Nama : Umi Latifah

NIM : 4311417043

Rombel : Kimia B 2017

1. The oxidation of potassium iodide bt potassium persulfate in excess iodide was

followed by withdrawing samples at various times and titrating the liberated iodine
with sodium thiosulphate solution. The following were obtained at 25oC, calculate the
rate constant for the reaction.

Time (min) Titre (cm3) V∞-Vt Log (V∞-Vt)

0 0 18,80 1,274157
5 5,80 13,0 1,113943
10 9,80 9,0 0,954242
15 12,60 6,20 0,792391
20 14,50 4,30 0,633484
25 15,80 3,0 0,477121
30 16,80 2,0 0,301029
∞ 18,80 0

1.4

1.2 f(x) = − 0.16 x + 1.44

R² = 1

0.8
Log (V∞-Vt)

0.6 Log (V∞-Vt)

Linear (Log (V∞-Vt))
0.4

0.2

0
0 1 2 3 4 5 6 7 8 9
time (min)

Karena grafiknya linier, maka reaksinya adalah reaksi orde satu. Sehingga,
−k r
Slope=
2,303
−k r
−0,0322=
2,303
k r=(−0,0322 ) x (−2,303 )

k r=7,425 x 10−2 min−1

2. The hydrolisis of ethyl nitrobenzoate by aqueous sodium hydroxide was followed at
25oC by titration of the hydroxide at different stages of the reaction with 0,01 mol dm -
3
HCl. If the initial concentrations of both reactans is 0,01 mol dm -3 show that the
reactions is second order and calculate the rate constant.

Time (min) Titre (cm3) 1/titre (cm3)

95 9,3 0,107526
140 9 0,111111
222 8,5 0,117647
334 7,9 0,126582
805 6,1 0,163934

0.18

0.16 f(x) = 0 x + 0.1

R² = 1
0.14

0.12
1/titre(cm3)

0.1

0.08 1/titre (cm3)

Linear (1/titre (cm3))
0.06

0.04

0.02

0
0 100 200 300 400 500 600 700 800 900
t (menit)

Grafik menunjukan reaksi orde 2

y = 8.10-5x + 0,1.
slope = 8 x 10-5.
Oleh karena itu
Konstanta laju (k) = slope = 8 x 10-5 cm3 mol-1s-1atau 8 x 10-2 dm3 mol-1s-1

3. The hydrolisis of t-butyl iodide follows first-order kinetics at 26oC.

Bu1I + H20 ~ Bu 10H +HI
The Conductivity of the solution was measured with timeas follow
Time/min 0 2 4 6 8 I0 I7 22 28 oo
106 x conductivity/
n-1 m-1 5.5 I3.0 20.0 26.0 31.0 36.0 46.0 51.5 56.0 65.0
Calculate the rate constant of the reaction.

Time(min) Conductivity K∞-Kt log (Kt-K∞)

 0 5,5 59,5 1,7745169
2 13 52 1,7160033
4 20 45 1,6532125
6 26 39 1,5910646
8 31 34 1,5314789
10 36 29 1,4623979
17 46 19 1,2787536
22 51,5 13,5 1,1303337
28 56 9 0,9542425
∞ 65 0 0

2
1.8
f(x) = − 0.03 x + 1.77
1.6 R² = 1
1.4
1.2
log (Kt-K∞ )

1
log (Kt-K∞)
0.8
Linear (log (Kt-K∞) )
0.6
0.4
0.2
0
0 5 10 15 20 25 30
time(min)

Karenagrafik linear, maka reaksinya adalah reaksi orde satu. Sehingga:

−kr
Slope=
2,303
−0,0291=−( Slope ×kr )
kr =−(−0,0291 ×2,303 )
kr =0,06702
kr =6,702× 10−2min-2

4. The following results were obtained for the reversible cis-trans isomerisation of
stilbene at 280oC

Calculate the rate constants of the forward and reverse reactions.

Time (s) % c isomer Ct-c∞ Log (Ct-c∞)

 0 100 83 1,919078
1830 88,1 71,1 1,851869
3816 76,3 59,3 1,773054
7260 62,0 45 1,653215
12.006 48,5 31,5 1,498310
∞ 17 0 0

log
2.5
2
1.5 f(x) = − 0 x + 1.91
R² = 1
Axis Title

1 log
0.5 Linear (log)
0
0 00 00 00 00 00 00 00
20 40 60 80 10
0
12
0
14
0

Axis Title

Dari grafik tersebut dapat diketahui bahwa reaksi tersebut adalah orde 1.
Untuk mencari harga k, maka :
Slope = -k / 2,303
-k = slope x 2,303
-k = -3,50x 10-5 x 2,303
k= 8 x 10-5 s-1

5. The optical rotation α for the mutarotation of α-glucose at 20oC are as follows

α /degrees Time(menit) (Tt - T∞) Log(Tt - T∞)

20,26 10 9,66 0,984
18,92 20 8,32 0,920
16,82 40 6,22 0,793
15,22 60 4,62 0,664
14,06 80 3,46 0,539
13,18 100 2,58 0,411
10,60 ∞ 0 0
Show that the reaction is first order and calculate the rate constant k1 + k-1
Jawab :
 1.2

1
f(x) = − 0.01 x + 1.05
R² = 1
0.8
Log (Tt-T∞)

0.6
Log (Tt-T∞)
0.4 Linear (Log (Tt-T∞))

0.2

0
0 20 40 60 80 100 120
time(menit)

Grafik menandakan jika reaksi berorde 1

Slope = -0,0064

−k
Slope =
2,303

−k
-0,0064 =
2,303

k = 0,0147392

k= 1,47 x 10-2 /menit

6. The rate of reaction was followed by measuring the absorbance of a solution at a
various time

Time(min) Absorbance Log(At-A)

0 2,19 0,082
18 2,06 0,033
57 1,83 -0,070
130 1,506 -0,279
240 1,198 -0,661
337 1,051 -1,148
398 0,980 0
Assuming the Beer-Lambert law is obeyed, show that the reaction is firstorder and
determine the rate constant.

Jawab :
 0.2

0 f(x) = − 0 x + 0.12
R² = 0.99
0 50 100 150 200 250 300 350 400 450
-0.2

-0.4
Axis Title

-0.6 Log(At-A tak hingga)

Linear (Log(At-A tak
-0.8 hingga))
-1

-1.2

-1.4
Axis Title

Grafik menunjukkan bahwa reaksinya orde 1

−k
Slope=
2,303
−k
−0,0036=
2,303
-k = 2,303 x (-0,0036)
-k = -8,2908 x 10-3/min
k = 8,2908 x 10-3/min

7. Reaction of diacetone alcohol with alkali to give acetone produces a volume change,
which is measured on a cathetometer as the reaction proceeds. From the following
data obtained by G. Akerlof (J. Am. chem. Soc.,49 (1927), 2955) with 5 per cent
diacetone alcohol by volume in a KOH solution of concentration 2 mol dm -3,
calculate the order and the rate constant.
Time(s) Cathetometer Log(C
∞-Ct)
0 8 1,544
24,4 20 1,361
35 24 1,278
48 28 1,176
64,8 32 1,041
75,8 34 0,954
89,4 36 0,845
106,6 38 0,698
133,4 40 0,477
183,6 42 0
∞ 43 0

Jawab :
 2

Log (Ctak hingga-Ct)

1.5
f(x) = − 0.01 x + 1.56
1 R² = 1

0.5
Linear ()
0
0 20 40 60 80 100 120 140 160
Time

Reaksi merupakan orde 1

−k
Slope=
2,303
−k
−0,008=
2,303
-k = 2,303 x (-0,008)
-k = -0,018424
8. Solution of hydrogen peroxide (15 cm3) is catalytically decomposed by colloidal
silver into oxygen and water; complete decomposition of this solution gives 6.18 cm3
of oxygen at s.t.p., and the volume of oxygen collected over a period of time t is
tabulated.

waktu/min 2 4 6 8 14 ~
Volume O2/cm3 1,24 2,36 3,36 3,98 5,23 6,18
(T∞ - Tt)/cm3 4,94 3,82 2,82 2,2 0,95
log (T∞ - Tt)/cm3 0,6937269 0,58206 0,450249 0,34242 -
3 3 0,02228
Tentukan orde reaksi dan hitung tetapan laju reaksinya

Jawab:
 Chart Title
0.8
0.7
f(x) = − 0.06 x + 0.82
0.6 R² = 1
log (T∞-Tt)/cm3

0.5
0.4
0.3 Linear ()

0.2
0.1
0
-0.1 0 2 4 6 8 10 12 14 16

waktu/min

Grafik linier menandakan orde reaksi = 1

Slope = -0,0598

−kr
Slope =
2,303

−kr
-0,0598 =
2,303

kr = 0,137 min-1
9. Dekomposisi dari etilen oksida
C2H4O CH4 + CO
Pada 687K memberikan hasil seperti berikut

T /menit 0 5 7 9 12 18
Ptotal/torr 116,5 122,6 125,7 128,7 133,2 141,4
Tunjukkan bahwa reaksi berorde 1 dan hitung tetapan laju reaksinya

Jawab:

2po-p 116,5 110,4 107,3 104,3 99,8 91,6

2,06632 2,04296 2,01828 1,99913 1,96189
log 2po-p 6 9 2,0306 4 1 5
 2.3
2.25
f(x) = − 0.01 x + 2.26
2.2 R² = 1

2.15
2.1
2.05 Linear ()
2
1.95
1.9
1.85
0 5 10 15 20 25 30 35
Berdasarkan gambar diatas grafik berbentuk linear jadi terbukti bahwa reaksi berorde
satu, sehingga tetapan laju reaksinya adalah
−k
Slope =
2,303
-k = -0,0059 x 2,303
K = 0,01358 /menit

10. The gas-phase decomposition of di-t-butyl peroxide is a first-order reaction given by:
(CH3)3COOC(CH3)3 → 2CH3COCH3 + C2H6
The following results were obtained for the total pressure p measured at constant
volume at 14 7° C at
p/torr 179,5 198,6 210,5 221,2 242,3 262,1 280,1 297,1
t/min 0 6 10 14 22 30 38 46
Calculate the rate constant for the reaction.
Jawab:
(CH3)3COOC(CH3)3 → 2CH3COCH3 + C2H6
m Po - -
r x 2x x
s Po – x 2x X
Pada (CH3)3COOC(CH3)3 = Po – x
CH3COCH3 = 2x
C2H6 =x
P total = P (CH3)3COOC(CH3)3+ P CH3COCH3+ P C2H6
= Po – x + 2x + x
= Po + 2x
Jadi, x = (P– Po)/2
Maka, P pada(CH3)3COOC(CH3)3
P (CH3)3COOC(CH3)3 = Po – x
= Po – ((P– Po)/2)
= ((3Po – P)/2)
Pembuktianreaksiorde 1
P (CH3)3COOC(CH3)3 ((3Po – P)/2)/torr) pada 0 menit = (3Po – P)/2
 = (3(179,5) – 179,5)/2
= 179,5
P (CH3)3COOC(CH3)3 ((3Po – P)/2)/torr) pada 6 menit = (3Po – P)/2
= (3(179,5) – 198,6)/2
= 169,95
P (CH3)3COOC(CH3)3 ((3Po – P)/2)/torr) pada 10 menit = (3Po – P)/2
= (3(179,5) – 210,5)/2
= 164
P (CH3)3COOC(CH3)3 ((3Po – P)/2)/torr) pada 14 menit = (3Po – P)/2
= (3(179,5) – 221,2)/2
= 158,65
P (CH3)3COOC(CH3)3 ((3Po – P)/2)/torr) pada 22 menit = (3Po – P)/2
= (3(179,5) – 242,3)/2
= 148,1
P (CH3)3COOC(CH3)3 ((3Po – P)/2)/torr) pada 30 menit = (3Po – P)/2
= (3(179,5) – 262,1)/2
= 138,2
P (CH3)3COOC(CH3)3 ((3Po – P)/2)/torr) pada 38 menit = (3Po – P)/2
= (3(179,5) – 280,1)/2
= 129,2
P (CH3)3COOC(CH3)3 ((3Po – P)/2)/torr) pada 46 menit = (3Po – P)/2
= (3(179,5) – 297,1)/2
= 120,7

t/min p/torr ((3Po – P)/2)/torr Log ((3Po – P)/2)/torr)

0 179,5 179,5 2,25406445
6 198,6 169,95 2,23032117
10 210,5 164 2,21484385
14 221,1 158,65 2,20044008
22 242,3 148,1 2,17055506
30 262,1 138,2 2,14050804
38 280,1 129,2 2,11126251
46 297,1 120,7 2,08170727

Sehingga dihasilkan grafik sebagai berikut:

 di-t-butil peroksida
2.3

2.25
f(x) = − 0 x + 2.25
Log ((3Po – P)/2)/torr

2.2 R² = 1

2.15
di-t-butil peroksida
2.1 Linear (di-t-butil peroksida)
2.05

1.95
0 5 10 15 20 25 30 35 40 45 50
t/min

Dari grafik terbukti bahwa reaksi merupakan reaksi orde satu :

y = -0,0037x + 2,2529 menghasilkan slope sebesar -0,0037.

Untuk nilai konstanta laju (k), maka:

Slope = - (k/2,303)
k = -(slope (2,303))
= -(-0,0037 (2,303))
= 8,52 x 10-3 / min