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Teaching Mass and Energy Balances by Experiment: Curriculum
Teaching Mass and Energy Balances by Experiment: Curriculum
T
University of Massachusetts Lowell • Lowell, MA 01854
his paper describes a simple, yet innovative, ex- that are used in traditional engineering classes. For instance,
perimental project that was used as a term project in Farrell, et al.[3] developed a semester-long project for freshman
two core undergraduate-level chemical engineering ChE students at Rowan University. Their project involved the
(ChE) courses at the University of Massachusetts Lowell application of engineering measurements and calculations,
(UML). The project aimed to illustrate the critical nature of mass balances, and process simulation to the human respira-
experimentation in developing mathematical models for the tory system. Barak and Dori[4] described the incorporation of
analysis of laboratory experiments and for the design and an information technology-supported project-based learning
operation of pilot- and commercial-scale operations. A general method into three undergraduate chemistry courses at the
tank-draining problem was selected for the project because Technion Israel Institute of Technology. Students used com-
the draining of water from a container is a simple physical puterized molecular modeling as a tool to construct models of
situation that most students are familiar with from everyday complex molecules. This project encouraged understanding
life. The project was assigned as a part of a freshman-level of chemical concepts, theories, and molecular structures. Par-
Introduction to Chemical Engineering (ICE) course and a ticipating students performed much better on exams compared
sophomore-level Energy Balance and Introduction to Ther- to classmates who did not participate in the project. Hohn[5]
modynamics (EBIT) course. incorporated a hands-on experiment into a freshman ChE
To develop a mathematical model that correctly describes a course at Kansas State University. This experiment allowed
system, one must employ conservation laws for mass, energy, students to investigate a simple phenomenon—a carbonated
and momentum. However, the application of conservation
equations alone may not lead to an effective model. Rather, Nese Orbey is an associate professor at the Department of Chemical
an experimental hands-on project. Marisel De Jesús Vega received her B.S. in chemical engineering from
Educational researchers acknowledge that students learn University of Puerto Rico, Mayagüez campus. She recently completed her
Doctoral degree in chemical engineering at University of Massachusetts
more effectively by doing than by passively listening to a Lowell. Her research interests are microfluidic devices, microfabrication
lecture.[1] However, most engineering classes are taught in and materials.
a lecture format that involves only passive listening. As dis- Fulya Sudur Zalluhoglu received her B.S. in chemical engineering from
cussed by Felder and Silverman,[2] this traditional teaching the Middle East Technical University,Turkey. She completed her Doctoral
style does not match the learning styles of all students, leading degree in chemical engineering at the University of Massachusetts
Lowell. Her research interests are materials, microencapsulation and
some students to become bored, inattentive, and discouraged, sol-gel chemistry.
to perform poorly, and to change to other curricula. There have
been several major efforts to improve the teaching methods © Copyright ChE Division of ASEE 2017
When there is no mass flow into the system, Eq. (1) simpli-
TABLE 2
fies to Eq. (2).
Solution of the model equation for various values of n
d (ρV) n q(h) Solution of Eq. (4)
−ρq = (2)
dt 0 k h = h0–kt
Because temperature is constant, the density terms cancel 1/2 kh1/2 1 1 k
h 2
= h0 2 − t
out. Volume can be expressed in terms of the height of the 2
water and the cross-sectional area. Thus, Eq. (2) reduces to:
1 kh h=h0 exp{–kt}
d ( Ah ) dh dh q
−q = =A or =− ( 3) n (n≠1) khn h 1−n
h1−n
dt dt dt A − 0 = −kt
1− n 1− n
is taken to be the tank exit and with no mass input and no heat
and work terms, this equation reduces to the following form: Eq. (9) shows that the simultaneous solution of the mass and
d m ( U + PE + KE ) energy balance equations predicts that the volumetric flow
cv
= − ( H + PE + KE )out (6) rate q is proportional to h½, which was the experimentally
dt
obtained result.
COURSE EVALUATIONS
TABLE 4
Students were very enthusiastic about
Timetable used in the freshman class
designing and carrying out the experiment.
Week 1 • Lecture – conservation of mass
Most students in both years preferred to
Weeks 2-3 • Step 1 Obtain experimental data work in the laboratory; hence, teaching
• Plan experimental setup and procedure (submit as HW-1) assistants were able to obtain immediate
• Discuss with instructors feedback. Students made positive com-
• Obtain experimental data (submit as HW-2) ments while they were doing the experi-
ment. Some of these comments were:
• Discuss with instructors
• “This is my first time but I think it is
Weeks 4-5 • Step 2 Apply conservation of mass
simple.”
• Step 3 Postulate and evaluate constitutive relations (submit as HW-3)
• “I like it because it is actually kind of fun.”
Week 6 • Meet with instructors to review
• Prepare final report • “It is simple and no need to buy something
new just for the project.”
Week 7 • Presentations
• “I like it a lot because it is very simple.”
The tank-draining term project was assigned at the end of Students filled out a questionnaire at the
week 7, after the concept of the conservation of energy had end of the semester, and their feedback was overwhelmingly
been introduced during the students’ regular lectures. Working positive. Questionnaires and feedback are summarized below.
in teams of two, students provided an interim report of their Sophomore students
findings from Steps 1 to 3 at 4 weeks after the project was
assigned. Each team met with the instructors to discuss the The questionnaire for sophomore students included three
results in their interim report. The final report, which included sections. The first section contained six questions that students
the analysis in Step 4 and any revisions needed to the interim answered on a scale from 1 to 3, indicating that they disagreed
report, was due 2 weeks after the interim report. A few teams (1), agreed (2), or strongly agreed (3) with the statement.
needed to repeat their experiments. Students presented their The second section contained two yes/no questions. The last
projects to the class at the end of the semester. The timetable section evaluated the degree to which the anticipated ABET
is summarized in Table 3. outcomes were achieved.
Freshman students Questions for the first part are listed below, followed by
a summary of the students’ responses to these questions in
A different format from the above was followed for fresh- Figure 4.
man students who, unlike the sophomore students, had no
A. Was doing the experiment and analysis out of class more
previous background in the conservation of mass and energy
effective than a lecture?
equations. The conservation of mass was presented in week 1
of the semester in a standard lecture form. The project, which, B. Did you learn the concepts covered more effectively
for freshman students, involved only Steps 1 to 3, was then compared to an in-class lecture experience?
described. Step 4 (application of the general energy balance) C. You worked in teams of two. Did the interaction with
was not included. Some students working on the project another student help you to learn better?
during Fall 2014 found it difficult to postulate mathematical
D. Was this design project useful in explaining how model-
relations for the constitutive equation. Therefore, when we ing is done in chemical engineering?
70 Chemical Engineering Education
E. Was this project useful in demonstrating 100
that experiments are required in chemi-
cal engineering analysis? 90
% of Students
in which there is no chemical reaction) 60
compared to other processes you have
studied, such as a crystallization unit, 50 3
dryer, distillation column, etc.?
40 2
Most students responded positively (score 1
30
of 2 or 3) to these questions. Compared to the
lecture format, most students strongly agreed 20
or agreed that the hands-on approach was
10
more effective (63% and 32%, respectively)
and enabled them to learn more effectively 0
(42% and 53%, respectively). Students A B C D E F