WHS ¢ AP Chemistry Ko A J 4 6 * Thermochemistry WORK AND HEAT A gas expands from 264 mL to 971 mL at constant pressure. Calculate the work done (in joules) by the gas if it expands (a) against a vacuum and (b) against a constant pressure of 4.00 atm. Z oe | p=4.00atm \ A) P=O0 b) tie eee (4 TI-. 204) _w=-O @Tl-aH w Leatm lw O| Ww | -2807 ) 2. _A'gas expands in Volume from 26.7 mL. to 89.3 ml. at constant temperature: Calculate the work done (in Joules) ifthe gas expands (a) against a vacuum, (b) against a constant pressure of 1.5 atm, and (c) against a constant pressure of 2.8 atm, D=02 =) 5atm c)P=2.Batm N= —2.B (00893- W ==1. 56089370261) W= 2.860009" =e Occ ace —|15 Latin | Boece Bo A gas expands and does P-V work on the surroundings equal to 279 J, At the same time, it absorbs 216 J of heat from the surroundings. What is the change in energy of the system? W=-PAT BUza4w OU = alu + ©2719) r ‘The work done to compress a gas is 74.J. As a result, 26 J of heat is given off to the surroundings. Calculate the change in energy of the gas. Sos neg AU= tw = -Aalet TY HoT. ‘Two ideal gases at the same temperature and pressure are placed in two equal-volume containers. One container has a fixed volume, while the other is a cylinder fitted with a weightless movable piston. Initially, the gas pressures are equal to the external atmospheric pressure. The gases are then heated with a Bunsen bumer. What are the signs of g and w for the gases under these conditions? pve Container | Conteiner 2 o( = + on % ee nese we Calculate the work done in joules when 1.0 mole of water vaporizes at 1.0 atm and 100°C. Assume that the volume of the liquid is negligible compared with that of steam at 100°C, and ideal gas behavior. Pv =nRT \2- POY (Lo )(v)= 1.0 GOB20eX87) we 10G0.6) V230. @ L Ws =30.9 LL“ aam pos py) a