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Chapter m - CONSERVATION OF MASS AND ENERGY

Assumptions: 1) The gas in cylinder is a closed system.

2) Neglect kinetic and potential energy changes.

Analysis: The work is estimated by determining the area under the curve connecting the
data points. This is an estimate in that we do not have a continuous function
descnbing pressure versus volume, nor do we know if the process is a quasi-
equilibrium one.

Finding the area under curve may proceed in several ways: 1) Use rectangles
(as illustrated) to determine the area; 2) determine the ''best fit" equation
connecting the points and integrate that.

The area is found by summing p.w for each rectangle. 1:.. V = 100 cm = 0.000 I
3

m3.

W = :Ep1:..V and for 1:.. V = 0.0l)O}


W = ll.V:Epi
= (0.01)[1710 + 1350 + 1100 + 950 + 800 + 730 + 650

+ 575 + 525 + 475 + 425 + 380 + 350 + 330 + 300]

W = ( 0 ~3)(10650 kN/m 2)
w = ;,o,~kJ

3-86

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