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    This document contains experimental data from isothermal vapor-liquid equilibrium measurements of n-pentane and n-hexane mixtures at 33.55°C. Tables provide the temperature, pressure, mole fractions, and vapor phase compositions for each measurement. Additional information includes the normal boiling points and vapor pressures of the pure components. A second section contains similar experimental data for benzene and toluene mixtures at 373.15K.

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    This document contains experimental data from isothermal vapor-liquid equilibrium measurements of n-pentane and n-hexane mixtures at 33.55°C. Tables provide the temperature, pressure, mole fractions, and vapor phase compositions for each measurement. Additional information includes the normal boiling points and vapor pressures of the pure components. A second section contains similar experimental data for benzene and toluene mixtures at 373.15K.

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    7 views5 pages

    Tarea 3

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    This document contains experimental data from isothermal vapor-liquid equilibrium measurements of n-pentane and n-hexane mixtures at 33.55°C. Tables provide the temperature, pressure, mole fractions, and vapor phase compositions for each measurement. Additional information includes the normal boiling points and vapor pressures of the pure components. A second section contains similar experimental data for benzene and toluene mixtures at 373.15K.

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    of 5

    R= 1.

    987
    V T= 306.7
    n-pentano 114.5238 a12 -423.091205 A12
    n-hexano 131.613 a21 423.08917 A21

    Isothermal P-T-X-Y: N-PENTANE + N-HEXANE at T= 33.55°C

    T, K P, kPa x1 y1 P(bar) Y1 Y2
    303.7 25.61 0 0 0.2561 0.7649546516 1.000000
    303.7 30.9 0.0638 0.2011 0.3090 0.7807792932 0.999317
    303.7 33.2 0.1218 0.3054 0.3320 0.7955445284 0.997396
    303.7 35.8 0.17 0.4141 0.3580 0.8080787603 0.994731
    303.7 38.8 0.2213 0.4678 0.3880 0.8216668094 0.990697
    303.7 45.8 0.3291 0.6166 0.4580 0.8509469274 0.977529
    303.7 54.9 0.475 0.748 0.5490 0.8915786198 0.947025
    303.7 59.2 0.5401 0.7808 0.5920 0.9097250315 0.927518
    303.7 64.3 0.6064 0.8409 0.6430 0.9279050439 0.903129
    303.7 69 0.6864 0.8825 0.6900 0.9489524906 0.866699
    303.7 72.3 0.7683 0.9232 0.7230 0.9686504172 0.820231
    303.7 75.4 0.7977 0.9355 0.7540 0.9750296837 0.801016
    303.7 78.7 0.8729 0.9511 0.7870 0.9889280384 0.745137
    303.7 83.82 1 1 0.8382 1.0000000000 0.626467

    T= 33.55

    5 n-Pentano C5H12 3.97786 1064.840 232.014 0.929244000


    6 n-Hexano C6H14 4.00139 1170.875 224.317 0.288917668
    2.30099922
    0.43459525

    .55°C

    P-T-X
    P (Pteor-P)^2 1.0000
    0.56540475 ### 0.0010770 0.9000
    0.58656386 ### 0.0000576 0.8000
    0.60722207 ### 0.0001234 0.7000
    0.62553024 ### 0.0000671 0.6000
    0.64626891 ### 0.0000149 0.5000
    0.69466490 ### 0.0000687 0.4000
    0.77301118 ### 0.0001397 0.3000
    0.81397295 ### 0.0001484 0.2000
    0.86040619 ### 0.0003038 0.1000
    0.92400827 ### 0.0000384 0.0000
    0 0.2 0.4 0.6 0.8 1 1.2
    0.99965910 ### 0.0005506
    1.02992882 ### 0.0002423
    1.11639470 ### 0.0018078
    1.30099922 ### 0.0082890
    0.0129287
    1 1.2
    R= 1.987
    T= 373.15

    T= 100

    Isothermal P-T-X-Y Data : BENZENE +


    TOLUENE at 373.15K

    T, K P, kPa X P(bar) Y1 Y2 Pteor


    373.15 75.8 0 0.758 1 ### ###
    373.15 92.5 0.226 0.925 1 ### ###
    373.15 101.4 0.306 1.014 1 ### ###
    373.15 138.1 0.566 1.381 1 ### ###
    373.15 157.7 0.793 1.577 1 ### ###
    373.15 185.8 1 1.858 1 ### ###

    Psat
    Benceno C6H6 3.98523 1184.240 217.572 1.80378960
    Tolueno C7H8 4.05004 1327.620 217.625 0.74166586

    1.8

    1.6

    1.4

    1.2

    0.8

    0.6

    0.4

    0.2

    0
    0 0.2 0.4 0.6 0.8 1
    (P-Pteor)^2
    0.00026680
    0.00321555
    0.00277473
    0.00145711 b12 b21 α
    0.00004802 0 0 0.38255209
    0.00293877
    0.01070099
    T12 0 G12 1
    T21 0 G21 1

    0.6 0.8 1 1.2

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