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    Chetan IT-SOFC Brzing Internal Rivew - 4 PDF

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    Ashutosh Sharma
    The document summarizes experiments conducted to develop a hermetic seal through brazing for solid oxide fuel cells. Various brazing materials and parameters were tested, with TiCuSil foil achieving satisfactory hermetic sealing at 920°C for 20 minutes under vacuum conditions. Thermal cycling tests of the brazed joints showed they remained stable after 10 cycles from 24°C to 800°C. Experiments were also conducted to ensure positive electrical contact between current collecting leads and components through brazing, with the designed fixture achieving this goal. Prototypes were successfully brazed with the optimized brazing process.

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    Chetan IT-SOFC Brzing Internal Rivew - 4 PDF

    Uploaded by

    Ashutosh Sharma
    26 views5 pages
    The document summarizes experiments conducted to develop a hermetic seal through brazing for solid oxide fuel cells. Various brazing materials and parameters were tested, with TiCuSil foil achieving satisfactory hermetic sealing at 920°C for 20 minutes under vacuum conditions. Thermal cycling tests of the brazed joints showed they remained stable after 10 cycles from 24°C to 800°C. Experiments were also conducted to ensure positive electrical contact between current collecting leads and components through brazing, with the designed fixture achieving this goal. Prototypes were successfully brazed with the optimized brazing process.

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    chetan IT-SOFC Brzing Internal rivew -4.pdf

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    The document summarizes experiments conducted to develop a hermetic seal through brazing for solid oxide fuel cells. Various brazing materials and parameters were tested, with TiCuSil foil achieving satisfactory hermetic sealing at 920°C for 20 minutes under vacuum conditions. Thermal cycling tests of the brazed joints showed they remained stable after 10 cycles from 24°C to 800°C. Experiments were also conducted to ensure positive electrical contact between current collecting leads and components through brazing, with the designed fixture achieving this goal. Prototypes were successfully brazed with the optimized brazing process.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Flag for inappropriate content
    Download as pdf or txt
    26 views5 pages

    Chetan IT-SOFC Brzing Internal Rivew - 4 PDF

    Uploaded by

    Ashutosh Sharma
    The document summarizes experiments conducted to develop a hermetic seal through brazing for solid oxide fuel cells. Various brazing materials and parameters were tested, with TiCuSil foil achieving satisfactory hermetic sealing at 920°C for 20 minutes under vacuum conditions. Thermal cycling tests of the brazed joints showed they remained stable after 10 cycles from 24°C to 800°C. Experiments were also conducted to ensure positive electrical contact between current collecting leads and components through brazing, with the designed fixture achieving this goal. Prototypes were successfully brazed with the optimized brazing process.

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    © All Rights Reserved
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    of 5

    9060 P01 IT-SOFC Brazing-Internal review

    Date:-18/02/2015
    Attributes:-
    1) Hermetic sealing
    2) Thermal stability
    3) CELL Positive contact with current collecting leads

    Experiment summery

    Temperature  Soak time, 
    Trial No Date Brazing material Substrate vaccum/ Air Observation
    °C Min
    1 18‐07‐2014 Ag‐Cu SS316 Mesh YSZ coated+SS430 End plate 950 35 Air low wettablity(25%)
    2 21‐07‐2014 BNI‐TiH2 SS316 Mesh YSZ coated+SS430 End plate 1010 35 vaccum no wettablity
    3 25‐07‐2014 Ag‐CuO SS316 Mesh YSZ coated+SS430 End plate 970 35 Air average wettablity (50%)
    4 17‐07‐2014 TiCu Sil SS316 Mesh YSZ coated+SS430 End plate 855 30 vaccum good wettablity
    5 09‐08‐2014 TiCu Sil SS316 Mesh GDC coated+SS430 plate 855 35 vaccum no wettablity
    6 06‐09‐2014 TiCu Sil GDC pallets+SS430 plate  855 35 vaccum no wettablity
    7 06‐09‐2014 TiCu Sil GDC pallets(ACTIVATED)+SS430 plate  855 35 vaccum no wettablity
    8 12‐08‐2014  BNI‐TiH2 SS316 Mesh GDC coated+SS430 plate 855 35 vaccum no wettablity
    9 17‐09‐2014   BNI‐TiH2  GDC pallets +SS430 plate  950 35 Air no   wettablity
    10 19‐09‐2014  Ag‐CuO‐Mole 6%  GDC pallets +SS430 plate  950 35 Air good wettablity(more than 75% area)
    11 23‐09‐2014 Ag‐CuO‐Mole 8% SS316 Mesh GDC coated+SS430 plate  970 35 Air good wettablity
    12 26‐10‐2014  Ag‐CuO‐Mole 10% SS316 Mesh GDC coated+SS430 plate  970 35 Air 100% wettablity
    13 15‐09‐2014  BNI‐TiH2 SS430 pallets+SS430 plate 1010 30 vaccum  pore closed
    14 26‐09‐2014 TiCu Sil SS430 pallets+SS430 plate  850 35 vaccum braze joint good + pore not closed

    1010 vaccum
    15 10 ‐10 ‐201 Ag‐CuO‐Mole 8% SS316 Mesh GDC coated+SS430 plate(oxidised) 35 good wettablity but excess flow
    16 18‐10‐2014 TiCu Sil SS316 Mesh +SS430 End plate 880 35 vaccum braze joint good + pore not closed
    17 21‐10‐2014 TiCu Sil SS316 Disc (5 µ) +SS430 End plate 880 35 vaccum braze joint good + pore not closed
    18 25‐10‐2014 TiCu Sil (Wire) SS316 Mesh +SS430 End plate 880 35 vaccum sealing up to 95%
    19 25‐10‐2014 TiCu Sil(foil) SS316 Mesh +SS430 End plate 880 35 vaccum sealing up to 95%
    20 25‐10‐2014 TiCu Sil(Wire+foil) SS316 Mesh +SS430 End plate 880 35 vaccum sealing up to 95%
    21 05‐11‐2014 Ag‐CuO‐Mole 6% SS316 Disc (5 µ)GDC coated  +SS430 End plate 980 35 Air sealing not achived 
    22 05‐11‐2014 Ag‐CuO‐Mole 8% SS316 Disc (5 µ)GDC coated +SS430 End plate 980 35 Air Warpage probleam 
    23 05‐11‐2014 Ag‐CuO‐Mole 10% SS316 Disc (5 µ)GDC coated +SS430 End plate 980 35 Air Warpage probleam 
    24 07‐11‐2014 TiCu Sil(foil) SS316 Mesh +SS430 End plate(nickel coated) 880 35 vaccum sealing up to 95%
    25 13‐11‐2014 Ag‐CuO‐Mole 6% SS316 Disc (5 µ)GDC coated +SS430 End plate 880 35 Air Warpage probleam 
    26 09‐12‐2014 TiCu Sil(foil)  SS316 Disc (5 µ)GDC coated +SS430 End plate 880 35 vaccum Good contact with  Rib
    27 11‐12‐2014 TiCu Sil(foil) SS316 Disc (5 µ)GDC (Nickel coated )+SS430 880 35 vaccum Ni Electroless low bond strength

    28 19‐12‐2014 TiCu Sil (foil) (4.5%Ti ) SS316 Disc (5 µ)GDC coated +SS430 End plate 920 20 vaccum Good contact with  Rib


    29 25‐12‐2014 TiCu Sil(foil) (4.5%Ti)SS316 Disc (5 µ)GDC coated +SS430 End plate 920 20 vaccum Good contact with  Rib
    30 01‐01‐2015 TiCu Sil(foil) (4.5%Ti)CELL +SS430 Anode End plate 920 20 vaccum Prototype Study
    31 07‐01‐2015 TiCu Sil(foil) (4.5%Ti)SS430 plate +SS430 End plate 920 20 vaccum Hermetic sealing achieve
    32 15‐01‐2015 TiCu Sil(foil) (4.5%Ti)SS430 plate +SS430 End plate 920 20 vaccum Hermetic sealing Fail
    33 28‐01‐2015 TiCu Sil(foil) (4.5%Ti)CELL +SS430 Anode End plate 920 20 vaccum Prototype Study
    34 04‐02‐2015 TiCu Sil(foil) (4.5%Ti)SS430 plate +SS430 End plate 920 20 vaccum Hermetic sealing achieve
    35 10‐02‐2015 Ag‐Cu (70:30) SS316 Disc  +SS430 End plate 830 25 vaccum brazing materail not utectic phase
    1) Hermetic sealing:-
     Hermetic sealing is achieve with TiCuSil Foil with bottom sealing schema with
    impervious substrate ( metal plate )
     With porous substrate trials satisfactory completed optimized parameter
    achieved
     After stabilizing cell architecture final schema will be implement with optimized
    process parameter

    Brazing schema for TiCuSil  foil 
    Thermal stability:- Thermal cycling (24˚c -800˚c ) of joint is tested 10 Number cycle is
    tested
    observation :- Joint is stable after thermal cycling

    Thermal cycling graph  

    Joint before thermal cycling  
    joint after  thermal cycling  
    Positive contact with current collecting leads :-
    Experiment Conduct for insuring positive contact with current collecting
    lead fixture is designed for brazing
    observation :- positive contact is achieve

    cut section of brazing joint (SS430 End Plate  SS 316 Porous  substrate  

    positive contact achieved  

    Cross section view macrograph 
    Brazing for prototype

    Cell of batch ‐2 brazed with interconnect  

    Stack of cell 4  brazing completed For Prototype   Stack of cell 4  completed For Prototype  

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