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Thermodynamics Chapter1 161108051414 PDF
Thermodynamics Chapter1 161108051414 PDF
Quantity Unit
Mass kg
Length m
Time s
o 1.2 Basic Concepts of Thermodynamics (continued)
Derived units for thermodynamics in the S. I. System:
Force
A measure of the “push” or “pull” which is often
exerted on a body.
F=m∙a
F: force, 1 N = 1 kg∙m/s2
m: mass (kg); a: acceleration (m/s2)
o 1.2 Basic Concepts of Thermodynamics (continued)
Derived units for thermodynamics in the S. I. System:
Weight
The gravitational attractive force which the earth exerts on
a mass. It depends on the acceleration due to gravity and
varies with height and location on the earth.
w=m∙g
w: weight, 1 N = 1 kg∙m/s2
m: mass (kg); g: gravity (assumption: 9.81m/s2)
o 1.2 Basic Concepts of Thermodynamics (continued)
System
A collection of matter within a prescribed region
Surroundings
Cylinder
System
Piston
Boundary
Most common:
Pressure
Temperature At least 2
independent
Volume and specific volume properties of a fluid
Density and specific gravity known, then the state
of the system is
known
Additional:
Internal energy
Enthalpy
Entropy
Pressure
F
p=
𝛢
Piston
(mass=0)
p A = 0.01 m2
water
Atmospheric pressure, patm
A pressure due to the atmosphere at the surface of
the earth. It depends on the weight of air above the
surface.
Sea level ≈ 1.01325 × 105 N/m2 ≈ 1.01325 bar
Relationship:
pabs = pgauge + patm
Example:
The gauge pressure of the air in a vessel is 10 kN/m2.
Determine the absolute pressure of the air. Assume
the atmospheric pressure is 100 kN/m2.
Solution:
pabs = pgauge + patm
pabs = 10 + 100
= 110 kN/m2
Temperature, T (K)
For the degree of hotness or coldness of anything.
Celsius Kelvin
The same temperature interval
100˚C 373 K Conversion between the two
boiling pt*
temperature scales:
0˚C 273 K
freezing pt* T(K) = t(˚C) + 273
*atmospheric pressure
A thermodynamics property may be defined as
any quantity that describes the state of a system
and, conversely, as any quantity, the value of
which depends solely on the state of the system.
Solution:
Density, ρ(kg/m3)
Mass per unit volume
4.0 m
Volume = Length × Width
× height
Example:
The density of sea water is 1025kg/m3. What is
the specific gravity of sea water?
Solution:
System equilibrium
Rectilinear motion
Work transfer of a constant force F is the product
of the force and the distance traveled by the force
measured along the line of action of the force.
F F
Work transfer = F × S
Work transfer
Angular motion
» Work transfer of a constant torque is the
product of the torque and the angular
displacement by the torque.
Work transfer = r × θ
r: torque in N·m
θ: angular displacement in rad
torque
Work transfer
Convention
» Positive: when work energy is transferred from the
system to the surroundings
» Negative: when work energy is transferred into the
system from the surrounding
surroundings
work output
(positive)
system
work input
(negative)
boundary
Heat transfer
surroundings
heat loss
(negative)
system
heat supplied
(positive)
boundary
The principle of the conservation of energy states:
ΣQ = ΣW
Where:
ΣQ: the net heat supplied
ΣW: the net work done/work output
Example:
A system undergoes a complete thermodynamic cycle.
Determine the value of the work output, Wout.
Solution:
surroundings
Qout=3 kJ Wout ΣQ = ΣW
Qin + Qout = Win + Wout
system
Win=2 kJ
Wout = Qin + Qout - Win
Qin=10 kJ boundary =10×103 + (-3 ×103) – (-2 ×103)
=9×103 J (9 kJ)
Non-flow Processes
i. Suction stroke: T T
» The working fluid
flows into the
cylinder, which is
then sealed by
closing of the inlet
valve
Non-flow Processes
Example:
A cylinder of an internal combustion engine
Non-flow
ii. Compression stroke: process
T T
» Whilst the cylinder
is sealed, the fluid is
compressed by the
piston moving into
the cylinder
Non-flow Processes
Example:
A cylinder of an internal combustion engine
Non-flow
iii. Working stroke: process
» Heat energy is T T
supplied so that the
fluid possesses
sufficient energy to
force the piston
downward and
produce work output
Non-flow Processes
Example:
A cylinder of an internal combustion engine Fluid flows out
T T
iv. Exhaust stroke:
» The exhaust valve is
opened for the fluid
to flow out of the
cylinder
Non-flow Energy Equation
» When the fluid in a closed system is undergoing a non-
flow process from State 1 to State 2, the internal energy
of a fluid depends on pressure and temperature.
U2 - U1 = Q12 – W12
=1000 – 600
=400 kJ
or
inlet
Q out
W out
outlet
Hence:
Applying
Since
inlet
Q out
W in
outlet
Hence:
Solution:
Hence:
Since
Hence:
» b) applying
And