1-24.

20 MHz

2-0. 67 ppm

3-6 & 7

4-HCºCH

5-quartet

6-1:6:15:20:15:6:1

7-1 and 2

8-d = (sref - s sple) × 10^6

9- ghB0/4p

10-O2

11-3/4

12-2

13-They will each exhibit two discrete measurable energy states

14-²³Na will manifest 4 discrete energy states

15-42.6 MHz/Tesla

16-298 MHz

17-32.1 MHz

18-Parts per million (ppm)

19-3.5 ppm

20-440 Hz

21-Spin-spin relaxation

22-Both (a) and (b)

23-+½, –½

24-1H, 13C, 19F

25-ketone R2C=O; δ +190 to +230 ppm

26-A triplet and a quartet.

27- A doublet and a quartet.

28-1-Bromopropane: 3; 2-bromopropane: 2.

29-Acetone.

30- The spectroscopic data are consistent with B being (CH3)2CHCl.

31- CH3CCl2CH2CH3

32- Compound D contains three C atoms.

33-CH3OH

34-A doublet assigned to the CH3 group and a quartet assigned to the CH group.

35- CH3CH2COCH2CH3

36-CH3CH2CH2CN

37-CH3OCH2CH2OCH3

38-coupling between 1H nuclei attached to adjacent C atoms.

39-For this doublet, the coupling constant measured in Hz depends on the field
strength of the spectrometer.

40- 5

41-the contribution of the paramagnetic shielding of 13C is much larger than 1H due
to
the small 13C energy gap /(the contribution of the diamagnetic shielding of 13C is
much larger than 1H due to the small 13C energy gap)

42- DSS has a higher solubility in aqueous solution

43-J coupling constant

44- electron shielding

45- the chemical shift value of DSS is chosen as the chemical shift reference

46-the ratio of the number of protons corresponding to the resonance frequencies

47- 1.1% of total carbon

48-2, 2-dichloropropane

49-A three proton singlet. One proton triplet and a two proton doublet

50-CH3NHCOOCH2CH3

51-Br-CH = CH2

52-60 Hz, 100 Hz

53-Diethyl ether and t-Butyl alcohol

54-Coupling constant

55-Singlet

56-Quintet, 1 : 4 : 6 : 4 : 1

57-d doublet
58- (CH3)2CH-O-CH3

59-three 1H signals and four 13C signals

60-hydrogen c

61-the H on either C2 or C3

62-C2

63-Chemical shifts are larger when shielding effects are greater

64-six 1H signals and six 13C signals

65-C6

66-Hs on C1, singlet; Hs on C3, quartet; Hs on C4, triplet

67- CMe < C2 < C3 < C1

68-0.9

69-Low frequency

70-CH3CHCH2OH
|
CH3