Tables thermodynamiques.

Tableaux thermodynamiques
Table 1 : Enthalpies globales

(1∆4H2)43
T
HT = 0
f T =0 + ∫ CpdT (kcal / mole )
0
chaleur .de. formtion 1 23
Enthalpie sensible

T(k) H O N H2 O2 N2 CO CO2 H 2O HO N
053,101 060,193 113,531 002,024 002,075 002,072 -25,127 -91,732 -54,737 011,453 023,671
1000 056,588 063,745 117,018 006,967 007,501 007,202 -19,943 -83,749 -48,529 016,450 028,983
2000 061,566 068,729 121,986 014,680 016,223 015,490 -11,565 -69,877 -37,365 024,307 037,506
3000 066,524 073,715 126,968 023,232 025,251 024,233 -02,767 -35,200 -24,537 032,909 046,395
4000 071,492 078,758 132,064 032,346 035,256 033,153 +06,195 -40,197 -10,933 041,941 055,442
5000 076,460 083,908 137,463 041,896 045,333 042,174 +15,253 -24,983 +03,090 051,298 064,600
6000 081,428 089,178 143,322 051,824 055,570 051,256 +24,382 -09,287 +16,704 060,916 073,856

T
Table 2. Enthalpie sensible ∫ CpdT (kcal/kmole)
0
T(k) H H2 O O2 OH H 2O N2 NO Co2 Co

0298 01481 02024 01507 02075 02393 02363 02072 02194 02238 02073
0300 01490 02036 01517 02088 02406 02382 02085 02207 02255 02086
0400 01987 02731 02135 02798 03116 03191 02782 02921 03179 02786
0500 02484 03430 02645 03529 03822 04021 03435 03444 04224 03490
0600 02981 04130 03152 04284 04523 04876 04198 04381 05323 04210
0700 03478 04832 03616 05062 05233 05757 04925 05137 05482 04946
0800 03974 05537 04158 05860 05945 06666 05665 05910 07690 05700
0900 04471 06248 04659 06674 06684 07605 06428 06701 08792 06471
1000 04958 06967 05159 07501 07393 08576 07202 07506 10221 07257
1100 05465 07693 05658 08340 08131 09576 07990 08325 11531 08058
1200 05951 08428 06158 09129 08881 10606 08790 09154 12858 08867
1300 06458 09174 06656 10045 09642 11665 09602 09992 14225 09683
1400 06955 09930 07155 10909 10413 12750 10422 10838 15598 10520
1500 07452 10697 07653 11780 11196 13862 11251 11691 16987 11358
1600 07942 11474 08151 12657 11988 14995 12088 12550 18338 12203
1700 08446 12262 08649 13540 12770 16153 12930 13414 19801 13054
1800 08942 13058 09147 14429 13601 17330 13779 14282 21223 13950
1900 09439 13855 09645 15323 14420 18525 14632 15154 22654 14770
2000 09936 14680 10143 16223 15247 19740 15490 16029 24093 15635
2100 10433 15504 10641 17129 16022 20963 16351 16903 25539 16503
2200 10930 16334 11133 18040 16923 22211 17217 17781 26991 17375
2300 11426 17174 11636 18957 17270 23463 18085 18673 28458 18249
2400 11923 18020 12134 19373 18623 24739 18957 19559 29910 19125
2500 12429 18873 12632 20806 19482 26020 19831 20543 31878 20006
2600 12917 19933 13131 21739 20345 27310 20707 21338 32343 20887
2700 13414 20599 13630 22677 21215 28612 21586 22231 34374 21771
2800 13910 21471 14123 23620 22088 29921 22466 23125 35802 22657
2900 14407 22348 14692 24568 22965 31242 23349 24020 37285 23544
3000 14904 23232 15129 25521 23349 32558 24233 24918 38770 24431

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Tables thermodynamiques.

T
Table 3 : Enthalpie standard (∆Ηf )298 + ∫ C p dT
298

T(k) O2 N2 H2 Air H2 o Co Co2 Monatomics

0298 00000 00000 00000 00000 -241829 -110524 -393519 00000
0350 01524 01505 01496 01562 -240111 -109018 -391541 00959
0400 03018 02965 02952 03081 -238409 -107555 -389523 02122
0450 04535 04431 04411 04550 -236685 -106083 -387413 03152
0500 06070 05904 05873 06045 -234938 -104600 -385221 04191
0550 07645 07389 07332 07542 -233164 -103102 -382955 05231
0600 09238 08888 08977 08936 -231362 -101588 -380620 06270
0650 10854 10402 10343 10467 -229532 -100057 -378223 07309
0700 12494 11931 11725 12014 -227672 -098507 -375770 08348
0750 14154 13478 13213 13580 -225781 -096939 -373146 09388
0800 15832 15042 14691 15163 -223860 -095352 -370484 10427
0850 17528 16623 16175 16763 -221908 -093748 -367874 11466
0900 19239 18220 17665 18379 -219924 -092127 -365182 12506
0950 20964 19833 19163 20012 -217908 -090489 -362547 13545
1000 22703 21461 20669 21655 -215860 -088827 -359113 14584
1050 24453 23104 22185 23275 -213780 -087170 -357275 15624
1100 26214 24762 23710 24925 -211668 -085491 -354619 16663
1150 27984 26432 25244 26637 -209524 -083798 -351833 17702
1200 29764 28114 26789 28363 -207351 -082094 -349024 18742
1250 31552 29808 28344 30077 -205147 -080379 -346192 19781
1300 33348 31512 29910 31793 -202914 -078654 -343341 20820
1350 35152 33225 31486 33518 -200652 -076921 -340471 21860
1400 36963 34947 33073 35252 -198364 -075178 -337583 22899
1450 38782 36679 34671 36996 -196048 -073428 -334679 23938
1500 40606 38418 36279 38746 -193707 -071669 -331760 24977
1550 42438 40165 37899 40503 -191341 -069905 -328827 26017
1600 44275 41919 39529 42268 -188951 -068133 -325880 27056
1650 46119 43680 41171 44039 -186539 -066356 -322921 28095
1700 47969 45447 42822 45817 -184106 -064574 -319950 29135
1750 49825 47220 44484 47600 -181651 -062786 -316963 30174
1800 51687 48998 46156 49388 -179176 -060993 -313976 31213
1850 53554 50782 47837 51182 -176682 -059195 -310975 32253
1900 55428 52570 49528 52981 -174169 -057393 -307964 33292
1950 57308 54363 51227 54785 -171639 -055587 -304945 34332
2000 59193 56161 52935 56593 -169091 -053776 -301918 35371
2050 61085 57962 54651 58406 -166527 -051962 -298884 36410
2100 62982 59768 56375 60224 -163947 -050144 -295842 37449
2150 64884 61577 58107 62045 -161352 -048322 -292794 38489
2200 65792 63390 59847 63871 -158604 -046497 -289739 39528
2250 68706 65207 61594 65700 -156065 -044669 -286678 40567
2300 70625 67026 63348 67533 -153415 -042838 -283611 41606
2350 72549 68849 65109 69370 -150785 -041005 -280538 42646
2400 74479 70675 66878 71209 -148146 -039169 -277459 43685
2450 76414 72503 68653 73052 -145501 -037330 -274374 44724
2500 78355 74335 70434 74898 -142817 -035489 -271284 45764
2550 80301 76168 72220 76748 -140122 -033646 -268189 46803
2600 82251 78004 74074 78655 -137416 -031800 -265089 47842
2650 84207 79843 75839 80500 -134700 -029953 -261984 48882
2700 86168 81683 77616 82345 -131975 -028103 -258874 49921
2750 88133 83526 79453 84247 -129241 -206252 -255760 50960

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 Tables thermodynamiques.

Table 4 : Chaleur de formation ( kcal/mole)

∆H°f)T = 298 k
(∆ ∆H°f)T = 298 k
(∆
H2o (g) -57,7979 C6H6 +19,820
H2o (l) -68,3170 NH3 -11,030
Co2 -94,0518 C10,3 H20,6 -68,811 Kérosène
Co -26,4157
CH4 -17,8890

CHALEURS DE FORMATION A 298.15 °k

Substance [∆∆H°f]298 Substance [∆ ∆H°f]298 Chaleur de réaction
(kj/mole) (kj/mole)
Og 245,5970 H 2O g -241,9131
O2 g 000,0000 H 2O l -285,9425
Reaction ∆H R298° K
O3 g 142,3000 CL g 212,4300 (kj/kmole)
Hg 218,0190 CL2 g 000,0000 C (sol) + O2 → CO2 - 393 500
H2 g 000,0000 HCL g -095,2996 CO + ½ O2 → CO2 - 283 000
OH g 039,3600 CH4 g -074,9200 H2 + ½ O2 → H2O - 241 800
Sg 222,8800 C 2H 6 g -084,7100 CH2 (vap) +2O2 → CO2 +2H2O (vap) - 802 300
SO2 g -395,3200 C4H10 g -124,7780
C2H4 (vap) +3O2 → 2CO2 +2H2O (vap) - 1 323 200
H 2S g -020,1530 n - butane
C2H6 (vap) +3+½O2 →2CO2 + 3H2O (vap) - 1 427 900
Ng 470,8480 C4H10 g -131,6420
N2 g 000,0000 C6H6 (vap) +7+½O2 → 6CO2 + 3H2O (vap) - 3 169 500
isobutane
NO g 090,3980 C5H12 g -146,4900 C8H18 (vap) +12+½O2 → 8CO2 + 9H2O (vap) - 5 116 200
NO2 g 033,8650 n - pentane
Co2 + H2 → CO + H2O (vap) + 41 200
N 2O g 081,5800 C 6H 6 g 082,9600 ½H2 +OH → H2O (vap) + 281 300
NH3 g - 046,2100 benzène ½ N2 + ½ O2 → NO - 90 300
NO3H l - 173,2960 C2H2 g 226,8120 2H → H2 - 436 000
Cg 752,9210 C 2H 4 g 052,3190 2O → O2 - 498 400
C diamant 1,896900 C 2H 6 g -084,7100 2N → N2 - 945 600
C graphite 000,0000
COg -110,5600
CO2 g -393,6538

D’après M. Barrére et S Barrére .O.N.E.R.A. Notre technique 1 472. E S et National

Bareau of Standards U.S.A.

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 Tables thermodynamiques.

T
Table 5 : Enthalpie sensible. ∫ CpdT (Kj/mole)
0

T (k) H H2 O O2 OH H2 O N N2 NO NH3
298,15 06,199 08,474 06,726 008,685 10,016 009,911 06,199 008,672 009,183 010,037
300 06,236 08,522 06,768 008,739 10,070 009,970 06,240 008,727 009,237 010,108
400 08,317 11,431 08,936 011,711 13,042 013,356 08,317 011,644 012,226 013,808
500 10,397 14,356 10,652 014,771 15,997 016,830 10,397 014,587 014,415 017,813
600 12,477 17,256 13,193 017,931 18,952 020,408 12,477 017,571 018,337 022,041
700 14,557 20,224 15,135 021,187 21,903 024,096 14,557 020,614 021,501 026,770
800 16,633 23,175 17,403 024,527 24,883 027,900 16,633 023,723 024,736 032,362
900 18,713 26,151 19,500 027,934 27,892 031,835 18,713 026,904 028,047 036,891
1000 20,794 29,160 21,593 031,395 30,943 035,895 20,794 030,144 031,416 042,370
1100 22,874 32,999 23,682 034,907 34,032 040,080 22,874 033,442 034,844 048,087
1200 24,950 35,776 25,774 038,461 37,171 044,391 24,954 036,790 038,314 054,047
1300 27,030 38,998 27,859 042,043 40,357 048,824 27,030 040,189 041,821 060,204
1400 29,110 41,662 29,947 045,660 43,584 053,365 29,110 043,621 045,362 066,562
1500 31,190 44,772 32,032 049,305 46,861 058,019 31,190 047,091 050,063 073,079
1600 33,270 48,224 34,116 052,976 50,176 062,762 33,270 050,594 052,528 079,771
1700 35,351 51,223 36,200 056,672 53,532 067,608 35,351 054,118 056,144 086,594
1800 37,427 54,554 38,285 060,393 56,927 072,618 37,427 057,672 059,777 093,550
1900 39,507 58,332 40,369 064,134 60,355 077,536 39,507 061,242 063,427 100,519
2000 41,587 61,443 42,453 067,901 63,816 082,622 41,587 064,833 067,089 107,777
2100 43,667 64,992 44,538 071,693 67,311 087,762 43,667 068,437 070,768
2200 45,747 68,666 46,618 075,506 70,831 092,964 45,747 072,062 074,456
2300 47,623 71,882 48,702 079,344 74,376 098,230 47,828 075,695 078,156
2400 49,904 75,223 50,787 083,204 77,947 103,545 49,912 079,344 083,538
2500 51,984 78,993 52,871 087,083 81,542 108,907 51,992 083,003 085,585
2600 54,064 82,992 54,960 090,989 85,158 114,306 54,077 086,669 089,310
2700 56,144 86,117 57,048 094,915 88,795 119,756 56,165 090,348 093,048
2800 58,220 89,667 59,137 098,861 92,449 125,234 58,250 094,031 096,790
2900 60,300 93,338 61,230 102,829 96,120 130,763 60,342 097,727 100,536
3000 62,381 97,337 63,322 106,818 99,820 136,813 62,439 101,427 104,294

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T
Enthalpie sensible (suite) ∫ CpdT (kj/mole)
0

T (k) C C graphite CO CO2

298,150 006,525 001,051 008,676 009,367
300,000 006,563 001,051 008,731 009,438
400,000 008,647 002,097 011,652 013,306
500,000 010,727 003,394 014,607 017,680
600,000 012,808 004,985 017,621 022,279
700,000 014,892 006,785 020,701 027,130
800,000 016,972 008,710 023,857 032,186
900,000 019,052 010,719 027,084 037,410
1000,00 021,133 012,854 030,374 042,780
1100,00 023,213 015,030 033,718 048,472
1200,00 025,293 017,248 037,113 053,859
1300,00 027,373 019,550 040,553 059,539
1400,00 029,457 021,936 044,450 065,285
1500,00 031,538 024,322 047,539 071,099
1600,00 033,622 026,749 051,076 076,963
1700,00 035,706 029,177 054,638 082,877
1800,00 037,795 031,688 058,220 088,829
1900,00 039,879 034,158 061,820 094,818
2000,00 041,976 036,711 065,440 100,841
2100,00 044,077 039,264 069,073 106,893
2200,00 046,183 041,817 072,723 112,971
2300,00 047,539 044,412 076,381 119,153
2400,00 050,406 047,007 080,052 125,188
2500,00 052,528 049,602 083,735 131,333
2600,00 054,658 052,239 087,422 137,485
2700,00 056,793 054,876 091,122 143,663
2800,00 058,936 057,555 094,831 149,849
2900,00 061,087 060,233 098,543 156,065
3000,00 063,247 062,912 102,264 160,598

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Tables thermodynamiques.

T
dT
Table 6 : Entropies molaires ∫ C P ( j / mole.°K)
0
T
P0 = 1 atm ( Entropies absolues)

T (k) O2 (g) H2 (g) N2 (g) O (g) H (g) N (g) C (g) C

(C.Graphite) (C.Diamant)
0298,15 205,09 130,63 191,57 161,02 114,64 153,23 005,70 02,4397
0300,00 205,30 130,80 191,74 161,14 114,77 153,40 005,75 02,4770
0400,00 213,84 139,17 200,15 167,38 120,75 159,34 008,71 04,7700
0500,00 220,66 145,70 206,72 172,15 125,40 163,99 011,67 07,3700
0600,00 226,44 151,01 212,16 176,00 129,21 167,80 014,54 10,0000
0700,00 231,46 155,60 216,85 179,26 132,39 170,98 017,27 12,6000
0800,00 235,89 159,51 220,99 182,07 135,19 173,78 019,84 15,1100
0900,00 239,91 163,03 224,72 184,54 137,62 176,21 022,24 17,5000
1000,00 243,55 166,16 228,15 186,76 139,80 178,43 024,47 19,6700
1100,00 246,90 169,09 231,29 188,72 141,80 180,40 026,54 21,6800
1200,00 250,00 171,77 234,09 190,57 143,60 182,19 028,49 23,5600
1300,00 252,89 174,24 236,94 192,24 145,28 183,87 030,33
1400,00 255,57 176,59 239,49 193,79 146,83 185,42 032,07
1500,00 258,08 178,80 241,88 195,21 148,25 186,84 033,72
1600,00 260,46 180,90 244,14 196,55 149,59 188,18 035,28
1700,00 262,68 182,91 246,27 197,85 150,85 189,44 036,79
1800,00 264,82 184,80 248,28 199,02 152,02 190,65 038,21
1900,00 266,83 186,63 250,25 200,15 153,15 191,78 039,55
2000,00 268,75 188,40 252,09 201,20 154,19 192,83 040,85
2100,00 270,63 190,06 253,85 202,24 155,24 193,83 042,06
2200,00 272,39 191,65 255,52 203,21 156,20 194,79 043,28
2300,00 274,11 193,20 257,16 204,13 157,12 195,71 044,41

T (k) O2 (g) H2 (g) N2 (g) O (g) H (g) N (g) C

Graphite
2400 275,74 194,71 258,71 205,01 158,00 194,96 45,54
2500 277,33 196,17 260,17 205,88 158,88 197,47 46,58
2750 281,06 199,61 263,69 207,85 160,85 199,44 49,10
3000 284,53 202,79 266,91 209,69 162,65 201,28 51,44
3250 287,71 205,76 269,88 211,37 164,32 202,95 53,57
3500 290,72 208,52 272,64 212,92 165,87 204,55 55,63
3750 293,57 211,12 275,24 214,38 167,29 206,01 57,51
4000 296,25 213,59 277,67 215,76 168,63 207,39 59,35
4250 298,76 215,93 279,93 217,06 169,89 208,73
4500 301,19 218,15 282,10 218,27 171,10 210,03
4750 303,45 220,24 284,15 219,45 172,23 211,24
5000 305,63 222,25 286,08 220,53 173,28 212,46

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Entropie molaire, P=1 atm – (suite) ( J/mole K)

T (k) OH (g) NO (g) C (g) CO (g) CO2 (g) H2O (g) CH4 (g) C2H2 (g)
0298,15 183,70 210,70 158,04 197,97 213,71 188,81 186,25 200,90
0300,00 183,87 210,87 158,17 198,14 213,96 188,98 186,46 201,16
0400,00 192,45 219,49 164,16 206,55 225,26 198,77 197,43 214,72
0500,00 199,02 226,23 168,80 213,17 234,85 206,51 207,10 226,39
0600,00 202,75 231,83 172,61 218,65 243,22 213,04 216,14 236,61
0700,00 208,98 236,73 175,83 223,38 250,71 218,78 224,68 245,65
0800,00 212,96 241,04 178,60 227,61 257,45 223,88 232,76 253,86
0900,00 216,47 244,94 181,06 231,42 263,60 228,53 240,46 261,34
1000,00 219,70 248,49 183,24 234,89 269,25 232,80 247,82 268,29
1100,00 222,63 251,76 185,21 238,07 274,49 236,73 254,86 274,74
1200,00 225,39 254,77 187,01 241,07 279,38 240,46 261,59 280,76
1300,00 227,94 257,58 188,68 243,76 283,94 243,97 268,04 286,41
1400,00 230,33 260,21 190,23 246,36 288,21 247,28 274,19 291,77
1500,00 232,59 262,65 191,65 248,79 292,23 250,42 280,14 296,88
1600,00 234,73 265,03 193,04 251,05 296,00 253,43
1700,00 236,73 267,20 194,29 253,22 299,60 256,32
1800,00 238,70 269,25 195,46 255,27 303,03 259,08
1900,00 238,87 271,22 196,59 257,20 306,25 261,72
2000,00 242,30 273,10 197,68 259,08 309,39 264,27
2100,00 244,01 274,90 198,69 260,84 312,36 266,70
2200,00 245,52 276,62 199,69 262,72 315,21 269,09
2300,00 247,24 278,29 200,61 264,15 317,93 271,35

(Entropies molaires p = 1 atm)

T (k) OH (g) NO (g) C (g) CO (g) CO2 (g) H2O (g)

2400 248,74 279,84 201,53 265,74 320,57 273,56
2500 250,21 281,39 202,37 267,24 323,12 275,66
2750 253,68 284,95 204,42 266,57 329,06 280,72
3000 256,86 288,21 206,30 273,98 334,51 285,41
3250 259,88 291,23 208,10 276,95 339,61 289,76
3500 262,64 294,03 209,65 279,76 344,34 293,91
3750 265,28 296,63 211,16 282,35 348,78 297,80
4000 267,75 299,10 212,62 284,78 352,92 301,52
4250 270,09 301,40 213,96 287,08 356,86 304,96
4500 272,31 303,62 215,26 289,22 360,58 308,18
4750 274,44 305,67 216,52 291,27 364,10 311,28
5000 276,45 307,63 217,65 293,24 367,49 314,25

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