metanol(1)agua(2) T<K> 333.

15 60
A 16.5785 16.3872
B 3638.27 3885.7
C 238.5 230.17
P_sat<kPa> 84.562 19.953
ley de Raoult
P<kPa> x1 y1 x2 y2 gama1 gama2 Q
39.223 0.1686 0.5714 1.57198438 #DIV/0! #DIV/0!
42.984 0.2167 0.6268 1.47028545 #DIV/0! #DIV/0!
48.852 0.3039 0.6943 1.31984693 #DIV/0! #DIV/0!
52.784 0.3681 0.7345 1.24552668 #DIV/0! #DIV/0!
56.652 0.4461 0.7742 1.16268199 #DIV/0! #DIV/0!
60.614 0.5282 0.8085 1.09718365 #DIV/0! #DIV/0!
63.998 0.6044 0.8383 1.04970234 #DIV/0! #DIV/0!
67.924 0.6804 0.8733 1.03097269 #DIV/0! #DIV/0!
70.229 0.7255 0.8922 1.02132989 #DIV/0! #DIV/0!
72.832 0.7776 0.9141 1.01247532 #DIV/0! #DIV/0!

margules van daar wilson

a a 0.70497004 Ʌ12 1
b b 0.48546046 Ʌ21 1

calculando P_sat con la temperatura que me da el ejercicio se obtiene las siguientes constantes

metanol(1)agua(2) T<K> 333.15 60

A 16.5785 16.3872
B 3638.27 3885.7
C 238.5 230.17
P_sat<kPa> 80.6396761 20.0070447

P<kPa> x1 y1 x2 y2 gama1 gama2 Q

39.223 0.1686 0.5714 #DIV/0! Err:502
42.984 0.2167 0.6268 #DIV/0! Err:502
48.852 0.3039 0.6943 #DIV/0! Err:502
52.784 0.3681 0.7345 #DIV/0! Err:502
56.652 0.4461 0.7742 #DIV/0! Err:502
60.614 0.5282 0.8085 #DIV/0! Err:502
63.998 0.6044 0.8383 #DIV/0! Err:502
67.924 0.6804 0.8733 #DIV/0! Err:502
70.229 0.7255 0.8922 #DIV/0! Err:502
72.832 0.7776 0.9141 #DIV/0! Err:502
 margules van daar wilson
a 0 a 0.66600067 Ʌ12 1
b 0 b 0.7079646 Ʌ21 1
 Q/x1*x2 x1*x2/Q Qcal Funcion obj gama1_wilson gama2_wilson LN(gama1/gama2)
#DIV/0! #DIV/0! 0.30014614 #DIV/0! -4.1509718686 -3.1509718686 0.275631557063859
#DIV/0! #DIV/0! 0.3313866 #DIV/0! -3.085433295 -2.085433295 0.391715450675585
#DIV/0! #DIV/0! 0.36196209 #DIV/0! -2.09949952492 -1.09949952492 0.646843895933418
#DIV/0! #DIV/0! 0.36787938 #DIV/0! -1.7172524448 -0.7172524448 0.873053013331145
#DIV/0! #DIV/0! 0.36009733 #DIV/0! -1.43443771744 -0.43443771744 1.1944756254923
#DIV/0! #DIV/0! 0.33713964 #DIV/0! -1.25494198517 -0.25494198517 1.59380861338941
#DIV/0! #DIV/0! 0.30432691 #DIV/0! -1.15101437299 -0.15101437299 2.03102387837917
#DIV/0! #DIV/0! 0.26200463 #DIV/0! -1.08464927349 -0.08464927349 2.55049543750142
#DIV/0! #DIV/0! 0.23280875 #DIV/0! -1.05746554524 -0.05746554524 2.912444774114
#DIV/0! #DIV/0! 0.19559986 #DIV/0! -1.03446520462 -0.03446520462 3.40168960837962
∑ #DIV/0!
g1 = y1* Ptotal /x1*Psat 1 Ge cal= (-x1*ln(x1 +( x2 *A12)))-(x2*ln(x2+(x1*A21)))

g2=y2 *Ptotal/x2.Psat 2

GE = x1* lng1+ x2lng2

las siguientes constantes

ESTADISTICO

Q/x1*x2 x1*x2/Q Qcal Funcion obj gama1_wilson gama2_wilson LN(gama1/gama2)

Err:502 Err:502 0.30014614 Err:502 -4.1509718686 -3.1509718686 0.275631557063859
Err:502 Err:502 0.3313866 Err:502 -3.085433295 -2.085433295 0.391715450675585
Err:502 Err:502 0.36196209 Err:502 -2.09949952492 -1.09949952492 0.646843895933418
Err:502 Err:502 0.36787938 Err:502 -1.7172524448 -0.7172524448 0.873053013331145
Err:502 Err:502 0.36009733 Err:502 -1.43443771744 -0.43443771744 1.1944756254923
Err:502 Err:502 0.33713964 Err:502 -1.25494198517 -0.25494198517 1.59380861338941
Err:502 Err:502 0.30432691 Err:502 -1.15101437299 -0.15101437299 2.03102387837917
Err:502 Err:502 0.26200463 Err:502 -1.08464927349 -0.08464927349 2.55049543750142
Err:502 Err:502 0.23280875 Err:502 -1.05746554524 -0.05746554524 2.912444774114
Err:502 Err:502 0.19559986 Err:502 -1.03446520462 -0.03446520462 3.40168960837962
∑ Err:502
 margules
12

10

8
Q/(x1*x2)

0
0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9
f(x) =0
x1
 van laar
12

10

8
(x1*x2)/Q

0
0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9
f(x) =0
x1
 wilson
4

3.5

3
LN(gam1/gama2)

2.5

1.5

0.5

0
0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9

x1
 margules
12

10

8
Q/(x1*x2)

0
0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9
f(x) =0
x1
 van daar
12

10

8
(x1*x2)/Q

0
0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9
f(x) =0
x1
 wilson
4

3.5

3
LN(gama1/gama2)

2.5

1.5

0.5

0
0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9

x1