BINARY VAPOR LIQUID EQUILIBRIUM

CheCalc.com Date 10/08/14

Chemical Engineering Calculations By CheCalc
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Enter Binary Pair 1

Components 1-Propanol + Water
Antoine Equation Parameters 1 2
A 17.54 18.30
B 3166.38 3816.44
C -80.15 -46.13
Molar Volume, V cm3/gmol 219 56
Aij, Wilson Binary parameter cal/gmol 906.53 1396.64

T x-y Diagram P x-y Diagram

Pressure PSIA 20.0 Temperature °F 250.0
Temperature (Deg F)

Bubble Dew
50.0
Bubble Dew
45.0
230
40.0
225
35.0
220
Pressure, PSIA

30.0
215 25.0
210 20.0
205 15.0
200 10.0
195 5.0
190 0.0
0.00 0.20 0.40 0.60 0.80 1.00 0.00 0.20 0.40 0.60 0.80 1.00

Change the vertical axis manually if graph does not appear properly

T x-y Chart Data P x-y Chart Data

X Y Temperature X Y Pressure
°F PSIA
0.00 0.00 228.0 0.00 0.00 29.8
0.10 0.37 206.3 0.10 0.36 44.5
0.20 0.41 204.6 0.20 0.40 46.3
0.30 0.43 203.9 0.30 0.42 47.0
0.40 0.45 203.5 0.40 0.45 47.4
0.50 0.47 203.5 0.50 0.48 47.5
0.60 0.50 203.9 0.60 0.51 47.0
0.70 0.55 205.1 0.70 0.57 46.0
0.80 0.62 207.5 0.80 0.64 43.8
0.90 0.75 212.4 0.90 0.77 40.0
1.00 1.00 222.2 1.00 1.00 33.7

Basis
- Vapor pressure is calculated using Antoine Equation :
 Ln ( Pressure ( mmHg ) ) = A - B / ( Temperature ( °K ) + C )
- Flash calculations are based on Modified Raoult's Law
 BINARY VAPOR LIQUID EQUILIBRIUM
CheCalc.com Date 10/08/14
Chemical Engineering Calculations By CheCalc
User
Input

Enter Binary Pair 1

Components 1-Propanol + Water
Antoine Equation Parameters 1 2
A 17.54 18.30
B 3166.38 3816.44
C -80.15 -46.13
Molar Volume, V cm3/gmol 219 56
Aij, Wilson Binary parameter cal/gmol 906.53 1396.64

T x-y Diagram P x-y Diagram

Pressure Bar Abs 1.4 Temperature °C 121.1
Temperature (Deg C)

Pressure, Bara

Bubble Dew
0.25
Bubble Dew
115
0.20
110
0.15
105

100 0.10
95
0.05
90

85 0.00
0.00 0.20 0.40 0.60 0.80 1.00 0.00 0.20 0.40 0.60 0.80 1.00

Change the vertical axis manually if graph does not appear properly

T x-y Chart Data P x-y Chart Data

X Y Temperature X Y Pressure
°C Bar A
0.00 0.00 108.9 0.00 0.00 0.1
0.10 0.37 96.8 0.10 0.38 0.2
0.20 0.41 95.9 0.20 0.41 0.2
0.30 0.43 95.5 0.30 0.42 0.2
0.40 0.45 95.3 0.40 0.43 0.2
0.50 0.47 95.3 0.50 0.45 0.2
0.60 0.50 95.5 0.60 0.47 0.2
0.70 0.55 96.1 0.70 0.51 0.2
0.80 0.62 97.5 0.80 0.57 0.2
0.90 0.75 100.2 0.90 0.68 0.2
1.00 1.00 105.6 1.00 1.00 0.1

Basis
- Vapor pressure is calculated using Antoine Equation :
 Ln ( Pressure ( mmHg ) ) = A - B / ( Temperature ( °K ) + C )
- Flash calculations are based on Modified Raoult's Law