learner—through
global problem challenges, investigative projects, problem solving, and matching pedagogical strategies
to students' learning styles. Findings of related researches in the area of secondary and higher education
will be explored. The shape stresses educating science and non-science majors about the processes of
science, the role of science, and the science and society interaction.

Keyword: reshaping chemistry education, 21st-century learning, sustainable future, society

34
ID ICC00115

Design Learning Strategies to Improve Scientific Reasoning and Performance Argumentation


and Reduce Differences Learning Styles and Prior Knowledge
Ani Latifatun Naj’iyah1, Viyanti1*, Agus Suyatna1
1Magister Pendidikan Fisika Universitas Lampung, Bandar Lampung, Indonesia

*Correspondence author: viyanti.1980@fkip.unila.ac.id

Abstract. The purpose of this study is to design learning strategies that can be used to reduce differences
in learning styles and prior knowledge so that they do not affect the achievement of scientific reasoning
and student argumentation performance on the material of hydro power and wind energy. This study uses
the ADDIE (Analyze, Design, Develop, Implementation) development model, in this article is limited to
analyze and design Needs analysis data obtained through a questionnaire with respondents high school
student and teacher in Lampung. Data analysis techniques using qualitative descriptive analysis. The
results showed that teachers and students needed a learning strategy design that could improve scientific
reasoning and argumentation performance and reduce differences in learning styles and students' prior
knowledge. The learning strategy design developed modifies the PjBL syntax by integrating STEM which
contains problem solving activities, expanding scientific literacy, designing and making projects, and
communicating.

Keyword: learning strategies, scientific reasoning, performance argumentation, learning style, prior
knowledge

35
ID ICC00143

Toward an Education for Sustainable Development with RADEC (Read, Answer, Discuss,
Explain, and Create) Learning Model in Chemistry Education
Ismi Yohana2* and Wahyu Sopandi2
1Universitas Pendidikan Indonesia,
2Universitas Pendidikan Indonesia

*E-mail: ismiyohana@upi.edu

Abstract. This study wants to determine the effect of the RADEC (Read, Answer, Discuss, Explain, and
Create) learning model in chemical education in order to realize Education for Sustainable Development
(ESD). Education becomes one of the most important things in people's lives in their readiness to face a
rapidly changing future. Referring to Agenda 21 that was launched in the United Nations Conference on
Environment and Development (UNCED) in Rio de Janeiro, Brazil in 1992 provides clear direction on the
necessity of educational direction towards Education for Sustainable Development (ESD). Although these
principles have been articulated for more than 20 years, they have not been systematically included in
the chemistry curriculum. Failure in the relevance of learning to students' lives and their environment, so
that what happens at school only emphasizes content rather than process. Project work is an important
approach in supporting students' learning about sustainable development. Students engage in
collaborative learning, inquiry-based through the RADEC methodology, and highly structured classroom
activities help students develop creativity that enables success for the future.

Keyword: ESD, RADEC, Chemistry Education

To whom any correspondence should be addressed.

36
ID ICC00145
Effectiveness of learning models for improving science process skills: A review study.

Restiana, resti4300@gmail.com
Djukri, djukri@uny.ac.id
Postgraduate Program in Biologycal Education, State University of Yogyakarta, Yogyakarta, Indonesia.

resti4300@gmail.com

Abstract. The 2013 curriculum implementation expects learning to produce output in the form of science
process skills. Science process skills can be improve by applying appropriate learning models. This study
aims to analyze the types of learning models to improve science process skills. The research method is
a meta-analysis by analyzing articles qualitatively in international journal indexed SCOPUS and nationally
indexed SINTA in the last 5 years. Data analysis was performed by interpreting the same findings in the
journal as a percentage. Research shows learning models that can improve science process skills are;
guided inquiry model, guided-discovery model, practice based learning, problem solving learning and
project based learning. From various learning models, guided inquiry is more effective in improving
science process skills. Enhanced science process skills include indicators observing, classifying,
predicting, measuring, inferring, grouping, communicating, controlling variables, interpreting data,
formulating hypotheses, designing experiments and conducting experiments.

Keywords: Science Process Skills, Learning Models, Guided Inquiry

37
ID ICC00147
The Effectiveness of Integration Conceptual Change Learning Model with Cognitive Conflict
Strategy Toward Student’s Conceptual Understanding

Meida Wulan Sari1) dan Harun Nasrudin2)


1)Program Studi Pendidikan IPA, Universitas Sebelas Maret
2)Program Studi Pendidikan Kimia, Universitas Negeri Surabaya

e-mail: meidawulan@staff.uns.ac.id

Abstract. The aims of this research is to describe the profile of student’s conceptions, the
shifting of student’s misconceptions, and the reduction of student’s misconceptions. This
research was conducted in senior high school. The research design used the One-group
pretest-posttest. The results showed that the average percentage of student's
misconceptions before the implementation of integration conceptual change learning model
with cognitive conflict strategy on the ionic bonding, the covalent bonding, and the polarity
of a compound concept were respectively by 36,00%; 46,00%; and 54,67%, while the
average percentage of student's misconceptions after the implementation were respectively
by 1,33%; 3,33%; and 6,00%. The shifting of student’s misconceptions after the
implementation of integration conceptual change learning model with cognitive conflict
strategy showed that almost all the misconceptions into mastering concept. The percentage
of misconceptions into mastering concept on the ionic bonding, the covalent bonding, and
the polarity of a compound concept were respectively by 98,15%; 94,37%; and 87,8%. The
reduction level of student’s misconceptions based Hattie barometer were classified as high
category, 0,83. So the implementation of conceptual change learning model with conflict
cognitive strategies could effect student’s conceptual understanding.

Keywords: Conceptual Change Learning Model, Cognitive Conflict Strategy, Conceptual


Understanding, Chemical Bonding

38
ID ICC00164

Instructional Designs to Promote Scientific Literacy on Students and Teachers: a Review Study

Mahardika Himas Nugraeni1, a) and Paidi2, b)

1 Yogyakarta State University 2 Yogyakarta State University, Jl. Colombo No.1, Karang Malang,
Caturtunggal, Kec. Depok, Kabupaten Sleman, Daerah Istimewa Yogyakarta 55281

a)mahardikahimas.2018@student.uny.ac.id
b)paidi@uny.ac.id

Abstract. Scientific literacy is one of the essentials literacies in 21st world and 4.0 industrial revolutions.
Indonesia students’ scientific literacy is not in the satisfying level. In order to provide the student skills for
the upcoming society, scientific literacy of Indonesian students need to be improved. This study provides
several instructional designs that proved could promote students and teachers’ scientific literacy. This
review study was carried out by reviewing 15 international articles. Instructional designs that could
improve student’s scientific literacy based on the studies were: instructional with discussion method on
scientific topic; instructional that connecting science learning with culture through personal science
writing; instructional with effective argumentation on an energy-related environmental issue; literacy-
infused and inquiry based science instruction; student worksheet based on education for environmental
sustainable development; modified problem-based learning, project-problem based learning; using pop-
culture hook and authentic challenge-based learning, the differentiated instruction; instruction with
structured primary literature project; teaching material based on science literacy; science, technology,
society and environment (STSE) learning approach. Instructional designs and program to improve
teacher or teacher candidate’s scientific literacy were well-constructed teacher training programs;
intensive, multiple approaches teaching such as historical approach activities, generic activities, explicit-
reflective approach activities, and media news analysis activities; instruction with Toulminian model of
argumentation for logical examination of information on news about the application of STEM discoveries.

Keywords: scientific literacy, learning approach, learning method, learning model, learning strategy,
instructional design.

39
ID ICC00116

Design of e-modules to stimulate HOTS on static fluid materials with the STEM approach
Mera Afriyanti1, Agus Suyatna1*, Viyanti1
1Program studi magister pendidikan fisika, FKIP, Universitas Lampung, Indonesia

*Correspondence Author: asuyatna@yahoo.com

Abstract.The aim of this study is to develop an e-module to stimulate HOTS on static fluid material with
the STEM approach. The research method uses the design of research and development (R&D) using
the ADDIE model which consists of five stages, namely: analysis, design, development, implementation,
and evaluation. This article will only report two stages namely analysis and design. The instrument used
in the form of a questionnaire of product needs analysis and practitioners' validation sheets using a Likert
scale. Source of data for needs analysis are senior high school students and physics educators in
Lampung Province. Product design validation is carried out by qualified and professional physics
educators in their fields with the Masters in Physics Education category. Data were collected using
Google Form and analyzed using descriptive qualitative. The results showed that an e-module to
stimulate HOTS on static fluid material was very needed in the field. The e-module design that has the
potential to stimulate HOTS on fluid material includes learning activities to investigate hydrostatic
pressure, pascal law, archimedes law, capillarity and viscosity properties with the STEM approach. The
e-module presents study material in the form of videos and simulations about diving phenomena,
hydraulic jacks, submarines, which contain STEM components. The e-module directs the project of
manufacturing tools with the principle of hydrostatic pressure. Equipped with assessment as learning
that can strengthen the understanding of static fluid material.

Keyword: E-module, HOTS stimulus, STEM approach, static fluids

40
ID ICC00137

Is Integrated Science Book with Ethno-STEM Approach needed by Secondary School Students?
Arief Muttaqiin1* and Murtiani Murtiani2, Yulkifli Yulkifli2
1Department of Science Education, Universitas Negeri Padang, Jl. Prof. Dr. Hamka Air Tawar Padang
25131, Indonesia
2Department of Physics, Universitas Negeri Padang, Jl. Prof. Dr. Hamka Air Tawar Padang 25131,
Indonesia

*E-mail: muttaqiin.a@fmipa.unp.ac.id

Abstract. STEM is one of the approaches in learning that involves several disciplines in studying a
learning material. Through the STEM approach, students are required to be active in processing
knowledge so as to achieve learning objectives optimally. Contextual science learning will be more
meaningful if it has a close relationship with the surrounding context. This research develops integrated
science teaching materials with the Ethno-STEM Approach through ADDIE (Analysis, Design,
Development, Implementation, and Evaluation) methods. The research in this paper describes one phase
of the ADDIE development method, namely the Analysis phase. An online questionnaire was given to
several secondary school students to find out the need for integrated science teaching materials with the
Ethno-STEM Approach based on the perspective of students as users.

Keyword: STEM

41
ID ICC00146
Development of STEM-Based PBL Student Worksheets in Energetic Materials of First Year
Students

Andriani Dotimineli1 , Mawardi Mawardi2*


1Master Student of Chemistry Education Universitas Negeri Padang,
2 Chemistry lecturer Universitas Negeri Padang

*E-mail: bunda3asa@gmail.com

Abstract. This study aims to produce STEM integrated problem-based learning worksheets that students
can use to see the validity, practicality and effectiveness of LKM on student learning activities. This
research method is a research development using the Plomp model. The design of this study was the
design of one pretest-posttest group. The research subjects were students of chemistry majors Padang
State University 2019. The research instruments used were validation sheets, practicality sheets and
observation sheets of learning activities. This research shows that LKM have a very high level of validity,
very high level of practicality by students and high by the lecturer. The results showed that overall the
average student learning activities were very high. This shows that the LKM that has been produced can
be used as one of the teaching materials in the learning process on energetic material.
Keywords: student worksheets, problem based learning, STEM

42
ID ICC00167

Development pf Guided Inquiry learning Module using Promting Probing Technique in


Electrolite and Non- Electrolite Solution to Increase Thingking Ability Critical Participant In
Class X in Senior High School

Suha Kamilah3 and Hardeli2*

1Magister Student of Chemical Education at Universitas Negeri Padang


2Lecturer in Chemistry at Universitas Negeri Padang
*E-mail: suha.kamila15gmail.com

Abstract. The purpose of this to produce guided inquiry inquiry electrolyte and non-electrolyte chemistry
chemistry modules with probing techniques and determine the level of validity, practicality and use of
modules. This research includes education development research (EDR) using the Plomp development
model which has three stages, namely the initial research stage (preliminary research stage), the
prototype making stage (the prototyping stage) and the renewal stage (the assessment stage). When
making prototypes self-evaluation (self-evaluation), expert evaluation (expert review), individual
evaluation (one-to-one evaluation), small group evaluation (small group evaluation), while testing is done
through the field test (field test) in 2 schools namely SMAN 3 Payakumbuh and SMAN 5 Payakumbuh
The research instrument used was a questionnaire in the form of validity and practicality sheets, multiple
choice questions and critical thinking descriptions. The results of practicality by students in small groups
with an average of 0.89 and practicality by teachers on average 0.90 on the field test is very high.
Hypothesis test results show a significant difference between the learning outcomes of experimental
class students and the control class in schools with low ability, Hypothesis test results also show a
significant difference between the thinking ability of the experimental class and the control class, both in
schools with moderate to low student abilities.

Keyword: module, electrolyte solution and non electrolyte solution, guided inquiry, probing prompting
technique, critical thinking.

3
To whom any correspondence should be addressed.

43
ID ICC00259
Effect of Using Guided Inquiry-Based Chemical Bonding Modules on Student Learning
Outcomes
Iryani1 , Iswendi1, Bayharti1, Regi Fadila2
1Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Negeri Padang ,
2Kansai University, Japan
Kampus UNP, Jalan Prof. Dr Hamka, Air Tawar , Padang, Sumatera Barat, 25131, Indonesia
*E-mail: iryaniachmad62@gmail.com

Abstract. This research is a continuation of research on the development of guided inquiry-based


chemical bond modules that have been tested for validity and practicality, but have not yet been tested
for its effects. This study aims to reveal the influence of using guided inquiry-based chemical bonding
modules on the learning outcomes of class X students of SMAN 4 Padang and SMAN 9 Padang. This
type of research is quasi-experimental research using Non Equivalent Control Group Design. The
research was chosen using purposive sampling technique. The research instrument used a Learning
Outcomes Test in the form of multiple choice questions, consisting of an initial test (pre-test) and a final
test (pos-test). The average value of the increasing on student learning outcomes of SMAN 4 Padang in
the experimental class was 41.21, higher than the control class with a value of 35.00. While, the average
value of the increase in student learning outcomes of SMAN 9 Padang in the experimental class was
18.14, higher than the control class with a value of 10.14. The data of the two subject classes at SMAN
4 Padang are normally distributed and homogeneous. T-test results at the significant level of 0.05, namely
t-count (1.79) > t-table (1.66). The data of the two subject classes at SMAN 9 Padang are normally
distributed and homogeneous. T test results at the significant level of 0.05, namely t-count (2.93) > t-
table (1.66). Student learning outcomes in the experimental class were significantly higher than in the
control class.. Based on the analysis it appears that student learning outcomes using the guided inquiry-
based chemical bond module is increase significantly.

Keyword: effectiveness, modules, guided inquiry, chemical bonding, learning utcomes

44
ID ICC00014

Strengthening Buffer Solution Learning Activities with Numbered Head Together Models
Equipped with a Combined Hand Out - Augmented Reality

Marwan1), Mohammad Masykuri*,2), dan Endang Susilowati3)


1,2,3Program Studi Pendidikan Kimia FKIP UNS
*Corresponding author: mmasykuri@staff.uns.ac.id

This study aims to determine the comparison of the effect between the Numbered Head Together (NHT)
model equipped with Handout-AR and NHT model equipped with Microsoft Powerpoint on student
learning activities on the buffer solution. The study was conducted using the experimental method. The
research sample was determined using the Cluster Random Sampling technique. The research data
were obtained using documentation and observation techniques. The documentation technique is used
to obtain data on the results of students' Middle Semester. The observation technique is used to obtain
data on the value of student learning activities. The research data were analyzed using the Mann Whitney
test. The results showed that the application of the NHT model equipped with Handout-AR could have a
better effect on student learning activities on buffer solution material than the application of the NHT
model equipped with Microsoft Powerpoint. These results are supported by the results of the Mann
Whitney test and the average value of student learning activities from the two experimental classes. Data
analysis using the Mann Whitney test produces asym values. Sig. 2-tailed (0,000) is greater than the
significance level / α (0.050). The experimental class I has an average value of learning activities (87.6)
which is greater than the experimental class II (68.4)

45
International Conference on Chemistry and Science Education 2020
(ICChSE 2020) Parallel Seminar

Science Topics
Name List
Room D
Meeting Link:
https://us02web.zoom.us/j/84541999640?pwd=cERFR1RneElRaHN5SFNxR1dWQ0Fodz09
Meeting ID: 845 4199 9640
Passcode: 300131
Time (Westren Indonesia
No Name Abstract Title
Time UTC: +7)
1 13.25-13.45 Talha Bin Emran, Ph.D Biochemical and computational
(Invited Speaker) approach of phytocompounds from
Tinospora crispa in the
management of COVID-19
13.45-14.00 QnA invited speaker
2 14.10-14.20 Basultan Hidayat Potential binding site of Coronavirus
Disease (COVID-19) Spike Protein:
an in silico Analysis
3 14.20-14.30 Siti Veren Joana Sury Synthesis and characterization of
polyaniline conducting with methods
photopolimerization
4 14.30-14.40 Darmawan Alisaputra The Study of Biodegradation
Bioplastic Based on Arrowroot
Starch With Glycerol Plasticizer And
ZnO Fillers
14.40-14.55 QnA presenter 2-4
5 14.55-15.05 Sony Ananta Herbal Plants from Riau Province as
Inhibitors of COVID-19 Binding to
ACE2 Receptor by Computer Aided
Molecular Design an In-Silico
Method
6 15.05-15.15 Nur Afdila The Study of DNA Adduct (8-OHdG)
Formation as A Cancer Risk
Biomarker as In Vitro in 2’-
Deoxyguanosine DNA Through
Fenton – Like Reaction With
Malondialdehyde (MDA)
7 15.15-15.25 Atika Yahdiyani Ikhsani, Synthesis of the Halal Fragrance
M.Sc. Compound Methyl p-Anisate from
Fennel Oil
15.25-15.40 QnA presenter 5-7
8 15.40-15.50 Erma Maryana, S.Si Extraction and Characterization of
Robusta Green Coffee Bean from

46
Temanggung as Potential
Pancreatic Lipase Inhibitor
9 15.50-16.00 Purwati, S. Si, Apt, M. Farm Repellent Activity Test Of Essential
Oil Gel Of Rosemary Leaves
(Rosmarinus Officinalis l) Againts
Aedes Aegypti Mosquitoes
10 16.00-16.10 Hesty Parbuntari, S.Pd, Molecular Encapsulation of
M.Sc Bioactive Molecules of Ruku-Ruku
Leaves (Ocimum tenuiflorum
Linnen) as a Preliminary Stability
Study
16.10-16.25 QnA presenter 8-10
11 16.25-16.35 -
12 16.35-16.45 -
13 16.45-16.55 -
16.55-17.10 QnA presenter 11-13
14 17.10-17.20 -
15 17.20-17.30 -
16 17.30-16.70 -
17.40-17.55 QnA presenter 14-16

47
Invited Speaker

Biochemical and computational approach of phytocompounds from Tinospora crispa in the


management of COVID-19
Ahmed Rakib1, Talha Bin Emran2*
1Department of Pharmacy, Faculty of Biological Sciences, University of Chittagong, Chittagong-4331,
Bangladesh
2Department of Pharmacy, BGC Trust University Bangladesh, Chittagong-4381, Bangladesh

*E-mail: talhabmb@bgctub.ac.bd

Abstract. A pandemic effected by the novel coronavirus (SARS-CoV-2 or COVID-19) began in December
2019 in Wuhan, China and the number of newly reported cases remains to increase. More than 1.1 million
cases reported globally and about 60,000 of them died as of this writing (4th April 2020). Recently, it has
been confirmed that the SARS-CoV-2 main protease (Mpro) enzyme is responsible not only for viral
reproduction but also impeding host immune responses. The Mpro provides a highly approved
pharmacological target for the discovery and design of inhibitors. No specific therapies are available and
investigations about COVID-19 treatment are lacking. Therefore, herein, we analyzed the bioactive
phytocompounds isolated by gas chromatography-mass spectroscopy from Tinospora crispa as potential
COVID-19 Mpro inhibitors, using molecular docking study. Our analyses unveiled that the top nine hits
might serve as potential anti-SARS-CoV-2 lead molecules where three of them exerts biological activity
and warrant further optimization and drug development process to combat COVID-19.

Keyword: Coronavirus, SARS-CoV-2, Tinospora crispa, COVID-19, Molecular docking

48
ID ICC00135

Potential binding site of Coronavirus Disease (COVID-19) Spike Protein: an in silico Analysis

Basultan Hidayat1, Iryani2, and Fitri Amelia3*

1Department of Chemistry, Universitas Negeri Padang, Padang, Indonesia,


2Department of Chemistry, Universitas Negeri Padang, Padang, Indonesia,
3Department of Chemistry, Universitas Negeri Padang, Padang, Indonesia.
*E-mail: fitriamelia@fmipa.unp.ac.id

Abstract. Coronavirus disease 2019 (COVID-19) was recently spread all over the world. The spike
protein of coronaviruses (S-protein) is the main agent for host cell recognition. Understanding the
potential of binding site of spike protein binding pocket may help to find the specific anti-coronavirus drug.
In this study, Dogsitescorer, site finder moe, and DEPTH were used for predicting binding pocket of spike
protein and its characteristic such as volume, surface area, depth, and druggability. Molecular interaction
studies between protein and ligands were performed using MOE 2009.10 Software. Based on pocket
prediction by Dogsitescorer, there are five out of eleven pockets which have potential binding with
inhibitor drugs and druggability score above 0.8. Molecular interaction studies revealed that interaction
between five potential pockets and ligands such as nafamostat, nelfinavir, and chloroquin diphospate
resulted in negative scores at all. Our result shows that pocket four and six are located on upper of the
S-protein and have high volume, 878.94 and 683.05 (Å3) respectively, yet the lower number of hydrogen
bond. Pocket five which is located in the middle of S-protein has a high number of hydrogen bond and a
drugable score. Our results suggest that both the upper and the middle position of binding sites in the S-
protein can be used to develop anti-coronavirus drugs.

Keyword: Coronavirus disease 2019 (COVID-19), Spike protein, potential binding site, molecular
interaction

49
ID ICC00025

SYNTHESIS AND CHARACTERIZATION OF POLYANILINE CONDUCTING WITH METHODS


PHOTOPOLIMERIZATION

Siti Veren Joana Sury, Alizar Ulianas*


Department of Chemistry, Padang State University, Jln. Prof. Dr. Hamka Air Tawar Barat, Padang,
West Sumatera, Indonesia Telp. 0751 7057420
*Email: alizarulianas@yahoo.com

Abstract - Polymers as they are known are molecules formed from repetition of small molecules known
as monomers, polymers that are often used cannot conduct electricity. Along with the development of the
polymer era at this time can also conduct electricity known as conductive polymers. One of the conductive
polymers that attracts attention is polyaniline. Synthesis of polyaniline conductive polymers is carried out
with aniline monomers mixed with Ethylene Glycol Dimacrylate (DMPP) as Crosslinkers, and Dimethoxy
phenylacetophenone (DMPP) as the initiator. In this study, the polymerization process was carried out
by the photopolymerization method with a mixture of Aniline (mL), DMPP (0.1 g), and EGDMA (mL)
polymerized with photopolymer. The polymers obtained were tested for electrical conductivity, the
composition which showed optimum conductivity was in the ratio of aniline and EGDMA 1 : 1 with the
electrical conductivity of 0.001462 Ohm.cm-1. The conductivity measurement is done by using Four Point
Probe (FPP) and other characterization measurements using FTIR (Fourier Transform Infrared) and TGA
(Thermo-gravimetric Analysis).

Keywords: Conductive polymer, polyaniline, photopolymerization method

50
ID ICC00083

The Study of Biodegradation Bioplastic Based on Arrowroot Starch With Glycerol Plasticizer
And ZnO Fillers

Naela Ulul Maslahah1, Darmawan Alisaputra1, Endaruji Sedyadi1


1 Department of Chemistry, Faculty of Science and Technology, Islamic State University of Sunan
Kalijaga Yogyakarta, Jl. Marsda Adisucipto Yogyakarta 55281, Indonesia

*E-mail: alidarmawan982@gmail.com

Abstract. The Study of biodegradation bioplastic based on arrowroot starch with Glycerol Plasticizer and ZnO
Filler aims to understand the biodegradability of arrowroot starch-based bioplastics with additional ZnO on soil
media. This research was carried out in three stages: the production of arrowroot bioplastics with ZnO variations of
0%, 1%, 2%, 3%, 4%, and 5%, bioplastic characterization testing, and bioplastic biodegradation testing. Bioplastics'
characterization includes mechanical test (tensile strength, elongation, and young modulus), FTIR (Fourier
Transform Infra-Red), and biodegradation testing of bioplastics carried out on soil pH 5 and pH 6. The result showed
with variation 3% of ZnO produce are good mechanical and physical properties. Bioplastics produced tensile
strength of 5,9966 MPa, elongation of 5,00045%, and young modulus of 118,1268 MPa. The biodegradation test
results in soil pH 5 and pH 6, respectively, showed a decrease in the bioplastic mass up to 70% and 72% for 15
days.

Keywords: Bioplastics, Starch, ZnO, Biodegradation

51
ID ICC00138

Herbal Plants from Riau Province as Inhibitors of COVID-19 Binding to ACE2 Receptor by
Computer Aided Molecular Design an In-Silico Method

Riryn Novianty1, M.Si1,Sony Ananta1*, Muhammad Abdul Karim1


1Universitas Riau
*E-mail: rirynnovianty@lecturer.unri.ac.id

Abstract. Corona Virus Disease (COVID-19) is announced as pandemic by World Health Organization
(WHO) since 11th March 2020. Riau Province has many herbal plants e.g. Cheilocostus specious,
Euphorbia hirta l, Senna torra, Bryophyllum pinnatum, Daniella ensifollia, and Ziziphus mauritiana that
can cure many diseases and there is not report yet focusing on in-silico method using SARS-CoV-2
protease (PDB ID:6LU7). This study aims to reveal the potential of compounds contained in Riau
Herbal Plants as anti SARS-CoV-2 through its binding to protein receptors. The study was conducted
by molecular docking using Autodock Vina 1.5.6 and drug ability studies using Swiss ADME. The
docking results of six active compounds including diosgenin, flavonoid, tannin, triterpenoid,
chrysophanol, phytosterol were -8,3; -7,5; -7,5; -7,5; -7,2 -6,9 respectively against the affinity result for
natural ligand of COVID-19 (-6,1). This result indicates the stronger bond between ACE2 and inhibitors
because the affinity value of active compounds are higher than natural ligand of COVID-19. The Swiss
ADME results show that triterpenoid and tannin violate some Lipinski Rules that make their drug
likeness is low. In general all the active compounds were potential as candidates of SARS-CoV-2
antiviral but the most potential one is diosgenin in Cheilocostus specious.

Keyword: ACE2, COVID-19, herbal, inhibitor

52
ID ICC00141

The Study of DNA Adduct (8-OHdG) Formation as A Cancer Risk Biomarker as In Vitro in 2’-
Deoxyguanosine DNA Through Fenton – Like Reaction With Malondialdehyde (MDA)

Nur Afdila1 and Budiawan2*


1Department of Chemistry, Faculty of Mathematics and Natural Sciences, University of Indonesia,
Depok, 16424, Indonesia,
2Department of Chemistry, Faculty of Mathematics and Natural Sciences, University of Indonesia,
Depok, 16424, Indonesia

*E-mail: nur.afdila@sci.ui.ac.id1, dr.budiawan@gmail.com

Abstract. Malondialdehyde (MDA) has been widely reported as a biomarker, endogenous genotoxic
products formed from the results of lipid peroxidation and oxidative stress can bind and modify proteins,
phospholipids and DNA to form stable adducts. Increased oxidative stress triggers in how the adducts
formed. The formation of adducts linked to various patterns of diseases such as cancer, cardiovascular
and neurodegenerative diseases. This study was conducted to analyze the formation of DNA adduct 8-
OHdG due to oxidative damage of DNA caused by exposure to chemical compounds MDA and chromium
(VI). This research is done by using in-vitro studies with MDA compound and Fenton-Like reactions. The
variations done are pH and temperature, with the reaction products analysed by Hitachi Primaide reverse
phase HPLC with UV/vis detector at 254 nm wavelength.

Keyword: Malondialdehyde, Lipid peroxidation , Oxidative Stress, HPLC, 8-Hidroxy-2’ –Deoxyguanosine


(8-OHdG)

53
ID ICC00144

Synthesis of the Halal Fragrance Compound Methyl p-Anisate from Fennel Oil

Susy Yunita Prabawati1, Atika Yahdiyani1*, and Yoga Saputra1


Chemistry Department, Faculty of Science and Technology, UIN Sunan Kalijaga Yogyakarta,

*E-mail: atikaikhsani@gmail.com

Abstract. Synthesis of methyl p-anisate from Fennel Oil has been done. Methyl p-anisate is ester
compound which can use as halal fragrance. p-anisate acid was derivative of anethol from fennel oil
that undergo oxidation process by KMnO4 at 400C for 2 hours. Esterification with menthol carried out
at 400C for 7 hours. Identification and determination structure compound of product synthesis used
spectroscopic methods (FTIR and GC-MS). Identification of methyl p-anisate using FTIR showed the
presence of C-O ester at 1223,41 cm-1 and 1180,44 cm-1; and C = O carbonyl at 1689.64 cm-1. Methyl
p-anisate was different from menthol. It can be showed from mass spectra analysis did not have peaks
m/z 71 and m/z 57. Organoleptic evaluation were carried out by 20 semitrained panelists from the
Chemistry department. The results indicated that the level of fragrance for the methyl p-anisate (4,90)
was fragrant, the sharpness of the methyl p-anisate (5,90) was very sharp, and the level of preference
for the methyl p-anisate (5,00) was prefer. Thus, follow the conclusion that the compound showed
potent ability as chemical component in halal fragrant.

Keyword: Anethol, Esterification, Fragrance, Fennel oil, Methyl p-Anisate

54
ID ICC00150

Extraction and Characterization of Robusta Green Coffee Bean from Temanggung as Potential
Pancreatic Lipase Inhibitor

Erma Maryana1 , Endang Saepudib2*, Noer Laily1

1 Center for Agroindustry Technology, BPPT, Puspiptek Serpong 15314, Indonesia,


2 Department of Chemistry, Faculty of Mathematics and Natural Science (FMIPA), Universitas
Indonesia, Depok

*E-mail: endang.saepudin@sci.ui.ac.id

Abstract. Consumption of functional foods from natural ingredients can be one of the therapeutic steps
to treat obesity. Green coffee beans can be used as a functional food to help body weight loss. Its extract
was known contains a chlorogenic acid which plays important role in reducing body weight through the
mechanism of inhibition pancreatic lipase enzyme. The purpose of this study was to extract and
characterize of Temanggung robusta green coffee beans from Temanggung and also determine the
potency of the extract toward pancreatic lipase inhibition. This research was carried out through a
maceration and liquid-liquid partition. Qualitative and quantitative analysis of chlorogenic acid in extract
was carried out with TLC and HPLC at 324 nm. In vitro inhibition assay of chlorogenic acid against
pancreatic lipase have been done by determining the IC50 value. Result showed that CE and AF extract
contained a chlorogenic acid. Inhibitions assay showed that each extract were active as inhibitors with
IC50 values of CE and AF are 5.82 µg/ml and 10.49 µg/ml, respectively.

Keyword: green coffee, robusta coffee, chlorogenic acid, pancreatic lipase inhibition, obesity

55
ID ICC00156

REPELLENT ACTIVITY TEST OF ESSENTIAL OIL GEL OF ROSEMARY LEAVES (Rosmarinus


officinalis L) AGAINTS Aedes aegypti MOSQUITOES

Maharani Ayu Manik Pratiwi1 and Purwati2*


1 Fakultas Farmasi Universitas 17 Agustus 1945 Jakarta,
2 Fakultas Farmasi Universitas 17 Agustus 1945 Jakarta

*E-mail: putri_nuryadi@yahoo.com

Abstract. Rosemary leaf (Rosmarinus officinalis L) is a plant containing essential oils such as geraniol,
linalool, sineol, and burneol. Essential oils used as insect repellent. This research is about repellent test
of Rosemary (Rosmarinus officinalis L) gel for Aedes aegypti mosquito which aims to find out whether
Rosemary (Rosmarinus officinalis L) can provide activity as a repellent preparation for Aedes aegypti
mosquitoes. Rosemary essential oils (Rosmarinus officinalis L) are formulated in the form of gel
preparation with various concentration namely 6%, 12%, 24% and use positive control repellent supply
on the market that contains DEET. Volunteer completed that process over 4 days. The volunteer arms
were inserted into the cage containing 50 mosquitoes which had been applied to the gel. The test is
performed for 5 minutes every 4 hours, with 5 repetitions. The result shows that Rosemary essentials oil
(Rosmarinus officinalis L) gel has a repellent activity againts Aedes aegypti mosquito on F3 24%
concentration with 92,15% protection for 4 hours. The stability of gel preparation that organoleptic do not
change the color, taste, smell, and shape. Homogeneous gel preparation, with pH, dissipation, and
viscosity are suitable for 8 weeks at different temperatures (4°C, 25°C and 40°C), and do not irritation to
the skin.

Keyword: Aedes aegypti, essential oils, repellent, gel, Rosmarinus officinalis

56
ID ICC00009

Molecular Encapsulation of Bioactive Molecules of Ruku-Ruku Leaves (Ocimum tenuiflorum


Linnen) as a Preliminary Stability Study
Hesty Parbuntari4*, Sri Benti Etika1, Melindra Mulia1 and Elfanny Delvia1
1Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Negeri Padang,
Padang Utara, Padang 25132 West Sumatera, Indonesia

*E-mail: hesty5193@fmipa.unp.ac.id

Abstract. Ruku-ruku (RK) leaves in West Sumatra contain various essential oil which is known as
secondary metabolites. They could influence the use of these bioactive properties as medicinal
compounds. Essential oils have unstable properties to oxidation, evaporation, or chemical reaction. One
method for maintaining compound stability is the encapsulation method. This study performs the
encapsulation of RK in β-CD. By using the co-precipitation method, this study produces pure crystal with
62,5% of the efficiency of encapsulation. The diffraction pattern of RK-β-CD identified the crystals pattern
with a sharp peak of diffraction and most of these peaks showed patterns of diffraction in β-CD. The
absorption intensity of the pure CD was only 2.5 but after inserting the RK in its cavity the intensity
increased to 2.7. It shows that there is an interaction between the non-covalent part of β-CD and the
essential oil molecules. Furthermore, the RK-β-CD is more stable as the increase in the boiling point of
the ICs in the range of 282-289oC.

Keyword: Ruku-Ruku, β-Cyclodextrin, encapsulation, coprecipitation, stability

57
International Conference on Chemistry and Science Education 2020
(ICChSE 2020) Parallel Seminar

Science Topics
Name List
Room E
Meeting Link: https://zoom.us/j/96449117992?pwd=SVJXVFVjOTRkWTdUWU1tRGY4cnZ5Zz09
Meeting ID: 964 4911 7992
Passcode: 475361
Time (Westren
No Indonesia Time UTC: Name Abstract Title
+7)
1 13.25-13.45 Budhi Oktavia (Invited RESEARCH ON NATURAL SILICA,
Speaker) ACTIVATION, MODIFICATION
AND USE AS AN ADSORBENT
FOR ANIONS
13.45-14.00 QnA invited speaker
2 14.10-14.20 T LAVANYA, BSc DEVELOPMENT OF EFFECTIVE
Biotechnology WASTE MANAGEMENT
STRATEGIES IN THE
CHINNACHOKKIKULAM
COMMUNITY
3 14.20-14.30 Nora Kemala Weni Optimization of Hexavalent
Chromium Ion Adsorption Using
Natural Silica Modified with DMA
(Dimethylamine) by Batch Method
4 14.30-14.40 Emut Sukma Sejati The Effect of Multiple Electrode
Pairs to Electricity Potential of
Ceramic-based and Tempe Waste
Microbial Fuel Cell
14.40-14.55 QnA presenter 2-4
5 14.55-15.05 Dr. Yuli Yetri M. Si BIOMASSA WASTE OF COCOA
SKIN FOR BASIC ACTIVATED
CARBON AS SOURCE OF
ENERGY STORAGE
ENVIRONMENTALLY FRIENDLY
6 15.05-15.15 Media Roza, M.Si The Quality Analisis on the Food
Snack Consumed by The Islamic
School Students in Padang:
Biological, Chemical and Physical
Aspect
7 15.15-15.25 Alizar Ulianas Molecularly Imprinted Polymer
(MIPs) Nanomaterials Design as
Absorbing Cholesterol in Blood

58
15.25-15.40 QnA presenter 5-7
8 15.40-15.50 Dr. Desy Kurniawati., Effect of Contact Time Absorption of
S.Pd.,M.Si Rhodamin B, Methyl Orange and
Methylene Blue Colors on Langsat
Shell with Batch Methods
9 15.50-16.00 Dra. Sri Benti Etika, M.Si Optimizing the Optimum Condition
of C-Cinnamal Calik[4]
Resorcinarene (CSKR) Compounds
as Methanil Yellow Adsorbent
10 16.00-16.10 Indang Dewata Optimization of Catalyst Mass of
Sodium Carbonate and Ethylene
Glycol Solvent by Glycolisis for
Application of Microplastic Waste of
Polyethylene Terephthalate
16.10-16.25 QnA presenter 8-10
11 16.25-16.35 Trisna Kumala Sari, M.Si, Voltammetric Detection of
Ph.D Chromium (VI) with Gold Thin Layer
Modified Pencil Lead Electrode
12 16.35-16.45 -
13 16.45-16.55 -
16.55-17.10 QnA presenter 11-13
14 17.10-17.20 -
15 17.20-17.30 -
16 17.30-16.70 -
17.40-17.55 QnA presenter 14-16

59
Invited Speaker

RESEARCH ON NATURAL SILICA, ACTIVATION, MODIFICATION AND USE AS AN ADSORBENT


FOR ANIONS

Budhi Oktavia*, Robi Prasmi Kardi, Nora Kemala Weni, Renti Sefriani

Department of Chemistry, Padang State University, Jl. Prof. Hamka, Air Tawar Barat,
Padang, West Sumatera, Indonesia Telp. 0751 7057420
* budhioktavia@fmipa.unp.ac.id

Abstract. Silica is a mineral that is abundant in the earth's surface. Silica has also been used in human
civilization, such as making glass, electronic devices, adsorbents, fertilizers and others. Utilization of
natural silica requires technology that is reliable enough so that impurities in the natural silica do not
interfere with its use. In this study, tests have been carried out on natural silica, such as chemical and
physical activation, reactions with certain reagents and also modifications made to the natural silica. The
desired result is that natural silica can be used as an adsorben, ion exchange and also a stationary phase
in the chromatography column. From this research a natural silica modification has been obtained using
dimethylamine (DMA) to convert natural silica into positive charge so that it can be used to increase the
absorption of some anions.

Keywords : Natural Silica, Modification, Dimethylamine, Absorbent, Anion.

ID ICC00127

60
DEVELOPMENT OF EFFECTIVE WASTE MANAGEMENT STRATEGIES IN THE
CHINNACHOKKIKULAM COMMUNITY
Dr. S. Kalaivani Priyadarshini, T.Lavanya, M.S.Hazeena Fathima, I.Jeba Snetha, S.Suhasini,
A.K.A.Tharani

Abstract. The solid waste management project was implemented in Chinnachokkikulam, Madurai for
effective management of floral, kitchen and fruit wastes accumulated in the target community. In order to
implement the current project a questionnaire-based survey was carried out to assess the types of waste
generated, segregation, reuse or recycling of waste and disposal-based strategies available in the
community. Based on the pilot field study the current project was implemented. Among the different types
of waste generated, the vegetable, fruit and flower waste were further utilized for the production of
alternate value-added products like incense sticks, the fruit peel was used for water purification and also
tested for heavy metals (chromium and copper) absorption. The water purified with the peels was
subjected to atomic absorption spectrometry test to estimate the amount of heavy metals in the water
before and after purification showed an appreciable water filtration mechanism. Macroalgae collected
from Rameswaram was used as liquid fertilizer in the community showed an enhanced germination and
growth of the mustard see. The incense sticks, purification of water containing heavy metals using banana
and orange, and the liquid fertilizer is an advantageous method since it is economical, eco-friendly, and
compatible. Thus, through this life frontier engagement study awareness and generation of eco-friendly
strategies by using sustainable solid waste recycling process to reduce waste, eliminate its influence on
the environment and production of value-added product was demonstrated to the target community.

61
ID ICC00160

Optimization of Hexavalent Chromium Ion Adsorption Using Natural Silica Modified with DMA
(Dimethylamine) by Batch Method

Nora Kemala Weni1 and Budhi Oktavia2*


1Department of Chemistry, Padang State University
2Department of Chemistry, Padang State University

*E-mail: budhioktavia@fmipa.unp.ac.id

Abstract. Heavy metals are the most dangerous source of pollution in the environmental system because
they have non-biodegradable, toxic, even carcinogenic properties even in low concentrations (ppm).
Usually experience several conditions, namely insoluble, precipitated, dissolved, absorbed, inorganic,
reduced, oxidized, and free metals. One of the heavy metals that can cause negative effects on humans
and living things is chromium ions. Waste from the use of chrome can pollute the environment. Chrome
is a heavy metal that has a dangerous impact to watch out for. Chromium (VI) in waters is found in two
species of ion form, namely as Cr2O72-anion (in acidic solution) and CrO42-anion (in basic solution). One
way to overcome chromium metal in waste is by absorbing it with adsorbent, DMA modified silica.
Chromium (VI) adsorption from aqueous solutions investigated at various pH, contact time, initial Cr (VI)
concentrations. The experimental results show that the modification of silica with DMA increases the
adsorption capacity for Cr (VI). The Langmuir adsorption isotherm produces a regression coefficient R2
= 0.9807. Maximum adsorption capacity of Cr (VI) 1,024 mg g -1 with initial Cr (VI) concentration of 100
mg L-1 was reached at pH 2.0 with stirring for 90 minutes.

Keyword: Adsorption, Cr (VI) ions, Silica, batch method

62
ID ICC00128

The Effect of Multiple Electrode Pairs to Electricity Potential of Ceramic-Based and Tempe
Waste Microbial Fuel Cell

Emut Sukma Sejati1* and Sudarlin1


1Chemistry Departement, Faculty of Science and Technology, UIN Sunan Kalijaga.

*E-mail: 16630030@student.uin-suka.ac.id

Abstract. Ceramic as low cost separator membrane has widely applied in dual chambered Microbial Fuel
Cell (MFC). Its big pores and other chemical and physical advantages make it suitable to substitute
expensive exchange separator membrane. The purpose of this study is to enhance the electricity of
ceramic based microbial fuel cell by using various number of carbon electrode pairs. However, the study
of ceramic with various carbon electrode pairs has never been published before. This study use tempe
waste as anolyte and KMnO4 as its catholyte to gain electricity. Tempe waste is incubated for 24 hours
before using. Running of the MFC is 48 hours straight with voltage and current check every 2 hours.
Three variety of electrode pairs are checked together in the same interval. Those data processed
statistically using Analysis of Variance (ANOVA) test to examine the significant difference of the voltage,
current, and power density as the parameters. The result of this study shows that the electricity of three
electrode pairs has the higher average of power density with the number 1447,91 mW/m 2, the difference
between three and two electrode pairs is around 588 mW/m2 and between three and one electrode pairs
is 910 mW/m2 . It has significant difference between one, two, and three electrode pairs in the parameters.
There is no significant difference in waste appearance although the number of Chemical Oxygen Demand
(COD) and Biochemical Oxygen Demand (BOD) has dropped down after the running.

Keyword: dual chamber, current, voltage, power density, COD, BOD, ANOVA

63
ID ICC00136

BIOMASSA WASTE OF COCOA SKIN FOR BASIC ACTIVATED CARBON, AS SOURCE OF


ENERGY STORAGE, ENVIRONMENTALLY FRIENDLY

Yuli Yetri1*, Eka Sunitra1, Rakiman1, Yazmendra Rosa1


1Mechanical Engineering Department, Politeknik Negeri Padang, Padang, Indonesia

*yuliyetri@pnp.ac.id

Abstract. Increased cocoa production is in line with the potential increase in cocoa pod waste. One way
to reduce the accumulation of biomass waste is to change the skin of cocoa pods into activated carbon
by combination of chemical activation and physical activation methods. The purpose of this study was to
utilize cocoa pods into activated carbon. Characterization of results using FT-IR, Thermal Gravimetry
Analysis, X-ray diffraction (XRD), Scanning Electron Microscopy (SEM), and X-ray energy dispersion
(EDX). Pre-carbonization at 250C for 2.5 hours, and activated charcoal with KOH activator 0.3M and
0.4M 700 oC. The results of analysis of the content of cocoa pods consist of lignin 51.98%, hemicellulose
21.06%, cellulose 20.15% and alpha selolusa 21.80%. The functional groups of cocoa pod powder using
FT-IR showed depolymerization for cellulose and hemicellulose content. Wave number 1051cm-1 shows
the functional group C-O stretcing vibration. The appearance of a peak of 1603cm-1 indicates the
presence of a C = O carbonyl group and a peak of 3422cm-1 indicates the presence of a hydroxyl group
(C-OH) in a compound contained in cocoa fruit extract. The physical properties of activated carbon
increased and their electrochemical properties decreased with an increase in activator concentration from
0.3 M to 0.4 M, with an activated carbon content of 87.05%. The specific capacitance value at a
concentration of 0.3 M is 90.2 F/gr with a density of 0.850gr/cm3 and a concentration of 0.4 M is 140.2
F/gr with a density of 0.802 gr/cm3. From the XRD analysis the degree of crystallinity of cocoa pods was
12.66%. Utilization of cocoa pod waste into activated carbon with a combination of physics-chemical
activation methods is capable of storing energy to overcome the current energy crisis.

Keyword: Cacao, Cacao waste, Activasi, Active carbon, Hemiselulosa

64
ID ICC00188

The Quality Analisis on the Food Snack Consumed by The Islamic School Students in Padang:
Biological, Chemical and Physical Aspect
Media Roza1, Milya Sari1 and Nurhasnah1
1Tadris IPA UIN Imam Bonjol Padang

*E-mail: mediarozaipa@gmail.com

Abstract. Food snacks are very commonly found around the madrasah (Islamic School), as what be
found in Padang. After conducting some observation on the snacks sold around the Madrasahs in
Padang, it was found was that the snacks are unsafe to consume. This study aimed to determine the
quality of snacks from aspects of biology, chemistry, and physics. Sample snacks have been taken from
all madrasah in the city of Padang. Sampling technique used for the snacks was done through purposive
sampling. Biological test data was performed on pathogenic bacteria content Escerichia coli and
Salmonella. Chemical test was also carried out on the hazardous chemical content of borax, formalin,
and rhodamin B. Physical contamination test was conducted to recognize the presence or absence of
hair, insects, sand, and wood on the snacks. The results found that samples of food snacks and beverage
in Madrasahs in Padang, were found to be contaminated with Escherichia coli, containing formalin, and
borax, as well as physical contamination.

Keyword: food snacks, madrasah, Escerichia coli, formalin, borax

65
ID ICC00004

Molecularly Imprinted Polymer (MIPs) Nanomaterials Design as Absorbing Cholesterol in Blood

Nadia Sabrina1,a Alizar Ulianas2,b, , Nurlely3,c and Yulkifli4d


1,2Department of chemistry, Faculty of Mathematics and Science, Universitas Negeri Padang, Sumatera
Barat, Indonesia
3Department of Physic, Faculty of Mathematics and Science, Universitas Indonesia, Jakarta, Indonesia
4Department of Physic, Faculty of Mathematics and Science, Universitas Negeri Padang, Sumatera
Barat, Indonesia

balizar_chem@yahoo.co.id (corresponding author)

Abstract. Nanomaterial Molecularly Imprinted Polymer (MIPs) from Methacrylic acid (MAA), Ethylene
glycolmethacrylate (EGDMA), 2,2-Dimetoksi-2-Phenyliacetonephenon (DMPP) and cholesterol as
monomer, crosslink and templates have been successfully synthesized by the photopolymerization
method using Ultra-violet light. MIPs has been characterized by SEM to see the physical shape and size
of his fingers, while cholesterol extraction and re-extraction in MIPs was analyzed by FTIR. The
absorption capacity of MIPs against cholesterol in solution was analyzed by the calorimetry method using
Liebermann-Burchard reagent. MIPs absorption of cholesterol in the blood was analyzed by Easy Touch
GCU. The results of SEM analysis (Scanning Electron Microscope) showed that MIPs were spherical
with a diameter of 1,038m to 2.702m. While FTIR analysis shows that MIPs cholesterol can be
extracted and re-extracted in MIPs. Test of MIPs absorption against cholesterol in solution is 84.49% for
0.30 grams of MIPs in 30 minutes of absorbance time. While the absorption of MIPs against cholesterol
in the human blood is 41.19 %%, it shows that pores and active groups of MIPs cholesterol are able to
selectively absorb cholesterol molecules.

Keywords: Molecularly Imprinted Polymer (MIPs) nanomaterial,photopolymerization, Cholesterol


absorbance

66
ID ICC00108

Effect of Contact Time Absorption of Rhodamin B, Methyl Orange and Methylene Blue Colors on
Langsat Shell with Batch Methods

Desy Kurniawati1* , Bahrizal1, Fransiska Adella1 , Trisna Kumala Sari1

*Department of Chemistry, Faculty of Mathematics and Natural Sciences, Padang State University,
Indonesia
*desy.chem@gmail.com
Abstract. This study aims to see the absorption capacity of langsat shell to the dye at the time of contact.
Textile dyes are dyes that are harmful to the environment and living things. This textile industrial waste
can cause a decrease in water quality. When this dye enters the human body it can be carcinogenic
which can cause cancer . Processing of this dye using langsat shell, components of langsat skin that
can absorb dyes are triterpenoids, saponins and flavonoids. This study uses a batch method by treating
the contact time variations of several dyes.The results showed that the biomass absorption of 11,578
mg/g in rhodamin B dyes, biomass absorption of 3,8425 mg/g in methyl orange dyes, and biomass
absorption of 36,735 mg/g in methylene blue dyes.

Keywords : Biosorption, Contact Time, Rhodamine B, Methyl Orange, Methylen Blue, Bath Method,
Column Method, Langsat ( Lansium domesticum)

67
ID ICC00170

Optimizing the Optimum Condition of C-Cinnamal Calik[4] Resorcinarene (CSKR) Compounds


as Methanil Yellow Adsorbent

S B Etika1, E Nasra1,
1Chemistry Department, Faculty of Mathematics and Sciences, Universitas Negeri Padang,
Indonesia

*E-mail: sribentietika67@gmail.com

Abstract. Rapid population growth causes many environmental problems, one of which is the pollution
of methanil yellow in the waters. One of the effective methods in controlling water due to dyesis through
the adsorption method with a batch system. C-SinamalKaliks [4] Resorsinarene (CSKR) compound is a
compound synthesized from cinnamon oil waste that has great potential to be developed as an adsorbent
for dangerous dyes. The purpose of this study is to determine the maximum absorption capacity of CSKR
against methanil yellow using optimum conditions parameters (concentration and contact time) that are
estimated to affect the absorption of methanyl yellow. Absorption of methanil yellow in solution by C-
sinamal calix [4] resorcinarene (CSKR) compounds is carried out at the optimum pH of 3 with varying
concentrations of 20, 50, 100, 150 and 200 mg / L.. The amount of methanil yellow reaches an absorption
capacity of 1.83 mg / g at a concentration of 150 mg / L while for the contact time is carried out at the
optimum pH and optimum concentration with variations in contact time 30, 60, 90, 120, 150, and 180
minutes. From the results of the study, the optimum contact time was 150 minutes with an absorption
capacity of 2.1375 mg / g.

Keyword: Adsorbent, C-Cinnamal Calix, Rhodamin B, Synthesis, Spectrofotometer.

68
ID ICC00171

Optimization of Catalyst Mass of Sodium Carbonate and Ethylene Glycol Solvent by Glycolisis
for Application of Microplastic Waste of Polyethylene Terephthalate (PET) in Seawater in
Padang City
Indang Dewata1*, Desy Kurniawati1, Trisna Kumala Sari1, KasmaWarni1
1Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Negeri Padang
Kampus UNP, Jalan Prof. Dr Hamka, Air Tawar , Padang, Sumatera Barat, 25131, Indonesia
*E-mail: i_dewata@yahoo.com

Abstract. Polyethylene Terephthalate (PET) is a type of plastic waste commonly found in the sea
especially disposable soft drink bottles. PET plastic waste can decompose into harmful microplastics if
swallowed by marine life. This study aims to determine the microplastic content of PET type in seawater
in the city of Padang by glycolysis method using ethylene glycol (EG) solvent with a sodium carbonate
as catalyst (Na2CO3) for depolymerization of PET to be a monomer of bis (2-hydroxyethyl terephthalate)
(BHET). Glycolysis is carried out for 1 hour at 1960C. In this study, the variation of sodium carbonate
(Na2CO3) catalyst mass used are 0.02 gram, 0.04 gram, 0.06 gram, 0.08 gram, and 0.1 gram) and
variation of ratio PET bottles: ethylene glycol (gram: mL) are 10 : 20, 10:30, 10:40 and 10:50. The result
obtained is 72.22% BHET product under optimum condition with amount of EG of 30 mL and Na2CO3
catalyst mass of 0.06 grams. The BHET was identified using FTIR to confirm the OH-, C-O, and C = O
groups. Seawater samples are taken from three locations namely Padang beach, Tabing beach and
Gajah Padang beac. The result shows absence of PET type microplastic in these samples.

Keyword: Polyethylene Terephthalate (PET), Glycolysis, bis (2-hydroxyethyl terephthalate) (BHET),


Microplastic, Na2CO3

69
ID ICC00072

Voltammetric Detection of Chromium (VI) with Gold Thin Layer Modified Pencil Lead Electrode
*Trisna Kumala Sari
Department of Chemistry, Faculty of Math and Natural Science, Universitas Negeri Padang
*trisna.kumala.s@fmipa.unp.a.id

Chromium is present as the oxidation states (III) and (V) in environmental and geological samples, while
hexavalent chromium Cr(VI) is toxic, mutagenic and carcinogenic metal. Therefore, the development of
an analytical method for rapid and sensitive determination of Cr(VI) at trace level is of great importance.
Cr(VI) has been reported to be determined by using stripping voltammetry at very various chemically
modified electrodes at very low concentration levels. The reproducibility, however, are more difficult to
attain with these electrodes. In this study, the electrochemical behavior of Cr(VI) was studied at gold thin
layer electrodeposited pencil lead electrode. Pencil lead electrode have many advantages, such as high
electrochemical reactivity, low cost, low technology and low background current. On the other hand,
pencil lead electrode exhibits poor electrocatalytic sensitivity. Gold thin layer electrodeposited at pencil
lead electrode is very interest technique for Cr(VI) detection. Pencil lead electrode modified with gold thin
layer by using potential-sweeping electrodeposition for one cycle in 50 µM HAuCl4. 4 H2O and 0.1 M KCl.
The applied potential at the electrode was scanned from 1.2 V to 0 V at a sweep rate 100 mV/s. Since
the speciation of Cr(VI) depends on the solution pH, which is available as CrO 42−, HCrO4−, H2CrO4 or
Cr2O72−, effect of supporting electrolyte matrix and pH are investigated. It was found that Cr(VI) gave a
well defined peak with a peak potential of 0.34 V vs. Ag/AgCl towards the reduction of Cr(VI) in cyclic
voltammograms when 0.1 M HClO4 was used as supporting electrolyte. The calibration curve for Cr(VI)
at gold thin layer electrodeposited pencil lead electrode shows linearity from 5 µM to 100 µM by cyclic
voltammetry without preconcentration process. When the electrode was electrochemically modified, it
was found that reduction peak appeared at the more positive potential at 0.35 V than that at unmodified
electrode at 0.05 V and also peak currents were more larger observed at pencil lead electrode modified.
The reduction potential shift was suggested to be due to electrochemically catalytic property of gold thin
layer electrodeposited on the pencil lead surface.

Keyword: Chromium(VI), Gold Thin Layer Pencil Lead Electrode, Voltammetry,


Electrocatalytic

70
International Conference on Chemistry and Science Education 2020
(ICChSE 2020) Parallel Seminar

Science Topics
Name List
Room F

Meeting Link: https://us02web.zoom.us/j/88384551749?pwd=MncweitKNFlIbCtDaHQyTDRrcDVaQT09


Meeting ID: 883 8455 1749
Passcode: 943060
No Time (Westren Name Abstract Title
Indonesia Time UTC:
+7)
1 13.25-13.45 Miftahul Khair, M.Sc,Ph.D Synthesis and Characterization of Pd-
supported Fluoro-dodecavanadates
Synthesis and Characterization of Pd-
supported Fluoro-dodecavanadates
13.45-14.00 QnA invited speaker
2 14.10-14.20 Dr. Akram La Kilo, S.Pd., Atomistic Simulation of La and Mn-
M.Si. Doped PbBi2Nb2O9 Aurivillius Phase
3 14.20-14.30 Dwi Oktaviana, S.TP Effect of Cross-linking and Fatty Acid
addition on the Functional Properties and
Disgestibility of Tapioca Starch
4 14.30-14.40 Zidni Rahmatika, S.Si Theoretical Modification of Pheophytin
Using Cu, Ni, and Zn Atoms as a
Sensitizer for Dye Sentized Solar Cell
(DSSC)
14.40-14.55 QnA presenter 2-4
5 14.55-15.05 Tirta Suci Dhian Kasih Green Preparation of Activated Carbon
by Ultrasonic Assisted Activation
6 15.05-15.15 Hidayatullah Putra Pyropheophorbide-α Derivatives as a
Hutasoit, S.Si Dye Compound for Dye-Sensitized Solar
Cell (DSSC): Theoretical Investigation
7 15.15-15.25 Ansori, ST. Central Composite Design for
Optimization of Biodiesel Production from
Palm Oil and Methyl Acetate using
Ultrasound Assisted Interesterification
15.25-15.40 QnA presenter 5-7
8 15.40-15.50 Dra. Syamsi Aini, M.Si, The Quantity Study of Na2SiO3 to
Ph.D Synthesize Fe3O4-Fe2O3 @SiO2
Composite by Using X-Ray Diffraction
Data
9 15.50-16.00 Renti Sefriani Modification of Natural Silica Using
Dimethylamine and It’s Application as a

71
Phosphate Ion Absorption
10 16.00-16.10 Dr.Hardeli, M.Si Titanium Dioxide with Ag
Electrodeposition for Solar Cell (DSSC)
Applications Using Extracts of Natural
Dyes
16.10-16.25 QnA presenter 8-10
11 16.25-16.35 Hary Sanjaya, M.Si Degradation Rhodamin-B Using ZnO-
TiO2 as Catalyst by Photosonolisyst
Method.
12 16.35-16.45 Okta Suryani, Ph.D COMPUTATIONAL STUDY OF
CHARACTERS AND ACTIVITIES OF
ORGANIC PHOTOSENSITIZERS FOR
HYDROGEN PRODUCTION FROM
WATER INSPIRED BY
13 16.45-16.55 -
16.55-17.10 QnA presenter 11-13
14 17.10-17.20 -
15 17.20-17.30 -
16 17.30-16.70 -
17.40-17.55 QnA presenter 14-16

72
Invited Speaker
Synthesis and Characterization of Pd-supported Fluoro-dodecavanadates

Miftahul Khair

Department of Chemistry, Faculty of Math and Natural Science, Universitas Negeri Padang

Abstract. Polyoxometalates (POM) have potential applications in fields of catalysis, magnetism,


medicine, electrochemistry, luminescence, and material science. Halide anions incorporation on a
spherical polyoxovanadate (POV) can reduce the surface charge and increase electronegativity.
Modification of polyoxometalate by attachment of noble metals like Pd is interesting in order to develop
new linkers for POM based coordination framework (POMOF) materials and for oxidation catalysts.
Herein we report the synthesis these types of POV: [n-Bu4N]4[V12O30F2] [1],
[VO(DMSO)5]2[{Pd(DMSO)2}2V12O32(F)2][2],and{n-Bu4N}4[{Pd(NO3)(DMSO)}2V12O32(F)2]·2DMO [3]
Complex [1] is prepared by reduction with hydrazine of (n-Bu4N)4[HV11O29F2]. Addition of Pd2+ to DMSO
solution of [1] gave complex [2]. Addition of nitrate salt of Pd2+ to DMSO solution of [V10O26] and F− ion
gave complex [3]. The successfully synthesized three complexes afford
spherical shape containing two anions F−. Complex [1] is mixed valence
[VV10VIV2O30F2]4- which shows electrochemical behavior potential for electron
sponge application. The reaction of precursor complex [1] with Pd 2+ and DMSO
afforded complex [3] which is first mixed valence Pd supported
fluorododecavanadate linker.. Spherical [3] anion consists of ten VO5 units and
two VO4 units. Two palladium with two DMSO ligands attached are supporting
the main cage at both sides. Cation [VO(dmso)5]+ comes from the partial
decomposition of complex [1] during the reaction. By the oxidation of
decavanadate {n-Bu4N}4[V10O26] in the presence of F− and Pd(NO3)2 in dimethyl
sulfoxide (DMSO), a palladium-supported fluoride-incorporated
dodecavanadate, [3] was synthesized. Even sharing similar main cage shapes
with [2], complex [3] is fully oxidized with nitrate and DMSO ligand attached to
Pd. The dodecavanadate component consisted of ten VO5 units and two VO4
units in the framework with two fluoride inside the framework and each VO4 unit
was coordinated to Pd2+. 51V NMR spectrum showed four peaks at −444, −458,
−525, and −542 ppm with the intensity ratio of 2:1:2:1, showing the stability of 1
in the solution state. In addition to their potential application, the complexes
show a very interesting feature of coordination chemistry where all types of
coordination geometry is presented just in one compound; square planar, tetrahedral, square pyramid,
and even octahedral geometry.

73
ID ICC00052

Atomistic Simulation of La and Mn-Doped PbBi2Nb2O9 Aurivillius Phase

Akram La Kilo1*, Ramona Nintias R. Abas1, Deasy N. Botutihe1, Jafar La Kilo1


1Department of Chemistry, Faculty of Mathematics and Natural Sciences, State University of Gorontalo,
Jl. Habibie, Desa Moutong, Kec. Tilongkabila, Bonebolango Gorontalo

*E-mail: akram@ung.ac.id

Abstract. This study aims to determine the effect of Mn 3+ and La3+ dopants on the structure of
PbBi2Nb2O9 (PBN) using atomistic simulation. PBN phase geometry is optimized before the phase is
doped with Mn3+ and La3+. Mn3+ partially replaces octahedral Nb5+ in the perovskite layer. While La3+
partially substitute Bi3+ in the bismuth layer and dodecahedral Pb2+ in the perovskite layer. The
concentration (x) of dopants that doped PBN is made in such a way that it produces a phase of Pb 1-2xBi1.5
+ 2xLa0.5Nb2-xMnxO9 (x = 0, 0.1, and 0.3) which is not charged. The simulation results show that the
optimized PBN cell parameters are in a good agreement with the experimental result. Increasing the
concentration of dopants makes the Pb1-2xBi1.5 + 2xLa0.5Nb2-xMnxO9 (PBLNM) phase to be less
stable, as indicated by the increased lattice energy. When x = 0.3, PBNM structure experiences an
elongation which is showed by the cell parameters of c increase while a and b decrease. La3+ prefers to
occupy bismuth oxide layer rather than the dodecahedral A-site of the perovskite layer. The results of
this simulation can explain the PBLNM structure of experimental results that do not pay attention to the
multiplicity of doped PBN with certain dopant concentrations.

Keyword: Aurivillius; PbBi2Nb2O9; atomistic simulation; mangan and lantanida dopants

74
ID ICC00074

Effect of Cross-linking and Fatty Acid addition on the Functional Properties and Disgestibility of
Tapioca Starch
Dwi Oktaviana11 and Endang Saepudin21*
1Departement of Chemistry, Faculty of Mathematics and Natural Sciences (FMIPA), Universitas
Indonesia, Depok 16424, Indonesia
*E-mail: endang.saefudin@sci.ui.ac.id

Abstract. The present work was carried out the effect of cross-linking and fatty acid addition on functional
properties and disgestibility of tapioca starch. Tapioca starch was chemically modified using sodium
trimetaphosphate (STMP)/sodium tripolyphosphate (STPP) and fatty acid addition used stearic acid
(C18). Thermogravimetric analysis exhibited higher thermal stability for the modified granules compared
to the native one. A-type were formed on native and cross-linking starch, then A-type and V-type
crystalline polymorphs were formed between starch and fatty acids. The both modification decreased
solubility, swelling power, paste clarity and the dual modification significantly decreased digestibility of
Tapioca Starch.

Keyword: tapioca starch, cross-linking, fatty acid addition, stearic acid

75
ID ICC00077

Theoretical Modification of Pheophytin Using Cu, Ni, and Zn Atoms as a Sensitizer for Dye
Sentized Solar Cell (DSSC)
Sudarlin1 and Zidni Rahmatika2*
1,2 Chemistry Department, Faculty of Science and Technology, Sunan Kalijaga Islamic State University,
Yogyakarta Jl. Marsda Adisucipto Yogyakarta 55281 Tel. + 62-274-540971

*E-mail: rahmatika.zidni@gmail.com

Abstract. Theoretical studies of pheophytin compound modified with Cu, Ni, and Zn atoms as a sensitizer
for dye solar cell compound (DSSC) have been carried out based on HOMO-LUMO energy parameters,
LUMO electron localization, spectra, light absorption efficiency, coupling constant, and sensitizer bond
length with TiO2 . This study aims to determine the parameters of bond length, spectra, molecular density,
HOMO-LUMO energy, LHE, and ΔG injection of pheophytin α and β complexes using the central atoms
of Cu, Ni, and Zn; and formulating the effect of adding central atoms of Cu, Ni and Zn on the
characteristics α and β pheophytin photoelectric and determine the best modification capable of
producing the best characteristics for pheophytin as a dye compound on the DSSC based on parameters
of bond length, spectra, molecular density, energy HOMO-LUMO, LHE, and ΔG injection. The theoretical
modification that used is DFT/B3LYP, the accuracy of the method used amounted to 89.27% and 96.09%.
Based on the above parameters the best modification sensitizer for DSSC is Zn Pheophytin β> Zn
Pheophytin α> Pheophytin β> Pheophytin α> Cu Pheophytin β> Ni Pheophytin α> Ni Pheophytin β> Cu
Pheophytin α.

Keyword: Feofitin α dan β, atom Ni, Cu, Zn, DFT, DSSC, energi orbital molekul, energi HOMO-LUMO,
konstanta kopling (Vrp), panjang ikatan, dan spektra efisiensi penyerapan cahaya (LHE)

76
ID ICC00091

Green Preparation of Activated Carbon by Ultrasonic Assisted Activation


Tirta Suci Dhian Kasih5 , M. Taufik1, and Miftahul Khair1,2*
1Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Negeri Padang,
Padang, Indonesia
2Halal Research Center, Universitas Negeri Padang, Padang, Indonesia

*E-mail: miftah@fmipa.unp.ac.id

Abstract. Activated carbon from palm kernel shell has been prepared by using ultrasonic assisted
activation. Carbonization was conducted at mild condition of 400ºC for 90 minutes heating time.
Ultrasonic irradiation (35 Watt, 40 KHz) for 15 minutes increases the carbon iodine number from
452.4021 mg/g up to 817.4907 which is higher than SNI 06-3730-1995 requirement of mg/ g 750 mg/g
for activated carbon. FTIR spectra results show that activated carbon has -OH groups at wave numbers
of 3000-3500 cm-1, C = C at wave numbers of 1550-1650 cm-1, CO at wave numbers of 1000-1260 cm-1
and CH at wave numbers of 810- 770 cm-1 . Adsorption test results showed that the prepared activated
carbon was able to absorb Pb+2 ion at the optimum concentration of 60 mg/L. Adsorption isotherm study
conducted by Langmuir equation produces a regression coefficient (R2 = 0.831 with a maximum
absorption capacity of 9.8039 mg/ g.

Keywords: activated carbon, ultrasonic, green chemistry, adsorbent, palm kernel shell

5
Departement of Chemistry, Padang State University, Padang, Indonesia.

77
ID ICC00109
Pyropheophorbide-α Derivatives as a Dye Compound for Dye-Sensitized Solar Cell (DSSC):
Theoretical Investigation
H P Hutasoit1* and Sudarlin1
1Department Chemistry, Faculty of Science and Technology, Universitas Islam Negeri Sunan Kalijaga,
Sleman 55281, Indonesia
*E-mail: putra.hutasoit@outlook.co.id

Abstract. A pyropheophorbide-α (PPhe-a) derivatives were theoretically investigated using DFT/TD-DFT


theory for DSSC application. Investigating the PPhe-a derivatives structure-properties relationships to
understand prospects as a dye on DSSC. The geometry optimization using NWChem with 6-31G* basis
set. The optimum HOMO-LUMO energy was calculated to be -4,855 eV for HOMO energy and -2,566 eV
for LUMO energy (3PPhe-a). The optimum coupling constant was calculated to be 0,465 (4PPhe-a). The
optimum ΔGinject was calculated to be -2,364 (3PPhe-a). The optimum LHE was calculated to be 0,577
(1PPhe-a). The UV-Vis absorption parameters and electron density parameters show the similarity of
characters. The results showed that PPhe-a derivatives can be used as a dye on DSSC. The 3PPhe-a
shows the optimum ability as a dye on DSSC.

Keyword: DFT, TD-DFT, HOMO-LUMO, coupling constant, ΔGinject and LHE.

78
ID ICC00139

Central Composite Design for Optimization of Biodiesel Production from Palm Oil and Methyl
Acetate using Ultrasound Assisted Interesterification

Ansori Ansori*1, Mahfud Mahfud*2


1 Department of Chemical Engineering, Faculty of Industrial Technology and Systems Engineering,
Institut Teknologi Sepuluh Nopember, Surabaya 60111, Indonesia
2 Department of Chemical Engineering, Faculty of Industrial Technology and Systems Engineering,
Institut Teknologi Sepuluh Nopember, Surabaya 60111, Indonesia

*E-mail: ansor17k54pascal@gmail.com; mahfud@chem-eng.its.ac.id

Abstract. High energy demand in the industrial world and pollution problems caused by the use of
fossil fuels causes the need for the latest innovations that will replace the use of non-renewable energy.
One of them is the replacement of diesel fuel with biodiesel. In this study, biodiesel production uses a
new route that will produce side products that have high market value in biodiesel. This route is called
interesterification, using methyl acetate instead of methanol which later produces triacetin as a by-
product. Triacetin is recognized as an additive in biodiesel which functions as an anti-knocking in diesel
engines. In this research, an interesterification study was carried out by ultrasound and a potassium
methoxide catalyst was used to increase the reaction rate and the yield of biodiesel. The operating
parameters used include the reactant molar ratio of 1:3; 1:6 and 1:9, catalyst concentration 0.5%; 1.0%;
and 1.5%, and reaction times 5, 10, and 15 minutes. The optimal operating conditions are the molar
ratio of methyl acetate to palm oil of 8.95, catalyst concentration of 1.44%, and interesterification time
of 10.03 minutes can produce the yield of biodiesel of 99.66%.

Keyword: biodiesel; central composite design; interesterification; triacetin; ultrasound.

79
ID ICC00154

The Quantity Study of Na2SiO3 to Synthesize Fe3O4-Fe2O3 @SiO2 Composite by Using X-Ray
Diffraction Data

Syamsi Aini*, Fajriah Azra, Nadia Rahma, , Agung Cahyadi


Chemistry Department, Faculty of Science, State University of Padang (Universitas Negeri Padang)
Jalan. Prof. Dr. Hamka, Air Tawar, Padang Post Code: 25131, West Sumatera. Indonesia

*E-mail: syamsiaini@fmipa.unp.ac.id

Abstract. Mesoporous silica on the surface of nanoparticle’s magnetic Fe3O4-Fe2O3 has been
synthesized in the one-pot reaction method by using Sijunjung iron sand and Na2SiO3 as raw materials.
The influence of Na2SiO3 mass on the existence of Fe3O4, Fe2O3, SiO2, and silica pore size on the surface
of Fe3O4-Fe2O3 composite has been studied. The Fe3O4-Fe2O3@SiO2 Composite product characterized
by using small-angle and high-angle X-ray diffraction patterns. The characterization results showed that
mesoporous silica began to form on the surface of the Fe3O4-Fe2O3 composite when 8.7 grams Na2SiO3
were used. The usage of much Na2SiO3 lead to the increase of OH- concentrations, and oxidized some
Fe3O4 to Fe2O3.
.

Keyword: Sijunjung iron sands, Na2SiO3, Fe3O4-Fe2O3 composite

80
ID ICC00158

Modification of Natural Silica Using Dimethylamine and It’s Application as a Phosphate Ion
Absorption

Renti Sefriani6 and Budhi Oktavia2*


1Chemistry Department Faculty of Mathematics and Natural Science Universitas Negeri Padang,
2Chemistry Department Faculty of Mathematics and Natural Science Universitas Negeri Padang
*E-mail: Budhioktavia@fmipa.unp.ac.id

Abstract. Natural silica is one of the biggest mining products in Indonesia. Silica has the ability to absorb
ions because it has two sites that actively activate silanol and siloxan groups that are accessible.
Modifications were made to improve the ability of silica to perform impulses. Water ions if they have very
high levels can release marine biota ecosystems, phosphate levels that are too high in waters can cause
eutrophication, which is the higher levels of oxygen entering the sea. To reduce phosphate levels,
phosphate adsorption is carried out using returned silica. The application of silica as a phosphate ion
absorber was analyzed through measurements with a spectrophotometer.From the results of
characterization with XRF, SiO2 content in silica reaches 98.893%, analysis of modified silica with FTIR
shows silica has an amida (C-C) group used by peaks at wavelength 2101,12cm-1 and amina (C-N) group
at 3,362,55cm-1. Adsorption of phosphate ions using pure silica has a maximum absorption of 0.2533 mg
/ g while silica after modification can adsorb a maximum phosphate ion of 1,1629 mg / g.

Keyword: Silica, Modification, Dimethylamine, Absorbent, Phosphate Ion

*To whom any correspondence should be addressed.

81
ID ICC00159

Titanium Dioxide with Ag Electrodeposition for Solar Cell (DSSC) Applications Using Extracts of
Natural Dyes

Hardeli, Hary Sanjaya, Indri PN., Lasmi Y, Rahmaneta L, Nurul FA


hardeli1@yahoo.com

Abstract. Dye Sensitizer Solar Cell (DSSC) is a dye-based solar cell which is an alternative to meet
energy needs, where these cells will convert sunlight energy into electrical energy. This study aims to
produce DSSC using Indium Tin Oxide (ITO) glass as a substrate and extract of red grape skin (Vitis
Vinifera), jengkol skin extract (Pithecellobium jiringa), resident fruit (Melastoma malabathricum L), and
mangosteen peel (Garcinia Mangostana) L) as a dye sensitizer. The semiconductor material used is
Titanium dioxide (TiO2), because titanium dioxide has a wide band gap, is inert, harmless and also has
a wide surface. The research began with the preparation of ITO glass which was carried out by a doctor
blade method coated with TiO2 paste, after being coated the glass was heated on a hot plate at 100 0C
for 30 minutes, and electrodeposition of Ag metal, after that the ITO glass was heated to the furnace and
dropped by dyes. In other ITO glass the conductive part is coated with carbon from heating on a candle,
after which solar cells are tested by assembling the glass like a sandwich, and dropped by an electrolyte
solution. The dye used is characterized by using UV-Vis and FTIR. The results of XRD analysis showed
that there was a decrease in the size of TiO2 crystals and that AgNO3 was still present in TiO2. The
decrease in crystal size will cause an increase in the surface area of TiO 2 thereby increasing DSSC
efficiency. The efficiency of DSSC that uses Ag electrodeposition on TiO2 (Ag-TiO2) has increased
compared to DSSC using pure TiO2, from 0.8% to 4.14% at 1 V electrodeposition voltage. This increase
occurs because a barrier layer of the process of recombination of electrons with electrolytes and an
increase in the surface area of TiO2. The optimum voltage and time of electrodeposition of Ag on TiO 2
are 1V and 15 seconds with the resulting DSSC efficiency of 6.00%. DSSC performance produced with
TiO2-Ag layer and co-pigmented pigments were 1.8062% jengkol peel, 4.40% resident fruit, 3.8039%
mangosteen peel, and 4.812% grape skin. The highest efficiency was obtained on DSSC by Ag
electrodeposition in TiO2 layer using grape skin as a source of dyes.

Keywords: DSSC, red grapes, jengkol skin, resident fruit, mangosteen peel, Ag electroplating

82
ID ICC00191

DEGRADATION OF RHODAMIN B USING CATALYST ZnO-TiO2 BY PHOTOSONOLYSIS METHOD


Sucitia Ferinda, Sherly Kasuma Warda Ningsih, Hary Sanjaya*
Departement of Chemistry, Faculty of Mathematic and Natural Science, Universitas Negeri Padang
Jln. Prof. Dr.Hamka Air Tawar Padang, Indonesia Telp. 0751 7057420
*email:hary.s@fmipa.unp.ac.id

Abstract—Research on the degradation of rhodamin B has been done by using photosonolysis method.
The purpose of this study is to determine much time the optimum, optimum pH and the amount of doping
TiO2 optimum degrade rhodamin B as well as the percent degradation. For determined the crystal
structure and particle size of the catalyst synthesis of ZnO-TiO2 optimum degrade rhodamin B using
XRD. For determine the value of the band gap Of the optimum ZnO-TiO2 catalyst synthesis in degrading
rhodmain B using UV-DRS, determining the absorption peak of Zn-O-Ti bonds from optimum ZnO-TiO2
catalyst synthesis in degrading rhodaminB using FTIR. The results showed that the optimum time to
degrade rhodamin B was 120 minutes at pH 6 with 94,318% degradation percentage. For effect pH
variation, the optimum degradation results at pH 3 with percent degradation of 98,93%. The effect of
TiO2 doping variation showed optimum degradation result obtained on doping variation of TiO 2 5% with
percentage degradation of 99,24%. The optimum catalyst structure of ZnO-TiO2 catalyst in degrading
rhodamin B with XRD is wurtzite (anatase) and the particle size is 48,75-103,87nm. The band gap value
of the optimum ZnO-TiO2 catalyst in degrading rhodamin B is 3.10 eV. The absorption peak of Zn-O-Ti
for optimum catalyst ZnO-TiO2 in degrading rhodamin B is 739,96cm-1.

Keywords—Band gap, Degradation, Photosonolysis, Rhodamin B, ZnO-TiO2

83
ID ICC00031

COMPUTATIONAL STUDY OF CHARACTERS AND ACTIVITIES OF ORGANIC


PHOTOSENSITIZERS FOR HYDROGEN PRODUCTION FROM WATER INSPIRED BY
PHOTOSYNTHESIS

1Okta
Suryani*, 1Hesty Parbuntari
1Universitas Negeri Padang

Corresponding Author: *okta.suryani.os@gmail.com

Light-driven water splitting into hydrogen and oxygen for storing solar energy in the form of chemical fuels
through dye-sensitized photocatalytic hydrogen production is emerging a promising method for solar
energy conversion among various H2 production technologies, to meet future global energy demand in
an environmentally benign way. As the main component in dye-sensitized catalytic hydrogen production,
photosensitizer should be well designed. In comparison with current dominated metal complexes, organic
photosensitizers used in photocatalytic hydrogen production present the relative superiority due to not
including precious and rare metal elements, not toxic, low in cost and abundant in resources. Several
visible-NIR light absorbing organic photosensitizers have been synthesized, however the efficiency of the
systems relatively low due to the low stability of photosensitizer in excited state. In order to seek more
highly efficient dyes, organic photosensitizers that contain heavy atom selenium (Se) have been designed
with different side chains using density functional theory (DFT) and time-dependent DFT (TDDFT), based
on BODIPY as parent dye. We further comprehensive investigated their properties such as energy levels,
absorption spectra, which are respectively the photo-induced electron transfer from the sacrificial electron
donor to the excited photosensitizer (PS*) and the electron transfer from the reduced form of PS (PS-) to
the H2-evolving catalyst, the oxidation potential (Eox) and the reduction potential (Ered). The results show
that BODIPY-Se exhibits not only a high molar extinction coefficient, a large absolute value of the free
energy of light-induced electron transfer but also a more negative reduction potential. Therefore,
BODIPY-Se is a very promising photosensitizer (PS) candidate for visible-light-driven hydrogen
production.

Keywords: H2 production, photosensitizer, BODIPY, heavy atom

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