Don’t Solve this DPP

NEET : 2020 .... If you don’t

want to be perfect

DPP-08 : GOC (Aromatic, Antiaromatic & Non-aromatic)

(Total DPP-10) XIth Batch Date : 31-08-2020
Q. Identify Aromatic, Antiaromatic and Non-aromatic compound?
Sr. Compound Planar Cyclic conjugation  bond Result
sp³

1. No Not 1 Non-Aromatic
sp² sp²
•• sp³

2. Yes Yes 2 Antiaromatic

sp² sp²
+
3.

4.

5.
+

6.

7.

8.

9.

10.

11.

12.
B
H

1
13.

14.

15.

O O
16. B
H

17.
O

18.
S

19.
N

20.
O
+

21.
O
O

22.
O

23.
N O
H
O

24.
N
H
N
25.
N

2
 CH3
B
26.

27.

28.

29.

30.

31.

••
N

32. ••
O
••

33.

34.

35.

3
36.

37.

38.

39.

40.

41.

42.

43.

44.

45.

46.

4
47.

48.
N

49.

50.

51.

52.

53.

54.

55.

56.

57.

58.

59.

5
60.

61.

62.

+
O•

O
•

••
••

63.

64. Following compound does not exist freely in nature?

1) 2)

3) 4)

Some Special
1. Cyclopentadiene is highly acidic because its anion is aromatic.

H H H

+ H+

Aromatic

2. While cycloheptatriene is not acidic because it is anion is antiaromatic which is highly destabilised.

H H H

+ H+

Antiaromatic Antiaromatic
6
3. Cycloheptatrienyl bromide is an ionic compound becuase its cation is aromatic which is highly stabilised.

Br
+

+ Br

Aromatic

4. Cycloheptatrienone is polar moleucle while cyclopentadienone is non-polar molecule.

O O
+

Aromatic