Q.1 Aspartame, an artificial sweetener is a peptide and has the following structure.

Which of the following

statement is correct about the molecule?

(I) It has four functional groups (II) It has three functional groups
(III) on hydrolysis it produces only one amino acid(IV) on hydrolysis it produces a mixture of amino acids
(1) I, III, IV (2) II, III, IV (3) II, IV (4) I, IV
Q.2 Find the product of the following reaction :

(1) (2) (3) (4) None of these

Q.3 A compound which can give positive iodoform test, bromine water test and FeCl3 test but doen’t give
Tollen's test, is:-

(1) (2) (3) (4)

Q.4 The most reactive positions for electrophilic substitution reaction of Anthracene are
8 9 1
7 2

6 3
5 10 4

(1) 1 & 4 (2) 1 & 2 (3) 2 & 3 (4) 9 & 10

Q.5 The correct IUPAC name for the given molecule is:

(1) 4-Bromocarbonyl-2-chlorocarbonyl-5-propanoyloxycyclohexane carboxylic acid

(2) 4-Bromocarbonyl-2-chlorocarbonyl-5-propan-2-oyloxycyclohexane carboxylic acid
(3) 2-Bromocarbonyl-4-chlorocarbonyl-5-propanoyloxycyclohexane carboxylic acid
(4) 4-Bromocarbonyl-2-chlorocarbonyl-5-propanoyloxycyclohexanoic acid
Q.6 Which of the following/(s) compounds can be oxidized by Tollen’s reagent but not by Fehling solution:-

(I) (II) (III) (IV) (V)

(1). II, IV and IV (2) III, IV and V (3) I and II (4) I, II, III, IV and V
Q.7 What is the decreasing order of strength of the bases OH¯, NH 2¯, H – C  C¯ and CH3 – CH2¯?

(1) CH3 – CH2¯ > NH2¯ > H – C  C¯ > OH¯

(2) H – C  C¯ > CH3 – CH2¯ > NH2¯ > OH¯
(3) OH¯ > NH2¯ > H – C  C¯ > CH3 – CH2¯
(4) NH2¯ > H – C  C¯ > OH¯ > CH3 – CH2¯

Q.8 Monomers used in the synthesis of Buna–S are :

(1) Conjugated diene + aromatic compound (2) Cumulative diene + aromatic compound
(3) Separated diene + aromatic compound (4) Alkadiyne + aromatic compound

Q.9 What are A, B and C in the given reaction?

(1) in all cases (2) in all cases

(3) in all cases (4) and

Q.10 The product X in the above reaction is
O
O
C – OC2H5
OC2H5 – C
H3O
O
OC2H5 – C
O C – OC2H5
O
COOH
COOH COOH HOOC
HOOC O
HOOC O HOOC O O HOOC
(1) (2) (3) HOOC (4) COOH

Q.11 Which of the following reaction will not give an aromatic product ?

(1) (2) (3) (4)

Q.12 Compare the two methods shown for the preparation of carboxylic acids:
(i ) CO
Mg
   
2 
(ii) H3O 
Method 1: RBr diethylether RMgBr RCO2H
H 2O,HCl
 
Method 2 : RBr  RCN
NaCN
heat RCO2H
Which of the following statements correctly describes this conversion?


 (1) Both method 1 and method 2 are appropriate for carrying out this conversion.
(2) Neither method 1 nor method 2 is appropriate for carrying out this conversion.
(3) Method 1 will work well, but method 2 is not appropriate.
(4) Method 2 will work well, but method 1 is not appropriate.

Br

2
Q.13 Fe

Major product of above reaction is:

(1) (2) (3) (4)

Q.14 Malamime-Formaldehyde resin is a thermosetting plastic made up of melamine and formaldehyde, Its
monomer melamine has the total number of lone-pairs :
(1)6 (2) 4 (3)8 (4) 10

Q.15 Consider the following sequence of reactions.

O

HOCH2.CH2OH 1. LiAlH4,Et2O
COOCH3 H
+
A +
2.H3O B

The products (A) and (B) are, respectively,

O
OH O O O

O
CH3OC
(1) O and COOCH3 (2) COOCH3 and COOCH3

O O O HO OCH2CH2OH OCH= CH2

(3) COOCH3 and CH2OH (4) COOCH3 and CH2OH

Q.16 Vitamin B12 contains metal :

(1) Ca(II) (2) Zn (II) (3) Fe (II) (4) Co (III)
Q.17 In the given reaction, [X] will be :
O

SeO
2  [X]
 O
O
O CH3

CHO CH3

(1) (2) (3) (4)

O O

Q.18 Stability order of following singlet halocarbene is

(1) CF2 > CCl2 > CBr2 > CI2 (2) CI2 > CBr2 > CCl2 > CF2
(3) CCl2 > CF2 > CBr2 > CI2 (4) CF2 > CI2 > CCl2 > CBr2

Q.19 Which one of the following can not be the product during dehydration of following alcohol.

H


(1) (2) (3) (4)

OsO4 Br2
B A
H2O2
Q.20 , A and B are :
Br OH Br OH

(1). Br OH (2). Br OH

Br OH Br OH

(3). Br OH (4.) Br OH

“Failure is the opportunity to begin again more intelligently.” – Henry Ford