Professional Documents
Culture Documents
World Guide To: Low-Charge Ammonia
World Guide To: Low-Charge Ammonia
World Guide To: Low-Charge Ammonia
GUIDE TO
LOW-CHARGE
AMMONIA
The information in this report, or upon which this report is based,
has been obtained from sources the authors believe to be reliable
and accurate. While reasonable efforts have been made to ensure
that the contents of this publication are factually correct, shecco does
not accept responsibility for the accuracy or completeness of the
contents, and shall not be liable for any loss or damage that may be
occasioned directly or indirectly through the use of, or reliance on, the
contents of this publication.
The use of low-charge ammonia has emerged as one The second part of the Guide will focus on the variety
of the key trends in the industrial refrigeration industry of applications where low-charge ammonia technology
in the last few years. Moreover, the technological has been used with concrete examples from around
developments have opened up opportunities for the world. In addition, it will outline standards and
ammonia beyond its traditional market. legislation that are key drivers for the reduction of
ammonia charge in systems, but also for the use of
With this report we aim to identify the underlying
HFC-free technology as such.
trends for low-charge ammonia technology in different
parts of the world. The report is released in three The third and final part of the report will zoom in on
parts, with this first part highlighting some of the the key trends for low-charge ammonia technology,
key characteristics of ammonia as a refrigerant and its advantages, drivers and major challenges in today’s
outlining a brief history of its use. market. It will compare developments in different
world regions, with focus on North America, Europe,
The term “low-charge ammonia” is not well defined
Japan and Australia. Moreover, gathering data through
yet although there are some efforts to bring more
analysis of survey, interviews with key experts it will
clarity into this. A clear definition and distinction from
outline the future opportunities and perspectives for
traditional ammonia systems is essential to strengthen
low-charge NH3 systems.
the position of low-charge systems especially in
light of growing legislative pressure on fluorinated
Klára Zolcer Skačanová refrigerants. Low-charge ammonia has the potential to
not only replace traditional ammonia systems but also
Manager, Market Development, shecco HFCs in applications where it was not possible to use
Lead Author ammonia before.
This chapter provides a short introduction into ammonia This chapter seeks to identify what is meant by ‘low- This chapter delves into the applications for low-charge
as a refrigerant. It takes a look at the characteristics of charge ammonia’, using industry feedback and know- ammonia technology from its beginnings in traditional
this molecule, its behaviour as a refrigerant, its role how, and looks at issues of defining a technology that ammonia refrigeration, such as in cold storage, food
and history in the refrigeration industry. is relatively new in the industrial refrigeration sector. It processing and logistic facilities, to its forays into HVAC
also provides overview of key types of the technology. and the pharmaceutical industry.
The use of ammonia as a refrigerant is regulated in In this chapter, the current market for low-charge Based on interviews, research, surveys and the market
most of the world due to its risk to human health. This ammonia systems and applications is looked at in today this chapter anticipates the market potential for
chapter looks at how regulations and standards on detail. It identifies the key trends and challenges in low-charge technology in the world, its future uses and
high charges of ammonia could offer opportunities for different world regions. the next steps that will need to be taken to make this
lower-charged technology. technology successful.
To address the higher toxicity of ammonia Ammonia 6,20 4,965 2,91 2,06
considerable efforts have been made to develop
HFC-410A 5,43 4,80 2,50 1,75
ammonia systems with reduced refrigerant charge
as the most effective way to improve safety while
HFC-134a 5,88 4,67 2,70 1,88
increasing system efficiency.
Compared with other commonly used refrigerants * Coefficient of performance (COP) is a number
for various applications, ammonia presents a higher determining a ratio of useful heating or cooling
provided to work required. Higher COP means lower
thermodynamic efficiency too, as measured in operating costs.
Coefficient of Performance (COP) in Table 2.
Aqua-ammonia First commercial Ammonia is the Ammonia starts Ammonia First installation
solution identified development of an dominant refrigerant for to get partially further replaced of low pressure
as the most effective ammonia compressor for land-based industrial replaced by by CFC-502 receiver (LPR)
fluid for evaporative refrigeration (D. Boyle) refrigeration in Europe HCFC-22 system
cooling (W. Cullen) and North America
First ammonia units First prototypes with Industry’s first use of First installation Montreal Low-charge ammonia
with microchannel low- and ultra-low plate heat exchangers of ammonia Protocol to chillers in public
condensers with low ammonia charge as low-charge low-pressure phase out CFCs buildings in Germany
charge condensers for receiver system and the UK
ammonia plant
xpansio
Pressure
r
(P
so
res
xp
mp
Co
5 Evaporator 1
So many benefits…
Enthal
py
AMMONIA21 What is
«low-charge ammonia»? 19
TYPES OF AMMONIA REFRIGERATION SYSTEMS
20 What is
«low-charge ammonia»? AMMONIA21
2/ LOW-CHARGE AMMONIA: 3: LOW-CHARGE AMMONIA: NH3/
PACKAGED SYSTEM CO2 SYSTEM
A packaged ammonia system eliminates the huge quantities of ammonia An ammonia/CO2 system can come in various formats (such as cascade,
inventory, and piping, by moving to smaller self-contained systems that CO2/NH3 with pumped volatile brine and ammonia DX system using liquid
are usually placed on the roof/ground outside preventing any danger CO2 overfeed) but the main idea is to isolate the ammonia charge, which
from leaks. These self-contained systems have about 4.3 lbs/TR (0.55 kg/ is usually between 4 and 6 lbs/TR (0.5 - 0.83 kg/kW), to the machine room
kW) ammonia charge and usually combine the compressor, evaporator and use the CO2 as the secondary coolant that can be pumped into cold
valve system and control systems into one easily installed and movable rooms in the facility. The system might require additional equipment to
packaged system. pump the CO2, along with extra compressors and other components for
the CO2 side.
AMMONIA21 What is
«low-charge ammonia»? 21
DO WE NEED A DEFINITION?
To further foster innovation in low-charge ammonia
and develop the technology for the HVAC (heating
“
by design, - Stefan Jensen, managing director and
founder of Australia-based Scantec Refrigeration
and air conditioning) market, along with increasing Technologies (Scantec) that has been developing ‘low-
food and worker safety in the refrigeration industry, charge’ technology since 2013.
experts agree it is necessary to clearly determine
what is «low-charge». “ I would hate to say a system with 501 lbs [227.5 kg]
is not a ‘low-charge system’ although, I’m not seeing
“ Those who want to go slow are typically not interested that there would be any penalty for not falling into the
in non-industrial applications and do not like ultra-low- definition of low-charge. So I’m not sure there’s any real
charge because that requires too much new technology. merit in trying to set anything in stone. I think a more
They are used to go through acceptance of ammonia qualitative definition is a better approach: ‘A system that
systems by authorities. They do not want a definition takes advantage of available and proven technology to
because they do not look as good. Those who would reduce the ammonia inventory in the system such that
like to see ammonia used in applications where it is not a minimum amount of refrigerant is used while not
typically applied today (HVAC and other chillers) would
like ammonia to be treated as any other A2L (or B2L)
“
introducing significant efficiency or reliability penalties’.
- Caleb Nelson, vice president, Azane Inc, the U.K.-based
“
refrigerant. - Professor Pega Hrnjak, the University of
Illinois at Urbana-Champaign, U.S.
Star Refrigeration’s low-charge ammonia manufacturer
for the U.S. market.
If the industry continues without a definition many Any definition will have to keep in mind how a low-
experts warn that «low-charge» will reduce the charge system can be safe, reliable and efficient while
substance of the term. speaking to the amount of ammonia content that can
be contained in a system (per lbs / kg) and the lbs/TR
“ The reason standards organisations, industry (kg/kW) ratio.
associations, contractors, end-users and everybody
else struggle with the definition of low-charge NH3 If a definition is agreed on it will lead to accelerated
systems is that there is no clear definition of such adoption of low-charge, provide quality technical
systems. The term ‘Low-Charge NH3’ is a marketing information and allow for less burdensome codes and
term commonly used for any type of ammonia regulations to be used by the industry when working
refrigeration system where an effort has been with ammonia.
made to reduce the ammonia refrigerant inventory
22 What is
«low-charge ammonia»? AMMONIA21
OPTIMIZING CHARGE
It is important when optimizing
Potential loss of Increased risk in and reducing the ammonia
system stability the event of an
ammonia leak
Safety charge in a system to take into
consideration the performance
and potential loss of stability
within a low-charge ammonia
low-charge ammonia systems and can instead rely on
refrigeration system when using
Relative risk
TOWARDS A U.S. DEFINITION systems will shoulder most of the work involved in safe
operation and maintenance under ARM-LC, which have
(that all have European branches). It states low-
charge is an ammonia system that requires a charge
Industry groups in the U.S. have been active on ammonia charge capacity ratios of 0.5 lbs/TR (0.065 kg/ of “no more than 10 pounds of ammonia per ton of
proposing a ‘low-charge ammonia’ definition but have kW) to 7 lbs/TR (0.91 kg/kW) compared to 20-30 lbs/ refrigeration,” or (1.3 kg/kW).
not yet incorporated this into standards or codes. TR (2.59-3.88 kg/kW) or more in conventional systems.
This will be good for end users, who have never worked Similarly, this low-charge ammonia definition has not
The U.S.-based International Institute of Ammonia with ammonia systems before, as they face less of so far been incorporated into any code or standard
Refrigeration (IIAR) is seeking to meet that demand for the burden to provide safety guidelines for operating either and is at the moment a guideline for the industry.
24 What is
«low-charge ammonia»? AMMONIA21
HOW LOW IS LOW-CHARGE AMMONIA? WILL THE REST OF THE WORLD JUMP
ON BOARD?
If the U.S. can determine a definition then South America will likely
30 jump on board. Currently, IIAR has chapters in Mexico, Costa Rica
and Caribbean, Colombia, Ecuador, Peru, Chile and Argentina that
incorporate and use its current standards.
Conventional systems:
25 20-30 lbs/TR Chile, for example, when coming up with its ammonia regulation
(2.59-3.88kg/kW) worked with an IIAR representative from the U.S. and the IIAR Chilean
chapter to develop an ammonia standard for the South American
Ammonia charge (lbs/TR)
AMMONIA21 What is
«low-charge ammonia»? 25
HOW WOULD YOU DEFINE A
LOW-CHARGE AMMONIA SYSTEM? QUALIFYING THE DEFINITION
“ The most important law we have to consider Regardless of whether definitions for low-charge go
regarding the use of refrigerants and measures needs ahead, manufacturers and researchers believe it will
to be taken against any risks comes from EN 378. It is also be necessary to define what is low-charge and what
a [harmonized] European standard so all the countries is ultra-low-charge so as to differentiate between the
have to follow.“ - Wolfgang Dietrich, responsible for
product management (chillers) at GEA.
most ambitious technology and the least for end users.
“ We should find a common ‘definition’ where the limit “ It depends from the technology used (factory-made
65% 35%
could be to still speak as ‘low-charge’. Currently I saw chiller/local built chiller), the type of a chiller (water-
‘low-charge’ arguments at [1.15 lbs/TR] 150 g/kW cooling cooled; air-cooled, evaporative condenser) and the
capacity and I know the ambitious level is [0.39 lbs/TR] temperature level of the application (low; AC or heat
“
FAVOR A DEFINITION FAVORING ONE BASED
50 g/kW cooling capacity. You see there is a wide range pump). - Wolfgang Dietrich, responsible for product
BASED ON SPECIFIC ON TOTAL QUANTITY OF
AMMONIA CHARGE AMMONIA ONLY “
in interpretation. - Wolfgang Dietrich, responsible for
product management (chillers) at GEA.
management (chillers) at GEA.
26 What is
«low-charge ammonia»? AMMONIA21
REFERENCES
Chapter one: ‘Ammonia as a Chapter two: ‘What is low-charge
refrigerant’ ammonia?’
ASHRAE - American Society of Heating, web.iiar.org/membersonly/PDF/CO/da- Chapp, T. (2014). Low Ammonia Charge userfiles/file/publications/notes/Note-
Refrigerating and Air-Conditioning En- tabook_ch2.pdf Refrigeration Systems for Cold Storage. Tech_25_EN.pdf
gineers (2016). Designation and Safety [online] IARW, GCCA & IACSC. Available
Classification of Refrigerants. Available Jha A.R. (2006). Cryogenic Technology and online at: http://ammonia21.com/files/ Lamb, R (2018). Low Charge, Packaged
online at: https://www.ashrae.org/tech- Applications. Butterworth-Heinemann. ammoniachargerefrigerationv1201410. Ammonia Solutions For Small Industrial
nical-resources/standards-and-guide- pdf Refrigeration Applications. Schaffhausen:
lines/ashrae-refrigerant-designations Paranjpey R. (2012). Advantages of Am- 2018 Eurammon Annual Conference.
monia Refrigerant over HCFC/HFC Refri- Garry, M. (2017). IIAR-2 takes charge. Available online at: http://www.euram-
Heaney C., Swinard R., Pang A., West S. gerants. Available online at: http://www. [online] ammonia21.com. Available mon.com/sites/default/files/attach-
(2007). Natural Refrigerants Case Studies ramesh-paranjpey.com/articles/Advan- online at: http://ammonia21.com/ar- ments/2018_eurammon_star_refrigira-
– Information and Case Studies for Aus- tages%20of%20Ammonia%20refrige- ticles/7593/iiar_2_takes_charge tion_robert_lamb_0.pdf
tralian Businesses. Australian Institute rant%20over%20HCFCHFC%20Refrige-
of Refrigeration, Air Conditioning and rants.pdf Garry, M. (2018). IIAR creates guidelines Liebendorfer, K. (2019). ARM-LC. Phoe-
Heating (AIRAH). Available online at: for low-charge ammonia. [online] ammo- nix, Arizona: IIAR 2019 Natural Refrigera-
https://www.airah.org.au/Content_Files/ Shecco (2018). Ammonia Refrigeration nia21.com. Available online at: http:// tion Conference & Expo
TechnicalPublications/natural-refrige- Safety Part 2 — Responding to an Accident. ammonia21.com/articles/8249/iiar_
rants-case-studies.pdf Available online at: http://ammonia21. creates_guidelines_for_low_charge_am- Lundell, T. (2016). IIAR Regulations &
com/knowledge/papersView/ammonia_ monia Standards. Chicago, Illinois: ATMOs-
Hrnjak P. (2019). Packaged ammonia refri- refrigeration_safety_part_2_responding_ phere America 2016. Available online
geration units continuously improve: How to_an_accident Hrnjak, P. (2017). Efficient very low at: http://www.atmo.org/presentations/
to measure and present performance?. charged ammonia systems. Ohrid: 7th IIR iles/5764258666cb21466180998ENLTU.
Proceedings of the 8th IIR Conference: Whitman W.C., Johnson W.M., Tomczyk Conference on Ammonia and CO2 Refri- pdf
Ammonia and CO2 Refrigeration Tech- J. (2005). Refrigeration & Air Conditioning geration Technologies
nologies, Ohrid, 2019. doi: 10.18462/iir. Technology. Thomson Delmar Learning. McLaughlin, C. (2018). Chile ammonia
nh3-co2.2019.0002 IIAR.org. (2019). International. [online] standard to be published soon. Ammo-
Williams A. (2018). Pearson: Low-charge Available online at: https://www.iiar. nia21.com. Available online at: http://
IAAR - International Institute of Ammo- trend marks ammonia ‘reinvention’. Avai- org/IIAR/WCM/International/WCM/ ammonia21.com/articles/8622/chile_
nia Refrigeration. The History of Ammonia lable online at: http://ammonia21.com/ International/International.aspx?h- ammonia_standard_to_be_published_
Refrigeration. Available online at: https:// articles/8377/pearson_low_charge_ key=b71408f3-c510-4550-8197-adf- soon1539843507
www.iiar.org/iiar/WCM/About_Ammo- trend_marks_ammonia_reinvention f94352ea1
nia_Refrigeration/The_History_of_Am- Pachai, A.C. (2019). How low is low-
monia_Refrgeration.aspx Woolrich W.R., Clark C.T. (2010). Refrige- IIR (2014). Refrigerant charge reduction charge? Schaffhausen: 2019 Eurammon
ration. Handbook of Texas Online. Avai- in refrigerating systems. [online] Paris: Annual Conference.
IIAR- International Institute of Ammonia lable online at: https://tshaonline.org/ International Institute of Refrigeration.
Refrigeration(2008). Ammonia Data Book handbook/online/articles/dqr01 Available online at: http://www.iifiir.org/
– Chapter 2. Available online at: http://
Get in touch with shecco’s market development team
to learn more about the market for natural refrigerants
or find out how we can help you in gathering market
intelligence and proactively building your business
with our tailored market development services, to get
your technology faster to market.
Email us at
research@shecco.com
shecco Japan
Global Business Hub Tokyo,
Otemachi Financial City Grand Cube 3F
Otemachi 1-9-2, Chiyoda-ku, Tokyo, 100-0004
shecco America
81 Prospect St, Brooklyn,
NY 11201
MarketDevelopment
© 2019 shecco. All rights reserved.