NEET/JEE : 2020-21

Don’t Solve this DPP

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DPP - 8 .... If you don’t

want to be perfect
Structure of Atoms
XI Regular : Date :- 25-08-2020
01. Which one is the wrong statement ? 06. Two electrons occupying the same orbital are
distinguished by
h
1) The uncertainty principle is E × t  1) Azimuthal quantum number
4
2) Spin quantum number
2) Half filled and fully filled orbitals have greater
3) Principal quantum number
stability due to greater exchange energy, greater
4) Magnetic quantum number
symmetry and more balanced arrangement
07. Which of the following atoms in its ground state
3) The energy of 2s-orbital is less than the energy of
2p-orbital in case of hydrogen like atoms
has the highest number of unpaired electrons ?
(Atomic numbers are given in brackets)
h
4) de-Broglie’s wavelength is given by  = , where 1) Chromium (24)
mv
2) Iron (26)
m = mass of the particle, v = group velocity of the 3) Manganese (25)
particle 4) Vanadium (23)
02. Which of the following electronic configurations 08. The correct set of four quantum numbers for
has maximum energy ? the electron in the outermost subshell of Cu
atom (atomic number 29) in its ground state, is
1)
n l ml ms
1
1) 4 0 0 
2) 2
1
2) 3 0 0 
2
3)
1
3) 4 1 0 
2
1
4) 4) 3 2 +1 
2
03. How many electrons can fit in the orbital for 09. Consider the following sets of quantum numbers
which n = 3 and l = 1 ? Which of the below setting is not permissible
1) 2 2) 6 arrangement of electrons in an atom ?
3) 10 4) 14 n l ml ms
04. Which of the following pairs of d-orbitals will 1
1) 4 0 0 
have electron density along the axes ? 2
1) dz2, dxz 2) dxz, dyz 1
2) 5 3 0 
3) dz2, dx2–y2 4) dxy, dx2–y2 2
05. The electronic configuration of Eu (Atomic No. 1
3) 3 2 –2 
63), Gd(Atomic No. 64) and Tb(Atomic No. 65) 2
are 1
4) 3 2 –3 
2
1) [Xe]4f65s16s2, [Xe]4f75d16s2 and [Xe]4f85d16s2
10. Which is the correct order of increasing energy
2) [Xe]4f76s2, [Xe]4f75d16s2 and [Xe]4f96s2
3) [Xe]4f76s2, [Xe]4f86s2 and [Xe]4f85d16s2 of the listed orbitals in the atom of titanium ?
4) [Xe]4f65d16s2, [Xe]4f75d16s2 and [Xe]4f96s2 (At. no. Z = 22)
1) 4s 3s 3p 3d 2) 3s 3p 3d 4s
3) 3s 3p 4s 3d 4) 3s 4s 3p 3d
Prof. Motegaonkar S. R. M.Sc. Che. Gold Medalist, SET/NET--JRF Qualified 1
11. Which of the following arrangement is possible? 1) Na+ 2) F 3) N 4) O2–
n l m s 21. Among the elements from atomic number 1 to

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1) 5 2 2 +1/2 36, the number of elements which have an
2) 2 2 0 –1/2 unpaired electron in their s-subshell is
3) 3 –2 1 +1/2 1) 4 2) 7 3) 6 4) 9
4) 0 0 1 +1/2 22. The statement that is not correct is
12. The maximum number of electrons in a subshell 1) Angular quantum number signifies the shape of
is given by the expression the orbital
1) 2n2 2) 4l + 1 3) 4l + 2 4) 4l – 2 2) Energies of stationary states in hydrogen like
13. For d-electron, the orbital angular momentum atoms is inversely proportional to the square of the
is principal quantum number
3) Total number of nodes for 3s orbital is three
6h 2h h 2h
1) 2) 3) 4) 4) The radius of the first orbit of He+ is half that of
2 2 2 
the first orbit of hydrogen atom
14. Which of the following sets of quantum
23. Which of the following is not in accordance with
numbers represents the highest energy of an
Aufbau principle ?
atom ?
1 1) 2)
1) n = 3, l = 0, m = 0, s = 
2
1 3) 4)
2) n = 3, l = 1, m = 1, s = 
2 24. The electronic configuration of Cu is
1 1) [Ne]3s23p63d 94s2 2) [Ne]3s23p63d 104s1
3) n = 3, l = 2, m = 1, s = 
2
3) [Ne]3s23p63d 34s24p6 4) [Ne]3s23p63d 54s24p4
1
4) n = 4, l = 0, m = 0, s =  25. What is the maximum numbers of electrons that
2
can be associated with the following set of
15. Which one of the following sets of quantum
quantum numbers ? n = 3, l = 1 and m = –1
numbers is possible ?
1) 4 2) 2 3) 10 4) 6
1) n = 3, l = 3, ml = –3, ms = +1/2
26. Assertion : Number of radial and angular nodes
2) n = 2, l = 1, ml = 2, ms = –1/2
3) n = 1, l = 0, ml = 0, ms = 0 for 3p-orbital are 1, 1 respectively.
4) n = 3, l = 2, ml = 3, ms = –1/2 Reason : Number of radial and angular nodes
16. What is the maximum number of electrons depends only on principal quantum number.
having same spin with n + l = 4 ? 1) If both assertion and reason are true and reason is
1) 3 2) 2 3) 4 4) 5 the correct explanation of assertion
17. What is the maximum number of orbitals that 2) If both assertion and reason are true but reason is
not the correct explanation of assertion
can be identified with the following quantum
3) If assertion is true but reason is false
numbers ? n = 3, l = 1, ml = 0
4) If both assertion and reason are false
1) 1 2) 2 3) 3 4) 4
27. Which of the following sets of quantum
18. The total number of orbitals associated with the
numbers is not possible ?
principal quantum number n = 3, is
1
1) 9 2) 8 3) 5 4) 7 1) n = 1, l = 0, ml = 0, ms = 
2
19. The maximum number of electrons which can
1
be held by subshell with azimuthal quantum 2) n = 1, l = 1, ml = 0, ms = 
2
number ‘l’ in an atom is given by 1
1) (2l + 1) 2) (2l + 2) 3) n = 2, l = 1, ml = 0, ms = 
2
3) 2(2l + 1) 4) 2(2l + 2) 1
20. The atom/ion that has the highest number of 4) n = 3, l = 1, ml = 0, ms = 
2
unpaired electrons is

Prof. Motegaonkar S. R. M.Sc. Che. Gold Medalist, SET/NET--JRF Qualified 2

28. What is the total number of electrons that can 34. The correct set of four quantum numbers for
have the values n = 2, l = 1, s = 1/2 in the the valence electron of rubidium atom (Z = 37)

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2 2 3
electronic configuration 1s 2s 2p ? is
1) 1 2) 3 3) 5 4) 7 1) 5, 1, 1, +1/2 2) 6, 0, 0, +1/2
29. Which of the following pairs is not correctly 3) 5, 0, 0, +1/2 4) 5, 1, 0, +1/2
matched ? .
1) Hund’s rule In orbitals of equivalent
energy electron spins
remain unpaired if
possible
2) Pauli’s exclusion No two electrons can
principle have all the four
quantum numbers
identical
3) Zeeman effect The effect of magnetic
field on the atomic
spectra
4) Uncertainty It is impossible to
principle determine the position of
an electron
30. The orbital diagram in which Aufbau principle
is violated is

1) 2)

3) 4)
31. “No two electrons in an atom will have all the
four quantum numbers same”. The statement
is known as
1) Uncertainty principle
2) Pauli’s exclusion principle
3) Hund’s rule
4) Aufbau principle
32. Identify the correct statement.
1) Quantum numbers (n, l, m, s) are obtained
arbitrarily
2) All the quantum numbers (n, l, m, s) for any pair
of electrons in an atom can be identical under special
circumstance
3) All the quantum numbers (n, l, m, s) may not be
required to describe an electron of an atom
completely
4) All the quantum numbers (n, l, m, s) are required
to describe an electron of an atom completely
33. Maximum number of electrons in a subshell
with l = 3 and n = 4 is
1) 14 2) 16
3) 10 4) 12

Prof. Motegaonkar S. R. M.Sc. Che. Gold Medalist, SET/NET--JRF Qualified 3