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EXAM 1 Chem 2
EXAM 1 Chem 2
Title: Exam 1
Started: February 24, 2010 4:08 PM
Submitted: February 24, 2010 4:57 PM
Time spent: 00:49:42
Total
19/20 = 95% Total score adjusted by 0.0 Maximum possible score: 20
score:
1.
1. London Dispersion
3. Hydrogen bonds
4. Ion-dipole forces
5. Ionic bonds
Score: 1/1
2.
Which of the following substances would be expected to have the highest heat of
fusion?
1. CF4
2. methane
3. CI4 100%
4. CCl4
5. CBr4
Score: 1/1
3.
How much energy in J is needed to convert 99 g of solid ethanol at -130 oC to
liquid at -85oC. You might need to know that:
mp = -114 oC and bp = 78oC
The heat of fusion is 4.6 kJ/mol and the heat of vaporization is 46.0 kJ/mol.
Finally, the specific heats of the solid, liquid and gas are, respectively 2.1, 3.2
and 1.8 J/g oC.
1. 12510
2. 22400 100%
3. 20100
4. 468000
5. 112000
Score: 1/1
4.
Score: 1/1
5.
Score: 1/1
6.
What is the strongest form of intermolecular force between solute and solvent in
a solution of pentane, C5H12(l), in toluene, C7H8(l)?
1. hydrogen bonding
2. dispersion 100%
3. dipole-induced dipole
4. ion-dipole
5. dipole-dipole
Score: 1/1
7.
Which of the following is more soluble in water, methanol or CI2H2(l). Don't try to
type the subscripts, just use letters and numbers.
Score: 1/1
8.
B. 2.17
C. 2.63
D. 3.33
E. 1.81
Score: 1/1
9.
Score: 1/1
10.
Which of the following aqueous solutions will have the highest boiling point?
A. 0.100 m CaCl2
E. 0.100 m NaCl
Score: 1/1
11.
12.
B. 209 g/mol
C. 4.77 g/mol
D. 298 g/mol
E. 0.29 g/mol
Score: 1/1
13.
A. I only
B. II only
D. III only
Score: 1/1
14.
For the reaction, 4 A(g) + 3 B(g) => 2 C(g), the following data were obtained at
constant temperature.
Experiment Initial [A], mol/L Initial [B], mol/L Initial Rate, M/min
1 0.200 0.150 5.00
2 0.400 0.150 20.0
3 0.200 0.300 10.0
4 0.400 0.300 40.0
Calculate the value of k to 3 significant figures.
Score: 1/1
15.
In a first order decomposition, how long does it take (in seconds) for 33% of the
compound to decompose given that k is 0.0402 sec-1 (give answer to 3 sig figs
using E notation)?
Score: 1/1
16.
The rate law for the reaction 2A => 4B is rate = k[A] with a rate constant of
0.445 sec-1. What is the half-life of the reaction?
1. 0.223
2. 1.56 100%
3. 4.49
5. 0.642
Score: 1/1
17.
The rate law of a particular reaction is found to be, rate = k[A]2[B]. Which of the
following statements is FALSE?
Score: 1/1
18.
Score: 1/1
19.
What is the overall reaction order for CO in a reaction with the following rate law?
Rate = k[Cl2][H+]2[CO]2
1. First
2. Fourth
3. Second
4. Fifth 0%
5. Third
Score: 0/1
20.
A. 0.30 M/S
B. -0.45 M/s
C. 0.20 M/s
D. -0.20 M/s
Score: 1/1