JEE Advanced 2018 Paper - 2 Question With Solution - Chemistry

(Page # 18) JEE (MAIN + ADVANCED) Examination (2018)
TM JEE ADVANCED 2018 [PAPER - 2]

Hindi _ [CHEMISTRY]
Section - 1 : (Maximum Marks : 24)
 This section contains SIX (06) questions.
 Each questions has FOUR options for correct answer(s). ONE OR MORE THAN ONE of these
four option(s) is (are) correct option (s).
 For each question, choose the correct option(s) to answer the questions
 Answer to each question will be evaluated according to the following marking chosen.
Full Marks : +4 If only (all) the correct option(s) is (are) chosen.
Partial Marks :+3 If all the four options are correct but ONLY three options are chosen.
Partial Marks : +2 If three or more options are correct but ONLY two options are
chosen, both of which are correct options.
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen
and it is a correct option.
Zero Marks : 0 If none of the options is chosen (i.e., the question is unanswered)
Negative Marks : –2 In all other cases.
- For Example : If first, third and fourth are the ONLY three correct options for a question with
second option being an incorrect option : Selecting only two of the three correct options (e.g., the
first and fourth options), without selecting any incorrect option (second option in this case) will
result in +2 marks. Selecting only one of the three correct options (either first or thrid or fourth
option), without selecting any incorrect option (second option in this case), will result in +1 marks.
Selecting any incorrect option(s) (second option in this case), with or without selection of any
correct option(s), will result in –2 marks.
1. The correct option(s) regarding the complex [Co(en) (NH3)3(H2O)]3+ :

(en = H2NCH2CH2NH2) is (are)
(A) It has two geometrical isomers
(B) It will have three geometrical isomers if bidentate ‘en’ is replaced by two cyanide ligands
(C) It is paramagnetic
(D) It absorbs light at longer wavelength as compared to [Co(en) (NH3)4]3+
la
dqy [Co(en) (NH3)3(H2O)]3+ dsl a
nHkZesal ghfodYi gS&
(en = H2NCH2CH2NH2)
(A) ; g nksT; kfefr ; l eko; ohj [ kr k gS
(B) ; g r hu T; kfefr ; l eko; oh j [ ks
xk ; fn f} nUr q
d ‘en’ dksnksl k; ukbM fy xs.Mks} kj k i zfr LFkkfi r dj fn; k t k,
(C) ; g vuq pq
Ecdh; gS
(D) ; g [Co(en) (NH3)4]3+ l svf/kd r j a x} S
/; Zi j i zd k' k dk vo' kks"k.k dj r k gS
Sol. A, B, D
The given complex
[Co(en)(NH3)3H2O]3+ has 2 – Geometrical Isomer as following
3+ 3+
NH 3 NH3
N NH3 N H2O
CO POS CO POS
N NH3 N NH3
H2O NH3
facial form Meridonial form
Both are optically inactive (PoS)

When en is replace by CN– then the complex will be [Co(CN)2(NH3)3 (H2O)] & it has three
geometrical isomers as –
: info@motion.ac.in, url : www.motion.ac.in, : 1800-212-1799

99, 8003899588
JEE (MAIN + ADVANCED) Examination (2018) (Page # 19)
NH3 NH 3 NH3
CN NH3 CN H2O H2O CN
CO CO CO
CN NH3 CN NH 3 CN NH3
H2O NH3 NH 3
facial form
(optically inactive) 2- Meridonial form
-
(trans wrt CN )
-
(Cis wrt CN )
[Co(en)(NH3)H2O] It has en & NH3 as strong field ligand so it is a low spin complx with
3+
Hybridisation d2sp3 & in dimagnetic
Co3+ 3d6
3d8 4S 4P
3d 4s 4d
2 3
d sp
hc
o = abs
as
strong field nature of Ligend inc. o Inc.
2. The correct option(s) to distinguish nitrate salts of Mn2+ and Cu2+ taken separately is (are) : -
(A) Mn2+ shows the characteristic green colour in the flame test
(B) Only Cu2+ shows the formation of precipitate by passing H2S in acidic medium
(C) Only Mn2+ shows the formation of precipitate by passing H2S in faintly basic medium
(D) Cu2+/Cu has higher reduction potential than Mn2+/Mn (measured under similar conditions)
vy x&vy x fy , x, Mn2+ r Fkk Cu2+ dsukbVªsV y o.kksdksi F̀kd dj usdsfy , l ghfodYi gS&
(A) Mn2+ Toky k i j h{k.k es afof' k"V gj k j a
x n' kkZ
r k gS
(B) ds
oy Cu vEy h; ek/; e esaH2S xq
2+
t kj usi j vo{ksi dk fuekZ
. k n' kkZ
r k gS
(C) ds
oy Mn /kq
2+
¡/ky s{kkj h; ek/; e esaH2S xq t kj usi j vo{ksi dk fuekZ. k n' kkZ
r k gS
(D) Cu /Cu, Mn /Mn (l eku voLFkkvkses
2+ 2+
aekfi r ) l smPp vi p; u foHko j [ kr k gS
Sol. B,D
Mn2+ is IV group radical in which group reagent is H2S + NH4OH


H2S 
 2H+ + S2


NH4OH 
 NH4 + OH–
H+ + OH–  H2O
so equilibrium shift in forward reaction [S–2] increases
KSP as IV group sulphide is higher & hence its solubility is higher
Cu2+ & Mn2+ gives some green flame is flame test Cu2+/Cu,+ve standard reduction potential (refer
the electro chemical series.)
3. Aniline reacts with mixed acid (cone. HNO3 and cone. H2SO4) at 288 K to give P (51%), Q (47%)
and R (2%). The major product(s) the following reaction sequence is (are) :
(1) Ac2O, pyridine (1) Sn/HCl

(2) Br2, CH3CO2H (2) Br2/H2O (excess)
R + S major product(s)
(3) H3O (3) NaNO 2, HCl/273-278K
(4) NaNO2, HCl/273-278K (4) H 3PO2
Corporate Office : Motion Education Pvt. Ltd., 394 - Rajeev Gandhi Nagar, Kota
Br
Br Br Br
Br Br
(A) (B) (C) (D)
Br Br
Br Br Br Br Br
Br Br
288 K i j , fuy hu] fefJr vEy (l kUnzHNO3 r Fkk l kUnzH2SO4) dsl kFk fØ; k dj dsP (51%), Q (47%) r Fkk R
(2%) nsr k gS
A fuEu vfHkfØ; k vuq
Øe dk eq[ ; mRikn gS&
(1) Ac2O, fi j hMhu (1) Sn/HCl

(2) Br2, CH3CO2H (2) Br2/H2O (vkf/kD; )
R + S eq
[ ; mRikn
(3) H3O (3) NaNO2, HCl/273-278K
(4) NaNO2, HCl/273-278K (4) H3PO2
Br
Br Br Br
Br Br
(A) (B) (C) (D)
Br Br
Br Br Br Br Br
Br Br
Sol. D
NH2 NH 2 NH2 NH 2
NO2
HNO3 + H2SO4
+ +
(2%) (47%)
NO2
NO2
(51%)
O
NH—C—Cl 3
NH2 NH—C—CH3
NO2 NO2
AC2O NO2
Py Br2/CH3CO2H
+ Br
N2 NH2
NO2 Et-OH NO2 NaNO 2 NO2

HCl
0–5°C
Sn+HCl
Br Br Br
Br NH2 Br
NO2 Br2/H2O NH2 NaNO2 + HCl N2 H3PO2

(excess) 0–5°C
Br Br Br Br Br Br
Br Br Br Br

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4. The Fischer presentation of D-glucose is given below.

CHO
H OH
HO H
H OH
H OH
CH2OH
D-glucose
The correct structure(s) of -glucopyranose is (are) :-
H H CH2OH H
O O O O
CH2OH CH2OH H CH2OH
HO OH HO OH H OH HO H
(A) H H (B) H H (C) HO H (D) H OH

H HO H H OH HO H HO
OH H OH OH H H OH H
D-Xy q
d kst dk fQ' kj fu: i .k uhpsfn; k x; k gS
A
CHO
H OH
HO H
H OH
H OH
CH2OH
D-Xyq
d ks
t
-Xy q
d ksik; j sukst dhl ghl a
j puk gS&
H H CH2OH H
O O O O
CH2OH CH2OH H CH2OH
HO OH HO OH H OH HO H
(A) H H (B) H H (C) HO H (D) H OH

H HO H H OH HO H HO
OH H OH OH H H OH H
Sol. D
CH=O H
H OH OH O
CH2OH
HO H O OH
HO H
H OH OH
H OH OH H
H OH
OH H HO
CH2OH
D-glucose OH OH
5. For a first order reaction A(g)  2B(g) + C(g) at constant volume and 300 K, the total pressure
at the beginning (t = 0) and at time t are P0 and Pt , respectively. Initially, only A is present with
concentration [A]0, and t1/3 is the time required for the partial pressure of A to reach 1/3rd of its
initial value. The correct option(s) is (are) :
(Assume that all these gases behave as ideal gases)
Rate constant
(A) (B) (C) (D)
Time [A]0 Time [A]0

fu; r vk; r u r Fkk 300 K i j , d i zFke dksfV vfHkfØ; k A(g)  2B(g) + C(g) dsfy , i zkj EHk (t = 0) r Fkk l e; t i j
nkc Øe' k%P0 r Fkk Pt gS A i zkj EHk ea
sdsoy A l kUnzrk [A]0 dsl kFk mi fLFkr gksrk gSr Fkk t1/3, A dsvka
f' kd nkc dksbl ds
i zkj fEHkd eku ds1/3 r d i gq
rd
¡pusdsfy , vko' ; d l e; gSA l ghfodYi gS&
(ekuk l H kh xS
l svkn' kZxS
l ksdhHkk¡fr O ; ogkj dj r hgS
)
nj fu; r ka
d
(A) (B) (C) (D)
l e; [A]0 l e; [A]0
Sol. A,D
A  2B + C
t=o P0
‘t’ P0–x 2x x P0 + 2x = Pt
 
 P0 

n  P  P0   = Kt
P0  t
 2 
 2P0 
n  3P  P  = Kt
 0 t
n{3P0 – Pt} = –kt + ln(2P0)

(–)ve slope (+)ve intervept (+) correct
 P0 
Kt1/3 = ln  P / 3  = ln (3)
 0 
6. 

For a reaction, A 
 P , the plots of [A] and [P] with time at temperatures T1 and T2 are given
below.
10 10
T1
T2
5 5
T2
T1
Time Time

99, 8003899588
If T2 > T1, the correct statement(s) is (are)

(Assume H° and S° are independent of temperature and ratio of InK at T1 to InK at T2 is greater
T2
than T1 . Here H, S, G and K are enthalpy, entropy, Gibbs energy and equilibrium constant,
respectively.)
(A) H0 < 0, S0 < 0 (B) G0 < 0, H0 > 0
(C) G0 < 0, S0 < 0 (D) G0 < 0, S0 > 0


, d vfHkfØ; k A 
 P , dsfy , r ki T1 r Fkk T2 i j l e; dsl kFk [A] r Fkk [P] dsoØ uhpsn' kkZ
, x, gS
A
10 10
T1
T2
5 5
T2
T1
l e; l e;
; fn T2 > T1 r ksl ghfodYi gS

T2
(ekuk H° r Fkk S° r ki i j fuHkZ
j dj r sgSr Fkk InK (T1) r Fkk InK (T2) dk vuq
i kr T1 l svf/kd gS
A ; gk¡ H, S, G
r Fkk K Øe' k%, UFksYi h] , UVªkW

i h] fxCl Åt kZr Fkk l kE; fu; r ka
d gS
)
(A) H0 < 0, S0 < 0 (B) G0 < 0, H0 > 0
(C) G0 < 0, S0 < 0 (D) G0 < 0, S0 > 0
Sol. A, C
A  P
Keq at T1 > Keq at T2(K2) from graph
T 2 > T1
 K2  H  1  1 
n  K  =  
 1 R  T1 T2 
H  0
ln k1  T2
ln k2  > T
1
S H  1 
  
R R  T1 
T2
S x  1  > T1
  
R R  T2 
S H S H

T1 – > T2. 
R R R R
S
(T1 – T2) 0
R
S  0
G° = H° – T.s°
G° < 0 both
>0
7. The total number of compounds having at least one bridging oxo group among the molecules
given below is________
N2O3, N2O5, P4O6, P4O7, H4P2O5, H5P3O10, H2S2O3, H2S2O5
uhpsfn, x, v.kq
v ksea
sl s; kS
fxdksdhl a
[ ; k t ksU; q
ur e , d l srqvkW
Dl ksl ew
g j [ kr sgS&
N2O3, N2O5, P4O6, P4O7, H4P2O5, H5P3O10, H2S2O3, H2S2O5
Sol. 5 or 6
O
N O N O
N2O3 O O=N-N O
symmetrical str.
unsymmetrical str.
O
O
N2O5 N O N
O O
P O P
O OO O
P4O6
P O P
O
P O P
P4O2 O OO O
P O P
O O
HO P O P OH
H H
O O O
HO P O P O P OH
OH OH OH
S
HO S OH
O O
HO S S OH
(5 or 6) It N2O3 is considered or not considered

99, 8003899588
8. Galena (an ore) is partially oxidized by passing air through it at high temperature. After some
time, the passage of air is stopped, but the heating is continued in a closed furnance such that
the contents undergo self-reduction. The weight (in kg) of Ph produced per kg of O, consumed is
_______.
(Atomic weights in g mol–1 : O = 16, S = 32, Ph = 207)
xsy suk ¼, d v; Ld½mPp r ki i j gok xq t kj usi j vka f' kd vkW
Dl hdr̀ gksrk gS
A dq
N l e; ckn gok dk i zokg j ksd nsrsgS
] fdUr q
, d ca n HkV~ Vhea sÅ"ek dk i zokg l r r ~j [ kr sgSft l l svo; o Lor %vi pf; r gksrsgSA O dsi zfr fdy ksxzke mRikfnr gq, Ph
dk Hkkj ¼ fdy ksxzke esa
½gksxk &
(i j ek.kqH kkj ] g mol–1 esa: O = 16, S = 32, Ph = 207)
Sol. 6.47
Involved reaction are
2Pbs + 3O2 
T1
 2PbO + 2SO2
Galena
2PbO + Pbs 
T2
 3Pb + SO2
T2 > T1
3Pbs + 3O2  3Pb + 3SO2
or PbS + O2  Pb + SO2
mole of O2 consumed = mol at Pb formed
103 Wt of Pb
=
32 207
103 x 207
Wt at Pb = = 6.47 x 103g
32
= 6.47 Kg
9. To measure the quantity of MnCl2, dissolved in an aqueous solution, it was completely converted
to KMnO4 using the reaction,
MnCl2 + K2S2O8 + H2O  KMnO4 + H2SO4 + HCl (equation not balanced).
Few drops of concentrated HCl were added to this solution and gently warmed. Further, oxalic
acid (225 g) was added in portions till the colour of the permanganate ion disappeard. The
quantity of MnCl2, (in mg) present in the initial solution is ________.
(Atomic weights in g mol–1 : Mn = 55, Cl = 35.5)
, d t y h; foy ; u esa?kq y sMnCl2 dhek=kk eki usdsfy , bl sfuEu vfHkfØ; k dk mi ; ksx dj r sgq , iw. kZ: i l sKMnO4 ea
s
i fj ofr Z
r dj fn; k t kr k gS
MnCl2 + K2S2O8 + H2O  KMnO4 + H2SO4 + HCl (l ehdj .k l a rqfy r ughgS
)
bl foy ; u esal kfUnzr HCl dhdq N cw¡nsfey k; ht kr hgSr Fkk /khjs&/khjsxeZfd; k t kr k gS
A vkxsvkW
Dl sfy d vEy (225 g)
dksi j esaXusV vk; u dk j a
x foy q
Ir gksusr d fey k; k t kr k gS
A i zkj fEHkd foy ; u esaMnCl2 dhek=kk (mg ea s) gksxh &
(i j ek.kqHkkj ] g mol esa: Mn = 55, Cl = 35.5)
–1
Sol. 126
+2 +7 –2
MnCl2 + K2S2O8 + H2O KMnO4 + H2SO4 + HCl
RA
vf = 5
Ox. reduction
vf = 2
KMnO4 + oxalic 

acidic
 Ni+2 + CO
2
225
 103 gm
26  64
225  103
×2 = 5 × nKMnO4
90
= 5 × nMnCl2
2.25  2  103 W in mg  103

=5×
90 55771
450  126
W=
90  5
w = 126
10. For the given compound X, the total number of optically active stereoisomers is_____.
OH H OH
This type of bond indicates that he configuration at the
H specific carbon and the geometry of the double bond is fixed.
* *
* This type of bond indicates that he configuration at the
OH specific carbon and the geometry of the double bond is NOT fixed.
OH
fn, x, ; kS
fxd X dsfy , i zd kf' kd l fØ; l eko; fo; ksdhl a
[ ; k gksxh&
OH H OH
bl i z d kj dk ca/k fof' k"V dkcZ
u i j foU; kl dksfu: fi r dj r k gS
H r Fkk f} ca
/k dh T; kfefr fLFkj j gr h gS
* *
* bl i z d kj dk ca/k fof' k"V dkcZ
u i j foU; kl dksfu: fi r dj r k gS
OH r Fkk f} ca
/k dh T; kfefr fLFkj ugh j gr h gS
OH
Sol. 7
23 total = 8
1 meso = Optically active = 8 – 1 = 7
11. In the following reaction sequence, the amount of D (in g) formed from 10 moles of acetophenone
is_______.
(A tomic weight in g mol–1: H = 1, C = 12, N = 14, O = 16, Br = 80. The yield (%) corresponding
to the product in each step is given in the parenthesis)
O
NaOBr Br2/KOH Br2(3 equiv)

A B C D
H3O
+
AcOH
(60%) (50%) (50%) (100%)
fuEu vfHkfØ; k vuqØe esa10 eksy , l hVksQhukW
u l sfufeZ
r gq
, D dhek=kk (g ea
s) Kkr dj ksA
(i j ek.kqH
kkj g mol : H = 1, C = 12, N = 14, O = 16, Br = 80. i zR; sd i n esamRikn dsvuq
–1
l kj (%) y fC/kczsd sV
esanhxbZgS%
NaOBr Br2/KOH Br2(3 equiv)

A B C D
H3O
+
AcOH
(60%) (50%) (50%) (100%)

99, 8003899588
Sol. 495
HO H2N NH 2 NH 2
Br Br
NaOBr Br 2/KOH Br2 (3 equiv)
H3O+ AcOH
10 mole (60%) (50%) (50%)

6 mol 3 mol 1.5 mol Br
100%
1.5 mol = 495 gm
12. The surface of copper gets tarnished by the formation of copper oxide. N2 gas was passed to
prevent the oxide formation during heating of copper at 1250 K. However, the N2 gas contains 1
mole % of water vapour as impurity. The water vapour oxidises copper as per the reaction given
below :
2Cu(s) + H2O(g)  Cu2O(s) + H2(g)
pH2 is the minimum partial pressure of H2 (in bar) needed to prevent the oxidation at 1250 K. The
 
value of ln pH2 is ___.
(Given : total pressure = 1 bar, R (universal gas constant) = 8 JK–1mol–1, ln(10) = 2.3. Cu(s) and
Cu2O(s) are mutually immiscible.
At 1250 K : 2Cu(s) + 1/2O2(g)  Cu2O(s); G = –78,000 J mol–1
H2(g) + 1/2O2(g)  H2O(g); G = 1,78,000 J mol–1; G is the Gibbs energy)
dkW
i j dk i `"B dkW i j vkW
Dl kbM dsfuekZ . k dsdkj .k /kq
¡/ky k gkst kr k gS
A 1250 K i j dkWi j dksxeZdj usdsnkSj ku vkW
Dl kbM
fuekZ
. k dksj ksd usdsfy , N2 xSl xqt kj ht kr hgS
A fQj HkhN2 xS l esav' kq
f) ds: i esa1 eksy % t y ok"i mi fLFkr gksrhgS
A
t y ok"i uhpsnhxbZvfHkfØ; k dsvuq
l kj dkW
i j dksvkW
Dl hdr̀ dj r hgS
A
2Cu(s) + H2O(g)  Cu2O(s) + H2(g)
pH2 , 1250 K i j vkW
Dl hdj .k dksj ksd usdsfy , H2 dk U; w
ur e vka
f' kd nkc (bar ea
s) gS
Aln pH2   dk eku gksxk &
(fn; k gS:
dqy nkc = 1 bar, R (l oZ
=k xS
l fu; r ka
d ) = 8 JK–1mol–1, ln(10) = 2.3. Cu(s) r Fkk Cu2O(s) i j Li j
vfeJ.kh; gS
A
1250 K i j : 2Cu(s) + 1/2O2(g)  Cu2O(s); G = –78,000 J mol–1
H2(g) + 1/2O2(g)  H2O(g); G = 1,78,000 J mol–1; G fxC l Åt kZgS
)
Sol. –14.6
Cu + O2  CuO
2Cu(s) + H2O(g)  Cu2O + H2
1
2Cu(s) + O (g)  Cu2O(s)
2 2
G° = –78000 = –nF E°
1
H2 + O  H2O(g)
2 2
G° = –178000
H2O(g)  H2 + H2O2 G° = +178000
2Cu(s) + H2O(g)  Cu2O(s) + H2(g)

G° = 1,00,000
  PH 
2
G =  1,00,000  8  1250ln   > 0
  PH2 O  g  
100000
  – ln P 
ln PH2 H2O >–
10000
  –2.3 × (–2) > –10

ln PH2
ln P  > –14.6
H2
13. Consider the following reversible reaction,

A(g) + B(g) AB(g).
The activition energy of the backward reaction exceeds that of the forward reaction by 2RT (in J
mol–1). If the pre-exponential factor of the forward reaction is 4 times that of the reverse reaction,
the absolute value of G (in J mol–1) for the reaction at 300 K is____.
(Given ; ln (2) = 0.7, RT = 2500 J mol–1 at 300 K and G is the Gibbs energy)
fuEu mRØe.kh; vfHkfØ; k i j fopkj dhft , %
A(g) + B(g) AB(g).
i ' p vfHkfØ; k dhl fØ; .k Åt kZ(J mol eas) vxzvfHkfØ; k l s2RT vf/kd gS
–1
A ; fn vxzvfHkfØ; k dk i w
oZ?kkr ka
d h; xq
. kka
d
mRØe.kh; vfHkfØ; k l s4 gksr ks300 K i j vfHkfØ; k dsfy , Gdk i j e eku (J mol–1 eas) gksxk &
(fn; k gS
; 300 K i j ln (2) = 0.7, RT = 2500 J mol–1 r Fkk G fxC l Åt kZ)
Sol. 8500
A + B  AB
(g) (g) (g)
Eab = Eaf + 2RT
Eaf – Eab = –2RT H°
Af = 4 Ab
Kf = Af e Eaf / RT
Kb = Ab e Eab / RT
kf Ab Eaf  Eab 
kb = Ab e
–
RT
Keq = 4 e+2
G° = –RT ln(Keq)
= –2500 [2 + ln(4)]
= –2500 [3.4]
= –250 × 34
1000  17
=–
2
G° = –8500 J/mol
Absolute value = 8500
14. Consider an electrochemical cell: A(s)  An+ (aq, 2M)  B2n+ (aq, 1M)  B(s). The value of H for the
cell reaction is twice that of G at 300 K. If the emf of the cell is zero, the S (in JK–1 mol–1) of
the cell reaction per mole of B formed at 300 K is___.
(Given : ln (2) = 0.7, R (universal gas constant) = 8.3 J K–1 mol–1. H, S and G are enthalpy,
entropy and Gibbs energy, respectively).
, d fo| qr j kl k; fud l sy A(s)  An+ (aq, 2M)  B2n+ (aq, 1M)  B(s) i j fopkj dhft , A 300 K i j l sy vfHkfØ; k
dsfy , Hdk eku Gl snksxq uk gksrk gS
A ; fn l sy dk emf ' kw
U; gksr ks300 K i j fufeZ
r B dsi zfr eksy l sy vfHkfØ; k
dk S (JK mol esa
 –1 –1
) gks
xk &
(fn; kgS: ln (2) = 0.7, R (l oZ =kxS
l fu; r kd
a ) = 8.3 J K–1 mol–1. H, S r FkkG Øe' k%, UFksYi h] , UVªkW
i hr FkkfxC
l Åt kZgS
)
Sol. –11.62
A(s)  An+ + ne–
B2n+ + 2ne–  B(s)
B+2n + 2A(s)  2An+ + B(s)
2
 An  
  4
Q =  2n   =
B 1
 

99, 8003899588
o RT
E = E°Ce11 – 2n F ln (4)
Ce11
(2n) (F) E°Ce11 = +RT ln(4)

–G° = +2RT ln(2)
G° = –2RT ln(2)
G° = H° – T.S°
T.S° = H° – G°
T.S° = G°
T.S° = –2RT ln(2)
S° = –2×8.3×0.7 = –16.6 × 0.7 = –11.62 J/mol K
15. Match each set of hybrid orbitals from LIST-I with complex (es) given in LIST-II.
LIST-I LIST-II
P. dsp2 1. [FeF6]4–
Q. sp 3
2. [Ti(H2O)Cl3]
R. sp d
3 2
3. [Cr(NH3)6]3+
S. d sp
2 3
4. [FeCl4]2–
5. Ni(CO)4
6. [Ni(CN)4]2–
The correct option is
(A) P  5; Q  4, 6; R  2, 3; S  1 (B) P  5, 6; Q  4; R  3; S  1,2
(C) P  6; Q  4, 5; R  1; S  2, 3 (D) P  4, 6, Q  5, 6; R  1, 2; S 3
lw
ph-I l a
d fj r d{kdksdsi zR; sd l eq
Pp; dksl w
ph-II esafn, x, l a
dqy ksdsl kFk l w
esfy r dhft , %
lw
ph-I lwph-II
P. dsp2 1. [FeF6]4–
Q. sp3 2. [Ti(H2O)Cl3]
R. sp3d2 3. [Cr(NH3)6]3+
S. d2sp3 4. [FeCl4]2–
5. Ni(CO)4
6. [Ni(CN)4]2–
l ghfodYi gS%
(A) P  5; Q  4, 6; R  2, 3; S  1 (B) P  5, 6; Q  4; R  3; S  1,2
(C) P  6; Q  4, 5; R  1; S  2, 3 (D) P  4, 6, Q  5, 6; R  1, 2; S 3
Sol. C
[FeF6]4– F– b– wFL so Sp3d2
3
[ Ti (H2O)3 Cl3] 3d1 configuration CN = 6 so d2sp3
[Cr(NH3)6]3+ 3d3 configuration CN = 6 so d2sp3
[FeCl4]2– Sp3 weak field lignd CN = 4
[Ni(CO)4] Sp3 Co is strong field lignd
8 2
Ni 3d 4s
4p 4d
3d
10 4S 4P 4d
sp3 hybridisation
[Ni (CN)4]2– CN– is strong field ligand
Ni2+ 8
3d 4S 4P
4S
2
dsp Hybridisation
16. The desired product X can be prepared by reacting the major product of the reactions in LIST-I
with one or more appropriate reagents in LIST-II.
(given, order of migratory aptitude: aryl > alkyl > hydrogen)
OH
Ph
Ph
Me
X
LIST-I LIST-II
Ph
HO
P. Ph 1. I2, NaOH
Me
OH + H2SO4
Me
Ph
H2N
Q. Ph 2. [Ag(NH3)2]OH
Me
OH + HNO2
Me
Ph
HO
R. Me 3. Fehling solution
Ph
OH + H2SO4
Me
Ph
Br
S. Ph 4. HCHO, NaOH
H
OH + AgNO3
Me
5. NaOBr
The correct option is
(A) P  1; Q  2, 3; R  1, 4; S  2, 4 (B) P  1, 5; Q  3, 4; R  4, 5; S  3
(C) P  1, 5; Q  3, 4; R  5; S  2, 4 (D) P  1, 5; Q  2, 3; R  1, 5; S  2, 3

99, 8003899588
lwph&I esavfHkfØ; kvksdseq

[ ; mRikn dksl w
ph&II esal s, d ; kvf/kd mfpr vfHkdeZ
d ksdsl kFk fØ; k} kj k oka
fNr mRikn dks
fufeZ
r fd; k t k l dr k gS
A
(fn; k gS
] ?kq
ea
r qdk Øe gS%, fj y > , fYdy > gkbMªkst u)
O
OH
Ph
Ph
Me
X
lw
ph-I lw
ph-II
Ph
HO
P. Ph 1. I2, NaOH
Me
OH + H2SO4
Me
Ph
H2N
Q. Ph 2. [Ag(NH3)2]OH
Me
OH + HNO2
Me
Ph
HO
R. Me 3. Qsgfy a
x foy ; u
Ph
OH + H2SO4
Me
Ph
Br
S. Ph 4. HCHO, NaOH
H
OH + AgNO3
Me 5. NaOBr
l ghfodYi gS&
(A) P  1; Q  2, 3; R  1, 4; S  2, 4 (B) P  1, 5; Q  3, 4; R  4, 5; S  3
(C) P  1, 5; Q  3, 4; R  5; S  2, 4 (D) P  1, 5; Q  2, 3; R  1, 5; S  2, 3
Sol. D
17. LIST-I contains reactions and LIST-II contains major products.

LIST-I LIST-II
P. + 1.
ONa Br OH
Q. + HBr 2.
OMe Br
R. + NaOMe 3.
Br OMe
S. + MeBr 4.
ONa
O
5.
Match each reaction in LIST-I with one or more product in LIST-Il and choose the correct option.
(A) P  1, 5; Q  2; R  3; S  4 (B) P  1, 4; Q  2; R  4; S  3
(C) P  1, 4; Q  1, 2; R  3, 4; S  4 (D) P  4, 5; Q  4; R  4; S  3, 4
lw
ph&I ea
svfHkfØ; k, ¡ r Fkk l w
ph&II ea
seq
[ ; mRikn mi fLFkr gS
A
lw
ph-I lw
ph-II
P. + 1.
ONa Br OH
Q. + HBr 2.
OMe Br
R. + NaOMe 3.
Br OMe
S. + MeBr 4.
ONa
O
5.
ph-I esami fLFkr vfHkfØ; k dksl w

lw ph&II ea
sl s, d ; k vf/kd mRikn dsl kFk fey kb, r Fkk l gh fodYi pq
fu, A
(A) P  1, 5; Q  2; R  3; S  4 (B) P  1, 4; Q  2; R  4; S  3
(C) P  1, 4; Q  1, 2; R  3, 4; S  4 (D) P  4, 5; Q  4; R  4; S  3, 4
Sol. B
P :
H3C H3C H3C CH2
CH3 CH3 CH 3
E2
+ +
H3C H3C H3C H3C CH 3
ONa Br OH
(i) (iv)
CH3
H3C
CH3
Q : H3C O + HBr + MeOH
CH 3 H3C
Br
CH3
H3C CH2
CH3
— +
R: MeO Na
E2
H3C H3C CH 3
Br
H3C H3C
CH3 2
CH 3
SN
S: + MeBr
H3C H3C
ONa OMe

99, 8003899588
18. Dilution process of different aqueous solutions; with water, are given in LIST-I. The effects of
dilution of the solutions on [H+] are given in LIST—II.
(Note: Degree of dissociation () of weak acid and weak base is << 1; degree of hydrolysis of salt
<<1; [H+] represents the concentration of H ions)
LIST-I LIST-II
P. (10 mL of 0.1 M NaOH + 20 mL of 1. the value of [H+] does not change on dilution
0.1 M acetic acid) diluted to 60 mL
Q. (20 mL of 0.1 M NaOH + 20 mL of 2. the value of [H+] change to half of its initial
0.1 M acetic acid) diluted to 80 mL value on dilution
R. (20 mL of 0.1 M HCl + 20 mL of 3. the value of [H+] changes to two times of its
0.1 M animonia solution) diluted to 80 mL initial value on dilution
1
S. 10 mL saturated solution of Ni(OH), in 4. the value of [H+] changes to times of its
2
equilibrium with excess solid Ni(OH)2 is initial value on dilution
diluted to 20 mL (solid Ni(OH), is still
present after dilution).
5. the value of [H+] changes to 2 times of its
initial value on dilution
Match each process given in LIST-I with one or more effect(s) in LIST-II. The correct option is
(A) P  4; Q  2; R  3; S 1 (B) P  4; Q  3; R  2; S  3
(C) P  1; Q  4; R  5; S  3 (D) P  1; Q  5; R  4; S  1
lwph&I ea st y dsl kFk fofHkUu t y h; foy ; uksdsr uqr k i zØe fn, x, gSAl w ph&II eas[H+] i j foy ; uksdhr uq r k dk i zHkko
n' kkZ
; k x; k gS
A
(l wpuk : nq cZ
y vEy r Fkknq cZ
y {kkj dsfo; kst u dhek=kk() << 1; y o.kdst y vi ?kVu dhek=kk<<1; [H+], H vk; uks
dhl kUnzrk dksfu: fi r dj r k gS )
lwph-I lwph-II
P. (10 mL, 0.1 M NaOH + 20 mL, 1. [H+] dk eku r uq r k i j i fj ofr Z
r ugh gksrk gS
0.1 M , l hfVd vEy ) 60 mL r d r uqdj r sgS
Q. (20 mL, 0.1 M NaOH + 20 mL, 2. r uq
d j .k i j [H+] dk eku bl dsi zkj fEHkd eku dk vk/kk
0.1 M , l hfVd vEy ) 80 mL r d r uqdj r sgS gkst kr k gS
R. (20 mL, 0.1 M HCl + 20 mL, 3. r uq
d j .ki j [H+] dkeku bl dsi zkj fEHkd eku dknksxq uk
0.1 M veks fu; k foy ; u) 80 mL r d r uqdj r sgS gkst kr k gS
1
S. 10 mL, Ni(OH) foy ; u t ksBksl 4. r uq
d j .k i j [H+] dk eku bl dsi zkj fEHkd eku dk
2
Ni(OH)2 dsl kFk l kE; esagS] dks gkst kr k gS

20 mL r d r uqfd; k t kr k gS(Bks l Ni(OH)
r uq
d j .k dsi ' pkr ~mi fLFkr gksrk gS
)
1
5. r uq
d j .k i j [H+] dk eku bl dsi zkj fEHkd eku dk
2
gkst kr k gS
lw
ph-I esafn; sx; si zR; sd i zØe dksl w
ph-II esal s, d ; k vf/kd i zHkko dsl kFk l q
esfy r dhft , A
(A) P  4; Q  2; R  3; S 1 (B) P  4; Q  3; R  2; S  3
(C) P  1; Q  4; R  5; S  3 (D) P  1; Q  5; R  4; S  1
Sol. D
(P) 10mol of 0.1M NaOH
 60ml
20 ml 0.1M CH3COOH
NaOH + CH3COOH  CH3COO– + Na+ + H2O
1 2 1
0 1
Buffer
Ans. P–1
(Q) 20ml of 0.1 M NaOH
+ 80ml
20 ml 0.1M CH3COOH
NaOH + CH3COOH  CH3COO– + H2O + Na+
2 2
0 0 2 (salt hydrolysis)

CH COO–  
 CH COOH + OH–
3 3
Kw
[OH–] = c
Ka
Kw
Kw K w  Ka
[H+] = OH  = Kw  C =
  Ka C
On direction,  Conc. 
[H+] 
K w  Ka  40
[H+]i =
2
K w  Ka  8000
[H+]f = = K w  Ka  20 × 2
2
Q – (5)
(R) HCl + NH3  NH4+ Cl–
2 2
0 0 2
Kw
[H+] =  Conc.
Kb
Kw 2 Kw 1
[H+] =  
Kb 40 = Kb 20
Kw 2 Kw 1
[H+]i =  
Kb 40 = Kb 20
Kw 2 Kw 1 1
[H+]f =  
Kb 80 = Kb 20 × 2
R4


(S) Ni(OH)2(s) 
 Ni2+ + 2OH–
n 2n
2
 n   2n 
 10  1000    1000  = K
   10  sp
2
 x   2x 
 20  1000    1000  = Ksp
   20 
S–1
99, 8003899588

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(Page # 18) JEE (MAIN + ADVANCED) Examination (2018)

TM JEE ADVANCED 2018 [PAPER - 2]

1. The correct option(s) regarding the complex [Co(en) (NH3)3(H2O)]3+ :

facial form Meridonial form

Both are optically inactive (PoS)

: info@motion.ac.in, url : www.motion.ac.in, : 1800-212-1799

Hybridisation d2sp3 & in dimagnetic

strong field nature of Ligend inc. o Inc.

(1) Ac2O, pyridine (1) Sn/HCl

(1) Ac2O, fi j hMhu (1) Sn/HCl

NO2 Et-OH NO2 NaNO 2 NO2

NO2 Br2/H2O NH2 NaNO2 + HCl N2 H3PO2

: info@motion.ac.in, url : www.motion.ac.in, : 1800-212-1799

4. The Fischer presentation of D-glucose is given below.

(A) H H (B) H H (C) HO H (D) H OH

(A) H H (B) H H (C) HO H (D) H OH

Time [A]0 Time [A]0

n{3P0 – Pt} = –kt + ln(2P0)

: info@motion.ac.in, url : www.motion.ac.in, : 1800-212-1799

If T2 > T1, the correct statement(s) is (are)

; fn T2 > T1 r ksl ghfodYi gS

r Fkk K Øe' k%, UFksYi h] , UVªkW

S H S H

(5 or 6) It N2O3 is considered or not considered

: info@motion.ac.in, url : www.motion.ac.in, : 1800-212-1799

3Pbs + 3O2  3Pb + 3SO2

or PbS + O2  Pb + SO2

mole of O2 consumed = mol at Pb formed

KMnO4 + oxalic 

2.25  2  103 W in mg  103

NaOBr Br2/KOH Br2(3 equiv)

NaOBr Br2/KOH Br2(3 equiv)

: info@motion.ac.in, url : www.motion.ac.in, : 1800-212-1799

10 mole (60%) (50%) (50%)

2Cu(s) + H2O(g)  Cu2O(s) + H2(g)

  –2.3 × (–2) > –10

13. Consider the following reversible reaction,

B+2n + 2A(s)  2An+ + B(s)

: info@motion.ac.in, url : www.motion.ac.in, : 1800-212-1799

(2n) (F) E°Ce11 = +RT ln(4)

[Ni (CN)4]2– CN– is strong field ligand

: info@motion.ac.in, url : www.motion.ac.in, : 1800-212-1799

lwph&I esavfHkfØ; kvksdseq

17. LIST-I contains reactions and LIST-II contains major products.

ph-I esami fLFkr vfHkfØ; k dksl w

: info@motion.ac.in, url : www.motion.ac.in, : 1800-212-1799

Ni(OH)2 dsl kFk l kE; esagS] dks gkst kr k gS

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